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AppliedEnergy154(2015)40–50 ContentslistsavailableatScienceDirect Applied Energy journal homepage: www.elsevier.com/locate/apenergy Experimental study of heat transfer enhancement in a liquid piston compressor/expander using porous media inserts Bo Yan1, Jacob Wieberdink1, Farzad Shirazi2, Perry Y. Li⇑, Terrence W. Simon, James D. Van de Ven DepartmentofMechanicalEngineering,UniversityofMinnesota,Minneapolis,MN55455,USA h i g h l i g h t s g r a p h i c a l a b s t r a c t (cid:2)Porousmediasroletoimprove compressor/expanderperformance shownexperimentally. (cid:2)Significantincreaseinefficiency increase(upto18%)atfixedpower density. (cid:2)Significantincreaseinpowerdensity (upto39folds)atfixedefficiency. (cid:2)Surfaceareaisthepredominant contributiontoimprovements. a r t i c l e i n f o a b s t r a c t Articlehistory: The efficiency and power density of gas compression and expansion are strongly dependent on heat Received25November2014 transferduringtheprocess.Sinceporousmediainsertscansignificantlyincreaseheattransfersurface Receivedinrevisedform24April2015 area,theiradditiontoaliquidpistoncompressor/expanderhasbeenhypothesizedtoreducethetime Accepted25April2015 tocompletethecompressionorexpansionprocessandhencethepowerdensityforagiventhermody- Availableonline14May2015 namicefficiency;ortoincreasethethermodynamicefficiencyatafixedpowerdensity.Thispaperpre- sents an experimental investigation on heat transfer with porous inserts during compression for a Keywords: pressureratioof10andduringexpansionforapressureratioof6.Abaselinecasewithoutinsertsand Liquidpiston fivecaseswithdifferentporousinsertsaretestedinacompressionexperiment:3interruptedABSinserts Porousmedia withplatespacingof2.5,5,and10mmand2aluminumfoaminsertssizedwith10and40poresperinch. Gascompression/expansion Compressedairenergystorage(CAES) The 2.5mm and 5mm interrupted plate inserts were also tested in expansion experiments. Porous Efficiency insertsarefound,incompression,toincreasepower-densityby39-foldat95%efficiencyandtoincrease Powerdensity efficiencyby18%at100kW=m3powerdensity;inexpansion,powerdensityisincreasedthreefoldat89% efficiency,andefficiencyisincreasedby7%at150kW=m3.Surfaceareaincreaseisfoundtobethepre- dominantcauseintheimprovementinperformance.Thus,aliquidpistoncompressor/expandertogether withaporousmediummaybeusedinapplicationsrequiringhighcompressionratios,highefficiencies, andhighpowerdensitysuchasinanopen-accumulatorcompressedairenergystorage(CAES)systemor acompressorforcompressednaturalgas(CNG). (cid:2)2015ElsevierLtd.Allrightsreserved. 1.Introduction ⇑ Correspondingauthor. Compressed air is a potential cost effective, power-dense, E-mail addresses: [email protected] (B. Yan), [email protected] (J.Wieberdink),[email protected](F.Shirazi),[email protected](P.Y.Li), reliable and scalable means for storing energy at the utility [email protected](T.W.Simon),[email protected](J.D.VandeVen). scale compared to electric batteries, pumped-hydro and closed 1 Presentaddress:CumminsInc.,Columbus,IN47201,USA. hydraulic accumulators [1–4]. In a conventional compressed air 2 Presentaddress:DepartmentofMechanicalEngineering,UniversityofTehran, energy storage (CAES) system, compressed air is produced using Tehran,Iran. http://dx.doi.org/10.1016/j.apenergy.2015.04.106 0306-2619/(cid:2)2015ElsevierLtd.Allrightsreserved. B.Yanetal./AppliedEnergy154(2015)40–50 41 excess electricity and stored in underground caverns. It is then 2.5mm,5mmand10mmspacingbetweenplatesandaluminum combined with natural gas in a gas turbine to boost combustion foamswith10and40poresperinch(PPI).Thesewerechosento efficiency. As a storage device, its efficiency is typically less than span a range of surface area augmentation types, to utilize com- 50%[5].Inrecentyears,isothermalCAEShavebeenproposedboth merciallyavailablematerials(foams),andbasedondemonstrated byindustryandacademiaasanenergystorageapproachthatdoes advantages from previous computational studies (interrupted not require fuel [6,7]. Here, mechanical work is consumed in the plates) [24]. The input/output work, heat transfer and change in compressortocompressairduringthestoragephase,andrecuper- internalenergyoftheair,andcompression/expansionefficiencies ated in the expander as the compressed air expands during the arecalculatedduringcompression/expansionforcaseswithporous regenerationphase. inserts and compared with a benchmark case without porous For isothermal CAES to be viable, a high pressure (e.g. 200– inserts. This is the first experimental study of a compressor/ex- 300bar), powerful and efficient compressor/expander is critical. panderwithheattransferinsertsandaliquidpistonthathasbeen Such a compressoris also needed for compressing natural gas as conducted with precise documentation of the volume, pressure fuel for vehicles. Conventionally a high pressure gas compressor and bulk temperature of the air during compression and expan- consists of multiple stages with inter-cooling. This creates a sion.Theresultsshow,indeed,thatporousmediainsertscansig- zig-zag pressure–volume curve consisting of successive adiabatic nificantly improve the trade off between efficiency and power andconstantvolumecoolingsegments.Acompressorwithmulti- densityinaliquidpistoncompressor/expander. pleadiabaticstagesandidealinter-coolingisthemostefficientif The remainderofthe paperis structuredas follows. Section2 