Electrophoretic deposition : fundamentals and applications IV : selected, peer reviewed papers from the 4th international conference on electrophoretic deposition: fundamentals and applications, October 2-7, 2011, Puerto Vallarta, Mexico

224 Pages·2012·47.163 MB·English

by  A R Boccaccini, et al

Electrophoretic Deposition:
Fundamentals
and
Applications IV
Edited by
A. R. Boccaccini
O. Van der Biest
R. Clasen
J.H. Dickerson
Electrophoretic Deposition:
Fundamentals
and Applications IV
Selected, peer reviewed papers from the
4th International Conference on
Electrophoretic Deposition:
Fundamentals and Applications,
October 2-7, 2011, Puerto Vallarta, Mexico
Edited by
A. R. Boccaccini, O. Van der Biest,
R. Clasen and J.H. Dickerson
Copyright  2012 Trans Tech Publications Ltd, Switzerland

All rights reserved. No part of the contents of this publication may be reproduced or
transmitted in any form or by any means without the written permission of the
publisher.

Trans Tech Publications Ltd
Kreuzstrasse 10
CH-8635 Durnten-Zurich
Switzerland
http://www.ttp.net

Volume 507 of
Key Engineering Materials
ISSN 1662-9809
Full text available online at http://www.scientific.net

Distributed worldwide by and in the Americas by
Trans Tech Publications Ltd Trans Tech Publications Inc.
Kreuzstrasse 10 PO Box 699, May Street
CH-8635 Durnten-Zurich Enfield, NH 03748
Switzerland USA
Phone: [phone]
Fax: [phone] Fax: [phone]
e-mail: [email protected] e-mail: [email protected]
Foreword
This volume contains papers presented at the 4th International Conference on Electrophoretic Deposition:
Fundamentals and Applications, held on October 2-7, 2011, at CasaMagna Marriott Hotel, Puerto Vallarta,
Mexico, under the sponsorship of Engineering Conferences International (ECI).
This was the fourth of the successful conference series that initiated in 2002 in Banff, Canada. The
conferences in this series are the only international meetings focusing entirely on electrophoretic deposition
(EPD) as a materials processing tool for fabrication of both traditional and advanced materials, with an
increasing emphasis in nanomaterials. The conference attracted over 50 contributed talks and 31 posters
from participants from 21 countries. Contributions covering a large number of topics related to EPD were
presented reflecting the wide variety of fields in which EPD is being successfully applied, which, in turn,
demonstrates the versatility of the EPD technique as a materials processing technique. The topics ranged
from theoretical and numerical studies on the fundamental mechanisms of EPD to novel technological
developments and advanced experimental methods in EPD for efficient and cost-effective fabrication of a
variety of materials and structures. The program was organized in 15 technical sessions, 2 poster
sessions, and a final discussion session.
The papers included in this volume report on the successful application of EPD to the synthesis of a
wide variety of engineering materials and components, which include free standing ceramic deposits,
ceramic and composite coatings on metallic substrates, functional films, microelectronic substrates, carbon
nanotube and bioactive coatings, piezoelectric devices and solid oxide fuel cells. The application of EPD for
the manufacture of near net-shape components exhibiting accurate dimensions is also addressed,
including EPD manufacturing of nanoparticle heterostructures and densely packed nanostructured
functional films. A few papers also explored the production of ceramics and ceramic coatings by EPD and
the integration of EPD in manufacturing technologies of more or less complex components. There is
increasing interest in the use of alternating current and pulsed electric fields for manipulating nanoparticles
and for production of ceramic deposits from aqueous suspensions without bubble evolution. EPD
techniques employing high dc electric fields, coupled electric and magnetic fields as well as pulsed electric
fields are reported, and approaches to the deposition of carbon nanotube films, bacterial cells and bioactive
coatings are also included in this volume.
The conference confirmed the highly promising potential of EPD as materials processing method. The
progress and expansion of EPD to novel applications will necessitate further investigations on both
fundamental variables affecting the process and on integrating EPD in established manufacturing
technologies. The EPD conference series provides an excellent forum to tackle these issues and indeed
the motivation for the organisation of these conferences is to foment the continuing interactions and
exchanges within the EPD community. The conference in Mexico was the largest of the series so far, which
attracted some of the most recognised EPD experts. The present volume will constitute a valuable source
of information for those whose research interests are in the EPD field coming from different materials
sectors, including basic material development, nanomaterials, colloidal processing and electrochemistry,
both in industry and academia.
We are grateful to all authors and referees, who have supported this volume with their hard work,
contributing to its timely publication. The organisation of the conference would not have been possible
without the outstanding support of Ms. Barbara K. Hickernell, Mr. Kevin Korpics, and Ms. Tressa Gaffaney,
Director, Associate Director, and Conference Registration Coordinator, respectively, of Engineering
Conferences International.

