Geophysical Monograph Series Geophysical Monograph Series 206 Remote Sensing of the Terrestrial Water Cycle Venkat 231 Bioenergy and Land Use Change Zhangcai Qin, Umakant Lakshmi (Ed.) Mishra, and Astley Hastings (Eds.) 207 Magnetotails in the Solar System Andreas Keiling, 232 Microstructural Geochronology: Planetary Records Down Caitriona Jackman, and Peter Delamere (Eds.) to Atom Scale Desmond Moser, Fernando Corfu, James 208 Hawaiian Volcanoes: From Source to Surface Rebecca Darling, Steven Reddy, and Kimberly Tait (Eds.) Carey, Valerie Cayol, Michael Poland, and Dominique 233 Global Flood Hazard: Applications in Modeling, Mapping Weis (Eds.) and Forecasting Guy Schumann, Paul D. Bates, Giuseppe 209 Sea Ice: Physics, Mechanics, and Remote Sensing T. Aronica, and Heiko Apel (Eds.) 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Jovanelly 223 Natural Hazard Uncertainty Assessment: Modeling and 248 Dayside Magnetosphere Interactions Qiugang Zong, Decision Support Karin Riley, Peter Webley, and Matthew Philippe Escoubet, David Sibeck, Guan Le, and Hui Thompson (Eds.) Zhang (Eds.) 224 Hydrodynamics of Time‐Periodic Groundwater Flow: 249 Carbon in Earth’s Interior Craig E. Manning, Jung-Fu Lin, Diffusion Waves in Porous Media Joe S. Depner and Todd and Wendy L. Mao (Eds.) C. Rasmussen (Auth.) 250 Nitrogen Overload: Environmental Degradation, 225 Active Global Seismology Ibrahim Cemen and Yucel Ramifications, and Economic Costs Brian G. Katz Yilmaz (Eds.) 251 Biogeochemical Cycles: Ecological Drivers and 226 Climate Extremes Simon Wang (Ed.) Environmental Impact Katerina Dontsova, Zsuzsanna 227 Fault Zone Dynamic Processes Marion Thomas (Ed.) Balogh-Brunstad, and Gaël Le Roux (Eds.) 228 Flood Damage Survey and Assessment: New Insights from 252 Seismoelectric Exploration: Theory, Experiments, and Research and Practice Daniela Molinari, Scira Menoni, and Applications Niels Grobbe, André Revil, Zhenya Zhu, and Francesco Ballio (Eds.) Evert Slob (Eds.) 229 Water-Energy‐Food Nexus – Principles and Practices 253 El Niño Southern Oscillation in a Changing Climate P. Abdul Salam, Sangam Shrestha, Vishnu Prasad Pandey, Michael J. McPhaden, Agus Santoso, Wenju Cai (Eds.) and Anil K Anal (Eds.) 254 Dynamic Magma Evolution Francesco Vetere (Ed.) 230 Dawn–Dusk Asymmetries in Planetary Plasma Environments Stein Haaland, Andrei Rounov, and Colin Forsyth (Eds.) Geophysical Monograph 255 Large Igneous Provinces A Driver of Global Environmental and Biotic Changes Edited by Richard E. Ernst Alexander J. Dickson Andrey Bekker This open access Work is a co‐publication of the American Geophysical Union and John Wiley and Sons, Inc. This open access Work is a co‐publication of the American Geophysical Union and John Wiley and Sons, Inc. This edition first published 2021 by John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, USA and the American Geophysical Union, 2000 Florida Avenue, N.W., Washington, D.C. 20009 © 2021 The Authors This is an open access publication under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. The right of Richard E. Ernst, Alexander J. Dickson and Andrey Bekker to be identified as the editors of this work has been asserted in accordance with law. Published under the aegis of the AGU Publications Committee Brooks Hanson, Executive Vice President, Science Carol Frost, Chair, Publications Committee For details about the American Geophysical Union visit us at www.agu.org. 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Title: Large igneous provinces : a driver of global environmental and biotic changes / edited by Richard Ernst, Andrey Bekker, Alexander J. Dickson. Description: First edition. | Hoboken : Wiley, 2020. | Series: Geophysical monograph series | Includes bibliographical references and index. Identifiers: LCCN 2020025916 (print) | LCCN 2020025917 (ebook) | ISBN 9781119507451 (cloth) | ISBN 9781119507475 (adobe pdf) | ISBN 9781119507499 (epub) Subjects: LCSH: Global environmental change. | Climatic changes. Classification: LCC GE145 .L37 2020 (print) | LCC GE145 (ebook) | DDC 363.738/74072014–dc23 LC record available at https://lccn.loc.gov/2020025916 