//j4t o7V 79f 1 '92 "TITANIUM SCIENCE AND TECHNOLOGY VOLUME I 94--00280 94 6 "A(cid:127) I Best Available Copy TITANI '92 SCIENCE ArýD T OLOGY ~CH VOLUME I Proceedings of a Symposium sponsored by the Titanium Committee of the Minerals, Metals & Materials I Structural Metals Division Held at the Seventh World Titanium Conference June 29 -July 2. 1992 in San Diego, California Edited by F.H. FROES and I.L. CAPLAN A Puication of TMS a. . 41? NTIS CRAMI DTIC TAB Unannou;:..ý Justificatio;. *... Distribut~ior.'! /S Availat,;.- - Avail d;.dIor 1 Dist Special 42D Commornwealth Drive Wamsaftl. Peanaylysnim, VAN (412)7764000 [email protected]).Ngtma &bmiwla~s Bacty j@n t lmpona&bl for state- mamasao-r opinlo. and is abmsoled of liabflty &,tcramini. ofinforma- tIon contained in this pbbesicamo. Printe in tbe UfhleBLOMaaofAnwma~ lUbia7 IONf MaownmmaeaCb awftm*g* sNIuMmboerj 987682 Authar~mza~taopb~anmpylt.rj~,n' terna o- peroag use, orthe intasva or persnal use of sepacfic cilint., to granted by The Ulnealas, Moalk & Material S~oyduhtYtC (Ohr anrIMuSm re. gistered wthi t Contur TE praeevd th" the boo in o $iSAO0 per TM " isppy aid dbustly to Copyright Cluer. aaft entr,27 anreams sa es , 2sath, that have base panned a phto. If You are intweated in purolming a OWy of ftit book, orif you would like, to receive the latet Ims publicattiose catalog plea. telePMon 1-600756-487. iI ! PREFACE It Is with a mixed sense of relief, accomplishment and pride that we open this final prologue to the Seventh World Titanium Conference. Relief that the uncountable hours spent in organizing the conference and compiling these proceedings are behind us. Accomplishment and pride that the conference went so well, including riding out the strongest earthquake that mother nature has served up to Southern California in quite some time. We thank the numerous people who verbally and in writing complemented us on both the technical program and social events -- it makes the hours spent worthwhile. We want to take this opportunity to thank the other members of the U.S. Organizing Committee for their hard work, the International Organizing Committee (IOC) representatives for their support and outstanding coordination, The Minerals, Metals & Materials Society staff for their superb management of the conference, and the Titanium Development Association for their efficient handling of the Exhibition. Furthermore, a special thanks is extended to the plenary and keynote speakers for theio conscientious preparation and participation. Finally, the Executive Committee deeply appreciates the much needed financial support generously provided by each of the sponsoring organizatiors and companies in these difficult economic times. j Of course these proceedings would not have been possible without the generally excellent manuscripts submitted by authors from around the world -- thank you all! We also want to mention the behind-the-scenes contributions of Debkumar Mukhopadhyay, graduate student at the University of Idaho, in compiling these proceedings. His diligent efforts were invaluable. This conference marked 20 years since the last international titanium conference was held in the United States in Boston, Massachusetts. At that time, only four countries made up the IOC and less than 200 papers were presented. Since then, the IOC has grown to sever countries, with the admittance of China in 1992. Conference attendance in San Diego exceeded 700 persons, representing 26 nations, presenting more than 400 papers. And so on to Birmingham, England in October 1995 for the Eighth World Titanium Conference. We wish Paul Blenkinsop and his "team"t he best of luck, and hope that everything goes as well for them as it did for us. Francis H. (Sam) Froes Ivan L. Caplan University of Idaho Naval Surface Warfare Center Mosoow, ID Annapolis, MD Conference Co-ChelneIn aid Aroceengs Editors -March 1993 V Ivan L. Caplan Co-chairman F.H. Froes Co-chairman Neil E. Paton Finance F.H. Froes, Ivan L. Caplan Technical Program/Proceedings James A. Hall Poster Sessions Harold D. Kessler Activities Rodney R. Boyer Secretary Neville R. Moody Student Activities Paul Bania Promotions Barbara