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DTIC ADA436021: Self-Disinfection and Decontaminating Interior Surfaces Based on Photocatalytic Titania/Easy-Release Coatings PDF

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FLES - NOITCEFNISID DNA GNITANIMATNOCED ROIRETNI SECAFRUS DESAB NO PHOTOCATALYTIC TITANIA/EASY - RELEASE COATINGS r e ti.raEeBboR Y,4 No1l2 a4f1f u,Bolaff utyBatisrevi n,Umargo rePtauda rsGlairetamoiB oz z.rIMehpotsirhC ,oNlaf f,usBeirtsu dcnaImraH Y 51 241 a rleu ta.oPJciN 0 Y8 ,N1y 2o 1r,Tetutits ncIinhcetyl orPealessneR TCARTSBA ysa etah tdetartsnome deva heW lyhte -mnih ty bdetrapm iseitilau qesaeler - ,sgnita oecnal idsetanimret ra pedixoi dmuinati ty bnoitcefnisi dcitylata chti wdenibmo cnehw yllaicifrepu sr on ideddebm eselcit tc uoddtehcatta -ssalgreb idfeta odc nsaecafr usssalgreb irfenil - e hetvorp mn ia,cscirb alfarutcetihc rdaesab r iCaA VfeHocnamrofr eypratinas hc u fsnooitacil-p pea hdtetaula vtecejo rsp i. hsTmets ygsnildnah ap/sgnitaoc tc u odstelcitr ecafr- u.e sshnToitisopm oscsa lsguorb idfeta od cnsaecafr usssalgreb ilflaw - APE Han idecal pere wslaireta mdeifidom -r iyarotarob adleretlif - detarbil ahct idwesuf n,imets ytscud eiciffu ssdohte mecneic secafru shti wdelpma sdn aslosoreaoib ’sevitidd aeh tenimrete do tevitisne syltn d nganitcefnis icditylatacot o. hnPoitatib adh nnaoitazinol olcairetc agbnigaruocs i oddtrag ehrt isweicaciffe fles VU ("thgi lkcalb "o teru-sopx ey bdecudn i,ytivitc agninaelc y -bdewollo fsa w,noitanimull i)A ceps . seuqinhc eetrutl ulcairetc adb ndaerarf n yi sblal e sw,agnihcae lnboitul oesu lebnelyht e fmyortemort NOITCUDORTNI demrifno cdn adetartsnome dnee bylsuoiver psa htI 2,1 citylatacoto h ypdbetcefnis i ednb arc itaaht evor pesoh to tralimi sseuqinhcet reta wn ismsinagroorci mgnilli kn ilufsseccu se bo td 5,4,3 cifice p es. hT 79 9 na1diehsilb uep r,asedi xmouinat i ftyortsime hncoitca eer h otgtnital etrs o,msliat ecdifitneics weiver 6 . o cdetcefn iyllaitneto pgnipee kdn agnizitina sf olao geh tgnidrageR gnidli urboiret n fisoecafr utscatn noitcefnisi delbataepe rdn aelbaile rro fsmetsy sretawredn umor fsecnereffi dnia meh tf oen o,nael csecafrus 'sepolevn egnidliu br o'stcu deh tff odehsa wylisa es ato ner aseborci mdeyortse dr odae dtah tsi laiborcimitna tc udd nganidli u nbtinemevorp meilbabo rlpanoitid d na,as u. hsTecafr us - seitrepo rrpenil hti wreilra edehsilpmocc anee bsa hsi h .Tsirbe detalucitra pf oevitnete rsse lsreni leh teka mo te bdluow ys areetawrednu -sgnita oecsaeler 7tpecno cema seh two ndn a gnidnuorru seh ts aevre so tdednetx eylwe ns i ysae .selcit-r aepdixo imduinat ictitylatacoto hrp oxfirt aemsaeler 1 Report Documentation Page Form Approved OMB No. 0704-0188 Public reporting burden for the collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding this burden estimate or any other aspect of this collection of information, including suggestions for reducing this burden, to Washington Headquarters Services, Directorate for Information Operations and Reports, 1215 Jefferson Davis Highway, Suite 1204, Arlington VA 22202-4302. Respondents should be aware that notwithstanding any other provision of law, no person shall be subject to a penalty for failing to comply with a collection of information if it does not display a currently valid OMB control number. 