DTIC ADA435998: Room Temperature Mineralization of Chemical Warfare Agents Using Hydrogen Peroxide - Pd/C

6 Pages·0.06 MB·English

by  Defense Technical Information Center

NOIT AEZ RI MULF OTAOLOARA RRECEENIRPIMA MMEFSEHRTTCANWE GGANISU
HYDROGEN PEROXIDE – C/ dP

udY nlaleco r .PeRcnerw a,Lreng a .WeWgroeG - gn auYhC

:BN S T,STC MAByA Cm.ErSA.U - RRT - , DG,0 MP.1k Ad0wR1a2hkc a3 l8,B1A5C - 5424

o tf onoitadix opee dehT d nCa/ dgPni ssutnalum itsne g)aW Ce(rafr alwacime hdc nsacinag rcoix
0 8t aedixore pnegordy hr onegyxoid - 90 (cid:176). l tane e ySdbetartsnom eydltnec esr aCw 1 sref fsosec o rspi hT
oelbaveihc ayllanoitidar trenna man islaireta mW Cgniyortse df osnae mlacimeh ca .noitarenicn iy byln
nwoh seva h)PMMD (etanopsohplyhte mlyhtemi dtnalumi snommo ceh tf osnoitagitsevn iruO
gHni seutahpso hcpinagro n ointoitazilarenim O – Pd/C at 90 (cid:176) oPtM M fDeogavae lecvitad i. xCO
2 2
repme tmoo rt aevitceff etso ms idic acinohpsohplyhtem dHecud eoer tuydltnerap p,aeruta O
2 2
dn a,erutarepme tmoo rt aegavael cevitadix odewoh sosl aX Vdn aD G,ylralim i .Snoitisopmoced
ttanedi voes l sanioitazilaren i,mlocylgidoi httnalum iss tdi n Da rH. oeFtahpso hcpinagro n finooitamrof
.erutarepm emtoor

NOITCUDORTNI

ydbehsilpmoc cnae esb ashtne gearafr alwacime h fcnooitaziratilim eed h,tyllacirotsiH
O C.e. i,stla slareni m,dezidix orieh to tstneg aeh tgnisirpmo cstnemel eeh tgniredne rsuh t,noitarenicni 2 - ,
3
PO 3 -, SO 2 -, NO -no c,revew o .Hct e, yllaicep s,eset iesgaro t tsnaoitarenic n fiyotef aes httuo bsanrec
4 4 3
.seigetar tnsoitazilartu elnacime h fcnooitpo dea hdtetpmo rsp a,hsae rsauolup orpaen 2 sdohte mhc u S
ts oepriuqer -no neh tf otnemtaert - rnooitarenic n yi.bg .,estcudo rdpezilartu e,ncixot o,tnoitadargedoib
.lasops iedtamit lru oefta tdserrefe rep h;tstl alsaren idmleiy 2

srekrowo cdn aneS dn asurohpsohponagr of onoitaz1ilareni meh tdetartsnome dyltnece r
,OC/ dgPni ssudnuopm orcuflusonagro dOrnCoHa at 80 - 90 (cid:176)sinahc edmesopo r ep. hCT n inwoh s,m
2 2
H,yllaitin i) 1:spet sgniwollo feh tsevlovn i,X Vro f1emehcS roH( tfih ssa greta weh tn idemro f
2 2
lat esametaren e)g OmCo r*fnoitcaer -late meh t) 2;edirdyh - hOt iswtca eerdirdyh late madlei yo t -
2
late meh t) 3dn a;edixorepordyh -dixorepordyh lat e,amtnadi xeovit cea hstmr oef - si h st. tisIeice posxo
n nasi u. hsTcinag rmootaoret e fhsonoitadi xpoe eddevres beo htt uyorr a octthguo h sttia hsteice prsettal
aelh td(i ccainobr adc ncairohpso h,pcirufl u,scirt idnle idylu o Xw,Vgnitt essuoeuqa O Cgnivlov erett
2
late meh t,ylevitanret l . A1emehc Sn inwoh ss a)snoitidno ccidic arednu - dn a,edixorepordyh
late meh tyltneuqesbus -Hmor fyltceri ddetarene ge bya m,oxo O . ltna eed Sn,a 1 gnicalp etra hdtevo rp
2 2
sHuoeu qhat iswes aeght O limi sdlei ydi d seavitcart t. salAone hrp orfoivah enboitadi xpoe erda
2 2
Odezirusser p,detae hhti wgnikrow dH na sHuoeu q,a eyb a O mrCo O r oeflbatpec cear osmpahr e spi
2 2 2 2
tdaemrofr e epdblu oscnoitca eer h fteiu rytllaicep s sesi i. hsTtne g Wa fCnooitaziratilim eedht moo r
edixore pnegordy hdeed n .Ierutarepmet -stnanimatnoc eddesab 3 yratil igmnuo myatiralup ogpnini aeg ra
1
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1. REPORT DATE 2. REPORT TYPE 3. DATES COVERED
00 JAN 2002 N/A -
4. TITLE AND SUBTITLE 5a. CONTRACT NUMBER
Room Temperature Mineralization Of Chemical Warfare Agents Using
5b. GRANT NUMBER
Hydrogen Peroxide - Pd/C
5c. PROGRAM ELEMENT NUMBER
6. AUTHOR(S) 5d. PROJECT NUMBER
5e. TASK NUMBER
5f. WORK UNIT NUMBER
7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) 8. PERFORMING ORGANIZATION
U.S. Army ECBC, ATTN: AMSSB-RRT-CA, 5183 Blackhawk Rd., APG, REPORT NUMBER
MD 21010-5424
9. SPONSORING/MONITORING AGENCY NAME(S) AND ADDRESS(ES) 10. SPONSOR/MONITOR’S ACRONYM(S)
11. SPONSOR/MONITOR’S REPORT
NUMBER(S)
12. DISTRIBUTION/AVAILABILITY STATEMENT
Approved for public release, distribution unlimited
13. SUPPLEMENTARY NOTES
This article is from ADA409494 Proceedings of the 2001 ECBC Scientific Conference on Chemical and
Biological Defense Research, 6-8 March , Marriott’s Hunt Valley Inn, Hunt Valley, MD.
14. ABSTRACT
15. SUBJECT TERMS
16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF 18. NUMBER 19a. NAME OF
ABSTRACT OF PAGES RESPONSIBLE PERSON

