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Food carbohydrate chemistry PDF

242 Pages·2012·8.608 MB·English
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F o Food Carbohydrate Chemistry o d C Food Carbohydrate Carbohydrates are major components of foods. They account for more than 90 a r percent of the dry matter of fruits and vegetables and provide 70 to 80 percent b of human caloric intake worldwide so, from a quantitative perspective alone, o they warrant the attention of food chemists. From the standpoint of food quality, h Chemistry y carbohydrates are multifunctional. Sugars are the major source of sweetness, d but in addition, carbohydrates provide flavor, color, and texture – desirable, r undesirable, and neutral – as well as having functional roles as thickeners, a t gelling agents, bodying agents, and stabilizers in foods. When it comes to e nutrition, carbohydrates are often blamed for such health issues as obesity, C diabetes, and dental caries. It should be realized that carbohydrates are, or Ronald E. Wrolstad h should be, the principal source of energy in our diet and that good nutrition e is based on the consumption of the appropriate carbohydrates, in the right m amounts, and in balance with other nutrients. i s Food Carbohydrate Chemistry relates basic carbohydrate chemistry to the t Press quality attributes and functional properties of foods. Structure and nomenclature r y of sugars and sugar derivatives are covered but limited to those compounds that exist naturally in foods or are used as food additives and food ingredients. Review and presentation of fundamental carbohydrate chemistry is minimal, with the assumption that readers have already taken general organic chemistry and general biochemistry. Chemical reactions focus on those that have an impact on food quality and occur under processing and storage conditions. How chemical and physical properties of sugars and polysaccharides affect the functional properties of foods is emphasized. Taste properties and non-enzymic browning reactions are covered, and the nutritional roles of carbohydrates are W addressed from a food chemist’s perspective. There is an extensive appendix r o that includes some laboratory and classroom exercises as well as lecture l s t demonstrations. a d The Author Dr. Ronald E. Wrolstad is Distinguished Professor of Food Science and Technology, Emeritus in the Department of Food Science and Technology, Oregon State University. Dr. Wrolstad has authored over 150 professional publications, including 115 papers in refereed journals and 17 books or book chapters. He has served on the editorial boards of numerous scientific journals including Food Chemistry, Journal of Food Processing and Preservation, and Journal of Food Science Education. He has served as chair of the Food Chemistry Division and Fruit and Vegetable Division of the Institute of Food Technologists. ISBN 978-0-8138-2665-3 Cover design: Meaden Creative Press 9 780813 826653 wrolstad_9780813826653_pb.indd 1 14/10/11 10:14:59 BLBS092-fm October8,2011 14:12 Trim:229mmX152mm CharCount= BLBS092-fm October8,2011 14:12 Trim:229mmX152mm CharCount= Food Carbohydrate Chemistry i BLBS092-fm October8,2011 14:12 Trim:229mmX152mm CharCount= TheIFTPressseriesreflectsthemissionoftheInstituteofFoodTechnologists— to advance the science of food contributing to healthier people everywhere. Developed in partnership with Wiley-Blackwell, IFT Press books serve as leading-edgehandbooksforindustrialapplicationandreferenceandasessen- tial texts for academic programs. Crafted through rigorous peer review and meticulousresearch, IFTPresspublications represent thelatest, most signifi- cantresourcesavailabletofoodscientistsandrelatedagricultureprofessionals worldwide.Foundedin1939,theInstituteofFoodTechnologistsisanonprofit scientific society with 22,000 individual members working in food