Equivalenceoftopologicalmirrorandchiralsuperconductivityinonedimension Eugene Dumitrescu1, Girish Sharma1, Jay D. Sau2, and Sumanta Tewari1 1Department of Physics and Astronomy, Clemson University, Clemson, SC 29634 2 CondensedMatterTheoryCenter,DepartmentofPhysics,UniversityofMaryland,CollegePark,MD20742 Recentlyithasbeenproposedthataunitarytopologicalmirrorsymmetrycanstabilizemultiplezeroenergy Majorana fermion modes in one dimensional (1D) time reversal (TR) invariant topological superconductors. Hereweestablishanexactequivalencebetween1D“topologicalmirrorsuperconductivity”andchiraltopologi- calsuperconductivityinBDIclasswhichcanalsostabilizemultipleMajorana-Kramerspairsin1DTR-invariant topologicalsuperconductors. Theequivalenceprovesthattopologicalmirrorsuperconductivitycanbeunder- stoodaschiralsuperconductivityintheBDIsymmetryclassco-existingwithtime-reversalsymmetry. Further- 5 more, weshowthatthemirrorBerryphasecoincideswiththechiralwindinginvariantoftheBDIsymmetry 1 class, which is independent of the presence of the time-reversal symmetry. Thus, the time-reversal invariant 0 topological mirror superconducting state may be viewed as a special case of the BDI symmetry class in the 2 well-knownAltland-Zirnbauerperiodictableoffreefermionicphases. Weillustratetheresultswiththeexam- n plesof1Dspin-orbitcoupledquantumwiresinthepresenceofnodelesss superconductivityandtherecently ± a discussedexperimentalsystemofferromagneticatom(Fe)chainsembeddedonalead(Pb)superconductor. J 5 Introduction : Mirror symmetry, when coupled with time- symmetry. We then establish an exact equivalence between ] reversal(TR)andparticle-hole(PH)symmetries,hasrecently “mirror Berry phase”1 used to justify the presence of multi- l l beenproposed1tostabilizeaone-dimensionaltopologicalsu- ple MKPs in DIII systems and the integer winding number a perconductingphasewithanintegernumberofspatiallyover- invariant ofthe BDIclass25. However, the winding invariant h - lappingzeroenergyMajoranafermionmodes. Thenumberof fortheBDIclasscontinuestobewell-definedandunchanged s Majorana edge modes in a so-called “topological mirror su- evenwhenthetime-reversalsymmetryisbroken. Theequiva- e m perconductor” is indexed by a mirror Berry phase γm Z lenceprovesthat“topologicalmirrorsuperconductivity”1can ∈ which was defined in Ref. 1. Mirror symmetry and a mirror beviewedasbelongingtotheBDIsymmetryclassinthewell- . t Berry phase topological invariant have been used to theoret- known periodic table of Altland-Zirnbaur classification of a m ically explain the existence of multiple Majorana modes in freefermionicphases4–6andthattheco-existingtime-reversal heterostructure based topological superconductors involving symmetrydoesnotqualitativelymodifythetopologicalphase. - d a proximity induced s±-wave pairing potential on spin-orbit Therefore, in one dimension the chiral BDI symmetry is in n coupled semiconductor wires1. A mirror symmetry has also factmoregeneralthanmirrorsymmetryinthesensethatper- o beenrecentlyinvokedtodiscussthetopologicalpropertiesin turbationswhichbreakboththesymplecticTRsymmetryand c thecontextofferromagneticatomicchainsembeddedonthe topological mirror symmetry may keep the chiral symmetry [ surfaceofaPbsuperconductor2,3. invariant,allowingmultipleMajoranafermionmodesevenin 1 Topological classification based on a unitary mirror sym- theabsenceofmirrorsymmetry. Incontrast,chiralsymmetry v metry aims to extend the Z -invariant of the DIII symmetry breakingtermsalsonecessarilybreakeithermirrorortimere- 2 5 class to allow the existence of multiple Majorana Kramers versalsymmetry(undereitherofthesecircumstancesthemir- 8 pairs(MKPs)1. IntheAltland-Zirnbauerframeworkofclassi- rorBerryphasecannotbedefined1)andthereforetopological 