J. Kamperman Conference Management Titanium Development Exhibition Management Association F.H. Froes The Minerals, Metals & Materials Society G. Beranger Soci6t6 Frangaise de Mdtalurgie et de Mat~naux T. Suzuki The Japan Institute of Metals S. Seagle ASM International I.V. Gorynin The Academy of Sciences G. Luetjering Deutsche Gesellschaft for Materialkunde P. Blenkinsop The Institute of Metals TamohNiJ |I 4 PROCEEDINGS DEDICATION Robert I. Jaffee 1 1 July 1917 -28 November 1991 Mentor, colleague, co-worker, friend. Bob Jaffee was some or all of these to the titanium community in general, and to many of us individually. For thirty-two years at Battelle, he was a major contributor to, and stimulator of, the rapidly growing field of materials, creating a materials science group around himself that was second to none in the world. His seminal work on the physical metallurgy of titanium still undergirds much of the technology which permits its effective use. As young men in the 50's, we did not hesitate to bring him our ideas, however tentative. He listened, was always objective, and responded with useful commentary. Later, I well remember working closely with him to co-edit the Proceedings of the Second International Titanium Conference -the previous time it was held in the United States in Boston, 1972. In particular, developing an index with him provided a window into his mind, a measure of what he considered to be important. He was precise, logical, and had a visionary perspective of the future. After Battelle, he did not rest on his laurels but undertook a second career -- 17 years beyond his first retirement and active until his death - at the Electric Power Research Institute. Here his focus shifted from aerospace to power generation, and he provided international leadership Bob's precison and logic have been experienced by many. His famous "NONSENSE" when sloppy thinking or parochial motives I intruded upon technical judgments, often led the way back to rationality. His energy and irrepressible enthusiasm were legendary, from his golf game to his membership or leadership of many advisory committees; early on I learned about "joy through work" -- another Jaffee'ism that enriched us. He was both a scientist and an engineer, fostering the development of science-based technology in the service of man. Bob received numerous honors, from the Presidency ofthe Metallurgical Society to membership in the National Academy of Engineering. I have tried to emphasize how he enriched so many of us, particularly In the titanium community, and in the tradition started with Dr. Wilhelm Kroll after the first conference. It is entirely appropriate to dedicate these Procsedings ofthe Seventh World iankim Conference to Dr. Robert I. Jaffee--mentor, colleague, co-worker, and friend. Dr. Harris M. Burte Chief Scentist, Materials Laboratory Wright Laboratories Dayton, OH. May 1992 S... I".qb IX * 4 4 - 4 1 a *~~Rbr . -J . - 11 July 1917 -28 November 1991 x II TABLE OF CONTENTS VOLUME . VO LU ME II ....................................................................................................... 957-1,968 VO LU ME III ................................................................................................... 1,969-2,982 PLENARIES Titanium Process Modelling ........................................................................... 3 F.H. Froes,H .L. Gegel, C.H. Hamilton, G.W. Kuhlman, andJ .H. Moll Advanced Alloys and Processes ................................................................. 15 PA. Blenkinsop Alloy Theory and Phase Transformations in Titanium Alloys ........................ 27 R. Penelle and C. Servant Surfaces and Elevated Temperature Effects ................................................ 41 M.A. Daeublera nd D. Helm Present Features in Production of Titanium Sponge and Ingot .................... 53 S. Tamamoto Material Science and li-Production Problems in View of New Horizons of the Application ........................................................................... 65 I. Gorynin MICROSTRUCTURE AND PROPERTIESi Microstructure -Property Relationships in Titanium Alloys (Critical Review) ..... 