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Effect of hybridization symmetry on topological phases of odd-parity multiband superconductors PDF

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Preview Effect of hybridization symmetry on topological phases of odd-parity multiband superconductors

Effect of hybridization symmetry on topological phases of odd-parity multiband superconductors T.O. Puel1,∗ P.D. Sacramento1,2, and M. A. Continentino1 1Centro Brasileiro de Pesquisas Físicas, Rua Dr. Xavier Sigaud, 150, Urca 22290-180, Rio de Janeiro, RJ, Brazil and 2CeFEMA, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal (Dated: August 16, 2016) We study two-band one-dimensional superconducting chains of spinless fermions with inter and intra-band pairing. These bands hybridize and, depending on the relative angular momentum of their orbitals, the hybridization can be symmetric or anti-symmetric. The self-consistent competi- tion between intra and inter-band superconductivity and how it is affected by the symmetry of the hybridization is investigated. In the case of anti-symmetric hybridization the intra and inter-band pairings do not coexist while in the symmetric case they do coexist and the interband pairing is 6 showntobedominant. Thetopologicalpropertiesofthemodelareobtainedthroughthetopological 1 invariant winding number and the presence of edge states. We find the existence of a topological 0 phaseduetotheinter-bandsuperconductivityandinducedbysymmetrichybridization. Inthiscase 2 we find a characteristic 4π-periodic Josephson current. In the case of anti-symmetric hybridization we also find a 4π-periodic Josephson current in the gapless inter-band superconducting phase, re- g cently identified to be of Weyl-type. u A 4 I. INTRODUCTION magnetic field [19, 20]. On the other hand, triplet pair- 1 ing has been found to be physically realizable in some Multiband models for the superconducting state and systems. In Ref. [6] it was shown that odd-parity super- n] their topological properties have received increasing at- conductivity occurs in superconducting (SC) multilay- o tention recently [1–6]. This consideration has been im- ers, wherethisstateisasymmetry-protectedtopological c portant to explain many important effects in topological state. Inaddition,tripletpairingisfoundin3He[21]and r- systems. Forinstance,topologicalsemimetals[7]andchi- in Sr2RuO4[22], as well as in some rare noncentrosym- p ral superfluidity [8] have been predicted in multiorbital metric systems [23]. Triplet pairing was also studied in u modelswhereorbitalswithdifferentsymmetriesinteract. the context of extended Hubbard chain [24]. s Two component fermionic systems with occupied s and Motivatedbytherecentlydiscussedtopologicalcharac- . at p orbitalstates wereshowntohavearichphasediagram tersofmultibandmodels[4,6],andbasedonthesimplest m in both one and two dimensions [4]. A general connec- modelthatdescribesthetopologicalpropertiesofachain tion between multiband and multicomponent supercon- ofspinlessfermions,westudytheKitaevmodelwithtwo - d ductivity has also been made [9]. Topological properties orbital-bands. We include and discuss inter- and intra- n in three-band models were also studied [10–13]. band superconducting couplings. A characteristic fea- o It is well known that the Kitaev model [14–16] – anti- ture of multiband systems is the hybridization between c symmetric pairs of spinless fermions in 1D – is the sim- the different orbitals. This arises from the superposi- [ plestmodelthatexhibitsatopologicalphasewithMajo- tion of the wave functions of these orbitals in different 2 rana modes in the ends of a p-wave chain, depending on sites. It can have distinct symmetry properties depend- v thestateofthesystem. Thetopologicalnon-trivialphase ing on the orbitals involved. If this mixing involves or- 9 presents Majorana fermions at its ends. Otherwise, the bitals with angular momenta that differ by an odd num- 0 chain is in a superconducting phase with trivial topolog- ber,hybridizationturnsouttobeanti-symmetric,i.e.,in 6 7 ical properties and has no end states[16]. An extension real space we have Vij =−Vji or in momentum, k-space, 0 of this effective spinless fermions model for a multiband V(−k) = −V(k). Otherwise hybridization is symmetric . hybridized system comprised of the Su, Schrieffer and respecting inversion symmetry in different sites [25]. 