Fluorinated Polymers, Volume 2 - Applications

396 Pages·2016·15.818 MB·English

by  Bruno Ameduri, Bruno Ameduri, Hideo Sawada, Hideo Sawada, Ben Zhong Tang, Toshio Masuda, Shohei Yamazaki, Masato Yoshida, Tadashi Narita, Kunio Kimura, Yoshitoni Morizawa, Ilkuo Yamamoto, Shinsuke Inagi, Atsuhiro Fujimori, H. R. Allcock, Harald Kaspar, Susanta Banerjee, Rudy Dams, Walter Navarrini, Doris Pospiech, Sabine Beuermann, James Goldbach, Joseph Thrasher, Armand Soldera, Xiaoyu Huang

Fluorinated Polymers
Volume 2: Applications
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RSC Polymer Chemistry Series
Editor-in-Chief:
Professor Ben Zhong Tang, The Hong Kong University of Science and
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6 Professor Alaa S. Abd-El-Aziz, University of Prince Edward Island, Canada
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7 Professor Stephen Craig, Duke University, USA
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7 ProfessorJianhuaDong,NationalNaturalScienceFoundationofChina,China
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9/ Professor Toshio Masuda, Shanghai University, China
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1 Professor Christoph Weder, University of Fribourg, Switzerland
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g | d Titles in the Series:
or 1: Renewable Resources for Functional Polymers and Biomaterials
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s.rs 2: Molecular Design and Applications of Photofunctional
ub Polymers and Materials
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p:// 3: Functional Polymers for Nanomedicine
htt 4: Fundamentals of Controlled/Living Radical Polymerization
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6 o 5: Healable Polymer Systems
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0 6: Thiol-X Chemistries in Polymer and Materials Science
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er 7: Natural Rubber Materials: Volume 1: Blends and IPNs
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m 8: Natural Rubber Materials: Volume 2: Composites and Nanocomposites
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o 9: Conjugated Polymers: A Practical Guide to Synthesis
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n 04 10: Polymeric Materials with Antimicrobial Activity: From Synthesis to
o Applications
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bli 12: Poly(lactic acid) Science and Technology: Processing, Properties,
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P Additives and Applications
13: Cationic Polymers in Regenerative Medicine
14: Electrospinning: Principles, Practice and Possibilities
15: Glycopolymer Code: Synthesis of Glycopolymers and their Applications
16: Hyperbranched Polymers: Macromolecules in-between Deterministic
Linear Chains and Dendrimer Structures
17: Polymer Photovoltaics: Materials, Physics, and Device Engineering
18: Electrical Memory Materials and Devices
19: Nitroxide Mediated Polymerization: From Fundamentals to
Applications in Materials Science
View Online
20: Polymers for Personal Care Products and Cosmetics
21: Semiconducting Polymers: Controlled Synthesis and Microstructure
22: Bio-inspired Polymers
23: Fluorinated Polymers: Volume 1: Synthesis, Properties, Processing and
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Fluorinated Polymers
Volume 2: Applications
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62 Edited by
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3 Ecole Nationale Sup´erieure de Chimie de Montpellier, Montpellier, France
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1 RSCPolymerChemistrySeriesNo.24
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c. PDFeISBN:978-1-78262-936-8
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s.r EPUBeISBN:978-1-78262-937-5
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PublishedbyTheRoyalSocietyofChemistry,
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oi: Because of the increasing need for better performing materials endowed
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g | with specific properties for high-tech applications, fluoropolymers have
or undergone a rapid development. Since their discovery in the 1930s, these
c.
s
s.r niche specialty polymers have been regarded as unique macromolecules
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u withanexceptionalcombinationofcharacteristics(derivedfromthestrong
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p:// C–F bond, such as chemical resistance, heat and light stability, electrical
htt insulationandliquidandsoilrepellency)toprovidesuperiorperformancein
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6 o the chemical, medical, aerospace, automotive, electrical and electronics
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0 industries.
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er The relationship between the structures of the monomers and the prop-
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e ertiesoftheresulting (co)polymersisofincreasinginterestinordertotune
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No these properties towards the most appropriate applications.
n 04 These fluoroplastics or fluoroelastomers have already been involved in
o many applications, ranging from surfactants, optical fibers, biomaterials,
d
he liners or ultrathin layers, electronics, seals and O-rings for the aerospace
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bli and automotive industries, coatings, piezoelectric devices, electrolytes and
