Electrophilic Monoiodination of Terminal Alkenes Supplementary

41 Pages·2013·2.36 MB·English

Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry
This journal is © The Royal Society of Chemistry 2013
Electrophilic Monoiodination of Terminal Alkenes
Sergiy V. Yemets,a Tatyana E. Shubinab and Pavel A. Krasutsky*a
a University of Minnesota, Natural Resources Research Institute, 5013 Miller Trunk Highway, Duluth, MN 55811, United States; E-mail:
[email protected]
b Computer-Chemie-Centrum and Interdisciplinary Center for Molecular Materials,University Erlangen-Nuremberg, Nägelsbachstr 25, Germany
91052

Supplementary Information

1. 1H and 13C NMR spectra……………………………………………………………………...2

2. Kinetic measurement data……………………………………………………………………21

3. Optimized geometries for all species…………………………………………………………34

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This journal is © The Royal Society of Chemistry 2013
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1. H and C NMR spectra

NMR spectra for all synthesized compounds (300 MHz 1H NMR and 75 MHz 13C NMR) were recorded using
Varian Unity Inova 300. 1H and 13C NMR chemical shifts are referenced to tetramethylsilane as internal standard
and reported in parts per million (ppm).

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