EFFECT OF WEATHERING AND ALTERATION ON POINT LOAD AND SLAKE DURABILITY INDICES AND THE CHARACTERIZATION OF THE DEBRIS FLOW AT THE QUESTA MINE, TAOS COUNTY, NEW MEXICO by Gertrude Fobiah Ayakwah Submitted in partial fulfillment of the requirements for the Degree of Master of Science in Mineral Engineering with Specialization in Geotechnical Engineering New Mexico Institute of Mining and Technology Department of Mineral Engineering Socorro, New Mexico May, 2009 This thesis is dedicated to God almighty for seeing me through, to my Mum Agnes Adjeley Fumey, my dad Emmanuel Okyere-Boakye Ayakwah and my siblings for their prayers and support during the writing of this work. ii Abstract Point load strength (Is50) and slake durability (ID )indices provide a measure of the 2 strength and durability of rock fragments. These are also related to the alteration intensity and weathering of the materials. Samples were collected from the rock piles, alteration scars, and debris flows at the Questa mine with the purpose of examining relationships between Is50 and ID , mineralogy, chemistry, weathering, hydrothermal alteration, and 2 other geotechnical parameters. The Is50 from the various rock piles ranges from 0.6-8.2 MPa and the ID ranges from 80.9-99.5%. The Is50 and ID results from the samples 2 2 collected indicate that, the samples from the debris flows are in average stronger (average Is50= 4.0 MPa and ID = 98.4%) than the rock-pile samples and that the alteration scar 2 samples are in average weaker (average Is50 = 2.8 MPa and ID = 89.2%) than the rock- 2 pile samples. However, most of these rocks are strong in terms of their Is50 and ID . 2 The debris flows studied are similar to the Questa rock piles in terms of lithology, slake and point load indices, friction angle and particle size distribution. The profile studied is not a typical weathered profile. This is because it was observed that there are no systematic variations in the composition of the samples collected from the profile, and this indicates that the debris flow was formed by several different flood events with slightly different sources. The results of the geochemical and geotechnical characterization indicate that, the samples collected from the debris flow are similar to each other and do not show signs of decreasing weathering from the top of the profile to the bottom. The cementation of the debris flow was found to be similar to the ones found in the rock piles and is formed by oxidation of sulfide minerals producing sulfates and iron oxides. The debris flows are therefore well cemented, even below the surface. Finally, the slake durability measurements of rock pile material collected from the hot zones were found to be similar to the measurements obtained for other materials in the Questa area. They also indicated high durability. ii Acknowledgements This study owes its success to several people who contributed in various ways. However, some key personalities require special mention. My heartfelt gratitude goes to my research supervisors; Dr. Virginia McLemore and Dr. Ali Fakhimi, for their encouragement, guidance and constructive criticisms which enabled me to produce this research work on time. I also thank Chevron Mining Inc. for funding this research work. I wish to also than the Questa Rock Pile Weathering Stability Project team for their assistance throughout the sampling and data analysis period of this project. To Dave Jacobs of Chevron Mining Inc, Ariel Dickens, Kojo Anim, Frederick Ennin, Samuel Nunoo, Dawn Sweeney, Kelly Donahue and Erin Philips, I say a big thank you for your help in the laboratory work and data analysis of this work. I express my profound gratitude to Dr. Navid Mojtabai, my academic advisor who has been a father and a consular to me since the day I applied for admission to this honorable institution and also offered a lot of encouragement. Finally, to Yirrah family in Virginia, Carilli family in Socorro, my aunties Diana, Edith, Charlotte, Vida in New Jersey for the love, encouragement and their prayers during hard times in my academic life. ii Table of Contents List of Figures ..................................................................................................................... v List of Tables ..................................................................................................................... ix 1.0 INTRODUCTION ................................................................................................. 1 1.1. Background ...........................................................................................................1 1.2 Thesis Overview ...................................................................................................2 1.3 Project Background ...............................................................................................3 1.4 Thesis Objective and Scope ..................................................................................4 1.5 Description of study area ......................................................................................5 1.5.1 Location ..........................................................................................................5 1.5.2 History of Questa Mine ...................................................................................6 1.5.3 Mine Features..................................................................................................8 1.5.4. Mine geology and mineralogy ......................................................................12 1.6 Rock mass and intact rock strength ....................................................................17 1.6.1 Rock durability and slaking ..........................................................................18 2.0 EFFECTS OF WEATHERING AND ALTERATION ON POINT LOAD AND SLAKE DURABILITY INDICES OF QUESTA MINE MATERIALS, NEW MEXICO…... .................................................................................................................... 