1. REPORT DATE 2. REPORT TYPE 3. DATES COVERED 00 JAN 2002 N/A - 4. TITLE AND SUBTITLE 5a. CONTRACT NUMBER Self-Disinfection And Decontaminating Interior Surfaces Based On 5b. GRANT NUMBER Photocatalytic Titania/Easy-Release Coatings 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) 8. PERFORMING ORGANIZATION Biomaterials Graduate Program, University at Buffalo, Buffalo, NY REPORT NUMBER 14214; Harmac Industries, Buffalo, NY 14215 9. SPONSORING/MONITORING AGENCY NAME(S) AND ADDRESS(ES) 10. SPONSOR/MONITOR’S ACRONYM(S) 11. SPONSOR/MONITOR’S REPORT NUMBER(S) 12. DISTRIBUTION/AVAILABILITY STATEMENT Approved for public release, distribution unlimited 13. SUPPLEMENTARY NOTES This article is from ADA409494 Proceedings of the 2001 ECBC Scientific Conference on Chemical and Biological Defense Research, 6-8 March , Marriott’s Hunt Valley Inn, Hunt Valley, MD. 14. ABSTRACT 15. SUBJECT TERMS 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF 18. NUMBER 19a. NAME OF ABSTRACT OF PAGES RESPONSIBLE PERSON a. REPORT b. ABSTRACT c. 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S DS OLDHANTIAERMETAM assug emDo rdfeniat bso arwedw o)p52 Pe(dixo imduinat i ftyolpp uAs d,nnaoitaroproC noitaropr oRC BmIo rtfnempiu qgenisseco rdpo orf odferape r splai omfuinat ietr uypllaicremmoc 22 , w. eN motsuc e h otttnecaj ddaellats ndi n)a Y,Nwe-p e,D.c n,Ita elHatipa Cd(etcurtsn osc akwrowtc uddettif 2 .m onoaR e 0ls0Cs1 aylrCotarobal APE Hdeviece rtcu dehT -tnatsn o,cderetlif -tnatsn o,cerutarepm et - 1f oseiticole vdellortno ct adewol fri ae h .Tmoo Rnael Ceh tmor fgnitix eri aytidimuh - dnoce sre psrete m2 2[ -en om[ mt3uo b faeorusse repvitis ocpita t ts,a]ru orh espel i5m -n in af ohthgie hguor h,tret a fw]ohc sret ecmib ut9cuob ae[tun irm etpe ecfib u0c 4t2uo b faeot awro lefmul o tavsanoitc etsc utds eetlbavomer o tserusopx edn asnoitcejn ilosore adetarbila cdeviece rgniva hretf a,wol fgnigrem ee h .T]etuni mrep ss a,pseuqinhc eltortnoc gnitare pyolsuounitn ohacguor hgtniti x oertoi rspeciv eldacityla nsauoir aovt ndie rehtr ugfni eybltnerr u schici h,wmets ytss esti h otyttilitasr etvae rsg aewr e. hdTo oehm ulfacimehc t adn ao tlanretn istnev ef oypocsorci moedi vwoll ao tdetnemurtsni erugiF [stcu ddeifido meh tf oslla weht 1]. .sutara ptp sayertotaro b emafhalotrg aciidt a em.re1 uhgciSF e hettavitcaoto h opdteriuq e srdae seur eswecru onsoitanimul leilbis idv ntaeloivart lsuuoremuN ingi sn odesa b,dn aredwo pedixoi dmuinatit gniluo ff otnempoleve deh tn ikro wroir ptnacif - esaeler sgnitaoc lacimeh3 2Cdetin Uf onoisivi