EPD Congress 2015 PDF
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2015 EPD Congress March 15-19, 2015 • Walt Disney World • Orlando, Florida, USA 2015 EPD Congress Proceedings of symposia sponsored by the Extraction & Processing Division (EPD) of The Minerals, Metals & Materials Society (TMS) held during March 15-19, 2015 Walt Disney World • Orlando, Florida, USA Edited by: James Yurko • Antoine Allanore Laura Bartlett • Jonghyun Lee • Lifeng Zhang Gabriella Tranell • Yulia Meteleva-Fischer Shadia Ikhmayies • Arief Suriadi Budiman Prabhat Tripathy • Guy Fredrickson Editors James Yurko Yulia Meteleva-Fischer Antoine Allanore Shadia Ikhmayies Laura Bartlett Arief Suriadi Budiman Jonghyun Lee Prabhat Tripathy Lifeng Zhang Guy Fredrickson Gabriella Tranell ISBN 978-3-319-48609-3 ISBN 978-3-319-48214-9 (eBook) DOI 10.1007/978-3-319-48214-9 Chemistry and Materials Science: Professional Copyright © 2016 by The Minerals. Metals & Materials Society Published by Springer International Publishers, Switzerland, 2016 Reprint of the original edition published by John Wiley & Sons, Inc., 2015, 978-1-119-08245-3 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned. specifically the rights of translation. reprinting. reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way. and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply. even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. Printed on acid-free paper This Springer imprint is published by Springer Nature The registered company is Springer In ternational Publishing AG The registered company address is: Gewerbestrasse 11,6330 Cham, Switzerland TABLE OF CONTENTS EPD Congress 2015 About the Editors ............................................................................................... xi EPD Council 2014-2015 .................................................................................. xix EPD Honors and Awards 2015 ...................................................................... xxiii Materials Processing Fundamentals Extractive Materials Processing Arsenic and Antimony Removal from Copper Concentrates by Digestion with NaHS-NaOH ................................................................................................5 M. Ruiz, F. Daroch, and R. Padilla Rate of Metal Deposition from Aqueous Solutions ........................................... 13 A. Suriano, S. Howard, and S. Safarzadeh Electrochemical Reduction of Cobalt Tetrafluoroborate in 1-Butyl-3- Methylimidazolium Tetrafluoroborate Ionic Liquid .......................................... 21 M. Li, Z. Shi, Z. Wang, and R. Reddy Extracting Alumina from Coal Fly Ash with Concentrated Sulfuric Acid Sintering and Ultrasound Aided Leaching ......................................................... 31 W. Luo, J. Xue, J. Zhu, K. Liu, C. Yang, and F. Mao Casting, Solidification, and Steel Processing A Cellular Automaton Model Coupled with Finite Element Method for Solidification Process of Beam Blank Continuous Casting ............................... 41 Y. Zhao, D. Chen, M. Ma, X. Wan, Y. Li, and R. Qin Numerical Simulation of the Coupled Turbulent Flow, Heat and Solute Transport in the Turbulent Flow Region of Slab Continuous Casting ............... 49 H. Chen, D. Chen, L. Gui, M. Long, Y. Huang, and Y. Ma Interphase Evolution and Defect Formation during Horizontally Directional Solidification Process of Sn-Zn Alloys .............................................................. 57 A. Kociubczyk, W. Desrosin, L. Boycho, C. Schvezov, and A. Ares Effect of Technological Parameters on Mold Powder Entrainment by Water Model Study ....................................................................................... 65 L. Zhang, Y. Li, Q. Wang, and C. Yan v Equivalency Comparison of Heat Transfer Coefficient in Liquid and Gas Quenches .............................................................................................. 73 Y. Lu, Y. Rong, and R. Sisson Determination of Cavity Profile Induced by Supersonic Jets Impinging onto Liquids Surface .......................................................................................... 81 Q. Li, M. Li, M. Feng, and Z. Zou Materials Processing In-Situ Gas Monitoring by Emission Spectroscopy ........................................... 91 T. Aarhaug, A. Ferber, P. Tetlie, and H. Dalaker Poster Session Thermodynamic Study on Vanadium Extraction with CO₂ and O₂ Mixed Blowing ........................................................................................................... 101 W. Du, Y. Wang, and G. Wen Effects of Power Ultrasound on Precipitation Process of Sodium Silicate Solutions .......................................................................................................... 109 T. Li, J. Xue, W. Luo, and J. Zhu CO₂ Capture and Conversion Using a Cobalt (III) Schiff Base Complex as a Catalyst at Ambient Conditions ................................................................ 117 J. Miao, J. Xue, J. Zhu, and K. Liu Effect of Laminar Cooling Parameters on Martensite Volume Fraction and Mechanical Properties of Hot Rolled Dual Phase Steel ............................ 