FERROELECTRICS ‐ APPLICATIONS Edited byMickaël Lallart Ferroelectrics - Applications Edited by Mickaël Lallart Published by InTech Janeza Trdine 9, 51000 Rijeka, Croatia Copyright © 2011 InTech All chapters are Open Access articles distributed under the Creative Commons Non Commercial Share Alike Attribution 3.0 license, which permits to copy, distribute, transmit, and adapt the work in any medium, so long as the original work is properly cited. After this work has been published by InTech, authors have the right to republish it, in whole or part, in any publication of which they are the author, and to make other personal use of the work. Any republication, referencing or personal use of the work must explicitly identify the original source. Statements and opinions expressed in the chapters are these of the individual contributors and not necessarily those of the editors or publisher. No responsibility is accepted for the accuracy of information contained in the published articles. The publisher assumes no responsibility for any damage or injury to persons or property arising out of the use of any materials, instructions, methods or ideas contained in the book. Publishing Process Manager Silvia Vlase Technical Editor Teodora Smiljanic Cover Designer Jan Hyrat Image Copyright Noel Powell, Schaumburg, 2010. Used under license from Shutterstock.com First published June, 2011 Printed in Croatia A free online edition of this book is available at www.intechopen.com Additional hard copies can be obtained from [email protected] Ferroelectrics - Applications, Edited by Mickaël Lallart p. cm. ISBN 978-953-307-456-6 free online editions of InTech Books and Journals can be found at www.intechopen.com Contents Preface IX Part 1 Sensors and Actuators 1 Chapter 1 Giant k Relaxor Single-Crystal Plate 31 and Their Applications 3 Toshio Ogawa Chapter 2 MEMS Based on Thin Ferroelectric Layers 35 Igor L. Baginsky and Edward G. Kostsov Chapter 3 Periodically Poled Acoustic Wave-Guide and Transducers for Radio-Frequency Applications 59 Sylvain Ballandras, Emilie Courjon, Florent Bassignot, Gwenn Ulliac, Jérôme Hauden, Julien Garcia, Thierry Laroche and William Daniau Chapter 4 Ferroelectric Polymer for Bio-Sonar Replica 75 Antonino S. Fiorillo and Salvatore A. Pullano Chapter 5 Ferroelectric Materials for Small-Scale Energy Harvesting Devices and Green Energy Products 95 Mickaël Lallart and Daniel Guyomar Part 2 Memories 115 Chapter 6 Future Memory Technology and Ferroelectric Memory as an Ultimate Memory Solution 117 Kinam Kim and Dong Jin Jung Chapter 7 Ultrahigh Density Probe-based Storage Using Ferroelectric Thin Films 157 Noureddine Tayebi and Yuegang Zhang VI Contents Chapter 8 Fabrication and Study on One-Transistor-Capacitor Structure of Nonvolatile Random Access Memory TFT Devices Using Ferroelectric Gated Oxide Film 179 Chien-Min Cheng, Kai-Huang Chen, Chun-Cheng Lin, Ying-Chung Chen, Chih-Sheng Chen and Ping-Kuan Chang Chapter 9 Ferroelectric Copolymer-Based Plastic Memory Transistos 195 Sung-Min Yoon, Shinhyuk Yang, Soon-Won Jung, Sang-Hee Ko Park, Chun-Won Byun, Min-Ki Ryu, Himchan Oh, Chi-Sun Hwang, Kyoung-Ik Cho and Byoung-Gon Yu Chapter 10 Use of FRAM Memories in Spacecrafts 213 Claudio Sansoè and Maurizio Tranchero Chapter 11 Adaptive Boolean Logic Using Ferroelectrics Capacitors as Basic Units of Artificial Neurons 231 Alan P. O. da Silva, Cicília R. M. Leite, Ana M. G. Guerreiro, Carlos A. Paz de Araujo and Larry McMillan Preface Ferroelectricity has been one of the most used and studied phenomena in both scien‐ tific and industrial communities. Properties of ferroelectrics materials make them par‐ ticularly suitable for a wide range of applications, ranging from sensors and actuators to optical or memory devices. Since the discovery of ferroelectricity in Rochelle Salt (which used to be used since 1665) in 1921 by J. Valasek, numerous applications using such an effect have been developed. First employed in large majority in sonars in the middle of the 20th century, ferroelectric materials have been able to be adapted to more and more systems in our daily life (ultrasound or thermal imaging, accelerometers, gy‐ roscopes, filters…), and promising breakthrough applications are still under develop‐ ment (non‐volatile memory, optical devices…), making ferroelectrics one of tomor‐ row’s most important materials. The purpose of this collection is to present an up‐to‐date view of ferroelectricity and its applications, and is divided into four books: Material Aspects, describing ways to select and process materials to make them ferroelectric. Physical Effects, aiming at explaining the underlying mechanisms in ferroelec‐ tric materials and effects that arise from their particular properties. Characterization and Modeling, giving an overview of how to quantify the mechanisms of ferroelectric materials (both in microscopic and macroscopic approaches) and to predict their performance. Applications, showing breakthrough use of ferroelectrics. Authors of each chapter have been selected according to their scientific work and their contributions to the community, ensuring high‐quality contents. The present volume focuses on the applications of ferroelectric materials, describing innovative systems that use ferroelectricity. The current use of such devices as sensors and actuators, in the field of acoustics, MEMS, micromotors and energy harvesting will be presented in chapters 1 to 5. The next section proposes a particular emphasis X Preface on the application of ferroelectric materials as transistors and memory devices (chap‐ ters 6 to 11), showing one of the future breakthrough uses of these materials. I sincerely hope you will find this book as enjoyable to read as it was to edit, and that it will help your research and/or give new ideas in the wide field of ferroelectric mate‐ rials. Finally, I would like to take the opportunity of writing this preface to thank all the au‐ thors for their high quality contributions, as well as the InTech publishing team (and especially the publishing process manager Ms. Silvia Vlase) for their outstanding sup‐ port. June 2011 Dr. Mickaël Lallart INSA Lyon, Villeurbanne, France