DTIC ADA463648: Water and Sediment Quality in the Yukon River Basin, Alaska, During Water Year 2005

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Water and Sediment Quality in the Yukon River Basin,
Alaska, During Water Year 2005

Open-File Report 2007-1037

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U.S. Geological Survey
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1. REPORT DATE 2. REPORT TYPE 3. DATES COVERED
2007 N/A -
4. TITLE AND SUBTITLE 5a. CONTRACT NUMBER
Water and Sediment Quality in the Yukon River Basin, Alaska, During
5b. GRANT NUMBER
Water Year 2005
5c. PROGRAM ELEMENT NUMBER
6. AUTHOR(S) 5d. PROJECT NUMBER
5e. TASK NUMBER
5f. WORK UNIT NUMBER
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20240
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The original document contains color images.
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a. REPORT b. ABSTRACT c. THIS PAGE SAR 75
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Standard Form 298 (Rev. 8-98)
Prescribed by ANSI Std Z39-18
Cover photograph: U.S. Geological Survey scientists measuring discharge at the mouth
of the Forty-mile River in Yukon Territories, Canada, August 2004
Water and Sediment Quality in the Yukon River Basin,
Alaska, During Water Year 2005
Edited By Paul F. Schuster

Open-File Report 2007-1037
U.S. Department of the Interior
U.S. Geological Survey
U.S. Department of the Interior
DIRK KEMPTHORNE, Secretary
U.S. Geological Survey
Mark D. Myers, Director
U.S. Geological Survey, Boulder, Colorado 2007

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Contents
Overview...................................................................................................................................................................vi
Acknowledgments.................................................................................................................................................vii
CHAPTER 1 - Introduction.......................................................................................................................................1
CHAPTER 2 - Fixed-Station Samples....................................................................................................................4
CHAPTER 3 - Dissolved Organic Carbon Characterization.............................................................................22
CHAPTER 4 - Dissolved Major Cations and Trace Elements..........................................................................25
CHAPTER 5 - Mercury Analyses..........................................................................................................................42
CHAPTER 6 - Dissolved Gasses and Dissolved Inorganic Carbon................................................................44
CHAPTER 7- Sediment Chemistry........................................................................................................................46
CHAPTER 8 - Sediment Mineralogy....................................................................................................................51
CHAPTER 9 - Sediment Concentration and Percent Organic Matter ..........................................................56
CHAPTER 10 - Total Particulate Carbon, Particulate Inorganic Carbon Particulate Organic Carbon,
and Total Particulate Nitrogen..................................................................................................58
CHAPTER 11 - Isotopic Analysis of Suspended Particulate Organic matter...............................................60
CHAPTER 12 - Uranium Isotopes.........................................................................................................................62
References Cited....................................................................................................................................................64

Figures
1. Map showing location of fixed-station water-quality sampling sites in the Yukon River Basin ..........3

Tables
1. Summary of site characteristics at five fixed stations in the Yukon River Basin .................................. 4
2. USGS National Water Quality Laboratory analyses-Yukon River at Eagle, Alaska................................5
3. USGS National Water Quality Laboratory analyses-Porcupine River near Fort Yukon, Alaska...........8
4. USGS National Water Quality Laboratory analyses-Yukon River near Stevens Village, Alaska........11
5. USGS National Water Quality Laboratory analyses-Tanana River at Nenana, Alaska.......................15
6. USGS National Water Quality Laboratory analyses-Yukon River at Pilot Station, Alaska..................19
7. Dissolved organic carbon concentrations and fractionation analyses from fixed-station sampling
sites in the Yukon River Basin .......................................................................................................................23
8. Selected dissolved major cations and trace elements from fixed-station sampling sites in the
Yukon River Basin............................................................................................................................................ 26
9. Mercury and methylmercury concentrations from fixed-station sampling sites in the Yukon River
Basin ..................................................................................................................................................................43
10. Carbon dioxide, methane, and dissolved inorganic carbon concentrations from fixed-station
sampling sites in the Yukon River Basin......................................................................................................45
11. Sediment chemistry data from fixed-station sampling sites in the Yukon River Basin ......................47
12. Sediment mineralogy data from fixed-station sampling sites in the Yukon River Basin.....................52
13. Suspended sediment concentrations and percent organic matter in sediment from fixed-station
sampling sites in the Yukon River Basin......................................................................................................57
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14. Total particulate carbon, particulate inorganic carbon, particulate organic carbon, and total
particulate nitrogen concentrations from fixed-station sampling sites in the Yukon River Basin....59
15. Suspended sediment isotopic data from fixed-station sampling sites in the Yukon River Basin......61
16. Uranium concentration and 234U/238U isotopic activity ratio analyses in water samples from fixed-
station sampling sites in the Yukon River Basin ........................................................................................63