1 0 Heeger (SSH) model[17] and the Kitaev model was done The bulk-edge correspondance guarantees that in the 6 in Ref. [18], where topological properties are discussed topological phases there are subgap edge states. In the 1 showing edge states that are of Majorana and fermionic case of a topological superconductor, zero energy Ma- : types. v jorana modes are predicted to appear and great effort i Triplet superconductivity is rare in nature. Thus, the has been devoted to prove their existence. Methods that X pursuitofalternativestocreatetripletsuperconductivity provide signatures of their presence have been proposed r lead to engineering a topological insulating chain (made and experimentally tested via for instance tunneling ex- a with strong spin-orbit material) in proximity of a nor- periments[26,27],interferometry[16],pointcontactsus- mal superconductor and in the presence of an applied ing the Andreev reflection [28] through the detection of zero-bias peaks [29], using the quantum waveguide the- ory[30]whichgivesthecorrectbulk-edgecorrespondence ∗ [email protected] [31] and fractional Josephson currents [14, 16, 32]. Also 2 signatures of the Majorana states may be found in bulk is measurements such as the imaginary part of frequency dependent Hall conductance [33] and the d.c. Hall con- H0 =(cid:88)(cid:110)(cid:0)εAk −µ(cid:1)a†kak+(cid:0)εBk −µ(cid:1)b†kbk(cid:111), (1) ductivity itself [34]. k The existence of topological phases is detected in this (cid:16) (cid:17) work numerically calculating the winding number and wherea†k b†k isthecreationoperatorofspinlessfermion by showing the existence of edge states at the ends of at A(B)-band with momentum k. Also, µ is the chemi- the chain. In addition, we calculate the Josephson cur- cal potential and we choose εA = −εB = 2tcos(k) ≡ ε k k k rentaccrossthejunctionbetweentwosuperconductorsto where t is the hopping amplitude. The hybridization identify regimes where the periodicity of the Josephson term is current on the phase differences between the supercon- (cid:88)(cid:110) (cid:111) ductors (original proposal by Kitaev[14]) or the equiva- Hh = V (k)a†kbk−V (−k)b−ka†−k+h.c. , (2) lent situation of a superconducting ring threaded by a k magnetic flux and interrupted by an insulator changes where V (k) = 2iV sin(k) ≡ V if the hybridization as as,k from the usual value of 2π to a 4π value [35]. As shown is anti-symmetric or V (k) = 2V cos(k) ≡ V if the s s,k before [14, 35–45] the existence of the Majoranas at the hybridization is symmetric, and V is the hybridization edges allows tunneling of a single fermion at zero-bias amplitude. Finally, the mean-field superconducting con- leadingtoa4π−periodiccurrentincontrasttotheusual tribution to the Hamiltonian is Cooper pair transport accross the junction which leads (cid:88)(cid:110) to the usual 2π−periodic current. Experimental realiza- H = ∆ a†b† +∆ b†a† SC k k −k k k −k tion to detect 4π-periodic Josephson junction has been k presented in Ref. [46] and an application to multiband (cid:111) +∆ a†a† +∆ b†b† +h.c. , (3) systems has recently been presented in Ref. [47]. A,k k −k B,k k −k This paper is organized as follows. In section II we with ∆ = i∆sin(k) where ∆ is the superconduct- k define the general Hamiltonian including symmetric and ing inter-band pairing amplitude, and ∆ = (A,B),k anti-symmetric hybridization. Also we proceed with the i∆ sin(k) where ∆ and ∆ are the supercon- (A,B) A B self-consistent calculations of the superconducting order ducting intra-band pairing amplitudes. We could parametersrelatedtothecompetitionbetweentheintra- also include a superconducting term that changes and inter-band pairings. The topological properties of Cooper pairs between different orbitals, which in the model are discussed in section III. We show a gen- terms of two particles interaction may be writ- eralcalculationofthewindingnumberwhenparticle-hole (cid:16) (cid:17) ten as (cid:80) g (k,k(cid:48)) b†b† a a +a†a† b b , symmetry is present in a 4 × 4 Bogoliubov-de Gennes k,k(cid:48) J k −k −k(cid:48) k(cid:48) k −k −k(cid:48) k(cid:48) (BdG) Hamiltonian. Also, we calculate the energy spec- where gJ is the interaction strength. Without fluctua- trum of a finite one-dimensional chain. The differences tion, i.e., in the BCS theory, this term appears as an betweentrivialandtopologicalphasesarediscussedfrom additive parameter to ∆A and ∆B, thus besides enhanc- the perspective of zero-energy states. We also make the ing the intra-band superconductivity it does not change equivalence of the topological regimes with the 4π peri- qualitatively the topological properties of the Hamilto- odicity of the Josephson current. Finally, in section IV nian considered here. we present the conclusions and review the main results. In the more compact BdG form, the Hamiltonian may be written in the Nambu representation [48] as H = (cid:80) C†H C , where C† =(cid:0)a†b†a b (cid:1) and k k k k k k k −k −k H =−µΓ −ε Γ +∆ Γ II. MODEL AND SELF-CONSISTENT k z0 k zz k yx CALCULATIONS 1 1 +∆ (Γ +Γ )+∆ (Γ −Γ ) A,k2 y0 yz B,k2 y0 yz We consider a two-band superconductor with hy- +Vk·I, (4) bridization and triplet pairing in 1D, i.e., a