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separators for lithium ion batteries and back-sheets for photovoltaics to
membranes for seawater desalination and fuel cells. These polymers are
nowadaysexperiencingenormousgrowthandtheirproductionisincreasing
by7%yearly.Inthelastdecade,around10reviews,chaptersandbookshave
been published that witness the great interest in these materials.
FluorinatedPolymersiscomposedoftwovolumesandincludes23chapters
written by internationally recognized industrial and academic experts,
outlining fundamental concepts and applied topics, starting with a general
introduction. Then, emphasis is placed on recent developments and
challenges, and most chapters describe comprehensive techniques of
synthesis,characterizationandpropertiesoffluoropolymers(FPs).Volume1
is devoted to the basic aspects of FPs, including the chemistry, synthesis of
RSCPolymerChemistrySeriesNo.24
FluorinatedPolymers:Volume2:Applications
EditedbyBrunoAmeduriandHideoSawada
rTheRoyalSocietyofChemistry2017
PublishedbytheRoyalSocietyofChemistry,www.rsc.org
vii
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viii Preface
keyreactantsandtechniquesofpolymerization,processing,andsimulation,
while Volume 2 concerns specific characterization and applications.
Regarding syntheses, those of initiators (especially peroxides, Chapter 1,
Volume1),monomers(Chapter2,Volume1),oligomers(Chapter4,Volume
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0 1), well-defined fluorotelomers (Chapter 11, Volume 1 and Chapter 1,
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F Volume 2) and alternating copolymers (Chapters 9 and 10, Volume 2), are
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6 highlighted, in addition to fluoroplastics and fluoroelastomers (Chapters 3
3
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2 and 4, Volume 2) and key (co)polymers such as polyacrylates (Chapter 8,
6
2
8 Volume 1 and Chapters 1 and 2, Volume 2), polyaromatics (Chapter 5,
7
1
8 Volume 1), PVDF (Chapter 6, Volume 2), polyphosphazenes (Chapter 3,
7
9
9/ Volume 2), perfluoropolyethers (Chapters 5 and 7, Volume 2), copolymers
3
10 and terpolymers based on vinylidene fluoride (Chapter 7, Volume 1 and
0.
1 Chapter 6, Volume 2), tetrafluoroethylene (Chapter 9, Volume 2), or
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d chlorotrifluoroethylene(Chapters5and10,Volume2).Inaddition,common
org | synthetic methods such as anionic polymerization (Chapter 3, Volume 1)
bs.rsc. aspnedcirfaicdipcraolcpeoslsyemsesruiczhatiaosneilnecstruopcehrecmritiiccaall(CCOha2p(Ctehra6p,teVrol7u,mVeol1u)maend1)maneldt
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p://p processing(Chapter10,Volume1)completetheseaspects,whileChapter11,
htt Volume 1 brings an insight into simulation.
on ThisbookalsooutlinessomecharacterizationsofFPssuchasthesurface
6
1 properties of poly(acrylate)s (Chapter 8, Volume 1 and Chapters 1 and 2,
0
2
er Volume2),self-assemblyofwell-architecturedFPs(Chapter9,Volume1)and
mb their applications in paints and coatings (Chapters 5 and 6, Volume 2),
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v energystorageandconversion(Chapter5,Volume1andChapters7,8and9,
o
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4 Volume2)andnanomaterialsforspecificapplications(Chapters11and12,
n 0 Volume2).Inaddition,environmentalaspects(Chapters1and2,Volume2)
o
ed are also supplied.
h
blis We would like to thank all contributors for their valuable chapters
Pu listed above.
Thesevolumes,forimmediateusebytoday’sengineersandindustrialand
academicscientistsandresearchers,andalsoforgraduatestudents,working
inthefieldsofmaterialsscience,polymerchemistryandenergyapplications
of polymers have been arranged to facilitate self-managed reading and
learning. They are both a source of data and a reference.
Bruno Ameduri
Hideo Sawada
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c. Chapter 1 Fluorinated Peroxides as Initiators of Fluorinated
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n 1.1 Introduction 3
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16 1.2 Computational Methods 5
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4 1.3.2 Molecular Structure of
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1.3.4 Thermal Decomposition of
Alkanoyl/Fluoroalkanoyl Peroxides 17
1.4 Conclusion 20
Acknowledgements 21
References 21
Chapter2 FluoroalkylatedStyreneDimers:Synthesis,Properties,and
Applications 22
Masato Yoshida
2.1 Introduction 22
RSCPolymerChemistrySeriesNo.24
FluorinatedPolymers:Volume2:Applications
EditedbyBrunoAmeduriandHideoSawada
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x Contents
2.2 General Aspects of the Addition of Perfluoroalkyl
Radicals to Olefinic Compounds 23
2.3 Process for the Formation of Head-to-head Type
Styrene Dimers Bearing Two Fluoroalkyl
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htt 3.2 Anionic Polymerization Reactivity of Fluorinated
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ber 1,3-Butadiene 53
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Tadashi Narita
4.1 Introduction 72
4.2 AnionicPolyadditionofFluorinatedVinylMonomers 73
4.3 RadicalPolyadditionofFluorinatedVinylMonomers 79
4.4 Conclusion 101
References 101
Chapter 5 Semifluorinated Aromatic Polymers and
Their Properties 103
Susanta Banerjee and Anindita Ghosh
5.1 General Introduction to Aromatic Fluorinated
Polymers 103
5.2 Fluorinated Poly(Arylene Ether)s 104
5.2.1 Preparation of Fluorinated
Poly(Arylene Ether)s 105