Drying Technologies in Food Processing CHEN: “chen_c000” — 2008/4/30 — 14:12 — page i — #1 Dedications Tomyfamily:Lishun,Lisa,NathanandBenjamin XDC Tomyfamilyforalltheirsupport ASM CHEN: “chen_c000” — 2008/4/30 — 14:12 — page ii — #2 Drying Technologies in Food Processing Edited by Xiao Dong Chen Department of Chemical Engineering Monash University Melbourne, Victoria Australia Arun S. Mujumdar Department of Mechanical Engineering Faculty of Engineering National University of Singapore Singapore CHEN: “chen_c000” — 2008/4/30 — 14:12 — page iii — #3 Thiseditionfirstpublished2008 ©2008BlackwellPublishingLtd BlackwellPublishingwasacquiredbyJohnWiley&SonsinFebruary2007.Blackwell’s publishingprogrammehasbeenmergedwithWiley’sglobalScientific,Technical,and MedicalbusinesstoformWiley-Blackwell. 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TP363.D79452008 (cid:1) 664.0284—dc22 2008006131 AcataloguerecordforthisbookisavailablefromtheBritishLibrary. Setin10/12ptTimesbyNewgenImagingSystems(P)Ltd,Chennai,India PrintedinSingaporebyC.O.S.PrintersPteLtd 1 2008 CHEN: “chen_c000” — 2008/4/30 — 14:12 — page iv — #4 Contents Contributors xi Preface xiii Introduction:structuralimagesofsomefreshandprocessedfoods xv XiaoDongChen 1 Fooddryingfundamentals 1 XiaoDongChen 1.1 Introductiontofoodmaterials 1 1.2 Dryingoffood 2 1.3 Physicalpropertiesoffoods 8 1.3.1 Thescalesofinterest 8 1.3.2 Mechanicalproperties 10 1.3.3 Shrinkageanddensities 15 1.3.4 Thermalpropertiesandconventionalheating 20 1.3.5 Colour 26 1.3.6 Equilibriumisotherms 29 1.4 Dryingratecharacteristiccurveapproachtocorrelatedryingrates– vanMeel’smethod 30 1.5 Diffusiontheoriesofdrying 32 1.5.1 EffectiveFickiandiffusivity 32 1.5.2 Intuitiveunderstandingofthediffusiontheory 34 1.5.3 DryingoffoodssimulatedusingtheeffectiveFickian diffusionlaw 36 1.5.4 Alternativeeffectivediffusiontheories 38 1.6 Driers 42 1.7 Concludingremarks 43 1.8 Notation 44 AppendixI:Typicalmasstransfercorrelations 46 AppendixII:Onthe‘effectiveness’oftheeffectivemoisturediffusivity benchmarkedagainsttheLuikovtheory 46 AppendixIII:DryingofpulpedKiwifruitlayerformakingfruitleather 52 References 52 2 Wateractivityinfoodprocessingandpreservation 55 BheshR.BhandariandBenuP.Adhikari 2.1 Introduction 55 2.1.1 Thermodynamicsofwateractivity 56 2.1.2 Definitionandsignificance 57 CHEN: “chen_c000” — 2008/5/2 — 14:35 — page v — #5 vi Contents 2.1.3 Sorptionisotherms 58 2.1.4 Hysteresisinsorptionisotherms 58 2.2 Composition-basedwateractivitypredictivemodels 59 2.2.1 Raoult’sLaw 59 2.2.2 Norrishmodel 60 2.2.3 Rossmodel 61 2.2.4 Money–Bornequation 62 2.2.5 Grovermodel 63 2.2.6 Salwinequation 64 2.3 Modelsforpredictionofsorptionisotherms 65 2.3.1 Two-parametermodels 65 2.3.2 Three-parameterisotherms 68 2.3.3 Effectoftemperatureonwateractivity 73 2.3.4 Wateractivityaboveboilingpoint 75 2.4 Typesofsorptionisothermsandhysteresisinisotherms 75 2.5 Determinationofsorptionisotherms 78 2.5.1 Gravimetricmethod 78 2.5.2 Manometricmethod 83 2.5.3 Hygroscopicmethods 84 2.5.4 Samplepreparationandequilibriumtime 84 2.6 Concludingremarks 86 References 86 3 Biologicalchangesduringfooddryingprocesses 90 XiaoDongChenandKamleshC.Patel 3.1 Introductiontodryingandfoodquality 90 3.2 Post-dryingproblems 91 3.3 In-dryingproblems 95 3.4 Foodbio-deteriorationbydrying–asub-celllevelapproach 106 3.5 Concludingremarks 108 3.6 Notation 109 References 109 4 Spraydryingoffoodmaterials–processandproductcharacteristics 113 BheshR.Bhandari,KamleshC.PatelandXiaoDongChen 4.1 Introduction 113 4.2 Basicconceptsofspraydrying 114 4.3 Componentsofaspraydryingsystem 117 4.3.1 Dryinggassupplyandheatingsystem 117 4.3.2 Atomizationsystem 118 4.3.3 Dryingchamber 121 4.3.4 Powderseparators 122 4.4 Dryingofdroplets 125 4.4.1 Fundamentalsofdropletdrying 125 4.4.2 Dryingkinetics 126 4.4.3 Residencetime 129 CHEN: “chen_c000” — 2008/5/2 — 14:35 — page vi — #6 Contents vii 4.5 Massandheatbalancesoveraspraydrier 130 4.5.1 