Functional Materials and Biomaterials PDF
Preview Functional Materials and Biomaterials
209 Advances in Polymer Science EditorialBoard: A.Abe·A.-C.Albertsson·R.Duncan·K.Duˇsek·W.H.deJeu J.-F.Joanny·H.-H.Kausch·S.Kobayashi·K.-S.Lee·L.Leibler T.E.Long·I.Manners·M.Möller·O.Nuyken·E.M.Terentjev B.Voit·G.Wegner·U.Wiesner AdvancesinPolymerScience RecentlyPublishedandForthcoming Volumes FunctionalMaterialsandBiomaterials Surface-InitiatedPolymerizationII Vol.209,2007 VolumeEditor:Jordan,R. Vol.198,2006 Phase-SeparatedInterpenetratingPolymer Networks Surface-InitiatedPolymerizationI Vol.208,2007 VolumeEditor:Jordan,R. Vol.197,2006 HydrogenBondedPolymers VolumeEditor:Binder,W. Conformation-DependentDesignofSequences Vol.207,2007 inCopolymersII VolumeEditor:Khokhlov,A.R. Oligomers·PolymerComposites· Vol.196,2006 MolecularImprinting Vol.206,2007 Conformation-DependentDesignofSequences inCopolymersI PolysaccharidesII VolumeEditor:Khokhlov,A.R. VolumeEditor:Klemm,D. 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Vol.190,2005 Functional Materials and Biomaterials Withcontributionsby X.DongLiu·A.R.Esker·M.Häußler·C.Kim·P.Lucas M.Matsunaga·N.Nishi·J.-J.Robin·B.Z.Tang D.-A.Wang·M.Yamada·H.Yu 123 TheseriesAdvancesinPolymerSciencepresentscriticalreviewsofthepresentandfuturetrendsin polymerandbiopolymerscienceincludingchemistry,physicalchemistry,physicsandmaterialscience. Itisadressedtoallscientistsatuniversitiesandinindustrywhowishtokeepabreastofadvancesin thetopicscovered. Asarule,contributionsarespeciallycommissioned.Theeditorsandpublisherswill,however,always bepleasedtoreceivesuggestionsandsupplementaryinformation.PapersareacceptedforAdvancesin PolymerScienceinEnglish. InreferencesAdvancesinPolymerScienceisabbreviatedAdvPolymSciandiscitedasajournal. SpringerWWWhomepage:springer.com VisittheAPScontentatspringerlink.com LibraryofCongressControlNumber:2007926112 ISSN0065-3195 ISBN978-3-540-71508-5SpringerBerlinHeidelbergNewYork DOI10.1007/978-3-540-71509-2 Thisworkissubjecttocopyright.Allrightsarereserved,whetherthewholeorpartofthematerial isconcerned,specificallytherightsoftranslation,reprinting,reuseofillustrations,recitation,broad- casting,reproductiononmicrofilmorinanyotherway,andstorageindatabanks.Duplicationof thispublicationorpartsthereofispermittedonlyundertheprovisionsoftheGermanCopyrightLaw ofSeptember9,1965,initscurrentversion,andpermissionforusemustalwaysbeobtainedfrom Springer.ViolationsareliableforprosecutionundertheGermanCopyrightLaw. 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Coverdesign:WMXDesignGmbH,Heidelberg TypesettingandProduction:LE-TEXJelonek,Schmidt&VöcklerGbR,Leipzig Printedonacid-freepaper 02/3100YL–543210 EditorialBoard Prof.AkihiroAbe Prof.Jean-FrançoisJoanny DepartmentofIndustrialChemistry PhysicochimieCurie TokyoInstituteofPolytechnics InstitutCuriesectionrecherche 1583Iiyama,Atsugi-shi243-02,Japan 26rued’Ulm [email protected] 75248Pariscedex05,France [email protected] Prof.A.-C.Albertsson Prof.Hans-HenningKausch DepartmentofPolymerTechnology TheRoyalInstituteofTechnology EcolePolytechniqueFédéraledeLausanne 10044Stockholm,Sweden SciencedeBase [email protected] Station6 1015Lausanne,Switzerland Prof.RuthDuncan [email protected] WelshSchoolofPharmacy Prof.ShiroKobayashi CardiffUniversity RedwoodBuilding R&DCenterforBio-basedMaterials KingEdwardVIIAvenue KyotoInstituteofTechnology CardiffCF103XF,UK Matsugasaki,Sakyo-ku [email protected] Kyoto606-8585,Japan [email protected] Prof.KarelDuˇsek Prof.Kwang-SupLee InstituteofMacromolecularChemistry, Czech DepartmentofPolymerScience& AcademyofSciencesoftheCzechRepublic Engineering HeyrovskýSq.2 HannamUniversity 