Gas adsorption in metal-organic frameworks: fundamentals and applications

543 Pages·2019·13.48 MB·English

by  Glover

Gas Adsorption in
–
Metal Organic
Frameworks
Fundamentals and Applications

Gas Adsorption in
–
Metal Organic
Frameworks
Fundamentals and Applications
Edited by
T. Grant Glover
Bin Mu
TheMOFshownonthecoverisNU-110adsorbingCO andwaspreparedbyDr.DavidDubbeldam
2
usingiRASPA.
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LibraryofCongressCataloging-in-PublicationData
Names:Glover,ThomasGrant,author.|Mu,Bin,author.
Title:Gasadsorptioninmetal-organicframeworks:fundamentalsand
applications/T.GrantGloverandBinMu.
Description:BocaRaton,FL:CRCPress/Taylor&FrancisGroup,[2018]|
Includesbibliographicalreferencesandindex.
Identifiers:LCCN2018006755(print)|LCCN2018013729(ebook)|ISBN
9780429891779(AdobePDF)|ISBN9780429891762(ePub)|ISBN9780429891755
(Mobipocket)|ISBN9781498754514(hardback:acid-freepaper)|ISBN
9780429469770(ebook)
Subjects:LCSH:Organometalliccompounds.|Crystallography.
Classification:LCCQD411(ebook)|LCCQD411.G572018(print)|DDC547/.05--dc23
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Contents
SafetyandAcknowledgments.................................................vii
Editors....................................................................... ix
Contributors ................................................................. xi
Chapter 1 Metal–OrganicFrameworksandReticularChemistry............. 1
T.GrantGlover
Chapter 2 SynthesisandCharacterizationofMetal–Organic
Frameworks...................................................17
HiroyasuFurukawa
Chapter 3 ThermodynamicsofAdsorption ................................83
MitchellArmstrong,BohanShan,andBinMu
Chapter 4 MassTransferinMOFs...................................... 109
JörgKärgerandYuWang
Chapter 5 PackedBedWaveTheory.................................... 205
M.DouglasLeVan
Chapter 6 SimulationofCrystallineNanoporousMaterialsandthe
ComputationofAdsorption/DiffusionProperties.............. 219
DavidDubbeldam
Chapter 7 CharacterizationTechniquesfortheAnalysisof
Metal–OrganicFrameworksduringandafter
Adsorption .................................................. 327
CamillePetit
v
vi Contents
Chapter 8 WaterStabilityofMetal–OrganicFrameworks ................ 363
KristaS.Walton
Chapter 9 GasStorageinMetal–OrganicFrameworks ................... 393
DarrenP.BroomandJacobW.Burress
Chapter 10 ToxicGasAdsorptionandReactioninMetal–Organic
Frameworks................................................ 451
GregoryW.Peterson
Chapter 11 PotentialIndustrialApplicationsofMetal–Organic
FrameworksforGasSeparations ............................ 481
JianLiu
Index...................................................................... 511
Safety and Acknowledgments
SAFETY
Becausepracticalinformationaboutthesynthesisandcharacterizationofthesemate-
rialsisprovided,ashortdiscussionoflaboratorysafetyisnecessary.Inallcases,itis
assumedthatanyoneconductingexperimentsrelatedtoMOFs,oranyotherchemical
process,isdoingsowithinanappropriateenvironment,suchasauniversity,govern-
ment,orcommerciallaboratorywhereappropriatesafetyprotocolsareinplace.For
any of the procedures discussed, it is expected that the procedure will be reviewed
priortoconductingtheexperimentwithanappropriatesafetyexpert,thatappropriate
personalprotectiveequipmentwillbeused,andthattheworkwillbeconductedunder
appropriateengineeringcontrols.Insomecases,specifichazardsmaybepresentthat
require additional precautions, including, but not limited to, cryogens, compressed
gases,radiation,oracutelytoxicchemicals.Itisexpectedthatifprofessionalguidance
isrequired,thatitwillbesoughtpriortoconductingexperiments.
ACKNOWLEDGMENTS
Iwouldliketoacknowledgetheworkofthecontributorstothisbook,withouttheir
effortsthistextwouldsimplynotexist.Also,itisimportanttoacknowledgethevar-
ious funding agencies that have enabled MOF research including, but certainly not
limited to, the U.S. Department of Defense, the National Science Foundation, the
Department of Energy, BASF, and the many other sources of scientific funding
that have advanced the field of porous materials. I would also like to acknowledge
Taylor & Francis Group, LLC for providing us the opportunity to produce this
book.IwouldliketothankProf.KevinN.Westformanyhelpfuldiscussionsabout
adsorption thermodynamics. Additionally, I would like to thank my PhD advisor,
Prof.M.DouglasLeVan,andmypost-doctoraladvisor,Prof.OmarM.Yaghi,both
of whom have madesignificant contributions to my education and research. Lastly,
IwouldliketoacknowledgemywifeBetsyandourchildrenWilliam,Camille,Cecilia,
andMiriam,allofwhomhavebeenpatientwithmewhileIworkonthisproject.
Prof.T.GrantGlover
June2019
vii

Editors
Dr.T.GrantGloverisanassociateprofessorofChemicalandBiomolecularEngi-
neeringattheUniversityofSouthAlabama.HeholdsaBSinChemicalEngineering
fromtheGeorgiaInstituteofTechnology,completedaPhDinChemicalEngineering
at Vanderbilt University under the direction of M. Douglas LeVan, and was post-
doctoral fellow at the University of California, Los Angeles under the direction of
Omar M. Yaghi. Prior to his faculty position, Prof. Glover worked for SAIC and
Leidos as a research scientist. His research interests include adsorption behavior,
adsorbentmaterials,metal-organicframeworks,andrelatedsurfacechemistry.
Dr.BinMujoinedthefacultyoftheArizonaStateUniversityintheSchoolforEngi-
neeringofMatter,TransportandEnergyinAugust2013.Earlier,BinMuworkedwith
Professor MichaelStranoinDepartmentofChemical EngineeringattheMassachu-
settsInstituteof Technology duringhis postdoctoral studies.Bin Mucompleted his
PhDinchemicalandbiomolecularengineeringfromtheGeorgiaInstituteofTechnol-
ogyin2011withProfessorKristaWalton.
ix