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Ram Naresh Bharagava  Pankaj Chowdhary Editors Emerging and Eco-Friendly Approaches for Waste Management Emerging and Eco-Friendly Approaches for Waste Management Ram Naresh Bharagava • Pankaj Chowdhary Editors Emerging and Eco-Friendly Approaches for Waste Management Editors Ram Naresh Bharagava Pankaj Chowdhary Department of Environmental Microbiology Department of Environmental Microbiology Babasaheb Bhimrao Ambedkar University Babasaheb Bhimrao Ambedkar University (A Central University) (A Central University) Lucknow, Uttar Pradesh, India Lucknow, Uttar Pradesh, India ISBN 978-981-10-8668-7 ISBN 978-981-10-8669-4 (eBook) https://doi.org/10.1007/978-981-10-8669-4 Library of Congress Control Number: 2018942202 © Springer Nature Singapore Pte Ltd. 2019 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. Printed on acid-free paper This Springer imprint is published by the registered company Springer Nature Singapore Pte Ltd. The registered company address is: 152 Beach Road, #21-01/04 Gateway East, Singapore 189721, Singapore Preface Rapid industrialization and urbanization is a serious concern for healthy and green environment. The contamination of environments (soil/water/air) with various toxic pollutants released from natural as well as anthropogenic activities and their adverse effects on living organisms needs focused research to mitigate and solve these prob- lems. This book provides a detailed knowledge on the different types of emerging toxic environmental pollutants discharged from various natural and anthropogenic sources, their toxicological effects in environments, humans, animals, and plants, as well as their biodegradation and bioremediation approaches by various emerging and eco-friendly approaches such as anammox technology, advance oxidation pro- cesses, membrane bioreactors, microbial degradation (bacteria, fungi, algae, etc.), and phytoremediation. Hence, this book provides a detailed knowledge on various types of emerging and eco-friendly approaches for the degradation and detoxifica- tion of pollutants, which is urgently required for the safety of environment, human, animal, and plants health. Chapter 1 conveys an impression on the usage, advantages, and shortcomings of current conventional, emerging treatment technologies available for the manage- ment of waste products generated by industrial activities. It is the overall introduc- tion about different wastewater producing industries and toxic organic and inorganic pollutants generated and their adequate treatment methodologies before its final disposal into the environment. Chapter 2 highlights the emerging contaminants con- stituting a group of natural and synthetic chemicals and microorganisms, which have proved to cause serious effects in laboratory organisms and therefore a threat to human, animal, and aquatic organisms. These are assumed to act as endocrine disruptors, are carcinogenic and teratogenic, and interfere with sex and reproduc- tion of organisms. Chapter 3 provides an overview of the application of bioremedia- tion of contaminated sites owing to municipal solid waste. The application of bioremediation technologies and well-organized mechanisms for environmental safety measures of these methods were discussed. Because some pollutants can seri- ously affect the environment, this chapter furthermore suggests strategies for better remediation of contaminated sites. Chapter 4 describes the anammox start-up and enrichment process in a submerge bioreactor and discusses about the performance v vi Preface of anammox bacteria for treating industrial wastewaters with relevant updated information. In this chapter, several reports showed that anaerobic membrane biore- actors (AnMBRs) were operated for a period of 100 to 500 days under completely anaerobic conditions and fed with synthetic media. This work demonstrated that anammox cultures can be enriched from sludges conveniently sourced from anaero- bic digesters in a reasonable time frame using the AnMBR, thus enabling the next stage of utilizing the biomass for treatment of industrial wastewaters. Chapter 5 explores the various positive and negative impacts of distillery indus- tries (DIs) wastes. DI is one of the most alarming dangers that faces living being including human and animals. The wastewater generated from distilleries creates a hazardous problem and causes serious environmental issues. Moreover, distillery wastewater (DWW) or spent wash has not only negative impact on environment but also positive aspects such as ferti-irrigation, energy generation, concentration by evaporation, production of many value-added products, etc. Chapter 6 describes about polycyclic aromatic hydrocarbons (PAHs), which are a class of diverse organic compounds with two or more intertwined benzene rings in a linear, angular, or bunch arrangement. Expulsion of PAHs is crucial as these are persevering toxins with ubiquitous event and adverse natural impacts. There are several remedial tech- niques, which are productive and financially savvy in elimination or removal of PAHs from the contaminated environment. However, biological approaches appear to be the most efficient and cost- effective environmental-friendly method to decon- taminate PAHs from source. Chapter 7 mainly highlights that industrial wastewaters such as distillery, pulp and paper, and tannery have