Table Of Content

Functional Nanomaterials for Sensors Because of their novel chemical and physical properties, functional nanomaterials have found increasing industrial applications in nanoelectronics, energy science, and biological applications. Functional Nanomaterials for Sensors surveys advances in functional nanomaterials and their use in sensing. It covers their properties, synthesis, design, fabrication, and applications, including for chemical, biological, and gas sensing, environmental remediation, fuel cells, catalysis, electronic devices, and biotechnology. FEATURES: • D escribes how nanomaterial functionalization is being used to create more effective sensors • D iscusses various synthesis procedures, characterization techniques, and which nanomaterials should be used for sensing applications • P rovides an in-depth look into oxide nanostructures, carbon nanostructures, and two-dimensional (2D) material fabrication • E xplores the challenges of using nanoscale sensors for large-scale industrial applications T his book is aimed at materials, chemical, biotech, and electronics researchers and industry professionals working on sensor design and development. Emerging Materials and Technologies Series Editor: Boris I. Kharissov The Emerging Materials and Technologies series is devoted to highlighting publica- tions centered on emerging advanced materials and novel technologies. Attention is paid to those newly discovered or applied materials with potential to solve pressing societal problems and improve quality of life, corresponding to environmental pro- tection, medicine, communications, energy, transportation, advanced manufactur- ing, and related areas. T he series takes into account that, under present strong demands for energy, material, and cost savings, as well as heavy contamination problems and worldwide pan- demic conditions, the area of emerging materials and related scalable technologies is a highly interdisciplinary fi eld, with the need for researchers, professionals, and academics across the spectrum of engineering and technological disciplines. The main objective of this book series is to attract more attention to these materials and technologies and invite conversation among the international R&D community. Nanotechnology Platforms for Antiviral Challenges : Fundamentals, Applications and Advances E dited by Soney C George and Ann Rose Abraham Carbon-Based Conductive Polymer Composites : Processing, Properties, and Applications in Flexible Strain Sensors Dong Xiang Nanocarbons: Preparation, Assessments, and Applications A shwini P. Alegaonkar and Prashant S. Alegaonkar E merging Applications of Carbon Nanotubes and Graphene E dited by Bhanu Pratap Singh and Kiran M. Subhedar M icro to Quantum Supercapacitor Devices : Fundamentals and Applications Abha Misra A pplication of Numerical Methods in Civil Engineering Problems M .S.H. Al-Furjan, M. Rabani Bidgoli, Reza Kolahchi, A. Farrokhian, and M.R. Bayati Advanced Functional Metal-Organic Frameworks : Fundamentals and Applications E dited by Jay Singh, Nidhi Goel, Ranjana Verma and Ravindra Pratap Singh N anoparticles in Diagnosis, Drug Delivery and Nanotherapeutics E dited by Divya Bajpai Tripathy, Anjali Gupta, Arvind Kumar Jain, Anuradha Mishra and Kuldeep Singh Functional Nanomaterials for Sensors Suresh Sagadevan and Won-Chun Oh For more information about this series, please visit: w ww.routledge.com/Emerging- Materials-and-Technologies/book-series/CRCEMT Functional Nanomaterials for Sensors Edited by Suresh Sagadevan and Won-Chun Oh F irst edition published 2023 b y CRC Press 6 000 Broken Sound Parkway NW, Suite 300, Boca Raton, FL 33487–2742 a nd by CRC Press 4 Park Square, Milton Park, Abingdon, Oxon, OX14 4RN C RC Press is an imprint of Taylor & Francis Group, LLC © 2023 selection and editorial matter, Suresh Sagadevan and Won-Chun Oh; individual chapters, the contributors Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying, microfi lming, and recording, or in any information storage or retrieval system, without written permission from the publishers. For permission to photocopy or use material electronically from this work, access www. copyright.com or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978–750–8400. For works that are not available on CCC please contact [email protected] Trademark notice : Product or corporate names may be trademarks or registered trademarks and are used only for identifi cation and explanation without intent to infringe. ISBN: 978-1-032-20495-6 (hbk) I SBN: 978-1-032-20496-3 (pbk) I SBN: 978-1-003-26385-2 (ebk) DOI: 10.1201/9781003263852 Typeset in Times b y Apex CoVantage, LLC Contents Preface .................................................................................................................... vii Editors .......................................................................................................................ix Contributors ..............................................................................................................xi Chapter 1 Functional Nanomaterials Processing Methods ................................... 