chain of sites where Γ = τ s , ∀ i,j = 0,x,y,z; τ and s are supporting two orbitals, let’s say orbitals A and B. The the Pauliijmatriice(cid:15)s ajcting on particle-hole and sub-band pairing between fermions may exist on different bands spaces, respectively, and s = τ are the 2×2 identity (inter-band)orineachband(intra-band)andarealways 0 0 matrices. With respect to the Hamiltonian parameters: ofp-wavetype,inthesensethatpairsofspinlessfermions V =−V Γ if the hybridization is anti-symmetric or arespatiallyanti-symmetric. Theproblemcanbeviewed k as,k zy V =V Γ if the hybridization is symmetric. as a generalization of the Kitaev model to two orbitals. k s,k zx In this section we present self-consistent results for Wealsohavethehybridizationtermbetweentheorbitals the superconducting parameters ∆, ∆ and ∆ us- A and B that may be symmetric or anti-symmetric. The A B ing the BdG formalism. The Hamiltonian defined simplestHamiltonianinmomentumspacethatdescribes in Eq. (4) can be solved using BdG transforma- those types of superconductivity and hybridization may (cid:104) (cid:16) (cid:17)∗ (cid:105) bewrittenasH=H0+Hh+HSC wherethekineticpart tions as ak = (cid:80)n uan,kγn,k+ vna,k γn†,−k and bk = 3 Figure 1. The first row shows the self-consistent solutions of the superconducting parameters, considering anti-symmetric hybridization. Theorderparameterscalculatedaretheinter-band(∆)andtheintra-band(∆ )ones. Forinstance,according A,B totheanti-symmetrichybridization,AandBcouldbetheorbitalssandp. Fortheseresultswesetg/2=g =g =1.7. Second A B row shows the corresponding energy spectrum gap and the phase diagram. Phase I is a gapless inter-band superconducting phase. II is a gapped intra-band superconducting phase. III is a topological insulating phase. IVa shows a trivial gapped inter-bandSC.IVbisatrivialinsulatingphase. Finally,Visametallicphase. Thephasediagramissymmetricaroundµ=0. (cid:104) (cid:16) (cid:17)∗ (cid:105) (cid:80) ub γ + vb γ† . This transformation di- Bogoliubov coefficients, we may write n n,k n,k n,k n,−k awengiteohrngaψylinzeei=gset(cid:0)nhuveana,lHkueasumbnai,nlktdovntnaiha,e−nkwinavvnbte,h−feukn(cid:1)foTncrt,miownhHeskprψeinnEorn=saψErenψtahrnee, ∆=gL1 (cid:88)k (cid:88)n isin(k)(cid:104)uan,k(cid:0)vnb,−k(cid:1)∗+ubn,k(cid:0)vna,−k(cid:1)∗(cid:105), n (8) the eigenstates. ∆ =g 2 (cid:88)(cid:88)isin(k)ua (cid:0)va (cid:1)∗, (9) The self-consistent solution implies that the pairings A AL n,k n,−k can be obtained using k n ∆ =g 2 (cid:88)(cid:88)isin(k)ub (cid:0)vb (cid:1)∗. (10) B BL n,k n,−k k n 1 (cid:88) ∆=g isin(k)((cid:104)a b (cid:105)+(cid:104)b a (cid:105)), (5) L k −k k −k A. Anti-symmetric hybridization k 2 (cid:88) ∆ =g isin(k)(cid:104)a a (cid:105), (6) A AL k −k Wefirstconsiderthecaseofanti-symmetrichybridiza- k tion(V )thatoccurswhentheorbitalsangularmomenta 2 (cid:88) as ∆ =g isin(k)(cid:104)b b (cid:105), (7) have different parities, like orbitals s and p. In Fig 1 we B BL k −k showtheresultsforthethreeorderparameterscalculated k self-consistently, when g/2 = g = g = 1.7. A similar A B model was considered before [49] with only inter-band pairing. The strength of the coupling g only changes the where g, g and g are the strength of the interactions superconducting amplitude of the SC phases (inter- or A B between fermions in different orbitals, in orbitals A and intra-band ones), thus its choice does not change quali- in orbitals B, respectively. At zero temperature, using tatively the results presented. It is interesting to point the representation of fermionic operators in terms of the out that the self-consistent results for the superconduct- 4 Figure2. Firstrowshowstheself-consistentsolutionsofthesuperconductingparameters,consideringsymmetrichybridization. The order parameters calculated are the inter-band (∆) and the intra-band (∆ ). For instance, according to the symmetric A,B hybridization, A and B could be the orbitals s and d. For these results we set g/2 = g = g = 1.7. Second row shows A B the corresponding spectral gap and the phase diagram. Phase I carries both types of pairings and has non-trivial topological properties. Phase IIa is a gapped superconducting phase also with both inter- and intra-band pairings, but trivial topological properties. Phase IIb is a normal insulator. The phase diagram is symmetric around µ=0. ing order parameters may converge to different results a gap closing, while the dashed lines represent a phase depending on the initial guesses. This is a consequence separation without closing the gap. Phase I in this fig- ofthefirstordernatureofthequantumphasetransitions ure is a gapless superconducting phase, driven by the between the different ground states. Therefore it is nec- inter-bandcoupling,anditwasshown[49]tobehavelike essary to calculate the energy of