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Environmental Pollution and Control PDF

378 Pages·1990·6.908 MB·English
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"If seven maids with seven mops Swept it for a half a year, Do you suppose/' the Walrus said, "That they could get it clear?" "I doubt it/' said the Carpenter, And shed a bitter tear. —Lewis Carroll Environmental Pollution and Control Third Edition by P. Aarne Vesilind and J. Jeffrey Peirce Department of Civil and Environmental Engineering Duke University Durham, North Carolina and Ruth F. Weiner Huntley College of Environmental Studies Western Washington University Bellingham, Washington Butterworth-Heinemann Boston · London Sydney · Toronto · Wellington Copyright © 1990 by Butterworth-Heinemann, a division of Reed Publishing (USA) Inc. AU rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without the prior written permission of the publisher. Recognizing the importance of preserving what has been written, it is the policy of Butterworth- Heinemann Publishers to have the books it publishes printed on acid-free paper, and we exert our best efforts to that end. Library of Congress Cataloging-in-Publication Data Vesilind, P. Aarne. Environmental pollution and control / by P. Aarne Vesilind and J Jeffrey Peirce and Ruth F. Weiner.—3rd. p. cm. Includes bibliographical references. ISBN 0-409-90272-1 1. Environmental engineering. I. Peirce, J. Jeffrey. II. Weiner, Ruth F. ΙΠ. Title. TD145.V43 1990 628.5-dc20 90-1657 CIP British Library Cataloguing in Publication Data Vesilind, P. Aarne Environmental pollution control.--3rd ed. 1. Environment. Pollution. Control measures I. Title Π. Peirce, J. Jeffrey ΙΠ. Weiner, Ruth F. 628.5 ISBN 0-409-90272-1 Butterworth-Heinemann 80 Montvale Avenue Stoneham, MA 02180 10 987654321 Printed in the United States of America to Pam, Steve, and Laurie B. and Shayn and Leyf and Lisa, Annie, Sarah, and Rachel Preface The objective of this book is to package the more important aspects of environmental engineering science and technology in an organized man- ner and present this mainly technical material to a nonengineering audi- ence. This book originally began as a set of class notes for a course offered at Duke University by the Department of Civil and Environmental Engineering. The course is designed for nonengineering students and has been a popular elective. The third edition owes some of its development to an undergraduate course offered since 1976 in the Huxley College of Environmental Studies at Western Washington University. Although the courses have no prerequisites, we assume that the student has a knowledge of high school or college freshman chemistry for nonmajors. A knowledge of college algebra is required, but calculus is not used. We do not intend for this book to be scientifically and technically com- plete. In fact, many complex environmental problems have been simpli- fied to the threshold of pain for many engineers and scientists. Our objective, however, is not to impress nontechnical students with the rigors and complexities of pollution control technology but rather to make some of the language and ideas of environmental engineering more understandable. P. Aarne Vesilind J. Jeffrey Peirce Ruth F. Weiner Chapter 1 Environmental Pollution The pictures of the earth from the manned space missions clearly illus- trated that not only is the earth round but that it is indeed a finite and lonely little blob. Somehow the sight of this forlorn spaceship, floating friendless in the blackness of space, brought home the fact that the earth and its natural resources are indeed all we have and that we must start worrying about the future of this earth. The present generation is the first to include among its list of concerns the very survival of the planet, a question that would have been meaning- less not too long ago. Before Copernicus not only was the world flat it also was the center of the entire universe. These past few centuries have wit- nessed the dramatic change from a human population that thought of itself powerless to change the earth and anything on its face to a generation that can literally blow the earth up if it so chooses. "Blowing up" can take many forms—from the obvious nuclear holo- caust to the less dramatic but equally effective method of increasing the ambient temperature through the greenhouse effect and destroying the delicate balance of life. Put simply, the slow, insidious process of destroy- ing our own home by contaminating and killing the earth's ability to support life is what we call environmental pollution. ROOTS OF OUR CONCERN WITH ENVIRONMENTAL POLLUTION There are two basic reasons for our concern with environmental pollu- tion: (1) human