allstageshavethesamecompressionratio[8].Asthenumberof provides an overview of the liquid piston compressor/expander stages increases, compression approaches the most efficient and the governing equations that describe it. Section 3 presents isothermalcompression.Whereasefficiencyofthecompressor/ex- thetestfacilitiesanddescribestheporousmaterialsthatareused. panderisgovernedbythepressure–volume(P–V)curve,thetimeit Section4describesthetesting,dataanalysisanduncertaintyanal- takestotracethecurveandhencethepower(work/time)depends ysis.Section5presentstheresultsforthecompressionandexpan- on the heat transfer rate in the compressor/expander or in the siontests.Sections6and7containdiscussionandconclusions. inter-cooling.Iflesstimeisallowedforheattransfer,theP–Vcurve deviates more and more from isothermal and becomes less and 2.Liquidpistoncompression/expansionprocesses less efficient. Hence, there is an inherent trade-off between effi- ciencyandpowerofacompressor/expander. Inaliquidpistonaircompressor/expander,airentersandexits This trade-off can be mitigated by optimizing the compression a compression/expansion chamber from the top, and liquid andexpansiontrajectories,orbyimprovingtheheattransfercapabil- (water in our case) from the bottom. The volume of the liquid ity.In[9–11],trajectoriesareoptimizedforthreecases:whenh(cid:3)A inthechamberiscontrolledbyahydraulicpump/motor.Incom- (the product between the heat transfer coefficient, h, and the heat pression mode, the compression/expansion chamber is initially transfersurfacearea,A)isaconstant, whenh(cid:3)A isvolumedepen- filled with air at ambient pressure. As liquid is pumped into the dent, and when h(cid:3)A is an arbitrary function. By matching power chamber,thevolumeofthe airaboveitis reducedand thepres- andavailabilityofheattransfercapability,several-foldimprovement sure is increased. In expansion mode, the chamber is initially inpowerdensitiesoveradhoc(sinusoidalorlinearcompression/ex- filled with mostly liquid and a small volume of compressed air pansion) profiles at the same efficiency can be achieved. Optimal abovetheliquid.Asliquidisallowedtoexitthechamber,thevol- volume-timetrajectoriesatlowpressureratios(1barto7bar)have ume of the compressed air increases and pressure is reduced. As beenvalidatedexperimentallyin[12,13].Theeffectivenessofusing such, the liquid column acts as a piston and mechanical work is tunedcompressiontrajectoriesisalsoshowninsimulationin[14]. applied and extracted via the hydraulic pump/motor for the liq- Heat transfer capability can be enhanced by actively spraying uid piston. The compression/expansion cycles can be repeated verysmallliquiddropletswithhighheatcapacityandlargetotal (frequently, if high power is desired) with the intake of ambient heat transfer surface area [15–18]. The approach pursued in this air or the exhaust of expanded air. With the liquid piston, the paper is the use of a liquid piston in a compression/expansion chamber can be filled with a porous medium since both liquid chamberfilledwithporousmaterial,asproposedin[19].Theliq- and air can flow through it. This can significantly increase the uidpistonfreelyflowsthroughtheporousmaterialwhichgreatly surface area for heat transfer for a given amount of initial/ex- increases the heat transfer area. Compared with a rigid piston, a panded air volume. liquid piston also forms an effective low friction seal for the air In this paper,airis treated as an ideal gas since pressures are beingcompressed.InadditiontotheCAESapplication,liquidpis- relatively low (1–12bar under compression) and temperatures ton is also being pursued as a cost-effective and efficient means are modest (200–450K). This assumption allows a mass-average tocompressnaturalgasforvehicleuse[20],aswellasforhydro- bulktemperaturetobederivedfromameasuredpressureandvol- gen[21]andsupercriticalCO [22].Numericalsimulationsoffluid ume.Anadditionalassumptionisthatthechamberandwaterlines 2 flowandheattransferwereconductedforvariousgeometries(tiny arerigidandthewaterisincompressible.Thispermitsthevolume tubes, metal foams and interrupted-plate heat exchangers) in ofairinthechambertobedeterminedbythedifferencebetween [19,23–25]. Preliminary experimental studies of enhanced heat theinitialairvolumeandtheamountofliquidintroduced. transferwiththeuseofinsertsarereportedin[26].However,since Let P and T be the ambient pressure and temperature. We 0 0 the instrumentation was limited, only limited qualitative infer- assumethatthecompressedairistobestoredinatankatthecon- encescouldbemade.Recently,aliquidpistoncompressorwasalso stantpressureofrP (risthecompressionratio)andthatthereis 0 demonstratedinabenchtopoceancompressedairenergystorage sufficientdwelltimeforthecompressed airin thestoragevessel (OCAES)system[27]. tocooldowntoT beforereusing.Theworkinputforthecompres- 0 Theobjectiveofthispaperistotestexperimentallytheeffec- sionprocessandworkoutputfromtheexpansionprocessareillus- tiveness of various porous media to increase the efficiency or trated as the horizontally-shaded areas under the P–V curves in power density of a liquid piston compression/expansion process. Fig. 1. The work input to compress V volume of ambient air at 0 Aseriesofcompressionandexpansionexperimentsusingdifferent ðP ; T Þtobestoredinthetankconsistsofthecompressionwork 0 0 typesofporousinsertsinalow-pressure(12barmaximumpres- to rP along a certain compression trajectory (f) defined by