Functional Polymer Blends and Nanocomposites: A Practical Engineering Approach

360 Pages·2014·10.395 MB·English

by  Gennady E. Zaikov, Liliya I. Bazylyak, A. K. Haghi

Functional Polymer Blends and Nanocomposites
HBZ AAP Research Notes on Polymer Engineering Science & Technology
A Practical Engineering Approach aghiazylaaikov
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This book has an important role in advancing polymer composites in macro and
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on the editorial boards of many international journals. He is a member of the e
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Montreal, Quebec, Canada.
ISBNISI:S B9BN7N8: -:9 197-7898-21-61-89-992526-68889995-5-58-899-5-5
900909000000000
ISBN: 978-1-926895-89-5
9 781926 895895 90000
9 78919972876189182996256889985598598595
www.appleacademicpress.com 9 781926 895895
FUNCTIONAL POLYMER BLENDS
AND NANOCOMPOSITES
A Practical Engineering Approach

FUNCTIONAL POLYMER BLENDS
AND NANOCOMPOSITES
A Practical Engineering Approach
Edited by
Gennady E. Zaikov, DSc, Liliya I. Bazylak, PhD, and
A. K. Haghi, PhD
Apple Academic Press
TORONTO NEW JERSEY
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ABOUT THE EDITORS
Gennady E. Zaikov, DSc
Gennady E. Zaikov, DSc, is Head of the Polymer Division at the N. M.
Emanuel Institute of Biochemical Physics, Russian Academy of Sciences,
Moscow, Russia, and Professor at Moscow State Academy of Fine Chemi-
cal Technology, Russia, as well as Professor at Kazan National Research
Technological University, Kazan, Russia. He is also a prolific author, re-
searcher, and lecturer. He has received several awards for his work, includ-
ing the Russian Federation Scholarship for Outstanding Scientists. He has
been a member of many professional organizations and is on the editorial
boards of many international science journals.
Liliya I. Bazylak, PhD
Liliya Bazylak, PhD, is Senior Staff Scientist in the Physical and Chem-
istry of Combustible Minerals Department at the Institute of Physical and
Organic Chemistry and Coal Chemistry at the National Academy of Sci-
ences of Ukraine in Lviv. She is the author of more than 200 publications.
Her scientific interests include physical chemistry, nanochemistry and
nanotechnologies, and chemistry of high molecular compounds.
A. K. Haghi, PhD
A. K. Haghi, PhD, holds a BSc in urban and environmental engineering
from University of North Carolina (USA); a MSc in mechanical engineer-
ing from North Carolina A&T State University (USA); a DEA in applied
mechanics, acoustics and materials from Université de Technologie de
Compiègne (France); and a PhD in engineering sciences from Université
de Franche-Comté (France). He is the author and editor of 65 books as
well as 1000 published papers in various journals and conference proceed-
ings. Dr. Haghi has received several grants, consulted for a number of
major corporations, and is a frequent speaker to national and international
audiences. Since 1983, he served as a professor at several universities. He
vi About the Editor
is currently Editor-in-Chief of the International Journal of Chemoinfor-
matics and Chemical Engineering and Polymers Research Journal and is
on the editorial boards of many international journals. He is a member of
the Canadian Research and Development Center of Sciences and Cultures
(CRDCSC), Montreal, Quebec, Canada.
CONTENTS
List of Contributors ....................................................................................ix
Preface .......................................................................................................xi
About AAP Research Notes on Polymer Engineering Science and
Technology .......................................................................................xvii
1. Distribution of internal Links of the Polymer Chain in the
Self-Avoiding Random Walks Statistics ....................................................1
Yu. G. Medvedevskikh
2. Polymeric Stars in Self-Avoiding Random Walks Statistics .................23
Yu. G. Medvedevskikh, L. I. Bazylyak, and G. E. Zaikov
 3.  The Number of Configurations of Polymeric Chain in the 
Self-Avoiding Random Walks Statistics ..................................................55
Yu. G. Medvedevskikh
4. Conformation of Linear Polymeric Chains at the Interface
Layer Liquid / Solid and Adsorption Isotherm ......................................77
Yu. G. Medvedevskikh, and G. I. Khovanets
 5.  Phenomenological Coefficients of the Viscosity for Low-Molecular 