the different states to Weyl superconductor. The phase II is a two-band super- obtain the true ground state for a given set of parame- conductor with only intra-band couplings. Phase III is ters. a topological insulator which was shown to have local- ized states at the edges [49] of a finite chain. The phase We note first that inter and intra-band superconduc- IVa shows gapped superconductivity and represents the tivity do not coexist as equilibrium states. Their coex- strong inter-band coupling superconducting phase. The istence implies that one of them is metastable. Second, phase IVb is a trivial insulator and there is no SC re- we note that the intra-band SC does not distinguish be- maining. Finally, phase V is a normal metallic phase. tween different bands, in the sense that the results are All those phases are symmetric around µ=0. Since the equal for both pairings. We note that considering any intra- and inter-band pairings do not coexist, the phases fixed value of the chemical potential in the region where with no intra-band pairing are similar to the results pre- thereisSC,whentheanti-symmetrichybridizationisin- viously obtained [49]. The main difference results from creased it eventually destroys the inter-band SC that is theappearanceoftheintra-bandpairinginsomeregions present. Ontheotherhand,ifwekeepincreasingthehy- of the phase diagram. bridization,itraisestheintra-bandSCuptoamaximum value until it suppresses the SC definitely. In Fig. 1d we show the spectral gap for the self- consistent results. Also we show the phase diagram in B. Symmetric hybridization the right plot of the same figure. As we can see, the consideration of inter-band, intra-band superconductiv- Analogouslytothepreviouscase,wealsocalculatethe ity and anti-symmetric hybridization results in a rich orderparametersself-consistentlyconsideringsymmetric phase diagram. In this figure, the solid lines represent hybridization(V ). Thisisthecasewhentheorbitalsan- s 5 gular momenta have equal parities, like orbitals s and d. (Z) number [50]. In Fig. 2 we show the results for the same set of values In the Z class of topological systems, the topological g,g andg astheanti-symmetriccase. First,wenotice phases in odd-dimensional systems (or, in other words, A B that the intra-band SC distinguishes between different those with chiral symmetry) are characterized by the bands, sincethereisachangeofsignbetweenthem. Un- topological invariant called winding number [50, 51]. like the anti-symmetric case, here there is a coexistence This invariant counts the number of the zero-energy of inter- and intra-band SC. Remarkably, the inter-band statesprotectedbythetopologicalpropertyoftheHamil- has the larger order parameter for all region of parame- tonian, and may be calculated in the usual way [51, 52]. ters. Ingeneral,thisindicatesthattheinter-bandSChas One needs to look for an hermitian matrix which anti- highercriticaltemperature,whichturnsouttoberespon- commutes with the Hamiltonian (H), i.e., find Γ such sibleforthesuperconductivityappearinginthematerial. that {H,Γ}=0. Considering spinless time-reversal sym- Note that symmetric hybridization is responsible for the metryandparticle-holesymmetry(PHS)thentheChiral emergence of intra-band SC. Very strong symmetric hy- operator that carries both symmetries is Γ . It implies x0 bridization eventually destroys superconductivity. that the Hamiltonian anti-commutes with that operator, In Fig. 2 we also show the spectral gap for the self- which can be used to bring the Hamiltonian to an off- consistent results. We also show the phase diagram in diagonal form. Using the basis that diagonalizes Γ , x0 the right plot of Fig. 2, as in Fig. 1. As before, the solid i.e., R−1 Γ R = D, with R = Γ − Γ and D a x0 xx zx lines represent a gap closing, while the dashed lines rep- diagonal matrix, implies that resentaphaseseparationwithoutclosingthegap. Phase (cid:18) (cid:19) I and IIa are gapped superconducting phases, with the 0 q(k) R−1 H R= . (11) coexistence of inter- and intra-band couplings, but dom- k q†(k) 0 inated by the inter-band one. Phase IIb is an insulating phase and there is no SC. All those phases are symmet- Writing a generic Hamiltonian in the form ric around µ = 0. The more interesting phase is phase (cid:88) I, which allows both types of couplings and shows non- Hk = hijΓij, i,j =0,x,y,z, (12) trivialtopologicalproperties. Thisphaseischaracterized i,j bylocalizededgestatesandfinitewindingnumber,aswill whosecoefficientsh maybeextractedfromanygeneric be shown in the next section. ij Hamiltonian H through h = 1Tr(Γ H), if we apply The robustness of the inter-band superconductivity ij 4 ij the PHS to Eq. (12) as H =−Γ HT Γ and proceed can be tested varying the relative amplitudes of the g, k x0 −k x0 with the block off-diagonal calculations described above g and g parameters. Considering, for instance, the A B we find that case g = g ≡ g and selecting the point µ = 0 and A B 0 V = 1, the appearance of the inter-band SC is not con- (cid:88) s q(k)= c (h +ih )σ , j =0,x,y,z, (13) j zj yj j tinuous with increasing g, but goes through a first order j transition at some point g >g near to g =g to a value 0 0 that always has a larger amplitude than the intra-band where c = c = +1 and c = c = −1, σ are the 0 x y z x,y,z ones. While the results of Figs. 2 consider a large g Pauli matrices and σ is the 2×2 identity matrix. 