a. REPORT b. ABSTRACT c. THIS PAGE UU 5
unclassified unclassified unclassified
Standard Form 298 (Rev. 8-98)
Prescribed by ANSI Std Z39-18
dn aD G,X Vf onoitazilareni meh terolpx eo ts iydut stnerru ceh tf otnetn ie h .Tsrennal pesnefe dlivi cdna
Heh tgnis uDH O - .mets yCs/dP
2 2

SCHEME 1
[Pd] [Pd]
CO. CO 2 VX

H 2 O H 2 H 2 O 2 HNO 3 + H 2 SO 4
+H 3 PO 4 + C O 2
+ H O
2
O
2 [Pd]

H OOH O
CO/H 2 O* O 2 H +
Pd (m) Pd (m) Pd (m) Pd (m)
or H - H O
2 2

*CO + H O CO + H
2 2 2

LATNEMIREPXE

%05H O er eswnoitc a. ehRcird lmAo rdfeniat beor e)w10 1eEp yatssuge DC(/ d %Pd5 na
2 2
% H0,5etartsb u,sC/ dgPnid dylabess esvsa ldgerr i nt taiudsoeirrac O d nraet a,wses aecm o ns,id na
2 2
.e Hlh CT.Hcnoc O dedd arehti esa w :noitu a .Cpmu pegniry sahti wylwol sn iderete mr oecn ot all a
2 2
%H 0 f5nooitca eerht O lHaitnatsb u nssitlus edr ncaimrehto xyelhg i shCi/ d %Ph5t iw O
2 2 2 2
. sisyla nRa MrN onfek aetr eswtouqi lLa m.1 a,cslavret ndietcel e! tsnAoitisopmoced 1 H, 31 d nCa 3 1 P
er eswtfi hlsacim e. hrCetemortce pRs M0N 0s3ulpyti nnUair agaVni sdueniat beor eawrtce pRsMN
S( MlTanret x oedtecnerefer 1 , lH, C)0DmCpp ( 31 )d% 0mn5,.pa8HC7p7 PO ( 13 el p.m )aAm s p,0pP
3 3 4
portce lyerallip a ycdbezyla noas lsa anwoitca e DreH hfto drakc atPtelw egaHni s)uE Cs(iseroh D3 CE
O Smrifno co tnoitcete dV Utceridn igniyolpm emetsys 2 .noi-tazilaren i.me .,inoitamr of
4