Elementary Liquids and Solutions ........................................................101
Yu. G. Medvedevskikh, and O. Yu. Khavunko
 6.  Viscoelastic Properties of the Polystyrene in Concentrated Solutions 
and Melts..................................................................................................129
Yu. G. Medvedevskikh, O. Yu. Khavunko, L. I. Bazylyak,
and G. E. Zaikov
 7.  Polyaniline / Nano-ТіО2-S Hybride Composites .................................175
  M. M. Yatsyshyn, A. S. Kun’ko, and O. V. Reshetnyak
8. Simulation of Corrosive Dissolution of PtBinary Nano-Cluster
in Acid Environment of Polymer Electrolyte Membrane (PEM) Fuel
Cells ..........................................................................................................197
  S. A. Korniy, V. I. Kopylets’, and V. I. Pokhmurskiy
viii Contents
9. Effect of Amino Naphthalene Sulfonic Acid Nature on the Structure
and Physical Properties of Their Copolymers with Aniline ................217
  O. I. Aksimentyeva, and V. P. Dyakonov
10.  UV / Vis-Spectra of Silver Nanoparticles as Characteristics of Their 
Sizes and Sizes Distribution ...................................................................231
  A. R. Kytsya, O. V. Reshetnyak, L. I. Bazylyak, and Yu. M. Hrynda
11. SynthesisandAnticorrosionActivity of the Zinc Phosphate
Nanoparticles ...........................................................................................241
  L. I. Bazylyak, A. R. Kytsya, I. M. Zin’, and S. А. Korniy
12.  An Influence of Kinetic Parameters of Reaction on the Size of 
Obtained Nanoparticles Under Reduction of Silver Ions
by Hydrazine ...........................................................................................255
A. R. Kytsya, L. I. Bazylyak, Yu. M. Hrynda,
and Yu. G. Medvedevskikh
13. Case Studies on Nanopolymrs and Their Chemicals Complexity
—New Approaches, Limitations and Control ......................................263
A. K. Haghi, and G. E. Zaikov
Index .........................................................................................................341
LIST OF CONTRIBUTORS
O. I. Aksimentyeva
Department of Physical and Colloidal Chemistry, Ivan Franko National University of L’viv; D.Sc. in
Chemical Sciences, the major staff scientist
L. I. Bazylyak
Physical-Chemistry of Combustible Minerals Department, Institute of Physical-Organic Chemistry
and Carbon Chemistry named after L. M. Lytvynenko, National Academy of Sciences of Ukraine;
Oxidizing Processes Chemistry Department; Dr. in Chemical Sciences, senior staff scientist
V. P. Dyakonov 
Institute of Physics, Polish Academy of Science; Dr. in Chemical Sciences
Yu. M. Hrynda
Physical-Chemistry of Combustible Minerals Department, Institute of Physical-Organic Chemistry
and Carbon Chemistry named after L. M. Lytvynenko, National Academy of Sciences of Ukraine;
Oxidizing Processes Chemistry Department; post-graduate training student
O. Yu. Khavunko
Physical-Chemistry of Combustible Minerals Department, Institute of Physical-Organic Chemistry
and Carbon Chemistry named after L. M. Lytvynenko, National Academy of Sciences of Ukraine;
Oxidizing Processes Chemistry Department; Dr. in Chemical Sciences, junior researcher
G. I. Khovanets
Physical-Chemistry of Combustible Minerals Department, Institute of Physical-Organic Chemistry
and Carbon Chemistry named after L. M. Lytvynenko, National Academy of Sciences of Ukraine;
Oxidizing Processes Chemistry Department; Dr. in Chemical Sciences, junior researcher
V. I. Kopylets’ 
Physical-Mechanical Institute named after G. V. Karpenko, National Academy of Sciences of Ukraine;
Dr. in Technical Sciences, senior staff scientist
S. A. Korniy
Physical-Mechanical Institute named after G. V. Karpenko, National Academy of Sciences of Ukraine;
Dr. in Technical Sciences, senior staff scientist
A. S. Kun’ko
Department of Physical and Colloidal Chemistry, Ivan Franko National University of L’viv; Dr. in
Chemical Sciences
A. R. Kytsya
Physical-Chemistry of Combustible Minerals Department, Institute of Physical-Organic Chemistry
and Carbon Chemistry named after L. M. Lytvynenko, National Academy of Sciences of Ukraine;
Oxidizing Processes Chemistry Department; Dr. in Chemical Sciences, senior staff scientist
Yu. G. Medvedevskykh
Physical-Chemistry of Combustible Minerals Department, Institute of Physical-Organic Chemistry
and Carbon Chemistry named after L. M. Lytvynenko, National Academy of Sciences of Ukraine;
Chief of the Oxidizing Processes Chemistry Department; D.Sc. in Chemical Sciences, the major staff
scientist