0 value, the results are qualitatively the same, as long as The winding number, W, is defined as the number of the inter-band SC is present. revolutions of det[q(k)] = m (k)+im (k) around the 1 2 origin in the complex plane when k changes from −π to π, III. TOPOLOGICAL PROPERTIES ˆ 1 π ∂θ(k) W = dk, (14) 2π ∂k A. Winding number in the BDI class −π with The symmetry-protected topological systems are clas- sified accordingly to their symmetries [50]. The Hamil- m (k) θ(k)=argdet[q(k)]=tan−1 2 . (15) tonian of equation (4) has particle-hole symmetry once m (k) 1 it obeys the relation H = −OH O−1 [50], where k k the operator written in the Nambu representation [48] For the generic case considered above we have that isO =Γ K, inwhichO2 =+1andK appliesthecom- plex conjxu0gate and inverts the momentum. In addition, m1(k) = (cid:88)dj(cid:0)h2zj −h2yj(cid:1) the Hamiltonian has simplified time reversal symmetry j for spinless fermions, H = H∗ . In the presence of and k −k both symmetries, the Hamiltonian belongs to the BDI (cid:88) m (k) = d (2h h ), (16) 2 j zj yj class of topological systems, and the one-dimensionality j guaranteesthatthespaceofthequantumgroundstateis partitioned into topological sectors labeled by an integer where d =+1 and d =−1. 0 x,y,z 6 B. Edge states in a finite chain Inordertofindtheenergyspectrumofafinitechainof fermions through the BdG transformation we write the Hamiltonian, Eq. (4) transformed to real space, in the form H=C†HC, (17) where C =(cid:0)a b a† b† ··· a b a† b† (cid:1)T (18) 1 1 1 1 N N N N andtheoperatorsa†(a )andb†(b )create(annihilate)a i i i i fermion in the orbital A and B, respectively, at position i in the chain. The matrix H is defined as   H ··· H 11 1N H = ... ... ... , (19) Figure 3. Schematic figure illustrating the 1D superconduct- H ··· H ing ring with a Josephson junction. N1 NN andiscomprisedbythefollowing(4×4)interactionma- following boundary conditions trices  −e−iφ/2t(cid:48) 0 0 0  H =−µΓ , Hrr,,rr+1 =−tΓzzz0−i∆2Γyx−i∆20Γy0+V (r+1), HN,1 =H1∗,N = 00 e−iφ0/2t(cid:48) eiφ0/2t(cid:48) 00 , HHr,r−1 ==−0tΓzz∀+r(cid:48)i∆(cid:54)=2Γry,xr++i1∆20oΓryr0−+1V, (r−1), 0 0 0 −eiφ/2t(cid:48) r,r(cid:48) (22) (20) where the superconducting phase difference φ across the where V (r+1) = −V (r−1) = −iV2Γzy for anti- junction is related to the magnetic flux through the ring symmetric hybridization, and V (r+1) = V (r−1) = by φ = 2πΦ/Φ , and Φ = h/2e is the superconduct- 0 0 V2Γzx for symmetric one. ing flux quantum. We have that t(cid:48) is the tunneling, or IfweconsidertheBdGtransformationasthefollowing inversely proportional to a barrier amplitude, across the junction. As mentioned above this is equivalent to the a =(cid:80) (cid:2)u (r)γ +v∗ (r)γ†(cid:3), original proposal of the Josephson junction between two br=(cid:80)n(cid:2)us,n(r)γn+v∗s,n(r)γn†(cid:3), (21) different superconductors with different pairing phases r n p,n n p,n n also separated by some tunneling amplitude accross an insulator (or metal). it diagonalizes the Hamiltonian, H = E0+(cid:80)nEnγn†γn, We may now analyze the junction effect on a current such that U†HU = E, where U is formed by all the flowingintheringaswechangethemagneticfluxbydis- BdG coefficients us, vs, up and vp, and has the property creteamountsoffluxquantum,bychangingthejunction to be unitary U†U = I. The matrix E is diagonal and phase φ by multiples of 2π. In a normal superconductor contains the energy spectrum (En) of the system. each additional flux quantum (∆φ=2π, usually called a pump)shouldleadthesystemtoitsinitialstate[54]. On the other hand, the topological superconductor (TSC) C. 4π Josephson effect changesitsparityateverypump[55],leadingthesystem to a different final state after pumping. The reason is In the previous section we have considered a 1D open that the TSC is allowed to have zero energy crossings in chain, i.e., there is no connection between sites 1 and N. itsspectrumofexcitationduringthepumpandtherefore In terms of eq. (20) we have H =H =0. Now we only returns to its initial state after a further change of N,1 1,N maythinkofachainasaringwithaJosephsonjunction the phase by 2π. coupling the ends, see Fig. 3. An extra hopping term