9 0 ficationoffreefermionicphases4–6, Majoranafermionshave mirrorsymmetrycannotbethoughtofasanindependentsym- 0 beenpredictedtooccurasedgestatesinlowdimensionalsys- metryinone-dimension. . temsbelongingtothetopologicalclassesD7–14,DIII15–25,and Mirror versus chiral symmetric systems: In this paper we 1 0 BDI26–33. Thisraisesthefundamentalquestionofwhetheror will consider a superconducting system with particle-hole 5 notmirrorsymmetryinonedimensionrefinesthetopological symmetryΞandtime-reversalsymmetryΘ. Superconducting 1 classification in the Altland-Zirnbauer framework, and if so, systems with mirror symmetry for which the “mirror Berry : is mirror symmetry a critical ingredient for the protection of phase”isdefined1 haveanadditionalunitarysymmetryoper- v i MKPsintime-reversalinvariantDIIIsystems? Inonedimen- ator such that [ ,Θ] = [ ,Ξ] = [ ,H] = 0 (where X sionitiswellknownthatthechiralBDIsymmetryclassalso H isMthe BdG HamMiltonian foMr which exMplicit examples are r supports an arbitrary number of Majorana end modes due to discussed in later sections) and 2 = 1. On the other a itsZinvariant26,27,32and,withconcurrentTRsymmetry,stabi- hand,systemsinthechiralBDIsyMmmetryc−lasshaveapseudo lizesmultipleMajorana-Kramerspairs25 asedgemodes. Itis timereversaloperator (with 2 =1)whichincombination thereforenaturaltoaskhowthesetwosymmetries(mirrorand withtheparticle-holesOymmetrOyΞdefinesachiralityoperator chiral),whichbothproducemultipleMKPsinthepresenceof =Ξ withtheproperties 2 =1, ,H =0,[Θ, ]=0. concurrent TR, are related andinvestigate the conditions un- CNoteth·aOtwehaveassumedheCrethatt{hCetwo}time-reverCsalop- derwhichtheymaydiffer,ifatall. erators and Θ commute. From these definitions it is clear O In this work we formulate a general procedure illustrat- thatwhentheseBDIsymmetryoperatorsarepresentonecan ing how the presence of mirror symmetry promotes a one- definea“mirror”operator = Θ,whichsatisfiesallthe M O· dimensionalclassDIIItopologicalsuperconductortothechi- properties mentioned for the Mirror operator. Alternatively ral topological class BDI that co-exists with a time-reversal for systems with time-reversal and mirror symmetry one can 2 definethepseudo-timereversal =Θ ,whichisrequired connectionofthetwochiralHamiltoniansarerelatedby O ·M tocharacterizesystemsintheBDIsymmetryclass.Therefore, (cid:88) superconducting systems with TR and BDI symmetries have a(k,θ =0)= f n,k ∇ n,k (7) n k (cid:104) | | (cid:105) thesameoperatorcontentassystemswithTRandmirrorsym- n metries. =(cid:88)f n,k Z(k)†∇ [Z(k)n,k ] (8) n k 0 EquivalenceofmirrorBerryphaseandBDIwindingnum- (cid:104) | | (cid:105) n ber: The topological invariant associated with the BDI sym- (cid:88) =a (k,θ =0)+ f n,k [Z(k)†∇ Z(k)]n,k (9) metryi.e. thewindingnumberfor coincideswiththemirror 0 n k 0 (cid:104) | | (cid:105) BerryphasedefinedinRef.[1]arCealsorelated. Toseethis, n wefollowRef.[1]todefinethemirrorBerryphaseanddefine =∂kArg[Det(U(k)V†(k))]=∂kArg[Det[Q(k)]]. (10) afamilyofHamiltoniansparametrizedbyθas Therefore the integral of the Berry connection, which is re- H(k,θ)=H(k)cosθ+ sinθ. (1) lated to the mirror Berry phase, is the same as the winding C numberinvariantoftheBDIclass. Noteherethatwehaveintroducedaslightmodificationtothe Example 1: Spin-orbit coupled nanowire proximity cou- definitionusedinRef.[1],whereforthechiralityoperatorwe pled to s± superconductor: As a concrete example, we il- haveused =Π insteadofΠ=iΘ Ξ.Butsince com- lustrate the equivalence of topological mirror and chiral su- muteswithCH thi·sMisessentiallyequival·entapartfromMthefact perconductivity for a system consisting of a spin-orbit cou- thatwiththistransformation,themirrorBerryphaseinRef.