Overallmassbalance 130 4.5.2 Overallheatbalance 133 4.6 Drierefficiency 134 4.6.1 Thermalefficiency 134 4.6.2 Evaporativeefficiency 136 4.6.3 Volumetricevaporativecapacity 136 4.7 Powdercharacterization 137 4.7.1 Particlemicro-structure 137 4.7.2 Particlemorphology 139 4.7.3 Physicalandfunctionalpropertiesofpowder 141 4.7.4 Dryingparameters 147 4.8 Spraydryingofvariousfoodproducts 149 4.8.1 Dairypowders 149 4.8.2 Micro-encapsulatedpowders 151 4.8.3 Sugar-richproducts 153 4.8.4 Egg 154 4.8.5 Enzymes 154 4.9 Concludingremarks 155 4.10 Notation 155 References 157 5 Low-pressuresuperheatedsteamdryingoffoodproducts 160 SakamonDevahastinandPeamsukSuvarnakuta 5.1 Introduction 160 5.2 Basicprinciplesofsuperheatedsteamdrying 161 5.3 Low-pressuresuperheatedsteamdryingoffoodsandbiomaterials 163 5.4 SomeadvancesinLPSSDoffoodsandbiomaterials 177 5.5 MathematicalmodelingofLPSSDoffoodsandbiomaterials 182 5.6 Concludingremarks 186 5.7 Notation 187 References 187 6 Heatpump-assisteddrying 190 MdRaisulIslamandArunS.Mujumdar 6.1 Introduction 190 6.2 Classificationofheatpumpdriers 191 6.3 Fundamentalsofheatpumpdriers 191 6.4 Heatandmasstransfermechanisms 197 6.5 Optimumuseofheatpumpsindryingsystems 210 6.6 Innovativeheatpumpdryingsystems 212 6.6.1 Multi-stagecompressionheatpumpdrying 213 6.6.2 Cascadeheatpumpdryingsystems 214 6.6.3 Heatpumpdryingsystemswithmultipleevaporatorsin seriesandinparallel 215 6.6.4 Vaporabsorptionheatpumpdrier 217 CHEN: “chen_c000” — 2008/5/2 — 14:35 — page vii — #7 viii Contents 6.7 Closingremarks 221 6.8 Notation 222 References 223 7 Freezeandvacuumdryingoffoods 225 CristinaRatti 7.1 Introduction 225 7.2 Statesofwater 225 7.3 Foodandairpropertiesinrelationtovacuumandfreeze-drying 227 7.4 Heattransfermechanismsatlowpressures 232 7.5 Vacuumdrying:principlesanddehydrationmodels 234 7.6 Freezedrying:principlesanddehydrationmodels 236 7.7 Illustrativeexample 239 7.8 Advancesinvacuumandfreezedryingoffoods 243 7.9 Closure 245 7.10 Notation 245 References 246 8 Post-dryingaspectsformeatandhorticulturalproducts 252 MohammadShafiurRahman 8.1 Introduction 252 8.2 Statediagramandstabilityconceptsofdriedproducts 252 8.3 Controllingqualityattributes 255 8.3.1 Microbialquality 255 8.3.2 Chemicalchangesandquality 257 8.3.3 Physicalchangesandquality 260 8.3.4 Vitaminsretention 265 8.4 Conclusion 265 References 265 9 Fooddrierprocesscontrol 270 BrentR.Young 9.1 Introduction–whyprocesscontrol? 270 9.1.1 Disturbancevariables 270 9.1.2 Controlbenefits 271 9.1.3 Examples 271 9.1.4 Chapterorganization 272 9.2 Whattocontrol(manipulatedandcontrolledvariables) 272 9.2.1 Controlledvariables 272 9.2.2 Manipulatedvariables 273 9.3 Wheretocontrol(controlstrategy) 273 9.3.1 Plant-widecontrolstrategyconfiguration 273 9.3.2 Commonloopsandexamples 274 9.4 Whentocontrol(controlphilosophy) 276 9.4.1 Aftersomethinghappens–feedbackcontrol 276 9.4.2 Assomethinghappens–feed-forward/predictivecontrol 278 CHEN: “chen_c000” — 2008/5/2 — 14:35 — page viii — #8 Contents ix 9.5 Howtocontrol(fundamentalcontrolmethods) 279 9.5.1 PIDfeedbackcontrolandtuning 279 9.6 Howtodoadvancedcontrol(advancedcontrolmethods) 292 9.6.1 Modelpredictivecontrol(MPC) 293 9.6.2 Adaptivecontrol 295 9.6.3 Artificialintelligenceincontrol 295 References 297 10 Fireandexplosionprotectioninfooddriers 299 XiaoDongChen 10.1 Introduction–thermalhazardsindriers 299 10.1.1 Conditionsforanexplosiontooccur 299 10.1.2 Howseriousistheproblem? 300 10.1.3 Whataffectsthedegreeofviolenceofadustexplosion? 300 10.1.4 Howtoreducetheriskofdustexplosion 301 10.2 Apracticalexample:milkpowderplantsafety 301 10.2.1 Fires 302 10.2.2 Explosionprotection 310 10.3 Testingforvariousexplosionparameters 314 10.4 Thehumanfactors 314 10.5 Concludingremarks 316 References 316 Index 319 Thecolourplatesectionfollowspage40 CHEN: “chen_c000” — 2008/5/2 — 14:35 — page ix — #9 CHEN: “chen_c000” — 2008/5/2 — 14:35 — page x — #10
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