22 2.1 Introduction .........................................................................................................22 2.2 Alteration and weathering of the Questa rock piles ............................................24 2.3 Field and Analytical Methods .............................................................................29 2.3.1 Sampling .......................................................................................................29 2.3.2 Laboratory Analysis ......................................................................................30 2.4 Results .................................................................................................................38 2.5 Discussion ...........................................................................................................43 2.6 Conclusions .........................................................................................................55 3.0 CHARACTERIZATION OF QUESTA DEBRIS FLOWS ................................. 57 3.1 Introduction .........................................................................................................57 3.2 Definitions...........................................................................................................58 3.3 Background .........................................................................................................60 3.4 Sampling and analytical methods .......................................................................63 3.5 Description of the debris flow profile .................................................................66 3.6 Results .................................................................................................................68 3.7 Discussion ...........................................................................................................70 3.8 CONCLUSIONS.................................................................................................83 4.0 HOT ZONE STRENGTH STUDY ...................................................................... 85 4.1 Introduction .........................................................................................................85 4.2 Background .........................................................................................................86 4.3 Methods...............................................................................................................87 4.4 Results .................................................................................................................88 4.5 Discussion ...........................................................................................................91 4.6 Conclusion ..........................................................................................................94 5.0 CONCLUSIONS AND RECOMMENDATIONS ............................................ 96 5.2 References Cited .................................................................................................98 APPENDIX A TEST RESULTS ............................................................................... 105 iii APPENIDX B. SUMMARY RESULTS OF QUESTA MATERIALS USED IN THE STUDY. .......................................................................................................................... 125 APPENIDX C. SUMMARY COMPARISM STATISTICS OF THE STRENGTH and DURABILITYCLASSIFICATION FOR QUESTA MATERIALS. ............................. 197 iv List of Figures Figure 1.1: Location map of the chevron molybdenum mine and vicinities. ......................6 Figure 1.2: Map of chevron mine site showing mine rock piles and mine features. ...........9 Figure 1.3: Conceptual geological model of GHN rock pile, as interpreted from surface mapping, detailed geologic cross-sections, trenches, drill holes, construction method and observations during reclamation of GHN (McLemore et. al., 2008a) ...............................11 Figure 1.4: Geologic map of Questa – Red River Vicinity (Ludington et al., 2004.) .......13 Figure 1.5: Map of the alteration scars at the Questa Mine. The red circles shows where samples were taken from, for point load and slake durability test. ....................................17 Figure 2.1: The point load strength equipment in use (sample under test), showing contact cones, the loading and measuring systems (display gage) and samples to be tested. ........32 Figure 2.2: Typical irregular samples after point load strength test showing their planes of failure……….. ...............................................................................................................33 Figure 2.3: slake durability equipment during usage comprising of the test drums and the motor for rotation. ..............................................................................................................36 Figure 2.4: A typical brushed sample, each piece weighing between 40 to 60 g before the slake durability test is performed. ......................................................................................36 Figure 2.5: A typical sample after slake durability test showing bigger and smaller pieces of rock fragments after the test. .........................................................................................37 Figure 2.6: Histogram plot of point load strength index at the rock piles location (GHN, SSS, SSW, MID and SPR). ................................................................................................42 Figure 2.7: Histogram plot of slake durability index at the rock piles location (GHN, SSS, SSW, MID and SPR). ................................................................................................42 Figure 2.8: Scatter plot of Slake Durability Index and Point Load Index vs. distance from outer edge of GHN rock pile. The weathering intensity was confirmed by petrographic analyses, especially textures, as described by McLemore et al. (2008a). See Figures 1.2 and1.3 for location of trenches and layers in GHN where samples were obtained. Appendix B includes a summary of the description of these samples. ..............................44 Figure 2.9: Point load strength index values for the rock piles, alteration scars and debris flows. The average point load strength index for each location is shown with a red circle. The number of samples for each location and the standard deviation are shown in parentheses. PIT samples are unweathered drill core samples of andesite and rhyolite (Amalia Tuff) of various hydrothermal alteration intensities. See Figure 1.2 for location of rock piles. See Figures 1.2 and 1.3 for location of trenches and geologic units in GHN where samples were obtained. Appendix B summarizes the location and description of these samples. ....................................................................................................................45 Figure 2.10: Slake durability index values for the rock piles, alteration scars, and debris flows. The average slake durability index for each location is shown with a red circle. The number of samples and the standard deviation for each location are shown in parentheses. PIT samples are unweathered drill core samples of andesite and rhyolite (Amalia Tuff) of various hydrothermal alteration intensities. See Figures 1.2. and 1.3 for location of rock piles and location of trenches and geologic units in GHN where samples were obtained. Appendix B summarizes the location and description of these samples. ..46 Figure 2.11: Variation in slake index, point load and alteration (QSP, Propylitic and Argillic) of the Questa rock materials. See Figure 1.2 for location of rock piles where v samples were obtained. Appendix B summarizes the location and description of these samples……….. .................................................................................................................47 Figure 2.12: Point load strength index values for different lithologies (Amalia, Andesite and Intrusive) which includes drill core and outcrop samples. The average point load strength index for each lithology is shown with a red circle. The number of the samples and the standard deviation are shown in the parentheses. See Figure 1.2 for location of open pit. Appendix B summarizes the location and description of these samples. ...........48 Figure 2.13: Slake durability index values for different lithologies (Amalia, Andesite and Intrusive) which include the drill core and outcrop samples. The average slake durability index for each lithology is shown with a red circle. The number of samples for each location and standard deviation are shown in the parentheses. See Figure 1.2 for location of open pit. Appendix B summarizes the location and description of these samples. ......48 Figure 2.14: Variations between slake durability index, point load index, mineralogy, and chemistry. The mineralogy and chemical analyses were performed on splits of the same sample set that were used in the geotechnical testing and represent the mineralogy and chemistry of the sample tested by geotechnical methods. See Figure 1.2 for location of rock piles. Appendix B summarizes the location and description of these samples. .........50 Figure 2.15: Variation in slake index and point load index of the Questa rock materials. 51 Figure 2.16: Variations between slake durability index, point load index, friction angle, and residual friction angle. The friction angle was determined on the fine-grained matrix from the same location as the samples tested for slake durability and point load, which were determined on larger rock fragments. See Figure 1.2 for location of rock piles. See Figure 1.3 for location of trenches in GHN where samples were obtained. Appendix B summarizes the location and description of these samples. ...............................................52 Figure 2.17: Variation in slake index, point load index and paste pH of the Questa rock materials. See Figure 1.2 for location of rock piles. See Figures 1.2 and 1.3 for location of trenches and geologic unites in GHN where samples were obtained. Appendix B summarizes the location and description of these samples. The upper part of the figure is for the all the other rock pile location and the analogs except the GHN whereas the lower part is GHN….. ..................................................................................................................54 Figure 2.18: Variation in slake index, point load and simple weathering indices (SWI) of the Questa rock materials. See Figure 1.2 for location of rock piles. See Figures 1.2 and 1.3 for location of trenches in GHN and geologic