Dhcrarte Pmor fdeniatb oere wstnegae rgnitao cf oseilppu s, wol gro ftnempiuq edezilaice p .Scn I,seigolonhceT -egrahcsid s-uoir aev h ftnooitcefnis idd nnaoitavitca t set secafrus 42 e rnpemice ptss ert odfe ssu aw O i fTnoois-revn orc odf n,anoitazilire tds nganinaelc ostgnita oc 2 elbisiv" -thgil - .smuo tt"asetulsCbatavitca slosor ecairehp-som t fatonemsses seacru ors otfnempiu qteliub ylenitu odre ssuaw 52 deeTnia t.r eC tekna lnboitalus nsisa lsguorb idfeilpp u)s A,Pll eeBul Bn(oitaroproC .c n,IRIADR I yBdbeilpp uesr eswenarbm elmarutcetihc rda n,akr oewtaiti n oistlairet admra otbc uddna .) 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s agwnita oecsaeler .enali slycedatco dn aecafru sroiretn ignom asecnereffi dlacimeh cdn alacigolohpro mrael cdewoh ssisylan aenilesaB ol gf oytilib aeh tdemrifno cdn asepy tnoitalusni w yrtsime- heccafr ues hetgna h octtnemtae retgrahcsid ysa ey bnoitacifido mrehtru ff ognitpecc assalgrebi feh teka mo tyltneiciffus -elcit r. asPgnita oecsaeler - V Utuohti wsecafru snoitalusn idednema c alairetcabitn af oecne-div eeltti ldewoh snoitanimull iA ,d nnaoit secneref f. isDep yntoitalus ndieifidom nnua hhttwo rlgairetc a fbtonet xde neat arretae rdagewo h,stc anfi snaeewt e sblal e sw,asep yctirb adf nnaoitalus ngino mdaevres beor ehwtwo rlgairetc arb oyftisnepo rnpi - wol gdn adeviecer -egrahcsid - ert .elire tgsni eybllau ssunemice pTs DeG hhtt i,wselpm a]sTD Gd[eta fgonita oeclbarusa edm nealbavres beov asgnoitartnecn owc o tlganita oncoisneps uesdixo imduinatiT dx nMa E ySdbecnedi v se,asrebif -alps isd anwoit ccaitylatacoto hdpo odg n,asisyla nyaar eseh ty bdey VU ("sthgilkcalb "dradnat sy bdetanimull ineh wslairetam ylt-nerrucn oyclida eerr eswgnita oecna l. i)SA ys a neganidivo r,pyrtsime heccafr ues hdtegna hrcehtr udf nsaelpm ansoitalus n oidtetrapmi - s,aesaeler cara hccibohpord yghnor t saslalew .selpm aorstet rag an otu ognirutlu cy bylidae rtso mdewei vsa wselpma stse tn oygoloi bf oecnesb ar oecneser pehT otoh py bdewollo f,setalp edixo imdu-ina t. isTisyla nlaaus idv nnaoitatnemucod - ,selpm agsniniatnoc V Uo tdesopxe d-ewoh ssemitemo s,thgi lA ra g nahotwo rlgairetc a fbgonitaunet tea h ntnioit cdaeyal ead ,selpm adsetaert nftuoa hsttasub ostras us jatwa hytgolo ifhbotworgt uloaiti nneiatips e, dst.ia sheTtalp oll osfy aed h nthitwo rtga h fteot adr nraog i nvnioitcud eerlbis isav aewreht gnidee slaitin ieh tgniw .tnemirepxe 5 ssergo r nPkiroW evitisne sero mro fdetnemelpm ignie bs isisylan aR Iwol flellara pro fput e :sA eh tgnissa psevlovn isi h .Tsecafru sroiretn ieh tt anoitcefnisi dn idevlovn ismsinahce meh tf onoitanimaxe rev owol fria la etra h otrsetemotohportce p naseica l npsieta lnpocil ids nmauinamr eg - stnemerusae memit .emi tf oegassa peh thti wdn a,thgi lV Uy bnoitanimull i,airetca bf onoitcudortn igniru deda me bnac evitanret l naganitcurtsn o ycdbeveih c ealbl iwwo llfellaraP lacisy he phntiht iswt itfa hetgass ar pia deta