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Evolution of Karst in the Lower Part of Crna Reka River Basin PDF

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Springer Theses Recognizing Outstanding Ph.D. Research Marjan Temovski Evolution of Karst in the Lower Part of Crna Reka River Basin Springer Theses Recognizing Outstanding Ph.D. Research Aims and Scope The series “Springer Theses” brings together a selection of the very best Ph.D. theses from around the world and across the physical sciences. Nominated and endorsed by two recognized specialists, each published volume has been selected foritsscientificexcellenceandthehighimpactofitscontentsforthepertinentfield of research. For greater accessibility to non-specialists, the published versions includeanextendedintroduction,aswell asaforewordbythestudent's supervisor explainingthespecialrelevanceoftheworkforthefield.Asawhole,theserieswill provide a valuable resource both for newcomers to the research fields described, and for other scientists seeking detailed background information on special questions. Finally, it provides an accredited documentation of the valuable contributions made by today’s younger generation of scientists. Theses are accepted into the series by invited nomination only and must fulfill all of the following criteria (cid:129) They must be written in good English. (cid:129) ThetopicshouldfallwithintheconfinesofChemistry,Physics,EarthSciences, Engineeringandrelatedinterdisciplinary fields such asMaterials,Nanoscience, Chemical Engineering, Complex Systems and Biophysics. (cid:129) The work reported in the thesis must represent a significant scientific advance. (cid:129) Ifthethesisincludespreviouslypublishedmaterial,permissiontoreproducethis must be gained from the respective copyright holder. (cid:129) They must have been examined and passed during the 12 months prior to nomination. (cid:129) Each thesis should include a foreword by the supervisor outlining the signifi- cance of its content. (cid:129) The theses should have a clearly defined structure including an introduction accessible to scientists not expert in that particular field. More information about this series at http://www.springer.com/series/8790 Marjan Temovski Evolution of Karst in the Lower Part of Crna Reka River Basin Doctoral Thesis accepted by the University of Nova Gorica, Slovenia 123 Author Supervisors Dr. Marjan Temovski Prof. AndrejMihevc Hertelendi Laboratoryof Environmental Research Centreof the SlovenianAcademy Studies ofSciences andArts Institute of Nuclear Research of the KarstResearch Institute HungarianAcademy of Sciences Postojna Debrecen Slovenia Hungary Prof. Philippe Audra University of Nice Sophia-Antipolis Nice France ISSN 2190-5053 ISSN 2190-5061 (electronic) SpringerTheses ISBN978-3-319-24545-4 ISBN978-3-319-24547-8 (eBook) DOI 10.1007/978-3-319-24547-8 LibraryofCongressControlNumber:2015950911 SpringerChamHeidelbergNewYorkDordrechtLondon ©SpringerInternationalPublishingSwitzerland2016 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpart of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission orinformationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilar methodologynowknownorhereafterdeveloped. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publicationdoesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexemptfrom therelevantprotectivelawsandregulationsandthereforefreeforgeneraluse. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authorsortheeditorsgiveawarranty,expressorimplied,withrespecttothematerialcontainedhereinor foranyerrorsoromissionsthatmayhavebeenmade. Printedonacid-freepaper SpringerInternationalPublishingAGSwitzerlandispartofSpringerScience+BusinessMedia (www.springer.com) Parts of this thesis have been published in the following journal articles: Temovski M., Audra Ph., Mihevc A., Spangenberg J., Polyak V., McIntosh W., BigotJ.-Y.(2013):HypogenicoriginofProvalataCave,RepublicofMacedonia:a distinct case of successive thermal carbonic and sulfuric acid speleogenesis. International Journal of Speleology, 42 (3), 235–264, Tampa, FL (USA). TemovskiM.(2013):KarstinMariovo—extension,characteristicsandimportance. Proceedings of the Symposium with international participation “Problems and perspectives of hilly-mountain areas”, 12–15.09.2013, Ohrid, Republic of Macedonia, Volume 1, 53–62, Macedonian Geographical Society. TemovskiM., Audra Ph., Spangenberg J.,Mihevc A.