1 G anjar Fadillah, Gani Purwiandono, Wiyogo Prio Wicaksono, and Is Fatimah Chapter 2 Functional Nanomaterials for Potential Applications ........................ 17 Isha Arora, Seema Garg, Harshita Chawla, Amrish Chandra, Suresh Sagadevan, and M. M. Abdullah Chapter 3 Functional Nanomaterials for Characterization Techniques ..............39 Is Fatimah, Gani Purwiandono, Ganjar Fadillah, and Wiyogo Prio Wicaksono Chapter 4 Conducting Polymer Nanocomposites as Sensors ............................. 61 S humaila, Sunny Khan, M. Zulfequar, Preeti Singh, Praveen Yadav, and Om Prakash Yadav Chapter 5 Carbon-Based Functional Nanomaterials for the Detection of Volatile Organic Compounds ........................................73 B hasker Pratap Choudhary and N. B. Singh Chapter 6 Functional Nanomaterials for Photocatalysis Applications ............. 103 K efayat Ullah, Bakht Mand Khan, and Won-Chun Oh Chapter 7 Functional Nanocomposites for Electrochemical Applications ......................................................................................129 Mehmood Shahid, Ahmed Usman, Waqar Ahmed, Suresh Sagadevan, Chariya Kaewsaneha, and Pakorn Opaprakasit Chapter 8 Functional Nanomaterials for Chemical Sensors ............................. 149 Ab Rahman Marlinda v vi Contents Chapter 9 Functional Nanomaterials for Gas Sensors .......................................171 S ugandha Gupta, Ravish Kumar Uppadhayay, and Ajeet Singh Chapter 10 Electronic Devices Including Nanomaterial-Based Sensors ............ 185 P reeti Singh, Syed Wazed Ali, Ravinder Kale, Suresh Sagadevan, and Himanshu Aggarwal Chapter 11 DNA-Aptamer–Based Electrochemical Biosensors for the Detection of Thrombin: Fundamentals and Applications .............201 M ohammad Al Mamun, Yasmin Abdul Wahab, M. A. Motalib Hossain, Abu Hashem, and Mohd Rafi e Johan Chapter 12 Functional Nanomaterials for Biosensors and Bio-Applications. ..............................................................................223 D hanalakshmi Vadivel and Daniele Dondi Chapter 13 Functional Nanomaterials for Health and Environmental Issues .......................................................................249 E stelle Leonard and Erwann Guenin Chapter 14 Implications of the Use of Functional Nanomaterials for the Environment and Health: Risk Assessment and Challenges .................................................................................289 M agdalena Luty-Błocho, Manuel Varon Hoyos, and Volker Hessel Index...................................................................................................................... 321 Preface Recently, with the improvement of human quality of life, many efforts are being made to live healthy, pleasant, and comfortable lives. Sensors are one of the essential factors for improving the quality of life, and high-performance intelligent sensors are required, so demand for them is expected to increase further in the future. Recently, functional materials that give functions to sensors are becoming more important. In particular, nanofunctional materials existing in various components and forms are attracting more attention because they have unique physical, chemical, mechanical, and optical properties differentiated from existing bulk materials. Recently, research on nanotubes including carbon nanotubes (CNTs) and nanocomposites has been very active to be further developed in existing nanoparticle research and applied as sensors. This book examines the latest nanosensor research and development (R&D) trends such as gas sensors, water quality sensors, biosensors, light sensors, and physical sensors, and it is predicted that high functionality and miniaturization of sensors by nanomaterials will be used as a very important part. R esearch on nanosensors using nanomaterials such as metals, inorganic, organic, biological, and composite materials having a shape of less than or equal to 100 nm in various compositions and forms such as nanoparticles, nanowires, and nanotubes has been actively reported. This is due to the unique physical, chemical, mechanical, and optical properties of nanomaterials. For example, when a nanosensing material having a large specifi c surface area is used in a gas sensor, a low concentration air pollution source may be detected even at a low