77 R.R. Boyer andJ .A. Hall Hot Deformation Microstructure Study in TI-6AI-4V and in ft-Cez Alloys ........... 89 C. Servant, C. Quesne, T. Baudln, and R. Pene/ie Structural Stability of j3-Cez Alloy ................................................................. 97 A. Henri and A. Vassel Deformation and Fracture Mechanisms in the f0 Metastable f-Cez Alloy ........ 105 C. Conbres, 0. Dumas, A.-M. Chaze, and B. Chanpin Fatigue and Fracture Toughness Properties of TI-6Al-4V with Acicular Alpha Microstructures .................................................................. 113 T. Mataumoto, T. Nishimura, S. Muranaka. and S. Ishigai The Effect of Thermal Treatment on the Cryogenic Mechanical Properties of Cast 5Ai-2.5Sn ELI Titanium ...................................................... 121 D.P. Dennies andJ .C. 06"eng Optimization of Service Properties for Titanium Forgings with Bimodal Microstructure ............................................................................. 131 H. Puschnlk,J . Fladischer,G . LOtjering, and R.S. Jaffee Microstructure and Mechanical Properties Relationship of f-Rich a-p n-itanium Alloy: SP-700 .............................................................................. 141 M. Ishlkawa, 0. Kuboyama, M. Nilkura, and C. Ouchi I Development of Titanium 0T4-1 Alloy ............................................................. 149 S.C. Sharma, R.K. Bannadi,R . Ganesh, andS .A. Badami Oxygen Effects on the Mechanical Properties of Timetal.21S ......................... 153 W.M. Panfis and P.J. Bania Microstructural Stability of Beta 21S ................................................................ 161 M. W. Mahoney, P.L. Martin, and D.A. Hardwick Effect of Heating-Rate on the Formation of (a+A) Microduplex Structure in a Ti-1 5V-3Cr-3Sn-3Al Alloy ........................................................... 169 K. Ameyama, T. Inaba, K. HMrota, K. Hirai,a nd M. Tokizane Effect of Cold Work and Heat Treatment in Alpha Region on Mechanical Properties of Ti-15-3 Alloy ....................................................... 177 MA Imam, P.K. Poulose, and B.B. Rath Deformation Behavior of an Age Hardenable Beta + Alpha-Two Titanium Alloy ..................................................................... 185 L.S. Qualtocchia nd D.A. Koss Correlation of Mechanical Properties and Microstructures of Ti-6AI-2Sn-2Zr-2Mo-2Cr-0.25Si Titanium Alloy ............................................ 193 H.R. Pheos and J.R. Wood Evaluation of "i-6Al-2Sn-2Zr-2Cr-2Mo-.23Si Sheet ......................................... 201 R.C. Bliss TMP Conditions -Microstructure -Mechanical Property Relationships in Ti-6-22-22S Alloy .......................................................................................... 209 A.K. Chakrabarti,R . Pishko, V.M. Sample, and G.W Kuhlman Theoretical Design of f-Type Titanium Alloys .................................................. 217 M. Mornaa, M. Kato, T. Karnimura, M. Fukumoto, I. Harada,a nd K. Kubo Omega Phase Formation in Titanium and Titanium Alloys .............................. 225 f G.T. Gray, III, C.E. Moars, and A.C. Lawson I Role of Composition and Microstructure in Dynamic and Static Fracture of Alpha-Beta Titanium Alloys ............................................................ 233 R.W Judy. Jr.a nd I.L. Caplan An Investigation on Strengthening Process and Its Strengthening Mechanism for TC Titanium Alloy ................................................................... 241 4 X.K. Meng, Y.G. Zhou, and H.Q. Yu Improvement of Structure and Properties of (Ct+P3)-Ttanium Alloys Using the Rapid Heating and Accelerated Cooling .......................................... 247 OM. Ivashin and P.E. Markovsky Void Nucleation, Void Growth and Tensile Behavior of M1-1i0V-2Fe-3Al ........... 255 H. Margoln and S.J. Pak Effects of Hydrogen on the Structure and Properties of Beta-CTm (TI-3Al-8V-6Cr-4Mo-4Zr) Sheet ........................................................................ 263 J.R. Wood and M.L. BogenspeTger Quantitative Texture Analysis of a-Based Titanium and Titanium Alloys-A Two Stage Approach .................................................. 271 A.W. Bowen XN