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DRYING, ROASTING, AND CALCINING OF MINERALS ' T M S J 0 15 th 144 Annual Meeting & Exhibition March 15-19, 2015 * Watt Disney World • Orlando, Florida, USA New proceedings volumes from the TMS2015 Annual Meeting, available from publisher John Wiley & Sons: • 6th International Symposium on High-Temperature Metallurgical Processing • Advanced Composites for Aerospace, Marine, and Land Applications II • Advances in the Science and Engineering of Casting Solidification • Characterization of Minerals, Metals, and Materials 2015 • Drying, Roasting, and Calcining of Minerals • Energy Technology 2015 • EPD Congress 2015 • Friction Stir Welding and Processing VIII • Light Metals 2015 • Magnesium Technology 2015 • Rare Metal Technology 2015 • TMS 2015 Supplemental Proceedings To purchase any of these books, visit www.wiley.com. TMS members: Log in to the Members Only area of www.tms.org and learn how to get your discount on these and other books offered by Wiley. V J DRYING, ROASTING, AND CALCINING OF MINERALS Proceedings of a symposium sponsored by The Minerals, Metals & Materials Society (TMS) held during TIMS2015 144™ Annual Meeting & Exhibition March 15-19, 2015 Walt Disney World • Orlando, Florida, USA EDITORS Thomas P. Battle Jerome P. Downey Lawrence D. May Boyd Davis Neale R. Neelameggham Sergio Sanchez-Segado P. Chris Pistorius TMS Wl LEY Copyright © 2015 by The Minerals, Metals & Materials Society. All rights reserved. Published by John Wiley & Sons, Inc., Hoboken, New Jersey. Published simultaneously in Canada. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of The Minerals, Metals, & Materials Society, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at www.copyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., Ill River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http:// www.wiley.com/go/permission. Limit of Liability/Disclaimer of Warranty: While the publisher and author have used their best efforts in preparing this book, they make no representations or warranties with respect to the accuracy or completeness of the contents of this book and specifically disclaim any implied warranties of mer- chantability or fitness for a particular purpose. No warranty may be created or extended by sales rep- resentatives or written sales materials. The advice and strategies contained herein may not be suitable for your situation. You should consult with a professional where appropriate. Neither the publisher nor author shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages. Wiley also publishes books in a variety of electronic formats. Some content that appears in print may not be available in electronic formats. For more information about Wiley products, visit the web site at www.wiley.com. For general information on other Wiley products and services or for technical sup- port, please contact the Wiley Customer Care Department within the United States at (800) 762-2974, outside the United States at (317) 572-3993 or fax (317) 572-4002. Library of Congress Cataloging-in-Publication Data is available. ISBN 978-1-119-07337-6 Printed in the United States of America. 10 987654321 Wl LEY TIÜS TABLE OF CONTENTS Drying, Roasting, and Calcining of Minerals Preface ix About the Editors xi Session Chairs xv Roasting Sulfation Roasting of a Bornite Flotation Concentrate to Optimize Silver Extraction in a Ferric Chloride Leach 3 R. Foy, S. Lloyd, B. Steinbom, and J. Downey Chlorination Roasting of Rare Earth Element Oxides 11 D. Gaede, B. Ruffier, J. Downey, J. Chorney, L. Twidwell, R. Foy, and K. Lyons Bromination Roasting of Rare Earth Oxides 19 B. Ruffier, D. Gaede, J. Downey, L. Twidwell, J. Chorney, R. Foy, and K. Lyons The Advantages of Thermal Analysis Prior to Bench-Scale Roasting 27 T. Salisbury and J. White Extraction of Indium from Zinc Oxide Flue Dust by Microwave Sulfation Roasting and Water Leaching 35 J. Chang, J. Peng, L. Zhang, and J. Chen Behavior of Arsenic, Antimony and Bismuth at Roasting Temperatures 