health and welfare and (2) our care about the remainder of nature. The latter concern is not only for the benefits we might derive from nature but because all of nature has its own right to exist. In this 1 2 ENVIRONMENTAL POLLUTION AND CONTROL chapter we devote most of the discussion to the first concern, human health and well-being, and turn to the latter reason for environmental con- cern, care about the remainder of nature, in the very last chapter of this book. Human health and well-being can be impacted by environmental pollu- tion in two distinctly different ways: (1) on a personal level of detrimental health effects due to contaminated water, air, or food or (2) on a global level as the slow yet progressive deterioration of our habitat, resulting in the eventual destruction of the human species and perhaps all life. Such a concern is not very personal, since the possibility of that occurring in our lifetime is about as probable as the sky falling. (Yet we still have many "Chicken Littles" running around trying to set dates when the world will come to an end.)1 Our personal concern with environmental pollution revolves around immediate health problems, and there are plenty of them to worry about from chlorinated pesticides through heavy metals and asbestos to contaminated indoor air. The idea that contamination of the environment is detrimental is not new. Although most ancient civilizations had strict prohibitions against various forms of pollution, it wasn't until the mid-nineteenth century that the idea of taking care of our own environment became a concern to peo- ple. Contaminated water and air were recognized as being associated with some diseases, and efforts were made to clean up the cities. For example, a resolution in 1869 by the Massachusetts Board of Health proclaimed: We believe all citizens have an inherent right to the enjoyment of pure and uncontaminated air and water and soil; that this right should be regarded as belonging to the whole community; and that no one should be allowed to trespass upon it by his carelessness or his avarice or even his ignorance. This was a worthy resolution and would serve well as a code of conduct for civilization today. The fact that environmental pollution can make peo- ple sick and even prematurely kill people through various forms of envi- ronmentally mitigated diseases is a major driving force for environmental pollution control. On a different level, we deplore the destruction of our "sacred places" in nature because of the detrimental effect this has on our mental health. Many of us enjoy the outdoors, and the wilder and more alone the encoun- ter, the more we like it. We would be very much the poorer if nature were not out there for us to be a part of and to enjoy. But this defense of nature ^ee, for example, Paul Erlich's "Eco-catastrophe" (San Francisco: City Lights Books, 1969), which begins with the prediction: "The end of the oceans came late in the summer of 1979. . . ." ENVIRONMENTAL POLLUTION 3 is anthropocentric, i.e. for the good of the people, not for the good of the rest of nature. This is not to say that such a desire is inappropriate, selfish, or wrong. It is a legitimate desire just as freedom from infectious diseases is a human desire. It must be recognized, however, for what it is, a benefit to humans. The concern with human health is a tricky problem since it involves the concept of the analysis of risk. Everything we do in life involves a risk (even staying in bed—you might get hit by lightning or the building might burn down around you), and we manage risk by reducing it whenever possible and desirable. Before we discuss the concern of risks due to the contamination of our environment, it is necessary to understand the prin- ciples of risk assessment. RISK ANALYSIS A substance is considered a pollutant because it is perceived to have an adverse effect on the environment and, either directly or indirectly, an adverse effect on human health. It is sometimes difficult to determine, however, if there is an effect or if the effects have been deleterious or detrimental. For example, we are now quite certain that cigarette smoke is unhealthy. We have specifically identified inhaled cigarette smoke as contributing significantly to lung cancer, chronic obstructive pulmonary disease, and heart disease. Notice that we do not say that cigarette smoking causes these health problems because we have not identified the causes—the etiology—of any of them at least in the sense that we have identified the poliomyelitis virus as the cause of polio. How then has cigarette smoking been identified as a contributing factor if it cannot be identified as the cause? Cigarette smoking can serve as a good example of how