(2013):Hypogenic origin of Cave Provalata. Rare case of successive carbonic and sulfuric acid speleogenesis. 8th IAG International Conference on Geomorphology, 27–31.08.2013, Paris, France. TemovskiM.,AudraPh.(2013)EvolutionofCaveProvalata.Remarkableexample of hypogenic thermal carbonic and sulfuric acid speleogenesis. In: Filippi M., Bosák P. (Eds), Proceedings of the 16th International Congress of Speleology, 21–28.06.2013, Brno, Czech Republic, Volume 3, 412–417, Czech Speleological Society, Prague. Temovski M. (2013): Phantom speleogenesis in a thermal environment. 21st International Karstological School “Hypogene speleogenesis”, 10–14.06.2013, Postojna, Slovenia. TemovskiM.,AudraPh.(2011):CaveProvalata:firstexampleofahypogenecave in Macedonia. 19th International Karstological School “Dinaric Karst”, 20– 25.06.2011, Postojna, Slovenia. ’ Supervisors Foreword The thesis of Marjan Temovski is an important milestone, not only regarding the knowledge of the karst of Macedonia especially lower part of Crna Reka River Basin, but also more generally regarding advances in karst science. Firstly, this pioneer work now represents an essential work about the caves and karst in this lesser studied karst region and using classical and modern methods gives many new surprising data and details not forgetting the whole picture, the morphology, and the evolution of karst landscape. The author’s aim is to give a general overview of the spatial and temporal evolution of the chosen karst terrain. As the karst surface is missing distinctive morphology and correlative sediments, the only place to search for the evidence of the past evolution were caves. His comprehensive cave inventory with new surveys is integrated within the mostupdatedapproachesingeomorphology.Sincethisterrainisextremelydifficult to access without any access to huge areas and deep wild gorges, it will be for decadesafoundingcontributionthatmaybeusedbyscientist,suchasarcheologists and hydrogeologists, and by land managers. Onecanfindinthisbookalltypesofthecavegenesisthatarestudiedpresently worldwide. The per ascensum speleogenesis, evidenced by 100-m-high rising phreatic shafts, is related to an important base-level rise occurring during thePliocene with the filling of basins by volcaniclastic materials. It implies first that 1000-m-deep gorgespreexistedbeforethisburyingeventandthatthecurrentlandscapedynamic correspondstoanongoingexhumationandrejuvenationofthepaleolandscape.The problematicofthepossibleinfluenceoftheMessinianSalinityCrisisthattriggered the incision along the neighboring Vardar valleys is under investigation. The occurrence of deep phreatic “vauclusian” springs along the Vardar and its tribu- taries and the evidence of a major pre-Pliocene incision phase point toward an important impact of the Messinian event in the landscape building. Ongoing thoughts are currently orientated to include this geomorphologic process for the understandingoftheNeogenebasinsevolution,whichwereonlyconsideredbefore vii viii Supervisors’Foreword from the tectonic point of view. This base-level rise is not only responsible of the origin of deep phreatic cave passages: Aggradation phases first filled caves pro- ducing paragenetic features before complete burying, and then, new cave systems developed from allogenic runoff onto volcano-clastic covers following the pro- gressive clearing of the thick plio-quaternary covers. Timing of main events is basedondating(Ar/Ar,U/U,paleomagnetism),allowingnotonlytodateProvalata caveactivityandBudimiricacavefilling,butalsohelpingtotrackthemainphases of landscape evolution connected to the Crna valley incisions and fillings, espe- cially the Mariovo Lake draining. The genesis of caves by ghost-rock weathering is a hot subject within the karst community,wherespecialistsaredebatingabouttheoriginofthefluidsresponsible of this weathering, i.e., from the surface or from deep origin. Marjan Temovski displays here an important example of hypogene ghost-weathering in dolomitic marbles, where rising hydrothermal fluids first weathered the rock along fractures producingghost-rock,beforethissoftmaterialhasbeenwashedawaybyturbulent flow to produce the cave as it can be observed now. It will be an important contribution to the ongoing debate. The most outstanding result concerns the sulfuric acid speleogenesis (SAS) in Provalata Cave, which has been dated