43 R. Padilla and M. Ruiz Characterization of Physico-Chemical Changes during the Alkali Roasting of Niobium and Tantalum Oxides 51 S. Sanchez-Segado, A. Ruzaidi, Y. Zhang, and A. Jha Mechanism of NaS0 on Refractory Gold Concentrate at Roasting 2 4 Pretreatment 59 Q. Li, J. Hu, Y. Yang, B. Xu, and T. Jiang Drying and Calcining Optimization on Drying of CuCl Residue by Hot-Air Using Response Surface Methodology 73 Z. Guo, S. Ju, T. Lei, J. Peng, L. Zhang, and F. Jiang v Application of Kumera Steam Dryers in Mineral Processing 81 C. Berg, S. Chen, and H. Mansikkaviita Dielectric Properties and Microwave Drying Characteristics of CuCl Residue 89 Z. Guo, S. Ju, T. Lei, J. Peng, L. Zhang, and F. Jiang Moisture Dependent Dielectric Properties and Microwave Drying Behavior of Zirconium Hydroxide 97 A. Ma, X. Zheng, L. Zhang, J. Peng, S. Li, and Y. Zuo Optimization of Microwave Drying of Salt with Response Surface Methodology 105 B. Wang, L. Zhang, B. Liu, J. Peng, H. Xia, and Z. Li The Impact of Calcination Conditions on Production of Magnesium by the Magnatherm Process 113 J. Sever Calix Calciner: A Green Application in the Production of Magnesium 121 J. Sever Modeling and Design of Experiment in Calcination of Magnesites 127 B. Chakrabarti Study on Effect of Untreated and Calcined Olivine on Low Silicon Pellet Production Process and Quality 135 G. Qing, K. Wu, S. Chen, Q. Liu, and L. Ma Fluidization, Reduction Roasting, and Microwave Treatment Fluidization and Magnetization Roasting Technology Research on Siderite .. 145 W. Chen, Z. Liao, X. Liu, L. Zhang, J. Li, andX Liu The Temperature Behavior and Microwave Thermo Gravimetric Analysis Characteristic of Ammonium Paratungstate in a Microwave Field 153 G. Sheng-Hui, C. Fang, P. Jin-Hui, and Z. Lie-Xing Green Evaluation of Microwave Shaft Furnaces 161 J. Chen, G. Chen, and J. Peng vi Behavior of Phosphorus during Reduction Roasting of Oolitic Hematite Ore with High-Phosphorus Content 169 G. Li, C. Ouyang, M. Rao, Y. Zhang, and S. Zhang Effect of Additives on Phase Transformation of Nickel Laterite Ore during Low-Temperature Reduction Roasting Process Using Carbon Monoxide 177 S. Zhou, B. Li, Y. Wei, H. Wang, C. Wang, and B. Ma Effect of Temperature on Reduction Roasting of Low-Grade Iron Ore after Granulating with Coal 185 Z. Huang, R. Zhong, J. Zou, and T. Jiang Thermo-Physical Properties of Petroleum Coke during Calcining Graphitization Process 193 M. Long, J. Sheng, T. Liu, D. Chen, Y. Yang, S. Gong, and C. Chen Induration and Sintering Prediction of Non-Isothermal Oxidation of Magnetite Pellets 203 P. Pistorius and M. Tang Monitoring the Ring Formation in Rotary Kiln for Pellet Firing 209 D. Zhu, X. Zhou, Y. Luo, J. Pan, C. Zhen, and G. Huang Study on the Improvement of Preheating and Roasting Characteristics of Pellet Made by Organic-Bentonite Compound Binder 217 Y. Guo, T. Duan, A. Travyanov, T. Jiang, S. Wang, and F. Zheng Effects of Anthracite on Pelletization of Hematite Ore 225 Z. Tang, M. Rao, Y. Zhang, and G. Li Preparation of Straw Char by Preformation-Carbonization Process and Its Application in Iron Ore Sintering 233 X. Fan, Z. Ji, M. Gan, X Chen, L. Yin, and T. Jiang Influence of Modified Biomass Fuel on Iron Ore Sintering 241 M. Gan, X. Fan, Z. Ji, X Chen, T. Jiang, G. Li, and Z. Yu The Phase Transformation of Baiyunebo Iron Ore Treated with Reductant Sintering 249 B. Bai, Y. Guo, L. Yang, G. Gao, and J. Zhang vii Sintering and Energy Use Effect of Sinter Basicity on Sinter Productivity and Quality with High Rate of Recycled Materials 259 M. Zhang, M. Coe, and M. Andrade Research on NOx Reduction by Applying Coke Breeze Pretreated with Urea Additive in Iron Ore Sintering Process 269 X Fan, Z. Yu, M. Gan, X. Chen, Y Huang, T. Jiang, and G. Li The Generation Ability of Liquid Phase for Mixture of Iron Ore Powders and Lime: Prediction, Characterization and Influencing Factors 277 C. Ji, X. Lv, X. Zheng, C. Ding, and R. Zhang Author Index 289 Subject Index 291 viii

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