the 0 c sure) compression/expansion chamber are presented. The porous P–V (or T–V) profile, and the isobaric ejection of the compressed inserts under study are ABS plastic interrupted-plates with airintothetank: 42 B.Yanetal./AppliedEnergy154(2015)40–50 Inadditiontoefficiency,powerdensityisalsoanimportantfigure of merit for a compressor/expander. The storage power of a com- pressorisdefinedastheratioofthestorageenergyðE Þtothecom- P pressiontimet .Theoutputpowerofanexpanderisdefinedasthe c ratiooftheoutputwork(W )totheexpansiontimet .Thecom- out e pression/expansionpowerdensitiesaretherespectivepowersnor- malizedbythecompressor/expandervolume,whichconsistsofthe expandedairvolumeV andthesolidvolumeoftheporousinsert 0 V : ins E q :¼ p ð6Þ c t ðV þV Þ c 0 ins W q :¼ out ð7Þ e t ðV þV Þ e 0 ins A compressor/expander with a larger power density is advanta- geous as smaller or fewer units are needed for a given power requirement,so thatsystemismorecompactandthecapitalcost islower. Thetemperaturedynamicsofafixedmass(m)ofairisgivenby thefirstlawofthermodynamics: mcvdTðtÞ¼(cid:4)PðtÞV_ðtÞ(cid:4)Q_ðtÞ ð8Þ dt wherecv istheconstantvolumespecificheatcapacity,VðtÞisthe instantaneousairvolume,andQ_ðtÞistheheattransferrateoutof the air (to the environment assumed to be at T ). To achieve the 0 isothermal condition, it is necessary that the heat transfer equals inputpower: Q_ðtÞ¼(cid:4)PðtÞV_ðtÞ¼Power ðtÞ ð9Þ input AssumingNewton’slawofcooling: Q_ ¼hAðT(cid:4)T Þ ð10Þ 0 Fig.1. Pressure–volumecurvesforisothermal,adiabatic,andrealprocesses.Top: wherehAistheproductoftheheattransfercoefficientandsurface compression;bottom:Expansion. area,thenwehave W ðf Þ¼ðrP (cid:4)P ÞV (cid:4)Z VcðP(cid:4)P ÞdV ð1Þ mcvdT¼(cid:4)PdV(cid:4)hAðT(cid:4)T0Þdt ð11Þ in c 0 0 c 0 V0 Rearranging,wehave wherethesecondtermandV aredependentonf. c c mcvdTþPdV Similarly,theworkoutputfromexpandingavolumeV ofcom- (cid:4) ¼hA(cid:3)dt ð12Þ c ðT(cid:4)T Þ pressedairfromðrP ; T ÞtoP consistsoftheisobaricinjectionof 0 0 0 0 the compressed air to the expansion chamber and the expansion Eq.(12)showsthatifhAcanbeincreaseduniformlyateachairvol- work to P0 along an expansion trajectory (fe) defined by the P–V umeVsuchthathA!ahA,thenthesolutionto(12)willbescaled (orT–V)profile: asPðtÞ!PðatÞ;TðtÞ!TðatÞandVðtÞ!VðatÞ.Hence,thesameP–V Z Ve and T–V profiles can be accomplished faster by a factor of a, i.e. W ðf Þ¼ðrP (cid:4)P ÞV þ ðP(cid:4)P ÞdV ð2Þ t !t =a.Thisisachievedbyscalingtheliquidpistonflowrate out e 0 0 c 0 c=e c=e Vc bya((cid:4)V_ðtÞ!(cid:4)aV_ðatÞ).Withthedecreaseincycletimes,t ort , c e whereVeisthevolumeatwhichtheexpandingairreachesambient from(6),(7),thepowerdensitieswillalsobeincreasedbyafactor pressure,andVe andthesecondtermaredependentonfe. ofa. For a compressed air volume of Vc¼V0=r at pressure rP0, we Thisisthebasisforourhypothesisthatbyintroducingporous definethestoredenergyasthemaximumworkthatcanbeextracted media which increase the heat transfer surface area A, the com- given an ambient environmental temperature of T0. This can be pression/expansiontimeswillbereducedandthepowerdensities obtainedeitherfromWin orWout whenthecompression/expansion willbeincreasedwhilemaintainingthesameefficiency.Similarly, processisisothermalatT0.ThestoredenergyEP isgivenby: at the same power-density, it is expected that increasing A will Z V0 increase efficiency. The objective of this paper is to test this E ¼ðrP (cid:4)P ÞV þ ðP(cid:4)P ÞdV ¼P V lnðrÞ ð3Þ hypothesisexperimentally. P 0 0 c 0 0 0 Vc |fflfflfflfflfflfflfflfflfflfflfflffl{zfflfflfflfflfflfflfflfflfflfflfflffl} isothermal 3.Experimentalsetup Thus, we can define the compression and expansion efficiencies respectivelyas: Figs.2and3showaschematicandpictureoftheexperimental setup.Thesetupisdesignedtoallowtheliquidflowinandoutof E g :¼ P ð4Þ the compression/expansion chamber to be controlled and mea- c W in sured. Flow rate control permits the compression/expansion tra- W g :¼ out ð5Þ jectoriestobecontrolledsothatoperationoverarangeofpower e EP densitiescan be explored. Instantaneousair volume is calculated B.Yanetal./AppliedEnergy154(2015)40–50 43 compressor/expander so that the flow rate is determined by the pressure drop across the valve and the orifice area. By adjusting the orifice area from run to run, the average flow rate during expansionisadjusted,buttheflowrateisnotconstant. An advantage of conducting experiments with constant flow rates (as in compression) is that between any two experiments, the air volume trajectories V ðtÞ and V ðtÞ are related by a time 1 2 scaling,i.e.thereexistsascalarasuchthat V ðtÞ¼V ðatÞ; V_ ðtÞ¼aV_ ðatÞ 1 2 1 2 Aswasnotedearlier,thesolutiontoEq.