LC ebook record available at https://lccn.loc.gov/2020025917 Cover Design: Wiley Cover Image: Lava flow and sulfur emissions from the 2014-15 Bárðarbunga-Veiðivötn fissure eruption at Holuhraun (Iceland). Taken from Icelandic Coast Guard helicopter by Anja Schmidt, 21 January 2015. Set in 10/12pt Times New Roman by SPi Global, Pondicherry, India 10 9 8 7 6 5 4 3 2 1 CONTENTS List of Contributors ����������������������������������������������������������������������������������������������������������������������������������������������vii Preface ������������������������������������������������������������������������������������������������������������������������������������������������������������������xi Part I: The Temporal Record of Large Igneous Provinces (LIPs) 1� Large Igneous Province Record Through Time and Implications for Secular Environmental Changes and Geological Time-Scale Boundaries Richard E. Ernst, David P. G. Bond, Shuan-Hong Zhang, Kenneth L. Buchan, Stephen E. Grasby, Nasrrddine Youbi, Hafida El Bilali, Andrey Bekker, and Luc S. Doucet ................................3 2� Radiometric Constraints on the Timing, Tempo, and Effects of Large Igneous Province Emplacement Jennifer Kasbohm, Blair Schoene, and Seth Burgess ......................................................................................27 Part II: Environmental Impacts of LIP Emplacement 3� Global Warming and Mass Extinctions Associated With Large Igneous Province Volcanism David P. G. Bond and Yadong Sun ................................................................................................................85 4� Environmental Effects of Volcanic Volatile Fluxes From Subaerial Large Igneous Provinces Tamsin A. Mather and Anja Schmidt ...........................................................................................................103 5� Assessing the Environmental Consequences of the Generation and Alteration of Mafic Volcaniclastic Deposits During Large Igneous Province Emplacement Benjamin Black, Tushar Mittal, Francesca Lingo, Kristina Walowski, and Andres Hernandez ........................117 6� Environmental Impact of Silicic Magmatism in Large Igneous Province Events Scott E. Bryan .............................................................................................................................................133 7� Evaluating the Relationship Between the Area and Latitude of Large Igneous Provinces and Earth’s Long-Term Climate State Yuem Park, Nicholas L. Swanson-Hysell, Lorraine E. Lisiecki, and Francis A. Macdonald ..............................153 8� Preliminary Appraisal of a Correlation Between Glaciations and Large Igneous Provinces Over the Past 720 Million Years Nasrrddine Youbi, Richard E. Ernst, Ross N. Mitchell, Moulay A. Boumehdi, Warda El Moume, Abdelhak Ait Lahna, Mohamed K. Bensalah, Ulf Söderlund, Miguel Doblas, and Colombo C. G.Tassinari ...............................................................................................169 9� Phanerozoic Large Igneous Province, Petroleum System, and Source Rock Links Steven C. Bergman, James S. Eldrett, and Daniel Minisini ............................................................................191 v vi Contents Part III: Geochemical Proxies for the Environmental Effects of LIPs 10� The Osmium Isotope Signature of Phanerozoic Large Igneous Provinces Alexander J. Dickson, Anthony S. Cohen, and Marc Davies .........................................................................231 11� Sedimentary Mercury Enrichments as a Tracer of Large Igneous Province Volcanism Lawrence M. E. Percival, Bridget A. Bergquist, Tamsin A. Mather, and Hamed Sanei ....................................247 12� Platinum Group Element Traces of CAMP Volcanism Associated With Low‐Latitude Environmental and Biological Disruptions Jessica H. Whiteside, Paul E. Olsen, Sean T. Kinney, and Mohammed Et‐Touhami ........................................263 13� Assessing the Effect of Large Igneous Provinces on Global Oceanic Redox Conditions Using Non-traditional Metal Isotopes (Molybdenum, Uranium, Thallium) Brian