using Ar/Ar method on alunite and jarosite byproducts of SAS. Numerous other results are important and some have to be published. Several aspectsareannouncingfuturemajoradvances,namelythehypogenicspeleogenesis around sulfidic ores, the tracking of the Messinian Crisis milestones, and the cor- responding outlooks on Macedonian geomorphology which has been deeply renewed. Postojna Prof. Andrej Mihevc Nice Prof. Philippe Audra May 2015 Acknowledgments I would like to express my gratitude to everyone who helped and supported me during my doctorate studies. Iwouldespeciallyliketothankthementors,Dr.AndrejMihevcandDr.Philippe Audra, for their continuous support and numerous discussions, suggestions, and advicesofscientificandpersonalnature,aswellasprovidingmewithpossibilities of analyses, scientific contacts, and scholarships. I would also like to thank Dr. Pavel Bosak and Dr. Nadja Zupan Hajna for the fruitful discussions and help with paleomagnetic dating of sediments. A special thanks and acknowledgment goestoDr.AndrejKranjcforhiscontinuoussupportofyoungkarstologists,willing tohelpwheneverpossible.IamgratefultotheKarstResearchInstituteinPostojna and its members and employees for their hospitality, companionship, and discus- sions, making my visits in Postojna always pleasant. Forsupportandhelpwithfieldwork,IwouldliketothankZlatkoAngeleskiand otherfellowcaversfromSKZlatovrv—Prilep:DarkoNedanoski,DarkoJovanoski, and Mario Andonoski. Cavers and mountaineers from PSD Orle—Kavadarci, especially Nikola Minčorov and Jože Zmajšek are thanked for unselfish sharing of cave maps and locations. I would also like to thank SD Peoni—Skopje for pro- viding me with coordinates and cave map of Živovska Propast. I am extremely grateful to my parents Dragan and Biljana Temovski and my brother Ivan Temovski, for their unselfish and continuous support throughout my life and during my doctorate studies. ThisworkwaspartlyfundedbytheAdFuturaScholarshipforforeigndoctorate students in Slovenia (No. 11011-2/2009), and therefor I would like to thank the Slovene Human Resources Development and Scholarship Fund (Javni sklad Republike Slovenije za razvoj kadrov in štipendije) for their support. I would also like to thank the French Institute in Slovenia for receiving French GovernmentGrantin2010(No.702376F) and2013(No.786060J),whichfunded my research stay in Nice, France. ix Contents 1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.1 Foreword. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.2 Goals, Objectives and Approach . . . . . . . . . . . . . . . . . . . . . . . . 3 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 2 General Overview of the Research Area . . . . . . . . . . . . . . . . . . . . . 5 2.1 Geographical Location. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2.2 Previous Research. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 2.3 Geological Setting. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 2.3.1 Pre-Cenozoic Stratigraphy . . . . . . . . . . . . . . . . . . . . . . . 9 2.3.2 Main Tectonic Structures in the Pre-Cenozoic Rocks. . . . . 11 2.3.3 Cenozoic Stratigraphy and Tectonics. . . . . . . . . . . . . . . . 13 2.4 General Geomorphology . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 2.5 Climate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 2.6 Hydrography. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 2.7 Karst Extension. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 3 Methodology . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 3.1 Concepts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 3.1.1 Karst Evolution and Speleogenesis . . . . . . . . . . . . . . . . . 23 3.1.2 Epigenic Speleogenesis . . . . . . . . . . . . . . . . . . . . . . . . . 24 3.1.3 Hypogenic Speleogenesis. . . . . . . . . . . . . . . . . . . . . . . . 30 3.1.4 Karst and Caves in Conglomerates . . . . . . . . . . . . . . . . . 33 3.2 Research Methods. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 3.2.1 Morphological Analyses . . . . . . . . . . . . . . . . . . . . . . . . 34 3.2.2 Sediment Analyses . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 3.2.3 Water Analyses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 3.2.4 Cartographic Methods. . . . . . . . . . . . . . . . . . . . . . . . . . 37 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 xi

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