oycletairpor p. prAedl oehtalpts eltatnozir odh nraetemotohportce pdserarf ndietacid e fadsoenifnoc larutcetihc rda nnaoitalus nsisalgreb idfeifidom ndu ndaeifid o fmsoecafr ues hettacilp usdeta lmpuinamreg .sessecor pnoitcefnisi deh tn idevlovn iyrtsimeh cecafru seh tt akoo lresol caetatilica flli wdn a,senarbmem noitanimax ef odohte msih t,demrofre pgnie bkro weh tf ognidnatsredn urette bagnidivor po tnoitidd anI r oswise httnedu trs osfis aeb hstedivorp .)etadid n. aS,c.o M z.kzCI( SNOISULCNOC Oi Te(dixo imduinat ictitylatacotohP ys ade nsaelcitr aepn i)f -wo l,esaeler - lacitirc - ecafrus - noisnet 2 dn aytilibai vgnihsinimi df o,ylevitcepse r,elbapa cyltnednepedn ie bo tnwoh snee beva hsgnitao c)TSC( iminim O i fTsonoitanibm oecuq i. nsUecafr ursoiret n nisonedrubo igbniz lyhte mdn a - T=S Cd[etanimret 2 ne eebv aahtartsb usssalgreb idfeta odc n,assalgreb i,fnocil i,smuinamr e ngsognita orceyalon o]mm/ N2m2 ri a"orez "af oswol fdellortno cn idetset - mets ytscud dedee s,moo rnael c00 1ssal Camor fgnigreme retupmo Cwe nay bderotino mdn a,rotarene glosoreaoi bdellortno camor fdoo htix elani fao tyawdim )I ITSAOC (euqinhce Tgnilpma Slosore AdezimitpO 62 lan isfusr edvetaren er gosferutl umco r af.t aD ynoloc -nimrof d n,ashpargorc inmortce lgeninna c,sartce pdserarf nnioitcelf elranret n yidbetropp u,ssti ngu ygrene - xevisrepsid n ascsamo- idbeniat elrat od tnsanedrubo ilbairetc aebvit chat otba hwto h,sartce pysar noitacifido mecafru seseh ty bdecude ryltnacifingi seb O ifsTognita oeccafr ursoir e.t snI ysae/ - esaeler 2 d nganiniatni and miiyallaitnatsb un sa,catartsb usssalgreb idfeta od cnsasalgreb inyfolralucitr a,pstcudda .secap sdesol cdegnellah cyllacigoloi bn iytilau qri agnivorpmi STNEMGDELWONKCA e hettaudarG . ). AP,Pll eeBul Bn(oitaropr odCeeTniatr eydCbetropp uysllaitr aopz z .fIkCor oswis .secafruso irB orfetn eyCtisrevinU/yrtsud nsI'olaff u tByatisrevi n yUdbetropp uasretociN REFERENCES nyEgre nrEa l )oJ7S99 1S,(Skco l, BN,Didevi r, TYiDdna w.s 1oG 29 :,9g11 - 96 0562: 2,3lonhc eiT cnSoriv n)E899 1 A(lJlenn e,F MeDka l,B CsPsen a,M AyWbo c. a2J - 2653 noriv n)E49 9 r1Ka(wsej a, RLhRti m, SPcAizu r,u KKh, ZEsNmaill i,lWZani a, ZYn .Wi,i 3LCeW 439: 8,2lonhc eiTcS - 938 maa.idg 4 jaa,,aonRTk muaosNTtaM ,loiborc inMoriv nlEp p)A88 9 e1Tn(im o,aKNrumak a,aNT 8661:45 - 1670 627: 2,3lonhc eiT cnSoriv n)E899 1aA(mihsij u ,FoKtomis a ,HiYhcuk i ,KaKda n. u5S - 728 1:8 0,1mehC :lAoiboto hmPehcoto h)JP799 1eS(tnuH edL nsAal l. i6M - 35 lh o ,KrRei a ,BrAe y. e7M n iG az,wtMSlu hs,c sASo,onJRaramet nk,ocEMebl sh,atJHiff i ,rLGI )7991( l uxoeFlpuD - esaeleR ,sg nliattanoeCmno ryitvinrEuc eySgo lnoonihtcaecTif i:tmraerCgorP 6 decnavdA cixotnoN gniluofitnA sgnitaoC ygolonhceTnoitartsnomeD DCC WrSeNb mturNo p,eR - TR - 64 - ,CnDotgnih s,ayWrotaro bhacLrae sl ea ,RvS5aU1N/69 )599 1Ae (Hg.r 8uB slosoreaoiB ,LnFo taa cR,osBrehsil bsuiP w,eL )099 1)(sd eAn(Jet t, OCyJlee r, FRy Pe.r 9oM stnemnorivn