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Energy Storage. A Vital Element in Mankind's Quest for Survival and Progress PDF

575 Pages·1980·27.633 MB·English
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Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford. New York 10523, U.S.A. CANADA Pergamon of Canada. Suite 104, 150 Consumers Road, Willowdale, Ontario M2J 1P9, Canada AUSTRALIA Pergamon Pi iss (Aust.) Pty. Ltd., P.O. Box 544, Potts Point, N.S.W. 2011, Australia FRANCE Pergamon Press SARL. 24 rue des Ecoles, 75240 Paris, Cedex 05. France FEDERAL REPUBLIC Pergamon Press GmbH, 6242 Kronberg-Taunus, OF GERMANY Hammerweg 6, Federal Republic of Germany Copyright © 1980 Pergamon Press Ltd. Ail Rights Reserved. No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means: electronic, electrostatic, magnetic tape, mechanical, photocopying, recording or otherwise, without permission in writing from the publishers. First edition 1980 British Library Cataloguing in Publication Data International Assembly on Energy Storage 1st, Dubrovnik, 1979 Energy storage. 1. Energy storage - Congresses I. Title II. Silverman, Joseph 621.4 TJ165 80-40771 ISBN 0-08-025471-3 In order to make this volume available as economically and as rapidly as possible the authors' typescripts have been reproduced in their original forms. This method has its typographical limitations but it is hoped that they in no way distract the reader. Printed in Great Britain by A. Wheaton & Co. Ltd., Exeter PREFACE The International Assembly on Energy Storage took place at the Hotel Libertas, Dubrovnik, Yugoslavia during 27 May - 1 June 1979. It was the first international gathering of industrial, academic, and government experts to discuss all facets of energy storage: electrochemical, thermochemical and thermal, photochemical, and mechanical. In addition to panel sessions and lectures in these four areas, there were assessments using techno-economic models of the impact of various aspects of energy storage. Responses to a questionnaire circulated to the participants reveal that they adjudged the conference to be an outstanding success. This volume contains three main sections. The first consists of the plenary lectures; which are designed to summarize the progress, problems, and future opportunities in various areas of energy storage technology. The second consists of Summary Proceedings. It was compiled mainly at the conference site and includes summaries of both the papers and discussions at the plenary and panel sessions. The last section consists of the papers presented during the panel sessions. As Secretary-General of the Assembly and editor of its publications, I am pleased to acknowledge the contributions by various agencies and people to the success of the meeting and to the production of these proceedings. First there is the National Academy of Sciences (USA) and the Council of Academies of Science (Yugoslavia) for their sponsorship of the conference; Prof. C. Newton and Prof. L. Rakic were particularly helpful as representatives of the two sponsors. Dr. G. Pezdirtz, Director of the U. S. Department of Energy's Division of Energy Storage, is the originator of and the guiding spirit behind the conference. Prof. A. Despic and Dr. R. Smelt, the co-chairmen of the meeting, are noteworthy for their major roles in the organization and conduct of the conference. Dr. DeMarquis Wyatt, Secretary of the National Academy of Sciences' Committee on Advanced Energy Storage Systems, played an important role in all scientific aspects of the meeting including the publications; he also proved to be a genial banquet chairman. The noted science fiction writer, Mr. Frederik Pohl, lived up to his reputation with an original and stimulating banquet address. We were ably assisted in the pre-conference logistics of the Assembly by Mr. H. Lowitt and Ms. C. Rice; the services of both were provided by Resource Planning Associates (RPA), Inc. Mr. N. Ostojic of the Serbian Administration for International Scientific, Educational, Cultural and Technical Cooperation managed the proceedings at the Hotel Libertas with exceptional E.S.—A* ix X Preface skill. Special thanks are due to Mrs. W. Stevens for the direction of all aspects of the publications; she was ably assisted by Mrs. C. M. Chappas. Also, the RPA rapporteurs did an outstanding job in preparing the first draft of the Summary Proceedings, and in assisting the panel chairmen in the preparation of the panel reports. Finally, I acknowledge with sincere gratitude the cooperation of the participants in making the conference a success and providing a written record of the papers presented. I believe their contributions will prove to be of great benefit to all who work in the important field of energy storage. Joseph Silverman Institute for Physical Science and Technology University of Maryland College Park, MD 20742, USA ORGANIZATION OF ASSEMBLY GENERAL CHAIRMEN Prof. A. Despic Dr. R. Smelt EXECUTIVE COMMITTEE Prof. C. Newton Dr. G. Pezdirtz