A. R. Boccaccini, Erlangen, Germany
O. van der Biest, Leuven, Belgium
R. Clasen, Saarbrücken, Germany
J. H. Dickerson, Nashville, USA
Sponsored by:

Engineering Conferences International
32 Broadway, Suite 314, New York, NY 10004
Tel: [phone] Fax: [phone]
[email protected] www.engconfintl.org

Conference Co-chairs

A. R. Boccaccini
Department of Materials Science and Engineering
University of Erlangen-Nuremberg, Germany

O. Van der Biest
Department of Metallurgy and Materials Engineering
Katholieke Universiteit Leuven, Belgium

R. Clasen
Department of Powder Technology
University of Saarland, Saarbrücken, Germany

J. H. Dickerson
Department of Physics and Astronomy
Vanderbilt University, Nashville (TN), USA
International Organising Committee

C. Argirusis (National Technical University of Athens, Greece)
C. Bellmann (Institute for Polymer Research, Dresden, Germany)
C. Buie (Massachusetts Institute of Technology, USA)
L. Besra (IMMT, India)
Y. Castro (Inst de Ceramica y Vidrio, Spain)
R. Cloots (University of Liege, Belgium)
B. Ferrari (Inst. de Ceramica y Vidrio, Spain)
C. Galassi (ISTEC, Faenza, Italy)
E. Garcia (CIDETEC, Spain)
S. Hayashi (Akita University, Japan)
K. Kanamura (Tokyo Metropolitan University, Japan)
C. Kaya (Yildiz University, Turkey)
D. Kuscer (Jozef Stefan Institute, Slovenia)
J. Ma (Nanyang Technological University, Singapore)
A. Matsuda (Toyohashi University of Technology, Japan)
R. Moreno (Inst. de Ceramica y Vidrio, Spain)
K. Moritz (University of Freiberg, Germany)
H. Negishi (National Institute of Advanced Industrial Science and Technology, Japan)
S. Novak (Jozef Stefan Institute, Slovenia)
E. A. Olevsky (San Diego State University, USA)
M. J. Santillan (FCAI, San Rafael, Argentina)
P. Sarkar (Alberta Research Council, Canada)
Y. Shimizu (Kyusyu Institute of Technology, Japan)
J. B. Talbot (University of Califorinia, San Diego, USA)
K. Tatsumisago (Osaka Pref. University, Japan)
T. Uchikoshi (National Institute for Materials Science, Japan)
P. Vilarinho (University of Aveiro, Portugal)
J. Vleugels (Katholieke Universiteit Leuven, Belgium)
P. Xiao (University of Manchester, UK)
I. Zhitomirsky (McMaster University, Canada)