Eroodn In istnanimatno ClacigoloiB , ASTM 4r0ebm ueNd onCoitacilbuP - 010710 - 17, A,Paihpledali h,PMT SA )39 9) 1se( dg H ern,(uoRBsret t ,a .MPe0. p1AoP snegrell AroodnI -- esrevd Agnillortno Cdn agnissessA stcef fhEtlaeH C,Dnotgnihs a,Wsse ryPmeda clAanoit a,N )79 9rE1eA( y ,esMMuSl l ,orEGeR i.a1B1 noitarbilaC dna gnitseT htiw atroP elba losoreaoiB ,rotareneG olaff uYBN U,Ssecafruso irB orfetn eyCtisrevinU/yrtsud n,Itrop etRcejo rP n)i699 1Dh(Lcabnezte td SnPraMentt u.B21 detal edR nnaoitull orP irAood n fIsoecru ogSniziretcarahC stcef fkEniS r e)m .A,drEoneh c.iAT .7B 8 (P2MT 1TS,SA ,aihpledal i,hsPlaire tganMit s re.oT cf.oS ,AP pp57 - 86 r i)JA699 1rJ(etlu o,B CeMgro e,G KgSrebll o,D MoLgr a,V AlJlenn e,F MeDka l,B AyWboc a.J31 198: 6,4cos seAgan aeMtsaW - 898 3221: 9,2lonhc ei TcnSoriv n)E599 1Tn(Rwo rd B nNeaTe b.O41 - 1231 gn e.T51 )9 8l 9lP1a(v muinatiT lairetamoi Bo tecnerefe Rh-ti wnoitcaretn Iedixore PnegordyH ,snoitacilppA nedew S,gnipokni L,81 2.o Nnoitatressi D;ygolonhce Tdn aecneic Sn iseidut Sgnipokni L edicits esPurohpsohponag rfnOooitadarg ecDitylatacoto h)P59 9 o1Ja( h.Z61 O igTni ssu ndoetropp uS 2 yrtsime heCcafr ud Sndaioll o.Cv i,D.g t.Mc o.Sme h.Cre mhAt0 1,21 3t1carts b,AssalgrebiF O irTe vsotnatull ocPilone h fPnooitadarg ecDitylatacoto h)P599 1gS(me hdC n JaiSa s.T71 2 tc1art s,bsAerutcu rstuSoi rha tVriowtcudnocimeS dioll o.Cv i,D.g t.Mc o.Sme h.Cre mhAt0 1,216 yrtsime heCcafr udSna seitrepo rcPitylatacoto hdP ncaitylat aeC h ftnoosirapm o)AC599 1 A(nMosred n,A ArWentl e , ZuX.F81 O isTuoroporc ifMo diaol l.o vC,i gD.t cM.omS e.hrC ehmtA 0,1 32t6c1art s,bsAlaire taM ecafr udSn 2 yrtsimehC fle Sn istnempoleve Dwe N)8991 (Aamihsiju Fdn aKotomihsa H.91 -itn Adn agninaelC -Oi TgniggoF - 2 yrtsime heCcafr ud Sndaioll o.Cv i,D.g t.Mc o.Sme h.Cre mhAt6 1,20 5t0carts b,Asecafr udSetaoc x omiudina t)i6T 9 ,9y51r1au nn aoEJs( l.i0W2 d nlaacime h,Cstnatull onpw okdae rsbtsylat aecdi 32p p,swe NgnireenignE - 24 ,syol lmAuinat idT nmauinat irT okfoolt ulOacinhc edT nsasenis udBlr o)W899 1nM(onnacn o.C12 ecnerefn olcanoitanret n,i.c n,Islairet adMecnav dmAahroG noitaropr olCee tnSopp i.N22 ,ee h JR fCyosetru o,c88 9l1ir p,Atnempiu qgEnisseco rdPo o nFmiuinat i,T 09 9,1rebot c, OL,Inotgnirr a,Bnoitaropr oR CB,Inoisiv inDwotrobr a,HtnediserP n)i799 1Fr(Eesuahu e, NErRei a, BAkJesuot a, MErAey e, MWsAll e.W32 sgnideeco r,P7 9r’ewopretaW h tfo 1emulo V,rewopordy Hn oecnerefno Clanoitanretn Ie ,Y N,sreenign Elivi Cf oyteico Snacirem A, pp 451 - 460 ,lotnal p)l m2aJ I9r k9OAa1Sz(rp s,naDaKBwo G,rcEeM A y,neEeMSsne r,roMeSJt r,raEeC Ri.a4B2 632:81 - 242 e , isJ,lr RW iekrC,, PgceJE.oaiER5RMa2B 668: 0,2gnireenig nlEacit p)O189 1 A(aVmlaPeD - 872 e4sfh2gotnideec o)r1P 0r 0eE2h( ss,ieJFn rn,aeBBz ag,rrRWebs rr,oeTFitu or,leRC i.a6B2 ht launn A 5 2yraurbe F,yteico Snoisehd Aeh tf ogniteeM - ,Ag Vr ,0up5bp4smail l,i1 W0,0822 - 451 7

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