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Conversion Factors
_________________________________________________________ _ __
Multiply by To obtain
Length
nanometer (nm) 3.937 x10-8 inch (in.)
micrometer (μm) 3.937 x10-5 inch (in.)
millimeter (mm) 3.937 x10-2 inch (in.)
centimeter (cm) 3.937 x10-1 inch (in.)
meter (m) 3.281 foot (ft)
Area
square kilometer (km2) 3.861 x10-1 square mile (mi2)
Flow
cubic meter per second (m3/s) 35.31 cubic foot per second (ft3/s)
Volume
microliter (µL) 3.382 x10-5 ounce, fluid (oz)
milliliter (mL) 3.382 x10-2 ounce, fluid (oz)
liter (L) 2.642 x10-1 gallon (gal)
Mass
microgram (μg) 3.527 x10-8 ounce, avoirdupois (oz)
milligram (mg) 3.527 x10-5 ounce, avoirdupois (oz)
Degree Celsius (οC) may be converted to degree Fahrenheit (οF) by using the following equation:
F=1.8 (οC) + 32

Vertical coordinate information is referenced to the North American Vertical Datum of 1988
(NAVD 88)

Horizontal coordinate information is referenced to the North American Datum of 1983 (NAD 83)

Water year is the 12-month period October 1 through September 30 and is designated by the calendar year in which it
ends.

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Overview

This report contains water-quality and sediment-quality data from samples collected in the
Yukon River Basin from March through September during the 2005 water year (WY). Samples were
collected throughout the year at five stations in the basin (three on the main stem Yukon River, one
each on the Tanana and Porcupine Rivers). A broad range of physical, chemical, and biological
analyses are presented.
This is the final report in a series of five USGS Open-File Reports spanning five WYs, from
October 2000 through September 2005. The previous four reports are listed in the references
(Schuster, 2003, 2005a, 2005b, 2006). All five reports are also available on the World Wide Web:
WY 2001 http://pubs.usgs.gov/of/2003/ofr03427/
WY 2002 http://pubs.usgs.gov/of/2005/1199/
WY 2003 http://pubs.usgs.gov/of/2005/1397/
WY 2004 http://pubs.usgs.gov/of/2006/1258/
WY 2005 http://pubs.usgs.gov/of/2007/1037/

Water-quality and sediment-quality data from samples collected on the Yukon River and selected
major tributaries in Alaska for synoptic studies during WYs 2002–03 are published in Dornblaser
and Halm (2006) and also are available at: http://pubs.usgs.gov/of/2006/1228/.
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Acknowledgments

The USGS National Stream Quality Accounting Network (NASQAN) and the National
Research Program would like to thank the USGS Alaska Science Center, Water Discipline, in
Anchorage and the USGS Field office in Fairbanks. Without their field expertise and continuous
logistical support this work would not have been possible.
As the coordinator for the USGS Yukon River Basin studies and editor of all five data
reports, I would like to acknowledge each individual who participated in some capacity during these
5 years. The collective insight, help, and dedication of these individuals created a unique,
productive, successful, and fun work environment. The extensive list includes personnel and
volunteers from the USGS, Canadian government, universities, public schools, indigenous tribal
councils, advocacy groups, and village communities.

George Aiken, Ron Antweiler, Bernie Austin, Marilyn Austin, Bill Barber, Heather Best
John Borg, Tim Brabets, Christian Breen, Kenna Butler, Leon Caroll, Mark Carr, Veronica
Carrasco, Mark Castor, Ken Coe, Charlie Couvillion, Steve Darnell, Ryan Davis, Teri Dennison,
Jim DeRose, John DeWild, Dan Doctor, Mark Dornblaser, Dennis Eberl, Luke Eberl, Melanie
Estep, Dennis Evans, Jacques Finlay, Brian Forsyth, Zan Frederick, Doug Halm, Terry
Hanlon, Wade Hanna, Bob Hirsch, Rick Hooper, Art Horowitz, Randy Host, Marlys House, Erica
Keefe, Carol Kendall, Ben Kennedy, Jay Klinck, Rich Kopish, Dave Krabbenhoft, Tom
Kraemer, Rebecca Kyle, Dusty Langley, Pat LaTour, Russ Livingston, Dan Long, Pat Maltais, Bev
McNaughton, Bob Michel, Ed Neal, Gordie Nelson, Brian Neubert, Mark Olson, Shane Olund, Bob
Ourso, Scott Palfreyman, Mike Parker, John Pearce, Francis Peters, Terry Plowman, Pete
Raymond, Mike Reddy, Dennis Rosenkranz, Dave Roth, Andrea Ryan, Tom Sabin, Jenny
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