Kendall, Morten B. Andersen, and Jeremy D. Owens ..........................................................................305 14� Marine Anoxia and Ocean Acidification During the End‐Permian Extinction: An Integrated View From δ238U and δ44/40Ca Proxies and Earth System Modeling Ying Cui, Feifei Zhang, Jiuyuan Wang, Shijun Jiang, and Shuzhong Shen ......................................................325 15� Trends in Ocean S‐Isotopes May Be Influenced by Major LIP Events Ross. R. Large, Jeffrey A. Steadman, Indrani Mukherjee, Ross Corkrey, Patrick Sack, and Trevor R. Ireland ..................................................................................................................................341 16� Marcasite at the Permian‐Triassic Transition: A Potential Indicator of Hydrosphere Acidification Elena Lounejeva, Jeffrey A. Steadman, Thomas Rodemann, Ross R. Large, Leonid Danyushevsky, Daniel Mantle, Kliti Grice, and Thomas J. Algeo ...................................................................377 Part IV: Phanerozoic and Proterozoic Case Histories 17� The Monterey Event and the Paleocene‐Eocene Thermal Maximum: Two Contrasting Oceanic Carbonate System Responses to LIP Emplacement and Eruption Tali L. Babila and Gavin L. Foster .................................................................................................................403 18� Permian Large Igneous Provinces and Their Paleoenvironmental Effects Jun Chen and Yi‐Gang Xu ...........................................................................................................................417 19� Was the Kalkarindji Continental Flood Basalt Province a Driver of Environmental Change at the Dawn of the Phanerozoic? Peter E. Marshall, Luke E. Faggetter, and Mike Widdowson ..........................................................................435 20� Large Igneous Provinces (LIPs) and Anoxia Events in “The Boring Billion” Shuan‐Hong Zhang, Richard E. Ernst, Jun‐Ling Pei, Yue Zhao, and Guo‐Hui Hu ..........................................449 21� Breaking the Boring Billion: A Case for Solid‐Earth Processes as Drivers of System‐Scale Environmental Variability During the Mid‐Proterozoic Charles W. Diamond, Richard E. Ernst, Shuan‐Hong Zhang, and Timothy W. Lyons .....................................487 Index ������������������������������������������������������������������������������������������������������������������������������������������������������������������503 LIST OF CONTRIBUTORS Abdelhak Ait Lahna Moulay A. Boumehdi Department of Geology, Faculty of Sciences‐Semlalia, Department of Geology, Faculty of Sciences‐Semlalia, Cadi Ayyad University, Marrakech, Morocco Cadi Ayyad University, Marrakech, Morocco; and Instituto Dom Luiz, Faculdade De Ciências, Thomas J. Algeo Universidade de Lisboa, Lisbon, Portugal Department of Geology, University of Cincinnati, Cincinnati, Ohio, USA; and Scott E. Bryan State Key Laboratory of Geological Processes and School of Earth and Atmospheric Sciences, Mineral Resources, and State Key Laboratory of Queensland University of Technology, Brisbane, Biogeology and Environmental Geology, China Queensland, Australia University of Geosciences, Wuhan, China Kenneth L. Buchan 273 Fifth Ave., Ottawa, Ontario, Canada Morten B. Andersen School of Earth and Ocean Sciences, Cardiff University, Seth Burgess Cardiff, United Kingdom United States Geological Survey, Volcano Science Center, Menlo Park, California, USA Tali L. Babila School of Ocean and Earth Science, University Jun Chen of Southampton Waterfront Campus, National State Key Laboratory of Isotope Geochemistry, Oceanography Centre Southampton, Southampton, Guangzhou Institute of Geochemistry, Chinese United Kingdom Academy of Sciences, Guangzhou, China Andrey Bekker Anthony S. Cohen Department of Earth and Planetary Sciences, Department of Environment, Earth and Ecosystems, University of California, Riverside, California, USA; and The Open University, Milton Keynes, United Kingdom Department of Geology, University of Johannesbrug, South Africa Ross Corkrey Tasmanian Institute of Agriculture, University