[ pled semiconductor nanowire with proximity induced s±- 1] becomes the total Chern number of H(k,θ) . The Chern wavesuperconductivity1. Inprinciplethismaybeexperimen- numberisgivenbyintegratingthecurvatureoftheBerrycon- tally achieved by depositing an InSb nanowire onto an Iron nectionandusingStokestheoremisrelatedtotheintegralof based superconductor with a sign changing extended s-wave theBerryconnectionwrittenas orderparameter. TheeffectiveBogoliubov-deGennes(BdG) Hamiltonian for the nanowire with proximity induced super- a(k,θ)=(cid:88)fn n,k,θ ∇θ,k n,k,θ (2) conductivityisH =(cid:80)kΨ†kH(k)Ψk where, (cid:104) | | (cid:105) n H(k)=( 2tcos(k) µ)σ τ +α sin(k)σ τ (11) 0 z R y z − − atθ = 0,where n,k,θ arewave-functionsparametrizedei- +∆scos(k)σ0τx. | (cid:105) theronthetopHemisphereπ/2>θ >0orthebottomHemi- Here k k is the 1D crystal momentum and Ψ = sphere−π/2<θ <0. (c ,c ,≡c† x, c† )T is a four component Nambu spkinor TheHamiltonianH(k)isoff-diagonalwithanoff-diagonal k↑ k↓ −k↓ − −k↑ acting in the τ (particle-hole) and σ (spin) spaces. Addi- matrixQ(k)as tionally, t is the nearest neighbor hopping, µ is the chemi- (cid:18) (cid:19) calpotential,α isthestrengthofRashbaspinorbitcoupling 0 Q(k) R H(k)= Q(k)† 0 (3) (whichwehavenchosentobealongyˆwithoutlossofgener- ality)and∆ istheproximityinducedpairpotential. s AswithanysuperconductingmeanfieldBdGHamiltonian inthebasiswhere isdiagonalandhasawindingnumber definedintermsofCthephaseArg(det(Q(k)))26. ThematrWix Eq. (11) is invariant under a particle-hole transformation de- notedbytheoperatorΞ. ThePHconstraintforBlochHamil- Q(k)canalsobedecomposed(singularvaluedecomposition) tonians is ΞH(k)Ξ−1 = H( k) and the anti-unitary PH as − − operator in our basis is given by Ξ = σ τ . In addi- y y K Q(k)=U†Σ V , (4) tion to belonging in the time reversal symmetry class DIII k k k with a Z invariant (by virtue of the time-reversal symme- 2 try ΘH(k)Θ−1 = H( k) where Θ = iσ τ with the whereU ,V areunitaryandΣ isapositivediagonalmatrix. y 0 k k k − K K complexconjugationoperator),theHamiltonianinEq.(11)is The Hamiltonian H(k) can be transformed using a unitary alsoinvariantunderamirrorsymmetry1 = iσ τ since transformation y 0 H(k) −1 = H(k) (i.e. [ ,H(k)]M= 0). −Note that the (cid:18) (cid:19) M M M U 0 momentum has not changed sign under the mirror operation Z(k)= k (5) 0 V since the mirror operator is unitary and the reflection as- k M sociatedwiththemirrorsymmetryistakenabouta1Dmirror todefineanotherchiralHamiltonian line1. Since the Hamiltonian in Eq. (11) is invariant under Θ (cid:18) (cid:19) H¯(k)=Z(k)H(k)Z(k)† = 0 Σ(k) . (6) and M as defined above, it is also clearly invariant under Σ(k) 0 their composition which we define as = Θ . Ex- O · M plicitly, = σ τ which squares to +1 and the Hamilto- 0 0 SincethisHamiltonianH¯(k)haswave-functions n,k that nian in EOq. 11 tranKsforms under this operator according to 0 are easy to write down in terms of the diagonal m|atrix(cid:105)Σ(k) H(k) −1 = H( k), which is the pseudo time-reversal O O − one can easily check that this Hamiltonian has vanishing symmetry introduced above. The presence of a TR-operator windingnumber0andalsozeroChernnumber0. TheBerry with 2 = 1, alongwithPHsymmetry, meansthatEq.