16206Prague6,CzechRepublic 133Ojung-Dong [email protected] Daejeon306-791,Korea [email protected] Prof.W.H.deJeu Prof.L.Leibler FOM-InstituteAMOLF Kruislaan407 MatièreMolleetChimie 1098SJAmsterdam,TheNetherlands EcoleSupérieuredePhysique [email protected] etChimieIndustrielles(ESPCI) andDutchPolymerInstitute 10rueVauquelin EindhovenUniversityofTechnology 75231ParisCedex05,France POBox513 [email protected] 5600MBEindhoven,TheNetherlands VI EditorialBoard Prof.TimothyE.Long Prof.E.M.Terentjev DepartmentofChemistry CavendishLaboratory andResearchInstitute MadingleyRoad VirginiaTech CambridgeCB3OHE,UK 2110HahnHall(0344) [email protected] Blacksburg,VA24061,USA [email protected] Prof.BrigitteVoit InstitutfürPolymerforschungDresden Prof.IanManners HoheStraße6 SchoolofChemistry 01069Dresden,Germany UniversityofBristol [email protected] Cantock’sClose BS81TSBristol,UK Prof.GerhardWegner [email protected] Max-Planck-Institut fürPolymerforschung Prof.MartinMöller Ackermannweg10 DeutschesWollforschungsinstitut Postfach3148 anderRWTHAachene.V. 55128Mainz,Germany Pauwelsstraße8 [email protected] 52056Aachen,Germany [email protected] Prof.UlrichWiesner MaterialsScience&Engineering Prof.OskarNuyken CornellUniversity LehrstuhlfürMakromolekulareStoffe 329BardHall TUMünchen Ithaca,NY14853,USA Lichtenbergstr.4 [email protected] 85747Garching,Germany [email protected] AdvancesinPolymerScience AlsoAvailableElectronically ForallcustomerswhohaveastandingordertoAdvancesinPolymerScience, weoffertheelectronicversionviaSpringerLinkfreeofcharge.Pleasecontact yourlibrarianwhocanreceiveapasswordorfreeaccesstothefullarticlesby registeringat: springerlink.com Ifyoudonothaveasubscription,youcanstillviewthetablesofcontentsofthe volumesandtheabstractofeacharticlebygoingtotheSpringerLinkHome- page,clickingon“BrowsebyOnlineLibraries”,then“ChemicalSciences”,and finallychooseAdvancesinPolymerScience. 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Contents FunctionalHyperbranchedMacromoleculesConstructed fromAcetylenicTriple-BondBuildingBlocks M.Häußler·B.Z.Tang . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 PolymerMonolayerDynamics A.R.Esker·C.Kim·H.Yu . . . . . . . . . . . . . . . . . . . . . . . . . 59 Silicone-BasedPolymerBlends: AnOverviewoftheMaterialsandProcesses P.Lucas·J.-J.Robin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111 FunctionalMaterialsDerivedfromDNA X.DongLiu·M.Yamada·M.Matsunaga·N.Nishi . . . . . . . . . . . 149 EngineeringBlood-ContactBiomaterials by“H-BondGrafting”SurfaceModification D.-A.Wang . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179 AuthorIndexVolumes201–209 . . . . . . . . . . . . . . . . . . . . . . 229 SubjectIndex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233 AdvPolymSci(2007)209:1–58 DOI10.1007/12_2007_112 © Springer-VerlagBerlinHeidelberg Publishedonline:24March2007 FunctionalHyperbranchedMacromoleculesConstructed fromAcetylenicTriple-BondBuildingBlocks MatthiasHäußler·BenZhongTang((cid:1)) DepartmentofChemistry,TheHongKongUniversityofScience&Technology, ClearWaterBay,Kowloon,HongKong, andDepartmentofPolymerScienceandEngineering,ZhejiangUniversity, 310027Hangzhou,China [email protected] 1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 2 Synthesis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 2.1 Polycoupling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2.1.1 Palladium-CatalyzedPolycoupling . . . . . . . . . . . . . . . . . . . . . . . 5 2.1.2 MechanisticConsiderations. . . . . . . . . . . . . . . . . . . . . . . . . . . 8 2.1.3 Copper-CatalyzedPolycoupling. . . . . . . . . . . . . . . . . . . . . . . . . 