(12)hasthistimescaling property if the scaling hA!ahA is applied uniformly. The orifice determinedflowprofiles(asinexpansion),however,donotenjoy thispropertysothatthescalinganalysisisnotasexact.Forexam- ple, the air volume trajectories V ðtÞ and V ðtÞ for a 6s and 3s 1 2 expansiontimesarenotrelatedbyV_ ðtÞ¼2V_ ð2tÞ. 1 2 An Omega FTB-1412 turbine flowmeter (7), with a measure- ment range of 46.7–466.7cc/s, and a load cell (10), which mea- sures the weight of water that has left the expansion chamber, areusedtomeasuretheflowenteringorexitingthecompression/ expansionchamber.Athighflowrates,theturbinemeterisused (theloadcellmeasurementisinaccurateinthiscaseduetofluid Fig.2. Schematicoftheliquidpistoncompression/expansionexperimentalsetup. bysubtracting/addingtheamountofwaterthathasentered/exited thechamberfromtheinitialairvolume.Airpressureismeasured directlywithapressuretransducer.Withairvolumeandpressure, bulkairtemperaturecanbecalculatedfromtheidealgaslaw.This avoidstheuseofthermocouplesthatcanmeasureonlylocaltem- perature and because of theporous media, are restricted in their placements.Compression/expansionworks(W andW )canalso in out becalculatedfromairvolumeandpressuretrajectories. The compression/expansion chamber (1) is a 353mm long, 50.8mm internaldiametertransparentpolycarbonatecylinder.It can accommodate various porous media inserts. The empty volumeofthechamberis715cc.Theaspectratioandvolumewere determinedbasedoncommerciallyavailablesizesandflowcapa- bilities of the pump/valve to reach reasonable power densities (relatedtocompression/expansiontimes).Graduationsonthetube permitinitialandfinalwaterlevelstoberead.Aluminumendcaps at the top and bottom of the compression/expansion chamber serve as manifolds for making various connections. The top cap holds a Kulite ETM-375 pressure transducer (11) for air pressure measurement and a port (12) for charging the chamber with compressed air prior to expansion experiments. The bottom cap provides ports for liquid to enter and exit the chamber. Elastomeric O-rings are used at the end caps for sealing and tie rodsareusedtoholdthecylinderagainstthetwoendcaps. When operating in compression mode, a Wanner Hydra-cell positivedisplacementdiaphragmpump(3)supplieswatertothe circuit. The pump is capable of supplying a maximum flow rate of275cc/s.Areliefvalve(5)isusedtodivertaportionofthisflow back to tank. This fraction is set by controlling the pressure upstreamofthesolenoidcontrolvalve(6).Whenthatpressureis held constant, the flow through the relief valve to the tank and theflowintothecircuitareconstant.Aproportional–integralcon- trollerisusedtoregulatethisupstreampressure,measuredwith pressure sensor (4), to a specified level. When operating in com- pressionmode,theflowrateisadjustableandheldconstantfora givenexperiment. When operating in expansion mode, flow control is more limited. A needle valve (9) is placed downstream of the Fig.3. Pictureofthecompression/expansionchamber. 44 B.Yanetal./AppliedEnergy154(2015)40–50 areatT (cid:5)300K.Forcompression,constantflowratecompression 0 experiments from 1bar pressure and T temperature to 10bar 0 10 mm ABS 5 mm ABS 2.5 mm ABS 10 PPI 40 PPI were conducted at various compression times and with different Interrupted Interrupted Interrupted Aluminum Aluminum Plate Plate Plate Foam Foam inserts.Forexpansion,expansionexperimentsfrom12barandT0 to2barareconductedforarangeofexpansiontimesandwithdif- ferentinserts.Sinceexpansionflowratescannotbeactivelycon- trolled, expansion times are varied by adjusting the downstream orifice for each run. The orifice opening area is constant during eachrun,however. Baseline tests with no porous media inserts were conducted first.Forcompression,16experimentalrunsatdifferentflowrates, andhencepowerdensities,wereperformed.Ambientpressureand Fig.4. Fivetypesofporousinsertsusedincompression/expansionexperiments. temperaturewereusedasinitialconditions.Theinitialairvolume was typically 715cc. Exceptions were the shortest time, highest inertialforce);atlowflowrates,theloadcellisused(theflowrates power density cases when a smaller initial volume (410cc) was areoutofrangeoftheturbinemeter). used.Thisisduetolimitedpumpflowcapability.Effectsofdiffer- Thecompression/expansionchambercanbesafelypressurized encesininitialvolumearefactoredoutbyconsideringpowerden- upto12bar.Forcompressiontests,airiscompressedfromambi- sityinsteadofpower.Thedatatakenwhenthepressureisabove ent pressure to a pressure ratio of 10. For expansion tests, com- 10bar werediscarded. Powerdensities ranging from 3kW/m3 to pressed air at approximately 12bar is expanded to a final 180kW/m3weretested.Forexpansion,6experimentalrunsatdif- pressure of approximately 2bar. A pressureratio of 6 is used for ferent expansion times were performed by adjusting the down- all expansion tests. Thus, P ¼1 bar for compression, and stream orifice for each run. Initial pressure of 12bar, ambient 0 P ¼2barforexpansion.Thissetupiscapableofcompressionrates temperature and initial air volume of (cid:5)100cc were used in all 0 from 46.7cc/s to 275cc/s and (peak) expansion rates up to cases.Thedatatakenwhenthepressureisbelow2barweredis- 275cc/s. carded. Power densities ranging from 29kW/m3 to 223kW/m3 Thecompression/expansionchamber(1)canaccommodatevar- weretested. iousporousmediainserts.Fivedifferentporousinsertsareconsid- Testing with porous media inserts proceeded similarly as for ered in these tests: two metal foams and three interrupted-plate the baseline cases and over a similar range of power densities. styles, as shown in Fig. 4. Table 1 compares some of the insert For compression, all five porous media inserts shown in Fig. 4 properties. The metal foams used in these studies are open-cell andTable1weretested.Theentirechamberwasfilledwithporous aluminumfoamswith40poresperinch(PPI)and10PPI(Duocel media. Accounting for the insert volumes, the initial air volumes foamsfromERGAerospaceCorp.Oakland,CA).Thesefoamshave were 600–670cc., except for the highest power density cases, anominalporosity(i.e.theproportionofvoidvolumetototalvol- which were 350–460cc. For expansion, only the interrupted- ume)of93%.Theinterrupted-platesaremodeledafterthedesign plateinsertswith2.5mmand5.0mmplatespacingweretested. proposedin[24]andarefabricatedinABSplasticusinga3Dprint- Also, a small gap was left at the top of the chamber so that the ingprocess.Theinterruptedplatesdisruptandrestartthebound- arylayerssothatheattransferisenhanced.Theiropenstructures enablelow liquidflowdragand low tendencytotrap water.The threeinterrupted-platedesignshaveanominalplatethicknessof 0.8mm and a nominal plate length of 7.5mm. The inter-plate spacings of the three inserts are 2.5mm, 5.0mm and 10.0mm. Fig.5comparesthetotalsurfaceareafoundinthecompressor/ex- panderwhenthepistonisatbottomdeadcenter.Sincetheinserts aretobeplacedinthechamberuniformly,exceptforminoreffects oftheendcapareas,thedifferentinsertswouldhavetheeffectof scalingtheheattransfersurfaceareasnearlyuniformly. 