NO ISST SLDUUNCSASEIRD

deirr aecr esweidu tlsait i . ne1Ilb a nTniev ieg rsatne gda nsatnalum issuoir arv odfeniat baotaD
OP (etaohpsoh pcinagron ignitcete df onoitnetn ieh thti wPMM Dhti wtu 3 - y)b 13 gniv osr up,h RtPMN
4
Peh tf oegavael cevitadixo foor pevisulcno csih t,revew o .Hs-urohpsoh peh tf onoitazilareni mdn adno bC
surohpso hop w ytdberepm ashaw -sreziliba tgsniniatnoc %H 0e5 h nttinese rp O O Psa whcih wf oen o; 3 -
2 2 4
OlPaitnatsb uo,esn1lb andTietrop esrnoitca ePrM Me .Dhr ftolFesti 3 eh tdn a,-tnediv esa wnoitamro f
4
detcete do tderapmo cgniniame rPMM Df otnuom aeh ttcelfe rylere m1elba Tn idetrope rsnoisrevnoc
cudorp . 0et9rAutarepm ehtt idweir asvtcudo rep s.e shtT (cid:176)dic acinohpsohplyhte mlyhte mhto b,C
derruc cnooitisopmoc e,derutarepm emto o trta u,bdemr o)fAP Md(i ccainohpsohplyht edm n)aAPMM(
e htta h steicnereff isdi hrt onfoitanalp xeelbis s. oAAp P oMytltcerid P MyMaDwh tnaopitc aer fi
APMM fi egavael cevitadix ohti wevititepmo ce bdluo whcih w,sisylordy helpmi sro fdetcepx es iAP M
evisulc xhet itwnetsisn o scticudo rAp PeMn oel h,terutarepm emto o. trsAerutarepm edtetave ltea
no cllarev oe h .Tegavael cevitadixo ,s0t0n5a9oisrev (cid:176) ,%0 0d 1 n5,a32. 4e9r eewrutarepm emto od rnCa
HL m36. 5yln ognis udeveihc anoisrevno cretta leh thtiw O . )snoitca erreh teo hrt o Lf 0m o1dterapmo c(
2 2
t0A5 oj aem hst aewgavae lecv(cid:176)itadi xdo n,adevres bso atwcudo rspisylord yAhP M oMCn .msinahce mr
Hdenethgie ho tdetubirtt as inoisrevno cwo lehT O hgi he h .Tserutarepme tdetavel et anoitisopmoce d
2 2
0 t9naoisrevnoc ts osmraep peaga(cid:176)vae lecvitadi xso u. heTgavae lccitylord y ohdtetubirt tyalegr a slCi
ereh w,erutarepme tmoo rt aevitceffe Hderisednu O snoitcae reh tr o .Fdezimini ms inoitisopmoce d
2 2
2
OlPaitnatsb ueo1slnb annTiwohs 3 Heh -tf otah tdnoye bnoitamro f O ;adevres bso adwnuorgkc ab
4 2 2
Peh tf oycneilise reh to ttnematset weno dsnoit-cae rdednetx en i,detapicitn as a,t e .Ydno bC PhMtMiD
at 90 (cid:176) d XrtD ndVoaG,anfCa eru tmaoroerpmet O Planoitidd atnacifingi s,)wole bees ( 3 - detcete dsa w
4
. sy aldarev ersetfa

ELB.A1T

Substrate pmeT C/dP a H O lCH b H O c emiT noisr e v n o C d
2 2 2

25 µL DMMP e 90ºC g l0m 3 m5 62 .5 l 7m l8 0m .11 0h2 94.2%
25 µL DMMP 50 250 5.63 1.87 10 22 35.0
25 µL DMMP 22 250 e n o n 1.87 5.63 24 100
23 µL TG f 22 250 e n o n enon 5 72 >91 g

38 µL DH 22 250 e n o n enon 10 24 100 h
1L8XµV 22 250 e n o n enon 10 24 96.3
55 LµDG 22 250 e n o n enon 10 24 79.6
10 i 24 100

a .%5dt Pw b . l. CcHnoC c %05H O . d 1[ - ( . 0 ]0×)1tcudo rspelom/etartsb usselom e lyhtemiD
2 2
.etanohpsohplyhtem f .locylgidoihT .noitcete dG Thti wderefgret n ticudor p;etamits etimi lrewoL h DH
.reta wn iG To tsezylordy hyletelpmoc i HdnoceS O . 4hl2anoitid d nara otfca e ordtewol lnaoitid da
2 2

s ntoa ir toGd cFTnDaaHer eru tmaoroerpmet , 1 Cf osso letinife ddewoh sRM NH - dno bH
fnog itsnatrop mli lea h,teromreht r. u )Fe1rugi Fe(lpm alsortn o Gc oaTetvital eyrtisnetni
O,Snoitazilarenim 2,reve w. osHiserohport-ce lyerallip a ycdbevres bso a,w OCH - ,devres bto osn aw
4 3

