Electrochemistry: Volume 13 PDF
Preview Electrochemistry: Volume 13
Electrochemistry Volume 13 A Specialist Periodical Report Electrochemistry Volume 13 Editors Craig Banks, Manchester Metropolitan University, UK Roger Mortimer, Loughborough University, UK Steven McIntosh, Lehigh University, Bethlehem PA, USA Authors Sofiene Abdellaoui, University of Utah, Salt Lake City UT, USA Tiago Almeida Silva, Federal University of Sa˜o Carlos, Brazil Conchi O. Ania, Instituto Nacional del Carbo´n, Oviedo, Spain Orlando Fatibello-Filho, Federal University of Sa˜o Carlos, Brazil Leticia Garc´ıa-Cruz, University of Alicante, Spain Alicia Gomis Berenguer, Instituto Nacional del Carbo´n, Oviedo, Spain David P. Hickey, University of Utah, Salt Lake City UT, USA Kevin C. Honeychurch, University of the West of England, Bristol, UK Jesu´s Iniesta, University of Alicante, Spain Evaldo Jose´ Corat, National Institute for Space Research, Sa˜o Jose´ dos Campos, Brazil Evgeny Katz, Clarkson University, Potsdam NY, USA Paul. W. May, University of Bristol, UK Ross D. Milton, University of Utah, Salt Lake City UT, USA Shelley D. Minteer, University of Utah, Salt Lake City UT, USA Roger J. Mortimer, Loughborough University, UK Khiem Nguyen, University of Utah, Salt Lake City UT, USA Michelle Rasmussen, University of Utah, Salt Lake City UT, USA AdrianaS.Ribeiro,FederalUniversityofAlagoas,BrazilandLoughborough University, UK Hudson Zanin, Institute of Research and Development, Sa˜o Jose´ dos Campos, Brazil Print ISBN: 978-1-84973-980-1 PDF eISBN: 978-1-78262-027-3 ISSN: 0305-9979 DOI: 10.1039/9781782620273 A catalogue record for this book is available from the British Library r The Royal Society of Chemistry 2016 All rights reserved Apart from fair dealing for the purposes of research or private study for non-commercial purposes, or for private study, criticism or review, as permitted under the Copyright, Designs and Patents Act, 1988 and the Copyrightand Related Rights Regulations 2003, thispublication may not be reproduced,storedortransmitted,inanyformorbyanymeans,withoutthe prior permission in writing of The Royal Society of Chemistry, or in the case of reproduction in accordance with the terms of the licences issued by the CopyrightLicensingAgencyintheUK,orinaccordancewiththetermsofthe licences issued by the appropriate Reproduction Rights Organization outside the UK. Enquiries concerning reproduction outside the terms stated here should be sent to The Royal Society of Chemistry at the address printed on this page. Published by The Royal Society of Chemistry, Thomas Graham House, Science Park, Milton Road, Cambridge CB4 0WF, UK Registered Charity Number 207890 For further information see our web site at www.rsc.org Printed in the United Kingdom by CPI Group (UK) Ltd, Croydon, CR0 4YY, UK Preface Craig Banks,a Roger Mortimerb and Steven McIntoshc DOI: 10.1039/9781782620273-FP005 We are delighted to introduce volume 13 of Specialist Periodical Reports in Electrochemistry with a new editorial team (Banks, Mortimer and McIntosh) which presents comprehensive and critical reviews in all as- pectsofthefield,withcontributionsfromacrosstheglobe,providingthe readerwithaninformeddigestofthemostimportantresearchcurrently carried out in the field. Volume 13 returns to its roots and provides a range of topics written by leading experts researching at the forefront of electrochemistry. In the first Chapter, Honeychurch provides an up-to- date overview of developments of liquid chromatography dual electrode detectiondemonstratingthecurrentrangeofapplicationsthistechnique has been applied and it is noted that it is more sensitive and selective otherthatofmassspectroscopy.RibeiroandMortimerreviewtherecent progress of electrochromic and fluorescent properties of conjugated conducting polymers considering their preparation onto electrode sur- facesthroughtoapplicationsasasensors.Iniestaandco-workersexplore the use of screen-printed electrochemical platforms for biosensing ap- plications highlighting that these versatile electrodes can be modified and adapted for a plethora of sensing fields. Fatibello–Filho and col- leagues consider the preparation of vertically aligned carbon nanotubes highlighting that their electrochemical performance is dependent upon various structural factors of the nanotubes and their orientation and design. Minteer and co-workers overview the fundamental of direct and mediated bioelectrocatalysis as well as pertinent applications which spans environmental,foodandsecuritythroughtoself-poweredsensors andbiofuelcells.Last,Katzprovidesafascinatingoverviewofbiocatalytic electrodes and biofuel cells and considers implantable biofuel cells op- erating in vivo which can provide prower for operating biomedical de- vices, for example. Duringthedevelopmentofthisvolume,ourco-editor,RogerMortimer unexpectedly passed away. Roger Mortimer graduated from