units where samples were obtained. Appendix B summarizes the location and description of these samples. The upper part of the figure is for the all the other rock pile location and the analogs excluding the GHN whereas the lower part is GHN. .........................................................................................55 Figure 3.1: Photograph of Goat Hill debris flow. Boxes show location of collected samples. Collected samples consist of a bulk grab of rock material stored in 5 gallon buckets and includes matrix (soil) and rock fragments. ....................................................67 Figure 3.2: Variations of slake index, friction angle, and point load index and percent gravel with depth from the base of the debris flow profile. No observed trend of parameters with depth. .......................................................................................................71 Figure 3.3: Variations of paste pH, paste conductivity, water content and dry density with depth from the base of the debris flow profile. No clear trend was observed between the parameters and depth. ........................................................................................................72 vi Figure 3.4: Gradation curves for the sieve analysis on the individual samples from the debris flow profile. .............................................................................................................73 Figure 3.5: Variations of FeO and Fe oxide minerals with depth from the base of the debris flow profile. No clear trend of parameters with profile. .........................................74 Figure 3.6: Variations of total feldspar (K-feldspar+plagioclase) with depth from the base of the debris flow profile. No clear trend of parameters with profile. ...............................74 Figure 3.7: Variations of selected trace elements with depth from the base of the debris flow profile. No clear trend of trace elements with profile. ...............................................75 Figure 3.8: Variations of sulphur and SO4 with depth from the base of the debris flow ..75 Figure 3.9: Variations of sulphur/sulphate ratio with depth from the base of the debris flow profile. No clear trend of sulphur/sulphate with profile. ...........................................75 Figure 3.10: Variations of geochemical and mineralogical parameters on the X-axis and sample location along the profile from base to top on the y-axis. No clear trend of parameters with profile. .....................................................................................................76 Figure 3.11: Clay mineralogy XRD scans for the debris flow weathering profile. I = illite, C = Chlorite, S = smectite, K = kaolinite, J = Jarosite. .....................................................77 Figure 3.12: Backscattered electron microprobe image showing a cemented grain consisting of small hydrothermally-altered phenocrysts within MIN-GFA-0001 sample. The cement consists of clay minerals (illite), jarosite, and Fe oxides. The numbered points represent points for mineral chemistry. ...................................................................79 Figure 3.13: Backscattered electron microprobe image showing well cemented grains of hydrothermally-altered phenocrysts within MIN-GFA-0001 sample. Illite, jarosite and Fe oxide crystals are cementing the rock fragments. The cementation is similar in chemistry and texture as that found in the GHN rock pile. The numbered points represent points for mineral chemistry. ..............................................................................................................79 Figure 3.14: Backscattered electron image (BSE) of a soil sample from GHN rock pile showing rock fragment and associated fine-grained matrix material. Note the similarity in texture of the cementation of rock fragments in this image compared to the image in Figure 3.13. The fine-grained matrix consists of clay minerals and gypsum. ...................80 Figure 3.15: Backscattered electron microprobe image showing well-cemented hydrothermally-altered phenocrysts within MIN-GFA-0006 sample. Illite, jarosite, Fe oxide and feldspar crystals are cementing the rock fragments. The numbered points represent points for mineral chemistry. .............................................................................81 Figure 3.16: Backscattered electron microprobe image showing hydrothermally-altered phenocrysts within MIN-GFA-0006 sample. Illite, jarosite, Fe oxide and kaolinite crystals cementing the rock fragments. The numbered points represent points for mineral chemistry…….. ..................................................................................................................81 Figure 3.17: Sample location along the profile, sample photos and microprobe images along with sample type and strength of cementing agents. ...............................................82 Figure 4.1: Location of venting drill holes and surface vent area (SGS-JMS-0001). Blue indicates drill holes drilled in 1999 that contain monitoring instruments for temperature, O and CO . Red indicates drill holes and surface vent area that do not contain 2 2 temperature and gas instrumentation and are sites monitored by the New Mexico Tech team………….. ..................................................................................................................86 Figure 4.2: Temperature log of drill hole SI-50 from Sugar Shack South rock pile. ........89 vii
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