health effects of pollutants are determined although cigarette smoke is not regu- lated the way other pollutants are regulated. During the twentieth century with the widespread use of vaccination and antibiotics, infectious diseases have ceased to be a primary cause of death. The life span of people in the developed countries of the world has length- ened considerably, and heart disease and cancer have become leading causes of death, and it was observed during the early 1960s that lifelong heavy cigarette smokers often died from lung cancer. But how do we determine what people die of, and how is the death related to a habit like heavy smoking? The cause of death listed on death certificates, which are the source of much epidemiological information, does not specify cigarette smoking as the cause of death. In order to relate death from lung cancer to smoking, one must show that significantly more 4 ENVIRONMENTAL POLLUTION AND CONTROL lung cancer deaths occur in smokers than in nonsmokers. Such a showing is called a standard mortality ratio (SMR) and is defined as: observed deaths SMR = ——— expected deaths The number of "expected deaths" in the above equation is the number of deaths from the particular disease (lung cancer in this case) that seem to happen without any identifiable cause. In the general population of smokers and nonsmokers, there are a certain number of lung cancer deaths. Even in nonsmokers, there are a certain, albeit small, number of lung cancer deaths. In this instance, then, the SMR can be defined as SMR = zr where D = lung cancer deaths in a given population of smokers s D = lung cancer deaths in a nonsmoking population o fthe same size m In this instance, the SMR is 11/1. Since the SMR is significantly greater than 1.0, we can say that cigarette smoke contributes significantly to lung cancer, or as it is usually phrased, smoking cigarettes significantly increases the risk of death from lung cancer. To be precise, the risk of death from lung cancer is eleven times as high for a heavy smoker as for a nonsmoker. Determination of the SMR tells something about the epi- demiology of smoking, but not about its etiology. There are three characteristics of epidemiological reasoning in this example that are important: • Not everyone who smokes heavily will die of lung cancer. • Some nonsmokers die of lung cancer. • Therefore one cannot unequivocally relate any given individual lung cancer death to cigarette smoking. Risk also can be expressed in other ways. One commonly used statistic in risk analysis is the number of deaths from a given cause per 100,000 population. For example, in the United States there are 350,000 deaths each year from lung cancer and heart disease that are attributable to smok- ing. The United States has a population of 240 million. The risk of death associated with the effects of cigarette smoking can thus be expressed as deaths per 100,000 population or 350,000 146 = 240 x 106 100,000 ENVIRONMENTAL POLLUTION 5 Table 1-1. Approximate Adult Deaths Annually per 100,000 Population Cause of Death Deaths/105 Population Cardiovascular disease 408 Cancer 193 Chronic obstructive pulmonary disease 31 Motor vehicle accidents 18.6 Alcoholism 11.4 Other causes 208 All causes 870 In other words, a heavy smoker in the United States has an annual prob- ability (or risk) of 146 in 100,000 of dying of lung cancer or heart disease. Table 1-1 presents some typical mortality statistics for the United States. A third way to present risk statistics is as deaths from a given cause per 1000 deaths. For example, there are approximately 2.2 x 106 deaths annually in the United States. Three hundred and fifty thousand of these, or 160 per 1000 deaths, are related to heavy smoking. In summary, risk of death due to some environmental cause can be expressed in three ways: 1. Risk of death from being exposed to a given environmental pollutant (SMR) number of deaths from a specific cause in a given population exposed to an environmental pollutant number of deaths from the same cause in a similar sized population not exposed to that pollutant 2. Risk of death from a given cause number of deaths associated with the cause in a given time total population, all of whom will die due to some cause 3. Risk of death from a given cause _ number of deaths associated with the cause total number of deaths Example 1.1 A butadiene plastics manufacturing plant is located in Beaverville, and the atmosphere is seriously contaminated by butadiene, a suspected car- cinogen. The cancer death rate in the community of 8000 is 36 people per year and the total death rate is 106 people per year. Does Beaverville appear to be a healthy place to live?

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