Imperial College London in 1977. Thereafter, he remained at Imperial until 1980, when he completed a PhD on heterogeneous catalysis under the supervision of Dr Michael Spiro. He developed his lifelong interest in the surface modification of electrodesurfacesduringapostdoctoralfellowshipwithProfessorFredC Anson at California Institute of Technology in 1981. His scientific hori- zons were then further broadened at the University of Exeter, where he collaborated with Dr David R Rosseinsky. At Exeter, he carried out im- portantstudiesonthephenomenonofelectrochromisminthinfilmsof aManchesterMetropolitanUniversity,UK bLoughboroughUniversity,UK cLehighUniversity,USA Electrochemistry,2016,13,v–vi | v (cid:2)c TheRoyalSocietyofChemistry2016 mixed-valence metal coordination complexes, and then extended the concept to conducting polymers. Lecturing positions soon followed, firstlyatAngliaRuskinUniversity(1984/87),secondlyatSheffieldHallam University(1987/89).Finally,hejoinedLoughboroughUniversityin1989. HewaspromotedtoSeniorLecturerin1999,toReaderin2001,andthen to a Personal Chair in Physical Chemistry in 2006. Roger was a strong academic citizen and was an active member of the Midlands Electro- chemistryGroup,andactivelyinvolvedintheRoyalSocietyofChemistry through membership of a number of committees. His influence will continuethroughhismanypublicationsandthenumerousstudentswho have benefited from his teaching and research. Roger was also a keen runnerandwaspartofBarrowRunnersandregularlycompetedover10K and half-marathon distances and particularly favoured trail running. Roger was a key member of Barrow Runners social scene and was awarded club personality of the year 2014. Roger died unexpectedly on 2nd May 2015, age 59. We dedicate this volume to Roger; the electrochemical community will sorely miss him. vi | Electrochemistry,2016,13,v–vi CONTENTS Cover Preface v Craig Banks, Roger Mortimer and Steven McIntosh Design and application of liquid chromatography dual electrode 1 detection Kevin C. Honeychurch 1 Introduction 1 2 High performance liquid chromatography 1 3 Electrochemical detectors 4 4 Dual electrodes detection systems 5 5 Applications 9 6 Conclusions 18 Acknowledgements 18 References 19 Conjugated conducting polymers with electrochromic and 21 fluorescent properties Adriana S. Ribeiro and Roger J. Mortimer 1 Introduction 21 2 Conjugated conducting polymers 22 3 Advances in electrochromic and fluorescent conjugated 29 polymers 4 Applications 44 5 Concluding remarks 45 References 45 Electrochemistry,2016,13,vii–ix | vii (cid:2)c TheRoyalSocietyofChemistry2016 Preparation and electroanalytical applications of vertically aligned 50 carbon nanotubes Tiago Almeida Silva, Hudson Zanin, Evaldo Jos´e Corat, Paul. W. May and Orlando Fatibello-Filho 1 Introduction 50 2 Electrochemistry of carbon nanotubes 51 3 Synthesis and characterisation of VACNT 54 4 Electrochemical (bio)sensors based on VACNT 67 5 Conclusions and future perspectives 92 References 92 Fundamentals and applications of bioelectrocatalysis 97 David P. Hickey, Ross D. Milton, Michelle Rasmussen, Sofiene Abdellaoui, Khiem Nguyen and Shelley D. Minteer 1 Introduction to bioelectrocatalysis 97 2 Bioelectrode development 98 3 Mediated electron transfer systems 100 4 Direct electron transfer systems 104 5 Materials strategies for improving current density and 108 stability 6 Applications of bioelectrocatalysis 117 References 123 Carbon materials based on screen-printing electrochemical 133 platforms in biosensing applications Jesu´s Iniesta, Leticia Garc´ıa-Cruz, Alicia Gomis-Berenguer and Conchi O. Ania 1 Overview 133 2 Carbon materials in electrochemistry 135 3 General aspects from the formulation of inks in 140 screen-printing carbon materials 4 Carbonaceous electrodes: physicochemical characterization 142 and electrochemical applications in sensing 5 Concluding remarks and future perspectives 164 Acknowledgements 165 References 165 Biocatalytic electrodes and biofuel cells controlled by 170 biomolecular signals and implantable biofuel cells operating in vivo – towards bioelectronic devices integrating biological and electronic systems Evgeny Katz 1 Introduction 170 viii | Electrochemistry,2016,13,vii–ix 2 Switchable electrodes controlled by external chemical and 171 biochemical signals 3 Coupling of switchable electrodes with biomolecular 173 computing systems 4 Biofuel cells controlled by logically processed biochemical 177 signals 5 ‘‘Smart’’signal-controlledbiofuelcells–achievementsand 188 perspectives 6 Harvesting power from biological sources – implantable 190 biofuel cells 7 Interfacing implanted biofuel cells with biomedical 194 microelectronic devices 8 Implantable biofuel cells operating in vivo – achievements 203 and perspectives Acknowledgements 203 References 203 Electrochemistry,2016,13,vii–ix | ix
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