9 2.2 Polyhydrosilylation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 2.2.1 Platinum-CatalyzedPolyhydrosilylation . . . . . . . . . . . . . . . . . . . . 13 2.2.2 Rhodium-andPalladium-CatalyzedPolyhydrosilylation . . . . . . . . . . . 13 2.3 Polycycloaddition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 2.3.1 Diels–AlderPolycycloaddition . . . . . . . . . . . . . . . . . . . . . . . . . 14 2.3.2 1,3-DipolarPolycycloaddition(ClickPolymerization) . . . . . . . . . . . . 15 2.4 Polycyclotrimerization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 2.4.1 HyperbranchedPoly(alkylenephenylene)s . . . . . . . . . . . . . . . . . . . 20 2.4.2 HyperbranchedPolyarylenes . . . . . . . . . . . . . . . . . . . . . . . . . . 26 2.4.3 HyperbranchedPoly(aroylarylene)s . . . . . . . . . . . . . . . . . . . . . . 33 3 Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 3.1 ThermalandOpticalProperties . . . . . . . . . . . . . . . . . . . . . . . . 37 3.2 PatterningandAssemblingBehaviors . . . . . . . . . . . . . . . . . . . . . 43 3.3 Photonic,MagneticandCatalyticProperties . . . . . . . . . . . . . . . . . 48 4 ConcludingRemarks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 Abstract Thisreviewarticlesummarizesthesynthetic effortsinconstructing functional hyperbranchedmacromoleculesfromacetylenictriple-bondbuildingblocks.Polymeriza- tionreactionsincludingpolycoupling,polyadditionandpolycyclotrimerizationhavebeen developedforthesynthesis ofnewhyperbranched polymerssuchaspolyynes, polyenes, polyarylenesandpolytriazoleswithnoveltopologicalstructuresandelectronicconjuga- tions.Polymerswithhighmolecularweights(upto>1×106)havebeenobtainedinhigh yields (up to 100%). Whilst their linear counterparts are often intractable, the hyper- branched conjugated polymers are completely soluble in common organic solvents and are hence readily processable by macroscopic techniques. The hyperbranched polymers exhibit an array of functional properties including strong light emission, stable optical 2 M.Häußler·B.Z.Tang nonlinearity and high photorefractivity. The polymers can generate fluorescent images, assemble into supramolecular patterns,and formwell-alignednanotubes. The polyynes canbepost-functionalizedthroughmetalcomplexation,whoserefractiveindexescanbe manipulated to a great extent by photoirradiation. The hyperbranched polymer com- plexescanserveasprecursorstosoftferromagneticceramicsandascatalystsforcarbon nanotubefabrications. Keywords Functionalmaterials·Hyperbranchedpolymers·Polyaddition· Polycoupling·Polycyclotrimerization Abbreviations AAO anodicaluminumoxide AFM atomicforcemicroscopy Ar aromaticring β molecularfirsthyperpolarizability Bu butylgroup c concentration C coremolecule CNT carbonnanotube ∗ Cp pentamethylcyclopentadienyl ligand CVD chemicalvapordeposition D dendriticunit D0.5 doseneededforanFgvalueof0.5(or50%) d33 macroscopicSHGcoefficient DB degreeofbranching DCM dichloromethane De exposuredose DMF N,N-dimethylformamide DSC differentialscanningcalorimetry EO electro-optical Fg gelfraction FOL opticallimitingthresholdfluence FTIR Fourier-transferinfraredspectroscopy Ft,m/Fi,m opticalsignalsuppressionratio GPC gelpermeationchromatography H strengthofmagneticfield hb-PA hyperbranchedpolyarylene hb-PAA hyperbranchedpoly(aroylarylene) hb-PAE hyperbranchedpoly(aryleneethynylene) hb-PAP hyperbranchedpoly(alkylenephenylene) hb-PP hyperbranchedpolyphenylene hb-PPE hyperbranchedpoly(phenyleneethynylene) hb-PTA hyperbranchedpolytriazole hb-PY hyperbranchedpolyyne Hc coercivity L ligand L linearunit l filmthickness f λ absorptionmaximum ab
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