(11) O 3 also satisfies the requirements to be in the topological class Operator Symmetry Ex.1 Ex.2 BDIindexedbyanintegerwindinginvariant Z. Aswe showedinthelastsection, themirrorBerrypWhas∈ecalculated Ξ PH σyτyK σyτyK ninumthbeeprresetnhcaetcoafnMbeadnedfinΘediswiidthenthtiecahletlopothfethBeDpIsewuidnodiTnRg M Mirror iσyτ0 idˆ·στ0 operatorW = Θ (with 2 = 1) and the PH operator Θ DIIITR iσ τ K iσ τ K O · M O y 0 y 0 Ξ. Belowwefirstreviewtheactionof andthepseudoTR operator onthePaulimatricesσ ,andMthenconsiderpertur- O BDITR K (dˆ·yˆ+i(dˆ×yˆ)·σ)K i O bationswhichremoveeachsymmetryindividually. Π DIIIChiral σ τ σ τ 0 y 0 y It is straightforward to observe the following relations in- volvingtheactionofTR(conventionalaswellaspseudo)and C BDIChiral σ τ dˆ·στ y y y mirrorsymmetriesonthePaulimatrices: Θσ Θ−1 = σ (12a) TABLEI.Summaryofsymmetryoperatorsandtheirexplicitforms i i − inExamples1,2.Particle-holeandtime-reversalsymmetriesareanti- σ −1 =+η σ (12b) i i i unitaryoperatorswhicharetheproductofaunitaryoperator,acting M M σ −1 = η σ (12c) inparticle-holeandspinspace,andthecomplexconjugationoperator i i i O O − K. whereη = 1fori=x,z andη =+1fori=y(notethat i i − inobtainingEq.12cwehaveusedthefactthat = Θ ). O ·M Thus,underthemirroroperation( )spincomponentsinthe M z x z planeacquireaphaseof 1whilethespincomponent − − normal to the mirror plane (see Fig. 1) is unchanged. Note thattheSU(2)angularmomentumalgebraoftheσ operators ([σ ,σ ]=2i(cid:15) σ )ispreservedundertheactionof since i j ijk k two(one)operatorsareeven(odd)under 34. O O Consider case (i) – A perturbation which potentially can break the mirror symmetry of Eq. (11) is a Zeeman term HZ =V·σwhen|Vxz|=(cid:54) 0where|Vxz|=(cid:112)Vx2+Vz2,and Mxz V = (V ,V ,V ). Such a perturbation also breaks the con- x y z y ventionalTRsymmetryΘbutkeepsthepseudoTRsymmetry αˆ ( Θ)andhencethechiralsymmetryofthetotalHamilto- x M· nianintactsolongasV =0. Thus,inthiscase,eventhough y themirrorBerryphasecannolongerbedefined,theBDIchi- ralinvariant remainswelldefinedandthesystemcanhost FIG.1. Mirrorsymmetryforspin-orbitcoupledwires(Example1). W an integer number of protected Majorana fermion modes at Inthiscasethe1Dnanowire(red)liesalongthex-axis.Thebluear- theedges. Nowconsidercase(ii)–whenV = (0,V ,0)the rowdenotesthedirectionofthespin-orbitfieldinspinspacewhich y Hamiltonianismirrorsymmetric( isunbroken)butchiral definesthemirrorplane(lightblue).WhenaZeemanfieldliesinthe and TR symmetries both break doMwn (i.e. the Hamiltonian mirrorplanethemirrorsymmetryisbrokenbutchiralsymmetryis is not invariant under Θ and, consequently, also not under preserved. IfaZeemanfieldisnormaltothemirrorplanethemir- rorsymmetryispreservedwhiletimereversalandchiralsymmetries = Θ). In this case, even though the mirror symme- O M· are removed. However, in this case, there is no mirror topological trypersists,themirrorBerryphaseprocedureisnolongerap- invariantsincethemirrorBerryphaseisonlydefinedinthepresence plicable due to the lack of time reversal symmetry (note that oftime-reversalsymmetry(classDIII).Figureformirrorsymmetry themirrorBerryphaseisonlydefinedinthepresenceofΘ1). forferromagneticatomchainembeddedonPbsuperconductor(Ex- Thus we find that the mirror symmetry helps us find a suit- ample2)shouldbeanalogous. ablepseudoTRoperator whichinturnhelpsusdefinethe O chiral operator = Ξ. This procedure is valid as long C O · astheTRoperatorΘisasymmetryorasincase(i)wherein physicalsystem. both Θ and are broken by the same Zeeman field. Such M a procedure of defining a chiral symmetry does not work in Example 2: Ferromagnetic atom (Fe) chain embedded case (ii) and also in case (iii) where the mirror symmetry is in Pb superconductor: Motivated by recent experimental broken(say,byanadditionalnext-nearest-neighborspin-orbit findings2,3, as a second illustrative example we consider a couplingHSO = α(cid:48)sin(2k)(c σ)τ withc yˆ25)butΘis simple effective model for a ferromagnetic (Fe) atom chain k · z ⊥ unbroken. Note that in both case (ii) and (iii) neither mirror embedded in a Pb superconductor which can support Ma- Chernnorthechiralwindingnumberinvariantcanbedefined. jorana modes and topological superconductivity. The effec- However,aswehaveestablishedinthiswork,whenbothin- tive mean-field BdG Hamiltonian, which gives a sufficient