Prof. L. Rakic Prof. J. Silverman Secretary-Genera I CONFERENCE COORDINATORS Mr. H. Lowitt (USA) Mr. N. Ostojic (Yugoslavia) PUBLICATIONS COORDINATOR Mrs. W. Stevens TRAVEL AND ACCOMMODATIONS COORDINATOR Ms. C. Rice RAPPORTEURS Ms. L. Burch Mr. H. Lowitt Dr. K. Mead Mr. L. Oliva Ms. C. Rice Mr. M. Siat Ms. M. Strauss SPONSORED BY National Academy of Sciences - USA Council of Academies of Science - Yugoslavia XL PROGRAM SUNDAY, 27 MAY 1979 REGISTRATION RECEPTION MONDAY, 28 MAY 1979 PLENARY SESSION I A: A. Despic (Yugoslavia), Chairman Call to Order Chairman's Remarks R. Smelt (USA) Welcome by Deputy Mayor Introductory Address J. Silverman (USA) Keynote Lecture A. Despic (Yugoslavia) PLENARY SESSION IB: V. S. Bagotskii (USSR), Chairman "Electrochemical Storage" K. Kordesch (Austria) "Thermochemical and Thermal Storage" G. Wettermark (Sweden) "Photochemical Storage" J. Rabani ( Israel) RECESS PLENARY SESSION I I A: J. P. Longwell (USA), Chairman "Mechanical Storage" Z. Stanley Stys (USA) xiii XIV Program "Modeling and Assessment" U. LaRoche (Switzerland) "An Overview of Energy Storage" N. Lidorenko (USSR) PLENARY SESSION I IB: J. Silverman (USA), Chairman Discussion of Plenary Papers TUESDAY, 29 MAY 1979 PANEL MEETINGS 1. Electrochemical Energy Storage Panel "Fuel Cells and Metal-Air Batteries as Electrochemical Energy Storage Systems" H. Cnobloch "Electrochemical Energy Storage on Board of Road Electric Vehicles" P. Montalenti and G. Brusaglino "Lithium Metal Sulfide Batteries for Electric Vehicles" P. A. Nelson "Oxygen Electrodes for Electrochemical Energy Storage Systems" E. Yeager "Electrocatalysis on Surfaces Modified by Foreign Metal Adatoms and Its Application in Fuel Cells" R. R. Adzic "Hydrogen Energy Scenario" S. Srinivasan "Fuel Cells for Transportation" H. Van den Broeck "Ambient Temperature Batteries for Electric Vehicles and Energy Storage" A. J. Salkind 2. Thermochemical and Thermal Energy Storage Panel Chairman's Introductory Remarks N. Kurti "Thermal Energy Storage for Non-Fossil Power Plants" P. V. Gilli and G. Beckmann "A Review of Current Aquifer Thermal Energy Storage Projects" C. F. Tsang Program xv "Large-Scale Annual-Cycle Thermal Energy Storage in Aquifers" C. F. Meyer "Thermal Energy Storage for Buildings" A. L. Berlad "Sweden - A Case for Long-Term Thermal Storage" W. Raldow and G. Wettermark "Thermal Energy Storage Using Metal Hydrides" H. Büchner "Summary of the U. S. Thermochemical Energy Storage and Transport (TEST) Program" T. T. Bramlette "Method of Storage and Recovery of Thermal Energy by the Use of the Chemical System: (Ethyl Sulfate) - (Ethylene, Sulfuric Acid)" R. Rigopoulos, P. Yianoulis, A. Cutinas and A. Tsolis "Research on Energy Storage at Risjo National Laboratory" 1. Ground Storage for Thermal Energy 0. Rathmann 2. Seasonal Heat Storage in Aquifers J. Reffstrup and J. Würtz 3. Natural Gas Storage in Salt Caverns S. Krenk, N. S. Ottosen, K. Jensen and I . Rassmussen 4. Energy Storage Bssed Upon Metal-Hydrogen Systems B. Vigeholm "Past, Present and Future Thermochemical Hydrogen Production Research" D. van Velzen 3. Photochemical Energy Storage Panel "Limitations of Artificial Photochemical Solar Energy Storage" M. Almgren "Some Recent Progress in Semiconductor-Liquid Junction Solar Cells" A. Hel ler and B. Miller "Processes in Photogalvanic Cells and Their Possibilities in Solar Energy Storage" 0. Haas "Photoelectrical Cell for Conversion and Storage of Solar Energy Based on Photosensitized Redox Reactions" 1. Kraljic "Electron Transfer Processes in Micellar Systems" E. Pelizzetti XVI Program "Photoredox Processes. Catalytic Generation of Hydrogen by Reactions of Metal Ions and Water" 0. I. Micic and M. T. Nenadovic "Protection, Size Factors and Reaction Dynamics of Collodial Redox Catalysts Mediating Light Induced Hydrogen Evolution from Water" J. Kiwi and M. Grätzel "Brief Summary of Canadian Research and Development of Interest to Photochemical Panel of the International Assembly on Energy Storage" E. J. Casey and D. R. Snelling 4. Mechanical Energy Storage Panel "Compressed Air Energy Storage Technology Program in the United States" M. V. Loscutoff "Actual C.A.E.S. Technology in Europe" J. Pellin "Demonstration of a Low Cost Flywheel in an Energy Storage System" D. W. Rabenhorst "A Flywheel Energy Storage and Conversion System for Photovoltaic Appl ications" A. R. Millner "Fluid Bed Augmented C.A.E.S. Systems" A. J. Giramonti "Flywheel Energy Storage Systems Operating on 'Single Active Axis' Magnetic Bearings" P. C. Poubeau 5. Modeling and Assessment Panel "Methods of Evaluating and Comparing Energy Storage Devices for Automobi les" H. C. Forsberg and E. Behrin "Energy Storage in Automotive Vehicles: An Analytical Model" R. F. McAlevy I I I "Heating with Off-Peak Electricity: A Cost-Effective Way to Save Oil and Gas" J. G. Asbury "The Assessment of Energy Storage Systems for Electric Utilities" H. G. Pfeiffer "Prioritization of Research Projects" C. R. Johnson

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