science, foodtechnology, andrelated professions inindustry,academia, andgovern- ment.IFTservesasaconduitformultidisciplinarysciencethoughtleadership, championing the use of sound science across the food value chain through knowledgesharing,education,andadvocacy. IFTPressAdvisoryGroup CasimirC.Akoh ChristopherJ.Doona FlorenceFeeherry JungHoonHan DavidMcDade RuthM.Patrick SyedS.H.Rizvi FereidoonShahidi ChristopherH.Sommers YaelVodovotz KarenNachay IFTPressEditorialBoard MalcolmC.Bourne DietrichKnorr TheodoreP.Labuza ThomasJ.Montville S.SuzanneNielsen MartinR.Okos MichaelW.Pariza BarbaraJ.Petersen DavidS.Reid SamSaguy HerbertStone KennethR.Swartzel A John Wiley & Sons, Ltd., Publication ii BLBS092-fm October8,2011 14:12 Trim:229mmX152mm CharCount= Food Carbohydrate Chemistry Ronald E. Wrolstad DistinguishedProfessorofFoodScienceEmeritus OregonStateUniversity A John Wiley & Sons, Ltd., Publication iii BLBS092-fm October8,2011 14:12 Trim:229mmX152mm CharCount= Thiseditionfirstpublished2012(cid:2)C 2012byJohnWiley&Sons,Inc.andInstituteof FoodTechnologists Wiley-BlackwellisanimprintofJohnWiley&Sons,formedbythemergerofWiley’s globalScientific,TechnicalandMedicalbusinesswithBlackwellPublishing. Registeredoffice: JohnWiley&SonsLtd,TheAtrium,SouthernGate,Chichester, WestSussex,PO198SQ,UK Editorialoffices: 2121StateAvenue,Ames,Iowa50014-8300,USA TheAtrium,SouthernGate,Chichester,WestSussex,PO198SQ,UK 9600GarsingtonRoad,Oxford,OX42DQ,UK Fordetailsofourglobaleditorialoffices,forcustomerservicesandforinformation abouthowtoapplyforpermissiontoreusethecopyrightmaterialinthisbookplease see our website at www.wiley.com/wiley-blackwell. Authorizationtophotocopyitemsforinternalorpersonaluse,ortheinternalor personaluseofspecificclients,isgrantedbyBlackwellPublishing,providedthatthe basefeeispaiddirectlytotheCopyrightClearanceCenter,222RosewoodDrive, Danvers,MA01923.Forthoseorganizationsthathavebeengrantedaphotocopy licensebyCCC,aseparatesystemofpaymentshasbeenarranged.Thefeecodesfor usersoftheTransactionalReportingServiceareISBN-13:978-0-8138-2665-3/2012. Designationsusedbycompaniestodistinguishtheirproductsareoftenclaimedas trademarks.Allbrandnamesandproductnamesusedinthisbookaretradenames, servicemarks,trademarksorregisteredtrademarksoftheirrespectiveowners.The publisherisnotassociatedwithanyproductorvendormentionedinthisbook.This publicationisdesignedtoprovideaccurateandauthoritativeinformationinregardto thesubjectmattercovered.Itissoldontheunderstandingthatthepublisherisnot engagedinrenderingprofessionalservices.Ifprofessionaladviceorotherexpert assistanceisrequired,theservicesofacompetentprofessionalshouldbesought. LibraryofCongressCataloging-in-PublicationData Wrolstad,RonaldE.,1939– Foodcarbohydratechemistry/RonaldE.Wrolstad.–1sted. p.cm.–(Instituteoffoodtechnologistsseries;48) Includesbibliographicalreferencesandindex. ISBN978-0-8138-2665-3(hardback) 1.Carbohydrates. I.Title. QD321.W882012 (cid:3) 547.78–dc23 2011036449 AcataloguerecordforthisbookisavailablefromtheBritishLibrary. Wileyalsopublishesitsbooksinavarietyofelectronicformats.Somecontentthat appearsinprintmaynotbeavailableinelectronicbooks. (cid:2) Setin9.5/12.5ptPalatinobyAptaraR Inc.,NewDelhi,India 1 2012 iv BLBS092-fm October8,2011 14:12 Trim:229mmX152mm CharCount= TitlesintheIFTPressseries (cid:2) Accelerating New Food Product Design and Development (Jacqueline H. Beckley, (cid:2) ElizabethJ.Topp,M.MicheleFoley,J.C.Huang,andWitoonPrinyawiwatkul) (cid:2) AdvancesinDairyIngredients(GeoffreyW.SmithersandMaryAnnAugustin) BioactiveProteinsandPeptidesasFunctionalFoodsandNutraceuticals(YoshinoriMine, (cid:2) EuniceLi–Chan,andBoJiang) BiofilmsintheFoodEnvironment(HansP.Blaschek,HuaH.Wang,andMeredithE. (cid:2) Agle) Calorimetry in Food Processing: Analysis and Design of Food Systems (Go¨nu¨l (cid:2) Kaletunc¸) (cid:2) Coffee:EmergingHealthEffectsandDiseasePrevention(YiFangChu) (cid:2) FoodCarbohydrateChemistry(RonaldE.Wrolstad) (cid:2) FoodIngredientsfortheGlobalMarket(Yao–WenHuangandClaireL.Kruger) (cid:2) FoodIrradiationResearchandTechnology(ChristopherH.SommersandXuetongFan) FoodbornePathogensintheFoodProcessingEnvironment:Sources,DetectionandControl (cid:2) (SadhanaRavishankar,VijayK.Juneja,andDivyaJaroni) (cid:2) HighPressureProcessingofFoods(ChristopherJ.DoonaandFlorenceE.Feeherry) (cid:2) HydrocolloidsinFoodProcessing(ThomasR.Laaman) (cid:2) ImprovingImportFoodSafety(WayneC.Ellefson,LornaZach,andDarrylSullivan) Innovative Food Processing Technologies: Advances in Multiphysics Simulation (Kai (cid:2) Knoerzer,PabloJuliano,PeterRoupas,andCornelisVersteeg) MicrobialSafetyofFreshProduce(XuetongFan,BrendanA.Niemira,Christopher (cid:2) J.Doona,FlorenceE.Feeherry,andRobertB.Gravani) (cid:2) MicrobiologyandTechnologyofFermentedFoods(RobertW.Hutkins) Multiphysics Simulation of Emerging Food Processing Technologies (Kai Knoerzer, (cid:2) PabloJuliano,PeterRoupasandCornelisVersteeg) Multivariate and Probabilistic Analyses of Sensory Science Problems (Jean–Franc¸ois (cid:2) Meullenet,RuiXiong,andChristopherJ.Findlay (cid:2) NanoscienceandNanotechnologyinFoodSystems(HongdaChen) (cid:2) NaturalFoodFlavorsandColorants(MathewAttokaran) (cid:2) NondestructiveTestingofFoodQuality(JosephIrudayarajandChristophReh) NondigestibleCarbohydratesandDigestiveHealth(TeresaM.PaeschkeandWilliamR. (cid:2) Aimutis) NonthermalProcessingTechnologiesforFood(HowardQ.Zhang,GustavoV.Barbosa– Ca´novas,V.M.Balasubramaniam,C.PatrickDunne,DanielF.Farkas,andJames (cid:2) T.C.Yuan) Nutraceuticals,GlycemicHealthandType2Diabetes(VijaiK.PasupuletiandJamesW. (cid:2) Anderson) OrganicMeatProductionandProcessing(StevenC.Ricke,MichaelG.Johnson,and (cid:2) CorlissA.O’Bryan) (cid:2) PackagingforNonthermalProcessingofFood(JungH.Han) Preharvest and Postharvest Food Safety: Contemporary Issues and Future Directions (RossC.Beier,SureshD.Pillai,andTimothyD.Phillips,Editors;RichardL.Ziprin, (cid:2) AssociateEditor) Processing and Nutrition of Fats and Oils (Ernesto M. Hernandez and Afaf (cid:2) Kamal–Eldin) ProcessingOrganicFoodsfortheGlobalMarket(GwendolynV.Wyard,AnnePlotto, (cid:2) JessicaWalden,andKathrynSchuett) Regulation of Functional Foods and Nutraceuticals: A Global Perspective (Clare M. (cid:2) Hasler) Resistant Starch: Sources, Applications and Health Benefits (Yong–Cheng Shi and ClodualdoManingat) v BLBS092-fm October8,2011 14:12 Trim:229mmX152mm CharCount= (cid:2) SensoryandConsumerResearchinFoodProductDesignandDevelopment(HowardR. (cid:2) Moskowitz,JacquelineH.Beckley,andAnnaV.A.Resurreccion) (cid:2) SustainabilityintheFoodIndustry(CherylJ.Baldwin) (cid:2) ThermalProcessingofFoods:ControlandAutomation(K.P.Sandeep) (cid:2) Trait–ModifiedOilsinFoods(FrankT.OrthoeferandGaryR.List) Water Activity in Foods: Fundamentals and Applications (Gustavo V. Barbosa– (cid:2) Ca´novas,AnthonyJ.FontanaJr.,ShellyJ.Schmidt,andTheodoreP.Labuza) WheyProcessing,FunctionalityandHealthBenefits(CharlesI.OnwulataandPeterJ. Huth) vi BLBS092-fm October8,2011 14:12 Trim:229mmX152mm CharCount= Dedication Thisbookisdedicatedtotwospecialmentors,onebeingmyMajor ProfessorattheUniversityofCalifornia,Davis,Dr.WalterG.Jennings. Hisconcernforstudentsandhisenthusiasmforresearchandteaching continuetoinspire.ThesecondisthelateRobertS.Shallenbergerwith whomIwasfortunatetoworkwhileonsabbaticalleaveatCornell Universityin1979–1980.Hisinfluenceonthisbookshouldbeevidenton nearlyeverypage.Iwouldalsoliketodedicatethebooktothemany undergraduateandgraduatestudents,whothroughtheirsuggestions, understanding,andmisunderstandinghelpedmetorevise,discard,and improvelecturepresentations,homeworkassignments,demonstrations, andlaboratoryexercises.Allofthoseitemswereaplatformforthisbook. vii BLBS092-fm October8,2011 14:12 Trim:229mmX152mm CharCount= viii

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