variantsaredefined(i.e.,inthepresenceofΘ),theyareiden- descriptionoftopologicalsuperconductivityoftheferromag- tical,andthetopologicalmirrorsuperconductivityandchiral neticnanowireassumingthattheunderlyingdegreesoffree- BDIsuperconductivityareequivalentdescriptionsofthesame dominthePbsubstratehavebeenintegratedout,canbewrit- 4 tenas33,35,36H =(cid:80) Ψ†H(k)Ψ where, it breaks = Θ) and thus the system belongs to class k k k O M· D where even number of localized Majorana bound states H(k)=( 2tcos(k) µ)σ τ (13) 0 z hybridize into finite-energy quasiparticles. Thus the mirror − − +∆ sin(k)d στ +V στ . symmetryalonedoesnotprotectspatiallylocalizedMajorana p x 0 · · multiplets at the sample edges. Let us now introduce a Zee- In Eq. (13) ∆ is the magnitude of the induced spin-triplet p man field which only lies in the mirror plane which is per- pairing potential in the ferromagnetic nanowire. The Zee- pendiculartothedˆ-vector. Nowthemirroroperatornolonger mantermduetoaconstantinternalmagnetizationinthefer- commuteswiththeHamiltonianH andthusmirrorsymmetry romagnet, V = (V ,V ,V ) (which is assumed to be V = x y z isbroken. HoweverinthiscasesinceΘisalsobrokenbythe (0,0,J)). Zeeman field the pseudo TR operator = Θ remains Agenericd-vectorpointinginanarbitrarydirectioninspin O M· unbroken. Thus chiral symmetry is unbroken and this is a spaceiswrittenasdˆ=(sinθcosφ,sinθsinφ,cosθ)inpolar classBDIsystemasdiscussedearlCier33,35,36. coordinates. In order to understand the role of mirror sym- Conclusion: In this work we show that topological mir- metry let us first consider Eq. (13) with no intrinsic magne- ror superconductivity that results from the co-existence of a tization (i.e V = 0). In this case, the only spin space Pauli mirrorsymmetryandsymplectictime-reversalsymmetrymay matrix (σ) appears in the superconducting term and the ob- also be viewed as a co-existence of symplectic time-reversal vious choice of would be = idˆ στ . Thus the mir- 0 andchiraltopologicalsuperconductivityintheBDIsymmetry ror plane is the pMlane perpendiMcular to th·e dˆ-vector. Follow- classinone dimension. ThemirrorBerryphase1 isfound to ingtheprocedurediscussedpreviouslywedefineanoperator coincidewiththewindingnumberinvariantthatcharacterizes =Θ =(iσ sinθcosφ+σ sinθsinφ iσ cosθ) = z 0 x theBDIsymmetryclassinonedimension. Thewindingnum- O ·M − K (dˆ yˆ+i(dˆ yˆ) σ) . Clearly 2 =+1and H(k) −1 = berandotherqualitativeaspectsofthephasesuchasnumber · × · K O O O +H( k) and thus fulfills the requirements of a class BDI of edge Majorana modes, continue to survive even when the − or pseudo time reversal operator. The chiral operator is symplectictime-reversalΘandmirror-symmetry arebro- = Ξ = dˆ στ forourHamiltonian. Indeed, thefCorm kenweakly.ThusthetopologicalmirrorphaseisadMiabatically y C O· · oftheoperatorsinExample1canbeunderstoodbytheabove connected to a BDI phase by infinitesimal perturbations that relationdescribingthestructureofthe operator.Inthespin- breakthemirrorandtime-reversalsymmetrywhilepreserving O orbit coupled system the direction of the spin-orbit field (re- theBDIchiralsymmetry .Suchaperturbationdoesnothave C member the Rashba term involved a σ ) plays the role of an aqualitativeeffectsuchassplittingedgeMajoranamodes.We y effectived-vector forthe effectivep-wavepairing createdby illustrate our point with two examples, namely, a spin-orbit thecombinationofspin-orbitcouplingandsingletsupercon- coupledsemiconductornanowirewithproximityinducedex- ductivity. tended s-wave pairing potential1, and the recently discussed NowletusturnontheeffectiveZeemanfieldVandexam- experimental system of chains of ferromagnetic atoms on a inewhathappenstothemirrorsymmetry. 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