4.Methods 4.1.Testingmethods Totesttheeffectofporousmediainsertsontheefficiencyand Fig.5. Totalsurfaceareaavailableattheonsetofcompression.Thisareainclude powerdensityinliquidpistoncompressionandexpansion,thefol- thetopcapandliquidpistonsurface. lowingtestswereperformed.Theambientandinitialtemperature Table1 Detailedpropertiesofporousinserts.Cellsizecorrespondstohydraulicdiameter.Specificareaistheratioofsurfaceareatovolume.Dataforthemetalfoamsareprovidedbythe manufacturer(ERGAerospace,OaklandCA)anddatafortheinterruptedplatesarecomputedfromCADmodels. Media Inserttype Material Cellsize(mm) Specificarea(m(cid:4)1) Porosity(%) 40PPI Metalfoam Aluminum 0.5 1732 92 10PPI Metalfoam Aluminum 2.0 709 93 2.5mm Interrupted-plate ABS 2.5 655 81 5mm Interrupted-plate ABS 5.0 377 88 10mm Interrupted-plate ABS 10.0 203 86 Baseline No-insert Polycarbonate 50.8 78.7 100 B.Yanetal./AppliedEnergy154(2015)40–50 45 Table2 Uncertaintyinexperimentalmeasurements. Measurement Instrument Measuringrange Measurementuncertainty Pressure ETM-375 0–17bar ±0.1%ofFullscale Flow FTB-1412 140–467cc/s ±0.6%ofReading Flow FTB-1412 47–140cc/s ±1.0%ofReading Flow Loadcell 0–100g/s ±0.5%ofReadingatsteady-state Initialairvolume Graduatedcylinder N/A ±2cm3(baseline) ±2.8cc(withInserts) Table3 Uncertaintyinefficiencyfortheoreticalcompressionandexpansiontrajectories. Baseline 2.5mm 5.0mm 10.0mm 10PPI 40PPI Errorinisothermalcompressionefficiency ±1.5% ±1.7% ±1.6% ±1.6% ±1.6% ±1.6% Errorinadiabaticcompressionefficiency ±0.9% ±1.0% ±0.9% ±0.9% ±0.9% ±0.9% Errorinisothermalexpansionefficiency ±1.2% ±1.2% ±1.2% N/A N/A N/A Errorinadiabaticexpansionefficiency ±0.4% ±0.4% ±0.4% N/A N/A N/A initialairvolumecouldbereadfromthegraduationsonthecham- 5.Results ber.Initialairvolumeswere(cid:5)100cc.Onlydatatakenatpressure below 10bar (for compression) and above 2bar (for expansion) 5.1.Typicalflowprofiles areusedfordataprocessing. Further details of the experimental setup and data processing The typical flow profiles for compression and expansion are canbefoundin[28]. shown in Fig. 6. As expected, the flow rates are nearly constant for the compression tests, as maintained by active control. For 4.2.Datareductionmethods expansion,becauseafixedorificeisusedforeachtest,theflowrate decreasesaspressuredecreases.Ideally,themaximumflowshould Liquid flow rates and pressures are obtained using the occur at the beginning. However, because the on/off valve takes Matlab/xPC Target Real-Time System (Mathworks, MA) and a sometimetofullyopen,theflowrateincreasescontinuouslyfrom 16-bitdataacquisitioncardatasamplingrateof1kHz.Airvolume zerotoamaximumflowinstead. iscalculatedfrom: Z t VðtÞ¼V0(cid:4) FlowðsÞds ð13Þ 5.2.Pressure–volumeandtemperature-volumeprofiles 0 whereV0istheinitialairvolumeandFlowðsÞistheliquidflowrate. 5.2.1.CompressionP–V/T–V Bulkairtemperatureisobtainedfromtheidealgaslaw: Thepressure–volumeandtemperature–volumeprofilesforthe baseline compression tests with different compression times are TðtÞ PðtÞVðtÞ ¼ ð14Þ shown in Figs. 7 and 8. As compression time decreases, the P–V T P V 0 0 0 and T–V profiles tend from being close to the isothermal profiles Theworkinput,Win,workoutput,Wout,efficiencies,gc andge and towardstheadiabaticprofiles. power-densities,q andq ,areobtainedfromnumericalintegration Typicaleffectsofdifferentinsertsonthepressure–volumeand c e oftheP–Vtrajectory,andfromEqs.(1)–(7). temperature–volumeprofilesforthecompressiontestsoversimi- lartimesareshowninFigs.9and10.Curveswithothercompres- 4.3.Uncertaintyanalysis siontimeshavesimilartrends.Theseshowthattheintroductionof inserts shifts the profiles towards the isothermal profiles. It is Theuncertaintiesofthemeasuredvariablesaresummarizedin apparent that the 10mm and 5mm interrupted-plates are the Table2.Pressure,volumeandtemperatureareessentialinthecal- leasteffectiveinserts. culationofefficiencyandpower.Ofthese,pressureisknownwith Atcompressiontimeof2s,insertsreducepeaktemperatureby themostcertainty,asitismeasureddirectly.Standarderrorprop- 90–120K (57–75% of the temperature rise in the baseline empty agation analysis shows that air volume and temperature are cylindercase). ComparisonbetweenFigs.8and 10showsthatto knownwithsomewhatlesscertainty.Forexample,theworstcase limittemperaturerisetoT =10withoutanyinserts,acompression 0 pressure error is at the initial (ambient) pressure (1.7%, time of 60s is needed. However, with the use of inserts (40PPI, (cid:6)0:017bar)andtheworstcasevolumeerrorisattheendofcom- 10PPIfoams,and2.5mminterrupted-plates),compressiontimes pression(6.1%,(cid:6)4:3cc). canbereduced30timesto2s,hencesignificantlyimprovingcom- To estimate the impact of