e.r1 ugiF noitca e)rmotto b D1(dH n)aelddi m G(dT n)apo tl(ortn o GcrT odfeniat baortce pRs MHN
.)noissucs ieDe ss(erutxim
3
O Cf onoitulov eeh thti wtnetsisnoc . 2emehc Sn inwoh ss a 1 e h otdtetca e GrtTa hdtewo hRs MHN
2
oflus OG Te(nofl uds n)aOG Te(dix ydbetcet e. sddAevres beor eswtcudo rrpehtr u oftn u,b) 1 H NMR
2
y bdemrifno cdna 31 ,OD He(dixofl ues hst atwcudo r DplHaiti nei h,tR MCN 31 hc i,h)w m3p .p,773 .:3C5
OG To tyltceri ddedeecorp ( 31 . )e2mehc S)(m p4p. 4,50. 5:5C s u. hdTevres beor eswtcudo rrpeh tooN
2
OG Tf oegassa peh tn idevlovn isetaidemretni eh t,D Hr o .Fdevi ltroh se btsu mnoivilb olareni motn i
2
non -D Hf onoitceted -OD He(noflus O D fHsoisylord yehlic aef hhtt itwnetsisn o scOi G rT)o otOGT
2 2 2
emertx eeh tdna .O D fHyotiliba tcsitylordyh 4

SCHEME 2

O

]O[
S S
OH HO OH HO
]O[
TG TGO
O
OH OS HO [O] OS 4 -2 + CO 2
TGO
2

H O
2

O

S
lC lC
O

ODH
2
]O[
O
]O[
S S
lC lC lC lC
DH ODH

etacid n)iAPM E X(dV n)aAP M D(rG osftcudo rdpetcet eed h,tPM M oDrtalimiS moor
erutarepmet 2dn alylocani prieh tf oegavael cevitadix o ,spuo-r gloihtenahte)onimalyporposiid(
mehcS (ylevitcepser oot w rtyo aeadriuq esrnoitca eerse h ,te1lb a nTsinoisrevn oec h ytnbwo h. ss )Ae3
laitnatsb u,ssy aldarev e fseosru oec hrt e. vrOets atfahwem ogsnirruc cnooitca e XreV hhtt i,wetelpmoc
f ostnuom aeh tn isesaercni PO 3snoi-tcae reseh tn idevresb oer a odtednopserr oecsaerc nsii h,t Dr.G oF
4
eh tereh w,X Vro fxelpmo cero msa wnoitcae re h .T) 3emehcS (AP Mf otnuom aeh tn iesaerce deht
O,PA P oMdtedarg eAdP MdEemr oyfllaitini 3 lyte c sadaetalut-s oeptanohpso hnpwonk n nuda na
4
.dic acinohpsohplyhtem i hT citecaonohpso h,ptcudo rrpalim i nasdoes aebd a smtinemngis seavitatn est
. l tane e ySdbevres b,odica .edix oenihp1sohplyhteir tf onoitadix oeh tn i

SCHEME 3

O O
[O] [O]
P _ P _ OP 3-
O F "tsaf" O O wols 4

GD APM

O O O
[O] [O]
P N P _ O P _
O S "tsaf" O O wols O O
_
VX APME O

A +P +M OP 4 3-
4
SNOISULCNOC

C/ deP hgtni seurutarepm emto o trdaezilaren iem r DadH n Xa,VDG - cat .metsy sedixore pdezyla
2dn alylocani peh tf oegavael cevitadix oeh tdn aD Hf onoitazilareniM loih-tenahte)onimalyporposiid(
Peh tf oegavael cevitadix owol seh to tderapmo celica fer aX Vdn aD Gf ospuorg - .A P fMdon oCb

STNEMEGDELWONKCA

.krRnM aehWt .elpm aDe s Hhfstoisyla nEr aCo,f.pr oI CA,Eetnacie h.dCLrahci

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.1 ,. nA ;e,.SnC e ;h,.S nM ;i,.LnRosp m ;i,.SrBeked e ;n,.SnTa g ;o,.HrAefiP J. Am. Chem. Soc.
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.2 .,YgnaY - C. Chem. Ind. 1995 , 334 -niere hstecneref edr n,a733 .
.3 ,.gY n ;,a..rYGWen g)aaW( - .) sbs(e rn,pi.s e.Rf e.Dlo i.Bme h.Cfn o.Ci c1S0 0.2co re Phn.tIC
,.gY n ;a,..YrGWengaW -CE D,R.E s.e fR.elD o.imB e.hfC n.o iCCcES D8R 9E.9c1 o e.rnhCPIt -
SP gnireenign Edn atnempoleve D,-hcraese Rdoowegd Eymr A.S. U;400 ,r e,t9n9e9C 1.pp582 - 291.
.,Lreb m)Ec( . m.eghsnCwEeN 1999 , 77 (Mar. 8), 10.
.4 ,, nd..;o iWE.s.eEwERaL J. Am. Chem. Soc. 1925 , 47 , 2821 - 2836.

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