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Fume generation in gas metal arc welding PDF

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UUnniivveerrssiittyy ooff NNeeww HHaammppsshhiirree UUnniivveerrssiittyy ooff NNeeww HHaammppsshhiirree SScchhoollaarrss'' RReeppoossiittoorryy Doctoral Dissertations Student Scholarship Winter 1996 FFuummee ggeenneerraattiioonn iinn ggaass mmeettaall aarrcc wweellddiinngg Robert V. Albert University of New Hampshire, Durham Follow this and additional works at: https://scholars.unh.edu/dissertation RReeccoommmmeennddeedd CCiittaattiioonn Albert, Robert V., "Fume generation in gas metal arc welding" (1996). Doctoral Dissertations. 1925. https://scholars.unh.edu/dissertation/1925 This Dissertation is brought to you for free and open access by the Student Scholarship at University of New Hampshire Scholars' Repository. It has been accepted for inclusion in Doctoral Dissertations by an authorized administrator of University of New Hampshire Scholars' Repository. For more information, please contact [email protected]. INFORMATION TO USERS This manuscript has been reproduced from the microfilm master. UMI films the text directly from the original or copy submitted. Thus, some thesis and dissertation copies are in typewriter free, while others may be from any type of computer printer. The quality of this reproduction is dependent upon the quality of the copy submitted. Broken or indistinct print, colored or poor quality illustrations and photographs, print bleedthrough, substandard margins, and improper alignment can adversely afreet reproduction. In the unlikely event that the author did not send UMI a complete manuscript and there are missing pages, these will be noted. Also, if unauthorized copyright material had to be removed, a note will indicate the deletion. Oversize materials (e.g., maps, drawings, charts) are reproduced by sectioning the original, beginning at the upper left-hand comer and continuing from left to right in equal sections with small overlaps. Each original is also photographed in one exposure and is included in reduced form at the back of the book. Photographs included in the original manuscript have been reproduced xerographically in this copy. Higher quality 6” x 9” black and white photographic prints are available for any photographs or illustrations appearing in this copy for an additional charge. Contact UMI directly to order. UMI A Bell & Howell Information Company 300 North Zeeb Road, Ann Aitoor MI 48106-1346 USA 313/761-4700 800/521-0600 Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. FUME GENERATION IN GAS METAL ARC WELDING BY ROBERT V. ALBERT B.S. University Of Connecticut, 1979 M.S. Syracuse University, 1982 A DISSERTATION Submitted to the University Of New Hampshire In Partial Fulfillment of The Requirements for the Degree of Doctor of Philosophy in Engineering December 1996 Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. UMI Number: 9717849 UMI Microform 9717849 Copyright 1997, by UMI Company. All rights reserved. This microform edition is protected against unauthorized copying under Title 17, United States Code. UMI 300 North Zeeb Road Ann Arbor, MI 48103 Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. This dissertation has been examined and approved Dissertation director, Gail D. Ulrich, Prof of Chemical Engineering Stephan S.T. Fan, Prof of Chemical Engineering T- ^ — -___________________ Russell T. Carr, Associate Prof of Chemical Engineering P T. . Palligarna T. Vasudevan Associate Prof of Chemical Engineering David W. Watt Associate Prof of Mechanical Engineering \ % Date Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. ACKNOWLEDGMENTS I would like to thank my advisor Professor Ulrich for his guidance and belief in my ability to do this. I would like to thank Professor Thomas Eager of M.I.T. for bringing assistance and expertise to the project. I would like to thank Professor Joseph Brain of the Harvard School of Public Health for his help in toxicology evaluation. I would like to thank John Deere and company and the UNH office of Sponsored Research for finacial support. I would also like to thank L-tec Incorporated and Hobart Brothers Company, and Torit Division of the Donaldson Company, for donations of equipment. I would like to thank Professor Fan and the University of New Hampshire faculty for the many years of patience and learning. I would like to thank Johnathan Newell and Nancy Littlefield for their help throughout the years. Finally I would like to thank Harvard researchers Krishna Murthy and Jim Antonini for their collaboration in collecting and evaluating fume samples. iii Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. DEDICATION I dedicate this to my wife Jill and daughters Jean and Gwen. I would also like to recognize my parents for their support. iv Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. TABLE OF CONTENTS Acknowledgements....................................... iii Dedication...............................................iv Table Of Contents........................................ v List Of Figures........................................ vii List Of Tables.......................................... ix Abstract..................................................x CHAPTER I. INTRODUCTION.........................................1 II BACKGROUND...........................................5 Historical Perspective..............................5 Fume In General.....................................8 Physiological Effects..............................10 Arc welding In General.............................13 Fume Generation....................................20 Results Gleaned From Prior literature.............31 Effects Of Voltage, Current and Shield Gas On GMAW Fume Rates......................................... 36 Gas Metal Arc Welding Transfer.................... 40 Epidemiology....................................... 47 The Lung's Defense Systems........................ 47 Lung Evaluation....................................48 Literature Review..................................49 NIOSH.............................................. 49 American Welding Society...........................51 Sferlazza & Beckett................................52 III Theory..............................................59 Mechanisms......................................... 59 Fume Formation Model...............................61 Fume Generation....................................75 Steady State and Drop Temperature................. 85 Drop Formation....................................109 IV Experimental...................................... 118 Equipment and Methods.............................118 Harvard Exper iments...............................121 Results........................................... 123 v Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Fume Generation Data.............................123 Particle Properties..............................126 UNH Analysis..................................... 126 Harvard Analysis.................................130 V Discussion..........................................138 Fume Generation Rates.............................138 Question #1 Answer...............................141 Question #2 Answer...............................153 Question #3 Answer...............................156 Question #4 Answer.............................. 162 VI Conclusion..........................................167 Bibliography....................................... 171 vi Reproduced with permission of the copyright owner. Further reproduction prohibited without permission.

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