measurement uncertainties on the pactness.WhilethegeneraltrendoftheT–Vprofilesisthattem- estimate of efficiencies, adiabatic and isothermal compression perature increases monotonically as volume decreases, at small andexpansionprocessesareconsidered.Theserepresenttheslow- volume there are some small deviations. These deviations are estandfastestcaseswithefficienciesthatcanbecalculatedanalyt- likelyduetotheslightdropinflowattheendofthecompression ically,andthuspresentgoodboundsonthepossibleuncertainties. cycle (for the no-insert 2s case in Fig. 8). The increase in heat By perturbing these trajectories by the estimated errors in pres- transfersurfaceareatovolumerationeartheendofcompression, sure, volume and temperature, uncertainties in efficiency esti- sincethecapandliquidpistonsurfaceareasareunchangedwhen mates are obtained. Results are summarized in Table 3. thevolumesaresmall,andtheeffectofwaterevaporatingastem- Uncertainty values in efficiency are highest when the process is peratureincreasesarealsopossiblereasons.Theseeffectsbecome closetoisothermal(whenflowrateislow),butuncertaintyvalues moreapparentwheninputworkisrelativelysmall(lowcompres- areroughlythesameforthedifferentinserts. sionratesorgoodheattransfer). 46 B.Yanetal./AppliedEnergy154(2015)40–50 300 1.5 no insert 2s no insert 6s no insert 14s 250 2s compression time 1.4 no insert 23s s) no insert 60s 3/ m200 2s c 1.3 e ( 6s compression time 6s at n R150 T0 23s ssio 14s compression time T(t)/1.2 14s e mpr100 o 1.1 C 23s compression time 50 1 60s 0 5 10 15 20 25 Time(s) 0.9 0 0.2 0.4 0.6 0.8 1 V(t)/V0 300 Fig. 8. Temperature–volume profiles for baseline compression cases without 2s expansion time insertsatvariouscompressiontimes. 250 3m/s)200 4s expansion time 10 c e ( at 5s expansion time R150 on 5 Expansi100 7s expansion time e ratio I4s0opthpei r2msal ur 10ppi 2s s 50 Pres 25.m5mm mp laptlaet e2 s2s 2 10mm plate 2s 0 no inserts 2s 0 1 2 3 4 5 6 7 8 Time(s) Adiabatic Fig.6. Typicalcompression(top)andexpansion(bottom)flowrateprofiles. 1 0.1 0.2 0.5 1 V(t)/V0 10 Fig. 9. Pressure–volume profiles for compression cases with different inserts at Adiabatic similarcompressiontimesof2s. no insert 2s Increasing time no insert 6s no insert 14s 1.6 5 no insert 23s no insert 60s 1.5 No insert Isothermal o 2 sec compression e rati 1.4 ur ess 0 1.3 Pr 2 T(t)/T 1.2 10mm5 mm 1.1 12.5 mm 10ppi 40ppi 10 .1 0.2 0.5 1 0.90. 1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 V(t)/V0 V(t)/V0 Fig.7. Pressure–volumeprofilesforbaselinecompressioncaseswithoutinsertsat Fig.10. Temperature–volumeprofilesforcompressioncaseswithdifferentinserts various compression times. Isothermal and adiabatic profiles are added for atsimilarcompressiontimesof2s. comparison. processes with constant flow rates follow, nearly, a polytropic ItisinterestingtonotefromFigs.7and9thattheP–Vcurvesfor process: all compression times, with and without inserts, are close to straight lines on a log–log scale. This indicates that compression PðtÞVkðtÞ¼constant B.Yanetal./AppliedEnergy154(2015)40–50 47 wherethe(cid:4)kistheslope.Forisothermalandadiabaticprocesses,k 1 is1andtheratioofthespecificheats.SinceinputworkW andeffi- in 5/6 Isothermal ciencyg becomefunctionsonlyofthepolytropicindex,thissimpli- c 2.5 mm 7s fication allows us to compare, according to (12), different 2/3 Adiabatic 5.0 mm 7s compressionprocesseswithdifferentcompressiontimesanddiffer- No Insert 8s entinsertscasesthathavethesameefficiencies. 2.5 mm Adiabatic 1/2 P0 5 mm 5.2.2.ExpansionP–V/T–V P(t)/ Thepressure–volumeandtemperature–volumeprofilesforthe 1/3 Isothermal expansiontestsareshowninFigs.11–14.Inallcases,asevidenced inboththeP–VandT–Vcurves,theinitialportionofexpansionis close to the adiabatic process, whereas the latter portion tends No insert towardtheisothermalprocess.Thisshapeisaconsequenceofflow ratesdecreasingaspressuredecreases(Fig.6-bottom).Forsuchflow profiles,expansionworkislargeinthebeginningandmuchsmaller 1/61 2 3 4 5 6 V(t)/V towardsthelatterportionoftheexpansion.From(8)and(9),high 0 heattransferratesarenecessarytomaintaintheairtemperature,ini- Fig. 13. Pressure–volume profiles for expansion cases with different inserts at tially.Itiseasiertodosotowardstheendofexpansionduetothe similarexpansiontimesof(cid:5)7s. lowerpowerandlargerexposedsurfaceareaforheattransfer. Figs.11–14alsoshowthatforslowerexpansions(longerexpan- siontimes)andwiththeintroductionofinserts,transitiontothe 1 isothermal process occurs at smaller volumes. It is also apparent 2.5mm 2.4s 0.95 5.0mm 2.4s that the 2.5mm interrupted-plate insert is more effective than No Insert 2.1s the5mminterrupted-plateinserts.ComparisonbetweenFigs.12 0.9 and14showsthattolimittheminimumtemperatureto0:85(cid:3)T 0 T0 T(t)/ 0.85 1 Isothermal 0.8 5/6 Adiabatic no insert 3s 0.75 2/3 no insert 8s no insert 16s 0.7 1 2 3 4 5 6 1/2 V(t)/V0 P P(t)/ Fsiimg.il1a4r.eTxepmanpseiroantutirme–evsoolufm(cid:5)e2p:2rosfi.lesforexpansioncaseswithdifferentinsertsat 1/3 I6s 3s withoutanyinserts,anexpansiontimeof8sisneeded.Withthe useofinserts,expansiontimescanbereducedmorethan3times 8s tolessthan2.5s. Notethatfortheexpansionprocesswiththeorificedetermined 1/61 2 3 4 5 6 flowprofiles,theP–VandT–Vdatadonotfitapolytropicmodel,as V(t)/V0 intheexpansioncasewithconstantflowprofiles. Fig.11. Pressure–volumeprofilesforbaselineexpansioncaseswithoutinsertsat variousexpansiontimes. 