Coordinator of Local Organiser Committee: Dr Gregorio Vargas, Cinvestav, Saltillo, Mexico
____________________________________________________________________________________________
Acknowledgements
The conference co-chairs and the members of the organising committee wish to thank the following
organisations for their support of the conference:
Engineering Conferences International, USA
The European Ceramic Society
The American Ceramic Society, USA
The Electrochemical Society, USA
The National Science Foundation, USA
The Institute of Materials, Minerals and Mining, UK
Deutsche Gesellschaft für Materialkunde, Germany
Deutsche Glastechnische Gesellschaft, Germany
Table of Contents
Foreword, Conference Chairs, International Organising Committee, Acknowledgements
and Photograph of Participants
I. Advanced Experimental Techniques and Theoretical Approaches
Development of Diffusion Barrier Coatings for Mitigation of Fuel-Cladding Chemical
Interactions
V. Firouzdor, L. Wilson, K. Sridharan, B. Semerau, B. Hauch, J. Brechtl, J.I. Cole and T.R. Allen 3
Hybrid Electrophoretic Deposition with Anodization Process for Superhydrophilic Surfaces
to Enhance Critical Heat Flux
Y.S. Joung and C.R. Buie 9
Textured Ti SiC by EPD in a Strong Magnetic Field
3 2
M. Mishra, Y. Sakka, C.F. Hu, T.S. Suzuki, T. Uchikoshi and L. Besra 15
Pulse Electric Fields for EPD of Thermal Barrier Coatings
H. McCrabb, J. Kell and B. Kumar 21
Triethanolamine as an Additive in the Electrophoretic Deposition of TiTe O Thick Films
3 8
X.M. Su, A.Y. Wu and P.M. Vilarinho 27
Electrophoretic Deposition onto Ionic Liquid Layers
B. Neirinck, S. Schaltin, H. Marzouk, J. Fransaer, O. Van der Biest and J. Vleugels 35
AC Electrophoresis, a New Technique for Deposition of Ceramic Nanoparticles;
Introduction, Application and Mechanism
R. Riahifar, B. Raissi, E. Marzbanrad and C. Zamani 41
Direct Numerical Simulations of Electrophoretic Deposition of Charged Colloidal
Suspensions
J.S. Park and D. Saintillan 47
Fundamentals of Pulsed and Direct Current Electrophoretic Infiltration Kinetics
T.R. Palmer and C.R. Buie 53
II. Nanostructured Materials, Carbon Nanotubes and Thin Films
AFM Characterization of the Nanoparticles Arrangement by Electrophoretic Deposition
J.A. Escribano, I. Gonzalo-Juan, A.J. Sánchez-Herencia and B. Ferrari 61
High Voltage Electrophoretic Deposition of Aligned Nanoforests for Scalable
Nanomanufacturing of Electrochemical Energy Storage Devices
S. Santhanagopalan, A. Balram, E. Lucas, F. Marcano and D.D.S. Meng 67
Thin Films of Europium (III) Doped-TiO Prepared by Electrophoretic Deposition from
2
Nanoparticulate Sols
M. Borlaf, M.T. Colomer, H. Titzel, J.H. Dickerson and R. Moreno 73
Current Measurements as a Direct Diagnostic for Sub-Monolayer Growth of Nanoparticle
Films in Non-Polar Electrophoretic Deposition
A.J. Krejci, I. Gonzalo-Juan and J.H. Dickerson 79
A Controlled Colloidal Destabilization Approach for the Electrophoretic Deposition (EPD)
from Cobalt Ferrite and Magnetite Nanoparticles Suspensions in Diethylene Glycol
C. Baldisserri, D. Gardini and C. Galassi 85
Selective Deposition of TiO during Monolayer Formation of TiO and Iron Oxide
2 2
Nanocrystals by Electrophoretic Deposition in Non-Polar Solvents
I. Gonzalo-Juan, A.J. Krejci and J.H. Dickerson 89
Electrophoretic Deposition of Cadmium Sulfide Nanoparticles: Electric Field and Particle
Size Effects
I. López, A. Vázquez and I. Gómez 95