125 S. Daglılar, I. Kerti, and S. Yıldırım The Effect of Graphene on the Microstructure and Mechanical Properties of Aluminum/Graphene Produced by HPT ..................................................... 133 L. Zhao, H. Lu, and Z. Gao The Extent of Dopant Activation after Microwave and Rapid Thermal Anneals Using Similar Heating Profiles .......................................................... 141 T. Gunawansa, Z. Zhao, N. Theodore, A. Lanz, and T. Alford Application of Computational Thermodynamics to Steel Processing: The Case of Steel Cleanness ............................................................................ 149 A. Silva, L. Goulart, E. Araujo, R. Batista, and A. Martins vi Reaction Between MnO-SiO₂ Oxides with Low FeO Content and Solid Steel Deoxidized by Si and Mn during Heat Treatment ......................... 157 C. Liu, J. Li, H. Tang, and X. Gao Nucleation and Growth in the Equiaxed Zone of Metal Matrix Composites ...................................................................................................... 165 A. Ares and C. Schvezov Combined Effects of Silicon (Si) and Low Temperature Annealing on the Tensile Properties of Cartridge (70/30) Brass with Nickel (Ni) and Iron (Fe) Contaminants ............................................................................. 175 A. Adegbenjo, A. Adegbola, F. Raji, O. Ladiipo, T. Adeboje, and S. Ibitoye Effect of Lime on Alumina Extracting Property of Calcium Aluminate Slag .................................................................................................................. 181 B. Wang, Y. Zhang, L. Ma, and H. Sun Prepare for U₃O₈ from Ammonium Uranyl Carbonate Using Microwave Calcination ....................................................................................................... 189 B. Liu, J. Peng, L. Zhang, J. Hu, S. Guo, and D. Kong Solar Cell Silicon Silicon Production and Refining Directional Growth of Bulk Silicon from Silicon-Aluminum-Tin Melts ......... 201 Y. Li, Y. Tan, and K. Morita Preparation of Solar Grade Silicon Precursor by Silicon Dioxide Electrolysis in Molten Salts ............................................................................. 209 L. Li, J. Guan, A. Liu, Z. Shi, M. Korenko, J. Xu, B. Gao, and Z. Wang Effect of Temperature in Extraction of High Purity Amorphous Silica from Rice Husk for Silicon Production ........................................................... 219 C. Ilochonwu, C. Nwajagu, I. Onyenanu, and E. Nwonye Crystallisation and Mechanical Properties Numerical Modeling of Stress Distribution in a Bi-Grain Small Scale Silicon Ingot Including Crucible Deformation ................................................ 231 S. Gouttebroze and M. M'Hamdi vii Mechanical Strength of Silicon Solar Wafers Characterized by Ring-on-Ring Test in Combination with Digital Image Correlation ............... 241 V. Popovich, W. Geerstma, M. Janssen, I. Bennett, and I. Richardson Behavior for Nitrogen and Iron in the Bottom of Casting Multicrystalline Silicon Ingot .................................................................................................... 249 C. Zhang, K. Wei, W. Ma, J. Li, and Y. Dai Thermal Field Design and Optimization of Directional Solidification for Multicrystalline Silicon Growth ...................................................................... 257 W. Ma, X. Yang, and G. Lv Microstructure and Mechanical Properties of a Screen-Printed Silver Front Side Solar Cell Contact .......................................................................... 265 V. Popovich, M. Janssen, I. Bennett, and I. Richardson High-Temperature Electrochemistry II Molten Salt Technology Studies on the Purification of Na₃AlF₆-K₂SiF₆-AlF₃ Melt ............................. 277 Z. Tian, S. Yang, Y. Lai, X. Hu, and J. Li Nuclear and Rare Earth Technology Electrochemical Separation of Dy and Nd from Nd Magnet Scrap in a Molten LiCl-KCl ....................................................................................... 287 H. Konishi, H. Ono, E. Takeuchi, T. Nohira, and T. Oishi Sensors and Advanced Materials Production of Titanium Oxycarbide from Titania-Rich Mineral Sands........... 297 F. Fatollahi-Fard and P. Pistorius Experimental Thermodynamic Study on the Ag–Sb System at Elevated Temperatures ................................................................................................... 305 M. Aspiala, F. Tesfaye, and P. Taskinen viii Energy Storage Devices, Corrosion and Molten Salt Science Synthesis of High Performance LiMn₀₈ Fe₀₂ PO₄/C Cathode Material for Lithium Ion Batteries: Effect of Calcination Temperature ......................... 315 E. Dai, W. Chen, H. Fang, H. Wang, B. Yang, and W. Ma Author Index .................................................................................................... 323 Subject Index ................................................................................................... 325 ix
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