t(cid:48) couples the end point of the ring to the first point via someinsulatingjunction. Ifauniformmagneticfield(Φ) D. Symmetric hybridization flows through this ring, its effect may be captured by a Peierls substitution in the extra hopping term, t(cid:48) [53]. a. Winding number: we begin our analysis of the Thus, the Josephson junction may be represented by the topological phases of the proposed model with the wind- 7 potential. To be sure that the phase is topological we must calculate the winding number itself, or see if the parametric plot of m¯ (k) and m¯ (k) contains the origin 1 2 when k ∈ [−π,π]. The results for the winding number and the parametric plot are shown in Fig. 4 for the pa- rameters V = 1.2, µ = −1.04. This figure shows that s theparametricplotwrapstheorigintwice;itmeansthat the winding number in this case is two, W =2. The re- sultsforthewindingnumberclearlyshowthetopological phase, induced by symmetric hybridization, and dom- inated by inter-band superconductivity for small values ofthechemicalpotentialthatgrowsasthehybridization, V , grows. s b. Edge states – Since we have defined the topolog- ical region of the parameters, we may analyse the zero- energy modes explicitly through the energy spectrum of a finite chain. We have calculated the energy spectrum Figure 4. In the left panel we show the winding number calculated from the self-consistent results for symmetric hy- forachainofL=100sites,therefore,weget4Lenergies bridization, over the phase space of parameters. In the right for the spectrum. We have checked that this size is large panels we show the normalized parametric plot of real and enough to prevent finite size effects. We analyze the en- imaginarypartsofdet[q(k)]. Thenumberoftimesdet[q(k)] ergy spectrum for two fixed values of chemical potential, wraps the origin is the winding number and is illustrated in µ = 0 and µ = −1.4, and increasing the hybridization the right side. according to the self-consistent solution of Fig. 2. The results are shown in Fig. 5. What we immediately see is that the zero-energy states are robust, i.e., even when µ is non-zero they are present, which characterizes the zero-energy modes in the superconducting phase. We notice that those states are four-fold degenerated. We have checked that they have wavefunctions that are lo- calized exponentially close to the edges if the system is large enough. c. 4π Josephson effect: we may also analyse the topological properties of the system via Josephson junc- tion scheme, see Fig. 3. First, we look to the excitation spectrum (bogoliubons) during two pumps for each su- perconducting phase in the phase diagram. The results are shown in the first row of Fig. 6, where 6a is for the trivial phase IIa, whereas 6b and 6c are for the topolog- ical phase I for two values of the chemical potential. We may see that there are level crossings when the SC is in itstopologicalphaseandthereisnocrossinginthetrivial one. To explicitly see the periodicity of the Josephson cur- rent during the pump, we need to analyse the ground state energy (E ) of the superconductor preserving its 0 Figure 5. Here we show the energy spectrum of the self- parity, i.e., the ground state is composed by the solid consistent results, for two fixed values of the chemical po- (red) lines of the excitation spectrum. Dashed (blue) tential and increasing symmetric hybridization (µ=0 on (a) lines carry the opposite parity. Thus, the sum over the and µ=−1.4 on (b)). "negative" excitation to compute E needs to follow the 0 excitation when it crosses the zero energy state. In the topological phase, the crossing through zero energy is ing number calculation. For convenience, we’ll consider a direct consequence of the presence of the zero energy the case where ∆B = −∆A = ∆0. If we compare mode at the end of the chain. Here we have two zero Eq. (4) – with symmetric hybridization Vs,k – and Eqs. energy excitations at each end, thus it is natural that (16) we have m1(k) = µ2 +∆2k +∆20,k −Vs2,k −(cid:15)2k and we have two level crossings (we notice that region I with m (k) = −2(V ∆ −(cid:15) ∆ ). This suggests that the µ = 0 in Fig. 6 has a degenerate level crossing). When 2 s,k k k 0,k symmetrichybridizationmayinduceatopologicalphase, µ(cid:54)=0 the level crossing modes do not need to be degen- since we have non-vanishing m even to zero chemical erated,butwenoticethateventhoughwehavetwolevel 2 8 Figure 6. Results for the case of symmetric hybridization case as we vary the tunneling phase φ: i) First row shows the excitation spectrum that preserves the parity of the superconductor. ii) Second row shows the Josephson current through the Josephson junction. Here we have used L=150 and t(cid:48) =0.1. crossings (and their particle-hole symemtric), the cross- ings through