Cadmium Sulfide and Zinc Sulfide Nanostructures Formed by Electrophoretic Deposition
A. Vázquez, I. López and I. Gómez 101
b Electrophoretic Deposition: Fundamentals and Applications IV
Electrochemical Functionalization of Single-Walled Carbon Nanotubes Films Obtained by
Electrophoretic Deposition
L. Pilan, M. Raicopol, C. Damian and M. Ioniţă 107
Fabrication of Polyaniline/Carbon Nanotubes Composites Using Carbon Nanotubes Films
Obtained by Electrophoretic Deposition
L. Pilan, M. Raicopol and M. Ioniţă 113
III. Biomaterials and Biological Entities
Confocal Microscope Studies of Living Cells Deposited Using Alternating Current
Electrophoretic Deposition (AC-EPD)
B. Neirinck, L. Van Mellaert, O. Van der Biest, J. Anné and J. Vleugels 121
Electrophoretic Deposition of PEEK-TiO Composite Coatings on Stainless Steel
2
S. Seuss, T. Subhani, M.Y. Kang, K. Okudaira, I.E. Aguilar Ventura and A.R. Boccaccini 127
Electrophoretic Deposition of Bioactive Glass Coatings on Ti12Mo5Ta Alloy
J. Fauré, R. Drevet, S. Potiron, D.M. Gordin, H. Oudadesse, T. Gloriant and H. Benhayoune 135
Corrosion Resistance Study of Electrophoretic Deposited Hydroxyapatite on Stainless Steel
for Implant Applications
K.K. Chew, S.H.S. Zein, A.L. Ahmad, D.S. McPhail and A.R. Boccaccini 141
IV. EPD Integrated Manufacturing Technologies
EPD of Phosphors for Display and Solid State Lighting Technologies
J.I. Choi, E. Sluzky, M. Anc, A. Piquette, M.E. Hannah, K.C. Mishra, J. McKittrick and J.B.
Talbot 149
Macro- and Microscale Fabrication by Field Assisted Nanoparticle Assembly - The
Challenging Path from Science to Engineering
G. Falk 155
Electrophoretic Fabrication of Rechargeable Micro Lithium-Ion Battery with 3D
Configuration
H. Munakata, H. Kaido, K. Yoshima and K. Kanamura 163
EPD of Reverse Micelle Pd and Pt Nanoparticles onto InP and GaN for High-Response
Hydrogen Sensors
K. Zdansky, R. Yatskiv, O. Cernohorsky and K. Piksova 169
Electrophoretic Deposition of Polyaryletheretherketone (PEEK) from a Matching Density
Solvent Mixture
J. Hope and P. Hope 175
Examples of EPD Process Applications in the Electronic Industry and their Characteristics
N.J.M. van Leth and G.J. Verhoeckx 181
V. EPD in Ceramic Processing
Mechanical and Tribological Properties of Al O -ZrO Based Composites Prepared by EPD
2 3 2
P. Hvizdoš, V. Puchý, D. Drdlík and J. Cihlář 191
Fly Ash/Rare Earth Oxide Coatings by EPD: Processing and Characterization
A. Arizmendi-Morquecho, A. Chávez-Valdez, J. Aguilar and J. Álvarez 197
Stability and EPD of Concentrated Suspensions of Alumina with Nanosized Titania
T. Molina, M. Vicent, E. Sánchez and R. Moreno 203
Control of Electrophoretic Deposition Kinetics for Preparation of Laminated
Alumina/Zirconia Ceramic Composites
H. Hadraba, D. Drdlík, Z. Chlup, K. Maca and I. Dlouhý 209
Preparation of Perovskite-Type Oxide Thick-Film Device by EPD Method and its
Application for Electrochemical Hydrogen-Phosphate Ion Sensor
T. Inagaki, T. Matsumoto, S. Takase and Y. Shimizu 215
Development of Internal Stresses in Alumina-Zirconia Laminates
Z. Chlup, H. Hadraba, D. Drdlík, K. Maca and I. Dlouhý 221
Key Engineering Materials Vol. 507 c
Orientation Control of Hematite via Transformation of Textured Goethite Prepared by
EPD in a Strong Magnetic Field
T. Uchikoshi, T.S. Suzuki and Y. Sakka 227
Characterization of a Ceramic Powder Surface by Contact Angle Measurements and
Infrared Spectroscopy
B. Neirinck, D. Soccol, J. Fransaer, O. Van der Biest and J. Vleugels 233