endocrine-disrupting chemicals (EDCs), which cause serious effects in living organisms. EDC is a chemical agent, which interferes the synthesis, secretion, transport, binding, or elimination of natu- ral hormones in human and animal body that play a key role for the maintenance of various physiological and cellular functions such as homeostasis, reproduction, development, and behavioral activities. These also play significant role in metabo- lism, sexual development, hormones production and their utilization in growth, stress response, gender behavior, and reproduction even in development of living organisms. Therefore, there is an urgent need of awareness and critical research on the endocrine-disrupting chemicals present in industrial wastewaters. Chapter 8 highlights arsenic (As) toxicity and several conventional and emerging remediation methods. Arsenic is necessary for living beings. However, it is also an emerging issue by virtue of the toxicity it causes in living beings including human and animals. Basically, the groundwater contaminated by arsenic, coming from sources including arsenic-affected aquifers, has severely threatened humanity around the world. Arsenic poisoning is worse in Bangladesh and Uttar Pradesh where As(III) is found in higher concentration in groundwater. The dissolution pro- cess caused by oxidation and reduction reactions leads to natural occurrence of arsenic in groundwater. Microalgae possess a unique metabolic process making them highly efficient for the removal of nutrients as well as organic pollutants from industrial wastewater such as alcohol distillery wastewater. Microalgae generate dissolved oxygen increasing the efficiency of alcohol distillery wastewater treat- ment. Microalgal cells are represented to take up and store large amounts of N and Preface vii phosphorus as described in Chap. 9. Chapter 10 mainly highlights the endophytes and their significant role in pollutants’ mitigation or removal. These exist in tissues of host plant and have traditionally been studied for their plant growth-promoting properties, biocontrol activities, and production of bioactive compounds. Their bio- remediation potential is new and has tremendous opportunity for research and development. Endophytes are therefore interesting microorganisms in our effort to discover new tools for the bioremediation of pollutants. In this chapter, the nature of endophytes, their tolerance to pollutants, and their application and mechanisms in removing pollutants such as toxic metals and triphenylmethane dyes have been dis- cussed in details. Chapter 11 mainly focuses on the textile wastewater toxicity pro- file and various remediation strategies. This wastewater severely affects photosynthetic function of plant as well as aquatic flora and fauna by eutrophica- tion. So, the textile wastewater must be treated before their discharge. In this chap- ter, different treatment methods to treat the textile wastewater have been discussed such as physical methods (adsorption, ion exchange, and membrane filtration), chemical methods (chemical precipitation, coagulation and flocculation, chemical oxidation), and biological methods (aerobic and anaerobic) discussed in detail. Chapter 12 focuses on environmental exposure to toxic chemicals such as pesti- cides and fungicides, which are a significant health risk for humans and other ani- mals. Worldwide pesticides, fungicide, insecticides, herbicides, molluscicides, nematicides, and rodenticides are used as plant growth regulators. The pesticides, which are presently used, include a large composition of chemical compounds, which have great differences in their mode of action, absorbance by the body, metabolism, removal from the body, and the adverse effect on humans, animal, and other living entities. Chapter 13 provides the overall information on sources, char- acteristics, toxicity, and various physicochemical and biological treatment technol- ogies for the management of pulp and paper mill wastewaters. Pulp and paper mill wastewater at high concentration reduces the soil texture; inhibits seed germination and growth and depletion of vegetation while in aquatic system; blocks the photo- synthesis and decreases the dissolved oxygen (DO) level, which affects both flora and fauna; and causes toxicity to aquatic ecosystem. The advantages and disadvan- tages of several treatment methods (physicochemical and biological) have been also discussed in this chapter to upgrade the knowledge on various treatment methods. Chapter 14 mainly focused on the phytoremediation, using wild-type or transgenic plants and their attendant rhizospheric and endophytic bacteria to remove metal pol- lutants from contaminated sites. This environment friendly, cost-effective, and plant-based technology is expected to have significant economic, aesthetic, and technical advantages over traditional engineering approaches. Chapter 15 highlights on peroxidases, which obtained from several plant sources such as horseradish, tur- nip, soybean seed coat, pointed gourd, white radish, and some microbial sources have successfully been immobilized on/in various types of organic, inorganic, and nano supports by using different methods and employed for the treatment of indus- trial wastewaters having phenolic pollutants in batch as well as in continuous reac- tors. Chapter 16 mainly focuses on the nanotechnology and profitable production of