5.3.Efficienciesandpowerdensities 1.05 Efficiencies and power densities are calculated according to no insert 3s Eqs.(4)and(5)andareplottedagainsteachotherinFigs.15and no insert 6s 6s 16 for the compression and expansion tests, respectively. Error 1 no insert 8s no insert 16s bars(estimatedfromSection4.3)indicatelevelsofuncertainties. Figs. 15 and 16, show that the insert cases are more power denseatthesameefficiency,andmoreefficientatthesamepower 0.95 16s T0 density,thanthebaseline(noinsert)cases.Specifically,foracom- T(t)/ pressionefficiencyof95%,powerdensityisincreasedbyafactorof 0.9 10–37(with10mmplatesand40PPIfoam)atthesameefficiency. Similarly,forafixedexpansionefficiencyof89%,expansionpower density is increased by a factor of 3 with the use of inserts. The 0.85 8s 3s inserts can alsobe seen as improving efficiency for a given power density.Atthepowerdensityof100kW/m3,thecompressioneffi- ciencywasincreasedfrom78%to96%withtheadditionofporous 0.8 1 2 3 4 5 6 media (40PPI Al foam). At a power density of 150kW/m3, the V(t)/V0 expansionefficiencywasincreasedfrom83%to90%withtheaddi- tion of porous media (2.5mm interrupted-plates). These improve- Fig.12. Temperature–volumeprofilesforbaselineexpansioncaseswithoutinserts atvariousexpansiontimes. ments areexpected becausethe inserts provide moresurface area 48 B.Yanetal./AppliedEnergy154(2015)40–50 casesinFigs.17and18,respectively.Thisnormalizedpowerden- sityisalsothemeanpowerpersurfacearea.Byusingthetotalvol- umetodefinethespecificsurfacearea, thenegativeeffectofthe inserts occupying more volume (which can affect power density by 8–20%, depending on porosity)is also factored out. While the areasofthetopcapandtheliquidpistonsurfaceareincluded,their contributions are relatively small (except when the volume has become small). The difference in specific surface areas between compression and expansion cases is due to the gap between the topcapandtheinsertsintheexpansioncases. Inthecaseofcompression,Fig.17showsthataftersurfacearea isaccountedfor,thecaseswithporousinsertscollapsetoapprox- imatelythesamecurve.Particularly,at95%efficiency,thenormal- ized power densities lie between 0.1kW=m2 and 0.16kW=m2, within the range of data scatter. On the other hand, the baseline no-insertcaseisnoticeablylowerat0:045kW=m2.Thedifference isevenmorepronouncedatlowerefficiencies. Intheexpansioncase,Fig.18showsthattheefficiencyvs.nor- malizedpowerdensitycurvesforallcases(includingtheno-insert cases)alsocollapsetoapproximatelythesamecurve.However,the differencebetweeninsertandno-insertcasesdoesnotseemtobe significant. Because the compression processes (with the constant flow rates) are nearly polytropic, each experiment with the same effi- ciencywillhavesimilarP–V/T–Vcurves.From(12),thisnormaliza- tion allows other factors affecting heat transfer beyond surface area,suchasheattransfercoefficient,h,andheatexchangertem- perature, T , to be compared. Because the expansion processes 0 (with orifice flow control) are not polytropic, the comparison is more approximate, as the same efficiency does not necessarily implythesameP–V/T–Vcurves,andhence,thesameLHSof(12). Fig.15. Compressionefficienciesvscompressionpowerdensityforvariousinserts (pressureratio=10).Top:Allcases.Bottom:Expandedviewoftheinsertcases. Fig.16. Expansionefficiencyvs.expansionpowerdensityforbaselineandinsert cases(pressureratio=6). forheattransfer.Theorderofdecreasingeffectivenessoftheinserts to improve efficiency/power density in compression are: (1) 40PPI-foam, (2=) 10PPI-foam or 2.5mm plates, (4) 5mm plates, (5) 10mm plates, (6) no-inserts. For expansion, the order is: (1) 2.5mmplates,(2)5mmplates,(3)no-inserts.Theseorderscorrelate exactlywiththesurfaceareasprovidedbytheseinsertsinFig.5. 5.4.Efficienciesandpowerdensitiesnormalizedbyspecificsurface area To further investigate the role of surface area increase in performanceimprovement,efficienciesare plottedagainstpower Fig.17. Compressionefficiencyvs.powerdensitynormalizedbyspecificsurface densitiesnormalizedbythevolumespecificsurfacearea(i.e.ratio areaforvariousinsertsandcompressiontimes(pressureratio=10).Top:Allcases. ofsurfaceareatototalvolume)forthecompressionandexpansion Bottom:Expandedviewofhighefficiencyregion. B.Yanetal./AppliedEnergy154(2015)40–50 49 trajectory optimization, however, since the experiments in [12,13]wereperformedwithoutinserts. Whiletheexperimentsinthispaperhighlighttheheattransfer benefits,especiallytheincreasedsurfaceareaprovidedbythepor- ous media inserts, other aspects of the porous media need to be consideredwhenchoosingaporousmedium.In[19],longnarrow cylinderswereanalyzedforliquidpistonapplications.Preliminary experiments in [26] have shown that while these provide good heattransfer,differencesindraginsideandbetweenthecylinders induce unwelcome water jets. The open cell foams and interrupted-platesinthisstudyavoidthisissue.Themetalfoams wereselectedinthisstudyfortheirisotropicpropertiesandhigh porosity. The interrupted-plates were selected because of their interruptedboundarylayerfeatures,whichofferedpromisingflow featuresforheatexchangersandlowerdrag. Fig.18. Expansionefficiencyvs.powerdensitynormalizedbyspecificsurfacearea Porousmediamaterialsalsohavedifferentthermalconductivities forvariousinsertsandcompressiontimes(pressureratio=6). and thermal capacitances. The thermal conductivity of the Aluminium foam (167W/mK) is 1000 times higher than that of Theseresultssuggestthatsurfaceareaisindeedthemostimpor- theABSplasticinterruptedplates(0.19W/mK).Resultsinthispaper