of Mohamed K. Bensalah Tasmania, Hobart, Tasmania, Australia Department of Geology, Faculty of Sciences‐Semlalia, Cadi Ayyad University, Marrakech, Morocco; and Ying Cui Instituto Dom Luiz, Faculdade de Ciências, Department of Earth and Environmental Studies, Universidade De Lisboa, Lisbon, Portugal Montclair State University, Montclair, New Jersey, USA Steven C. Bergman SCB Geosciences, Vashon, Washington, USA Leonid Danyushevsky CODES Centre for Ore Deposits and Earth Science, Bridget A. Bergquist University of Tasmania, Hobart, Tasmania, Australia Department of Earth Sciences, University of Toronto, Toronto, Ontario, Canada Marc Davies School of Geography, Earth and Environmental Benjamin Black Sciences, University of Plymouth, Plymouth, United City University of New York Graduate School and Kingdom University Center, New York, New York, USA Charles W. Diamond David P. G. Bond Department of Earth Sciences and NASA Astrobiology Department of Geography, Geology and Environment, Institute, University of California Riverside, Riverside, University of Hull, Hull, United Kingdom California, USA vii viii LIST OF CONTRIBUTORS Alexander J. Dickson Andres Hernandez Department of Earth Sciences, Royal Holloway City University of New York Graduate School and University of London, Egham, United Kingdom University Center, New York, New York, USA Miguel Doblas Guo‐Hui Hu Instituto de Geociencias (CSIC‐UCM), Ciudad Institute of Geomechanics, Chinese Academy Universitaria, Madrid, Spain of Geological Sciences, Beijing, China; and Key Laboratory of Paleomagnetism and Tectonic Luc S. Doucet Reconstruction, Ministry of Natural Resources, TIGeR School of Earth and Planetary Sciences, Curtin Beijing, China University, Perth, Western Australia, Australia Trevor R. Ireland Hafida El Bilali Research School of Earth Sciences, Australian National Department of Earth Sciences, Carleton University, University, Canberra, Australian Capital Territory, Australia Ottawa, Ontario, Canada Shijun Jiang Warda El Moume Institute of Groundwater and Earth Sciences, Jinan Department of Geology, Faculty of Sciences‐Semlalia, University, Guangzhou, China Cadi Ayyad University, Marrakech, Morocco; and Department of Geology, Faculty of Sciences, Ibnou Jennifer Kasbohm Zohr University, Agadir, Morocco Department of Geosciences, Princeton University, Princeton, New Jersey, USA James S. Eldrett Shell International Exploration & Production B.V., Brian Kendall Rijswijk, The Netherlands Department of Earth and Environmental Sciences, University of Waterloo, Waterloo, Ontario, Canada Richard E. Ernst Department of Earth Sciences, Carleton University, Sean T. Kinney Ottawa, Ontario, Canada; and Lamont‐Doherty Earth Observatory of Columbia Faculty of Geology and Geography, Tomsk State University, Palisades, New York, USA University, Tomsk, Russian Federation Ross R. Large Mohammed Et‐Touhami CODES Centre for Ore Deposits and Earth Science, 2GPMH, Département des Sciences de la Terre, University of Tasmania, Hobart, Tasmania, Australia Université Mohammed Premier, Oujda, Morocco Francesca Lingo Luke E. Faggetter City College of New York, New York, USA School of Earth and Environment, University of Leeds, Leeds, United Kingdom Lorraine E. Lisiecki Department of Earth Science, University of California, Gavin L. Foster Santa Barbara, Santa Barbara, California, USA School of Ocean and Earth Science, University of Southampton Waterfront Campus, National Elena Lounejeva Oceanography Centre Southampton, Southampton, CODES Centre for Ore Deposits and Earth Science, United Kingdom University of Tasmania, Hobart, Tasmania, Australia Stephen E. Grasby Timothy W. Lyons Geological Survey of Canada, Calgary, Alberta, Department of Earth Sciences and NASA Astrobiology Canada Institute, University of California Riverside, Riverside, California, USA Kliti Grice Western Australian Organic and Isotope Geochemistry Francis A. Macdonald Centre, School of Earth and Planetary Science, Curtin Department of Earth Science, University of California, University, Perth, Western Australia, Australia Santa Barbara, Santa Barbara, California, USA