zero always happen at the same φ point. Second row of Fig. 6 shows the current flowing through the junction, which is the derivative of the ground state energy respective to the flux φ. We clearly see that the current has a periodicity of 2π (one pump) in the trivial phase, Fig. 6d. On the other hand, the periodicity of the Josephson currents in Figs. 6e and 6f are 4π (two pumps), characterizing the topological superconducting phaseandprovidinganalternativeevidenceforthepres- ence of Majorana states. E. Anti-symmetric hybridization d. Winding number: we proceed the analysis of the topological properties with the winding number calcula- tion. For convenience, and since the self-consistent re- sults do not distinguish the SC in the bands, we’ll con- sider the case where ∆ = ∆ = ∆ . Therefore, com- A B 0 paring Eq. (4) – with anti-symmetric hybridization, Vas Figure 7. Here we show the energy spectrum of the self- – and Eqs. (16) we have that m1(k)=µ2+∆2k−∆20,k− consistent results, for two fixed values of the chemical po- V2 −(cid:15)2 and m (k) = −2µ∆ . As a result we notice tential and increasing anti-symmetric hybridization (µ = 0 as,k k 2 0,k that only for a non-zero chemical potential and intra- on (a) and µ=−1.4 on (b)). band superconductivity we have non-vanishing m and 2 the system may include a topological phase. Calculating the winding number, as described in Eq. (14), one ob- property of phase III is hidden by particle-hole symme- tains a trivial solution (W =0) for all self-consistent so- try. Moreover, Ref. [49] shows that in this phase local- lutionsinparameterspace[49]. Eventhoughthewinding ized states are present in the edges of the chain (despite numberseemstoindicateatrivialsolution,theresultsof having finite energy when µ (cid:54)= 0). As concerns phase I, Ref. [49] for a system with no intra-band pairing show it is a topological phase that presents Weyl fermions [49] that the phases corresponding to regions I and III of the whose topological character remains also undetected by phase diagram in Fig. 1 are topological. The topological the winding number calculation. In that reference it is 9 Figure8. Resultsforanti-symmetrichybridizationaswevarythetunnelingphaseφ: i)Firstrowshowstheexcitationspectra that preserve the parity of the superconductor. ii) Second row shows the Josephson current flowing through the Josephson junction. Here we have used L=250 and t(cid:48) =0.1. shown an alternative procedure to uncover the topologi- there are no level crossings in the excitation spectrum cal nature of this phase. and the current is 2π periodic as we can see in Fig. 8a for the case of region IVa. e. Edge states – now we proceed with the analysis In phase I, even though we have no gap in the bulk of the zero-energy modes explicitly through the energy spectrum of an infinite system, it is still possible to cal- spectrum of a finite chain. We also have used L = 100 culatetheJosephsoncurrentinafiniteone. Thejunction sites, which is large enough to prevent finite size effects. itself opens up a small gap in the spectrum if L is not We analyze the energy spectrum for two fixed values of too large and t(cid:48) is not too strong. Of course, in the limit chemical potential, µ = 0 and µ = −1.4, and increasing L→∞thegapcloses, butifthetunnelingt(cid:48) istoolarge thehybridizationaccordingtotheself-consistentsolution (or the barrier too small) the junction just couples both of Fig. 1. The results for anti-symmetric hybridization ends analogously to a periodic boundary condition (i.e., are shown in Fig. 7. We immediately see that the zero- infinite system). Thus, a typical excitation spectrum for energy states for µ=0 are not robust, in the sense that very small energies in the gap generated by the coupling theydisappearwhenµ(cid:54)=0. Thisisthedifferenceofzero- accross the junction (positive and negative excitation) is energymodesinthesuperconductor(phaseIforsymmet- shown in Figs. 8b and 8c. richybridization)andzero-energymodesintheinsulator (phase III for the anti-symmetric hybridization). The Even though Figs. 8b and 8c show no level crossings chemical potential is not breaking any symmetry, but during the pumps, we may proceed with the same calcu- the zero-energy modes in the superconductor are topo- lations as before and obtain the Josephson current. The logically protected and survive after the introduction of result is shown in Figs. 8e and 8f for two values of the afiniteµ,whileintheinsulatorthosezero-energymodes chemical potential. Clearly, both figures exhibit 4π pe- are not protected and can be eliminated as you see in riodic Josephson current, even without zero energy level this figure. crossings revealing in some sense the hidden topological nature of this Weyl-phase. f. 4π Josephson effect: we may also analyse