tantfactorforincreasingefficiencyandpowerdensity.Thefactthat suggestthatattherelativelylowpressureratiosof6–10,thesedif- thenormalizedcurvescollapsetoasinglecurveimpliesthatallthe ferencesinconductivitiesand capacitances donothavesignificant inserts have similar effects, if any, on factors other than area that effects.Forexample,theABS2.5mminterruptedplatesandtheAl mayinfluenceheattransfer.Astheno-insertcasehasalowernor- 10PPIfoamhave similarsurfaceareas(Table1)butverydifferent malizedpowerdensitythantheinsertcasesatthesameefficiency, thermalconductivities.Takingporosityintoaccount,theheatcapac- theinsertcasesshowgreaterpositiveinfluenceontheseotherfactors itanceperunitairvolumeoftheABSplatesis2.3timesthatoftheAl thanno-insertcaseincompression.Apossibleexplanationisthatthe foam. Yet, theirperformances interms ofefficiency/power density porousmediaprovidemanysmallfeaturestointerrupttheflowand trade-off are not discernable from the data scatter in Figs. 15 and encourage new boundary layers to develop. The small hydraulic 17.Tounderstand whyperformanceis insensitive tothermalcon- diameters in the porous media also induce higher local velocities. ductivity, consider the (worst) cases with the fastest flow rates Bothcancauseheattransfercoefficients,h,toincrease.Anotherpos- (2s).Usingtheheattransfercorrelationsformetalfoaminvestigated sibilityisthattheheattransfersurfacesmayhaveheatedmoreinthe in[25],andfortheinterruptedplatesin[24],itisfoundthattheBiot no-insertcasethanintheinsertcase,thusincreasingtheT onthe 0 numberisoftheorderof10(cid:4)4fortheAlfoamandrangesfrom0.03 LHSof(12)anddecreasingthetemperaturegradient. to0.2fortheABSinterruptedplates.Thus,theAlfoamcanreason- ablybeconsideredasalumpedthermalmassbutthevalidityofthis assumption is not as clear for the interrupted plates. To further 6.Discussion investigatethisissue,zero-dimensional,two-energy-equations(both the air and the porous medium exposed to air are considered as Theresultsdescribedaboveshowclearlythatporousmediacan lumped masses) simulations are performed for the 2.5mm inter- significantly improve the trade-off between efficiency and ruptedplatecaseusingaslightlymodifiedheattransfercorrelation power-densityofaliquidpistoncompressor/expander.Theexper- proposedin[24]3andthevolumeprofilesfromtheexperiment.The imentsalsoshowthattheimprovementcanbeexplainedpredom- predictedtemperatureprofilematchestheexperimentwellwiththe inantlybytheincreaseinheattransfersurfaceareaintroducedby predicted efficiency (92.98%) matches that of the experiment theporousmedia.However,thepressureratiosinthesetestsare ((cid:5)93%). The predicted rise in porous medium temperature is only relatively low compared to the applications of compressed air 0.45K.Whentheplatesareassumedtobe1/4oftheiroriginalthick- energy storage or compressed natural gas for which pressures of ness of 0.8mm so that the Biot number would be comfortably less 200–300barareexpected.Thus,futureexperimentsmustconsider than0.1,thetemperaturerisebecomes1.8K.Thischangeintemper- higherpressureratios. ature rise decreases efficiency negligibly (from 92.98% to 92.89%). Theuseoffamiliesofconstantflowrates(forcompression)and Thesesmallmediatemperatureincreasesareconsistentwiththe2D orifice flows (for expansion) in the experiments simplifies the CFD simulations for metal foams and ABS interrupted plates in experimentalconditionstobetterisolatetheeffectsoftheporous [25,29] respectively. This analysis shows that because the thermal media within the flow control constraint of the experimental capacitanceissufficientlylargecomparedtothethermalenergyand setup.Asshownin[9–11]analytically,and[12,13]experimentally, theheattransfercoefficientsintheselowpressureratioexperiments, an optimized flow trajectory can significantly improve perfor- theeffectofthermalconductivitiesisinsignificant.Forlargerpressure mance of compression/expansion processes. Judicious choice of ratios,forexampleforour2ndstagesetup(7–210bar),theeffectof trajectories can also mitigate the effect of liquid pressure drop conductivitybothintheaxialandtheradialdirectionswouldbemuch whilemaximizingoverallperformance[11].Anoptimizedprofile more significant as the thermal energy and the heat transfer coeffi- typicallyconsistsofsegmentsofhighflowsatthebeginningand cientswillbeatleast1orderofmagnitudehigher. at the end of the process, and a slow (nearlyisothermal)portion Anotheraspecttobeconsideredisthelikelihoodfortheporous inthemiddle.Inthisregard,theorificeflowprofilesinexpansion mediatotrapwaterorair.Thisreducesthevolumetricefficiencyof resemble optimizedprofiles moreso than theconstant-flowpro- the compressor/expander as it prevents the ejection of the com- files in compression (see Fig. 6). This may explain partially why pressed air and the intake of fresh ambient air. In this respect, the baseline efficiency in expansion is higher than the efficiency despite their thermal characteristics, the 40PPI and 10PPI metal incompressionatsimilarpowerdensities,andthatthesubsequent improvement due to adding porous media is less dramatic in expansion than in compression. Further experiments are needed 3 ThecorrelationusedisNu¼2þ0:0876(cid:3)Re0:792(cid:3)Pr1=3.Thebiastermin[24]is9.7 to clarify the combined benefits of porous media inserts and insteadof2andtheoreticallyshouldbe1.Themodificationfitsthedatamuchbetter.

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