operating temperature, thereby low- ering power consumption and ultimately miniaturizing a sensor, and thus, a material having a very large specifi c surface area such as nanoparticles, nanowires, and graphene has been used. This book describes two points. The fi rst point is about how to manufacture nanostructured materials such as nanoparticles and nanowires, and the second point is about the latest nanosensor technology trends using nanomaterials. In fact, many nanosensor research results using nanomaterials are being published, so the contents covered in this book will be part of them, and it can be used as a reference for researchers and developers who want to conduct related research and development. T rends in sensor R&D technology using various nanomaterials were described. Although the vast amount of research worldwide deals with only a few research cases, nanomaterials are developed in various ways in the form of nanoparticles, nanowires, nanotubes, and nanocomposites, and it is confi rmed that they are expan- ding to various applications such as gas sensors, water sensors, biosensors, light sensors, and physical sensors. From this, furthermore, it can be predicted that future state-of-the-art sensor technologies will act as more essential factors for high functionality and miniaturization of nanomaterials. However, sensors using nanowires have the advantage of being able to manufacture nanowires of a wide variety of compositions and structures compared to the top-down method, but more research is needed on the technology for assembling and aligning nanowires in two dimen- sions as in the top-down method. In addition, although research has already been vii viii Preface conducted at advanced research institutes in various countries, research on the stability of ultrafi ne nanomaterials—such as toxicity to the human body and the environment—is expected to develop into a technology that can be sustainable for R&D and industrialization. Assoc. Prof. Dr. Suresh Sagadevan Fellow of the Royal Society of Chemistry (FRSC), London, United Kingdom Prof. Dr. Won-Chun Oh Department of Advanced Materials Science & Engineering, Hanseo University, Seosan-si, Chungnam, Korea Editors Dr. Suresh Sagadevan is an associate professor at the Nanotechnology & Catalysis Research Centre, University of Malaya. He has published more than 350 research papers in the ISI top-tier journals & Scopus. He has authored 12 international books series and 40 book chapters. He was selected as one among the top 2% of scientists worldwide by Stanford University consecutively in 2020 and 2021. In 2021, he was recognized for his outstanding contribution in the research activities with the award as Fellow of the Royal Society of Chemistry (FRSC). He was a guest editor and editorial board member of many reputed ISI journals. He is a member of many professional bodies at the national and international levels. He was a recognized reviewer for many reputed journals. Indeed, he is working in various fi elds such as nanofabrication, functional materials, crystal growth, graphene, polymeric nano- composite, glass materials, thin fi lms, bio-inspired materials, drug delivery, tissue engineering, supercapacitors, optoelectronics, photocatalytic, green chemistry, and biosensor applications. Dr. Won-Chun Oh is a full professor in the Department of Advanced Materials and Engineering at Hanseo University in Korea and the School of Materials Science and Engineering at Anhui University of Science and Technology in China, and he is guest professor in universities in China, Thailand, and Indonesia. He obtained the ‘Research Front’ award from Korean Carbon Society, and obtained the ‘Yangsong’ award from Korea Ceramic Society, the ‘Excellent Paper Award’ from Korea Journal of Material Research, and the ‘Best Paper Award’ from the Journal of Industrial and Engineering Chemistry for his pioneering work, and an ‘Award of Appreciation’ from ICMMA2011, ICMMA2014, and ICMMA2019. He is an Indian Chemical Manufacturers and Merchants Association (ICMMA) committee board member and has been appointed as one of the conference chairman and vice chairmen from 2007 to the present year. He was appointed as one of the ‘Top 100 Scientist in the World’ at IBC, UK and ‘Top 2% Scientists in the World’ at Stanford University. He is the author or a coauthor of 890 papers published in domestic and international journals and speeches on conference as special lectures, plenary lectures, and as a keynote lecture speaker. He serves as the editor-in-chief of the Journal of Multifunctional Materials and Photoscience, Asian Journal of Materials Chemistry , and is an Advisory Board member of the A sian Journal of Chemistry and Nanomaterials. ix