the topological properties of the system via Josephson junc- tion scheme (Fig. 3). We start looking to the ex- citation spectrum (bogoliubons) during two pumps for IV. CONCLUSIONS each superconducting phase in the phase diagram. The anti-symmetric case has three types of superconducting Inthispaperwehavestudiedamodelofap-wave,one phases: intraband gapped SC, interband gapped SC and dimensional, multiband superconductor. This represents interband gapless SC, as shown in Fig. 1e. Both gapped a generalization of the single band model for odd-parity superconductingphases(IIandIVa)showsimilarexcita- superconductivity that gives rise to a much richer phase tionspectraandtheirtypicalbogoliubonsthatkeepsthe diagram with a variety of quantum phase transitions. ground state parity are shown in Fig. 8a. As expected, Theodd-paritysuperconductivityispreservedinthisex- 10 tension, but inter-band superconductivity is now present thenatureofthetopologicalphasesandtheirendstates, in addition to the intra-band ones. The presence of two- we have analyzed the energy spectrum of a finite sys- bands in our model allows us to include hybridization, tem. We have compared the energy spectrum between increasing the space of parameters. We have considered the anti-symmetric and symmetric results, or the trivial symmetric and anti-symmetric hybridizations. Both are andtopologicalresults,respectively. Wealsocheckedthe permitted, depending on the parities we choose for the localization of the zero-energy states. angular momenta of the two orbitals. In order to provide further evidence for the presence Wehavecalculatedtheself-consistentsolutionsforthe ofedgeMajoranastateswehaveshownthatinthetopo- inter- and intra-band superconducting order parameters logicalphasesonefindsa4π-periodic(fractional)Joseph- as functions of the chemical potential and the strength son current as one changes the magnetic flux accross a of the symmetric or anti-symmetric hybridization. The ring composed of the superconductor with an insulator self-consistent calculation of the order parameters allow inserted between its ends. The result is consistent with to obtain the T =0 phase diagram of the system. When the results for the winding number and edge states for increasing anti-symmetric hybridization, both intra- and thetopologicalphaseinthecaseofsymmetrichybridiza- inter-band superconductivity emerge in the phase dia- tion. In addition, we also found the same 4π-periodic gram, buttheycompeteandexcludeoneanotherfordif- Josephsoncurrentinthehiddentopologicalphaseidenti- ferent values of band-filling. On the other hand, when fiedpreviouslyasWeyl-typeinthecaseofanti-symmetric increasingthesymmetrichybridization,bothtypesofsu- hybridization. perconductivity are present and they coexist. An inter- Asafinalnote,wehighlightthatsymmetrichybridiza- estingresultisthatinter-bandsuperconductivityhasthe tion in addition to odd-parity inter-band superconduc- highest value of order parameter, indicating that it has tivity stabilizes a topological non-trivial phase, which the higher critical temperature and makes it responsible presents localized states at the ends of the chain. for the superconductivity appearing in the system. ACKNOWLEDGMENTS A general approach for obtaining the winding num- ber of a system described by 4 × 4 matrices was pre- sented. It may be applied whenever particle-hole sym- The authors would like to thank the CNPq and metry and spinless time-reversal symmetry are present FAPERJ for financial support. They also are grate- in a Bogoliubov-de Gennes (BdG) Hamiltonian, which is ful to Emilio Cobanera for discussion and calling at- the case of the two-bands BCS superconductors studied tention to Ref. [47], and Griffith M.A.S. for useful here. Accordingtothisapproach,adominantinter-band discussions. Partial support from FCT through grant couplingwithsymmetrichybridizationbetweenbandsin- UID/CTM/04540/2013 is acknowledged. duces a topological superconducting phase. The non- trivial topological character of this phase was shown through a calculation of the winding number, using the self-consistent solutions for the different order parame- REFERENCES ters. In order to further clarify our results concerning [1] J.Kortus,PhysicaC:Superconductivity456,54 (2007), [9] Y. Tanaka, Superconductor Science and Technology 28, recent Advances in MgB2 Research. 034002 (2015). [2] X. X. Xi, Reports on Progress in Physics 71, 116501 [10] V. Stanev, Superconductor Science and Technology 28, (2008). 014006 (2015). [3] Y. Yang, W.-S. Wang, Y.-Y. Xiang, Z.-Z. Li, and Q.-H. [11] G. Go, J.-H. Park, and J. H. Han, Phys. Rev. B 87, Wang, Phys. Rev. B 88, 094519 (2013). 155112 (2013). [4] S. Yin, J. E. Baarsma, M. O. J. Heikkinen, J.- [12] S.-Y. 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