nanoparticles. It has the prospective to progress the environment, both through viii Preface direct utilization of those materials to distinguish, avoid, and eliminate contamina- tion, likewise indirectly by applying the nanotechnology to intention cleaner manu- facturing processes and generate environmentally accountable products. Chapter 17 describes the novel biphasic treatment approaches to remove pollutants from indus- trial wastewater. Different biphasic treatment systems including liquid-liquid two- phase partitioning and solid-liquid partitioning systems have proved successful for the cleaning of effluents containing textile dyes, heavy metals, organic contami- nants, pharmaceutical ingredients, and many other xenobiotic compounds. Chapter 18 mainly focuses on phycoremediation technology and their several remediation as well as beneficial aspects for environmental sustainability. It is well known that algae are widely distributed on the earth and are adapted to variety of habitats. This unique feature of their fast adaptation allows the algae to develop wide range of adoptable toward many environmental conditions, suited for wastewater remedia- tion and production of biofuel and other value-added products, including food, feed, fertilizer, pharmaceuticals, and, of late, biofuel. Furthermore, this book also boosts up students, scientists, and researchers work- ing in microbiology, biotechnology, and environmental sciences with the funda- mental and advance knowledge about the environmental challenges. In addition, readers can also get valuable information/awareness related to various environmen- tal problems and their solutions. Lucknow, Uttar Pradesh, India Ram Naresh Bharagava Pankaj Chowdhary Contents 1 Conventional Methods for the Removal of Industrial Pollutants, Their Merits and Demerits.................................................. 1 Sandhya Mishra, Pankaj Chowdhary, and Ram Naresh Bharagava 2 Toxicological Aspects of Emerging Contaminants ............................... 33 Miraji Hossein 3 An Overview of the Potential of Bioremediation for Contaminated Soil from Municipal Solid Waste Site .................... 59 Abhishek Kumar Awasthi, Jinhui Li, Akhilesh Kumar Pandey, and Jamaluddin Khan 4 Anammox Cultivation in a Submerged Membrane Bioreactor .......... 69 M. Golam Mostafa 5 Toxicity, Beneficial Aspects and Treatment of Alcohol Industry Wastewater ............................................................ 83 Pankaj Chowdhary and Ram Naresh Bharagava 6 Bioremediation Approaches for Degradation and Detoxification of Polycyclic Aromatic Hydrocarbons .................. 99 Pavan Kumar Agrawal, Rahul Shrivastava, and Jyoti Verma 7 Endocrine-Disrupting Pollutants in Industrial Wastewater and Their Degradation and Detoxification Approaches ...................... 121 Izharul Haq and Abhay Raj 8 Arsenic Toxicity and Its Remediation Strategies for Fighting the Environmental Threat ................................................. 143 Vishvas Hare, Pankaj Chowdhary, Bhanu Kumar, D. C. Sharma, and Vinay Singh Baghel 9 Microalgal Treatment of Alcohol Distillery Wastewater ..................... 171 Alexei Solovchenko ix x Contents 10 Endophytes: Emerging Tools for the Bioremediation of Pollutants ............................................................................................. 189 Carrie Siew Fang Sim, Si Hui Chen, and Adeline Su Yien Ting 11 Textile Wastewater Dyes: Toxicity Profile and Treatment Approaches .................................................................... 219 Sujata Mani, Pankaj Chowdhary, and Ram Naresh Bharagava 12 Pesticide Contamination: Environmental Problems and Remediation Strategies ................................................................... 245 Siddharth Boudh and Jay Shankar Singh 13 Recent Advances in Physico-chemical and Biological Techniques for the Management of Pulp and Paper Mill Waste ........ 271 Surabhi Zainith, Pankaj Chowdhary, and Ram Naresh Bharagava 14 Role of Rhizobacteria in Phytoremediation of Metal-Impacted Sites .......................................................................... 299 Reda A. I. Abou-Shanab, Mostafa M. El-Sheekh, and Michael J. Sadowsky 15 Remediation of Phenolic Compounds from Polluted Water by Immobilized Peroxidases ....................................................... 329 Qayyum Husain 16 Nanoparticles: An Emerging Weapon for Mitigation/Removal of Various Environmental Pollutants for Environmental Safety ....................................................................... 359 Gaurav Hitkari, Sandhya Singh, and Gajanan Pandey 17 Biphasic Treatment System for the Removal of Toxic and Hazardous Pollutants from Industrial Wastewaters .................... 397 Ali Hussain, Sumaira Aslam, Arshad Javid, Muhammad Rashid, Irshad Hussain, and Javed Iqbal Qazi 18 Phycotechnological Approaches Toward Wastewater Management ....................................................................... 423 Atul Kumar Upadhyay, Ranjan Singh, and D. P. Singh

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Rapid industrialization is a serious concern in the context of a healthy environment. With the growth in the number of industries, the waste generated is also growing exponentially. The various chemical processes operating in the manufacturing industry generate a large number of by-products, which a
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