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Design, Development, and Applications of Engineering Ceramics and Composites Design, Development, and Applications of Engineering Ceramics and Composites Ceramic Transactions, Volume 215 A Collection of Papers Presented at the 8th Pacific Rim Conference on Ceramic and Glass Technology May 31-June 5, 2009 Vancouver, British Columbia Edited by Dileep Singh Dongming Zhu Yanchun Zhou Volume Editor Mrityunjay Singh ©WILEY A John Wiley & Sons, Inc., Publication Copyright © 2010 by The American Ceramic Society. All rights reserved. Published by John Wiley & Sons, Inc., Hoboken, New Jersey. Published simultaneously in Canada. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at www.copyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http://www.wiley.com/go/permission. Limit of Liability/Disclaimer of Warranty: While the publisher and author have used their best efforts in preparing this book, they make no representations or warranties with respect to the accuracy or completeness of the contents of this book and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives or written sales materials. The advice and strategies contained herein may not be suitable for your situation. You should consult with a professional where appropriate. Neither the publisher nor author shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages. For general information on our other products and services or for technical support, please contact our Customer Care Department within the United States at (800) 762-2974, outside the United States at (317) 572-3993 or fax (317) 572-4002. Wiley also publishes its books in a variety of electronic formats. Some content that appears in print may not be available in electronic format. For information about Wiley products, visit our web site at www.wiley.com. Library of Congress Cataloging-in-Publication Data is available. ISBN 978-0-470-88936-7 Printed in the United States of America. 10 9 8 7 6 5 4 3 21 Contents Preface ix Introduction xi DEVELOPMENTS IN ENGINEERING CERAMICS Elastic and Vibration Properties of Diamond-Like B-C Materials 3 J. E. Lowther Towards Simulation-Based Predictive Design of Glasses 17 Liping Huang and John Kieffer Dynamic Behavior of Thick Alumina Plates with Tunneled Interfaces 27 F. Orgaz, T. Gómez del Rio, A.Varela and J.F. Fernández Deposition Phase Diagrams for Chemical Vapor Deposition of 41 BCI -CH -H System 3 4 2 Shanhua Liu, Litong Zhang, Yongsheng Liu, Laifei Cheng, Xiaowei Yin, and Qingfeng Zeng The Relation between Optical Properties and Lattice Defects of 49 Translucent Aluminum Nitride Ceramics Fabricated by the Novel Annealing Process Yukihiro Kanechika, Yuriko Kaito, Masanobu Azuma, and Hiroshi Fukushima Thermodynamic Calculations of ZrC-SiC System for Chemical Vapor 65 Deposition Applications from SiCl4-ZrCI -CH -H 4 4 2 Qiaomu Liu, Litong Zhang, Yiguang Wang, and Laifei Cheng Debindering of Non Oxide Ceramics under Protective Atmosphere 77 Dieter G. Brunner, Gaby Böhm, Friedrich Raether, and Andreas «limera Softening of Rare Earth Orthophosphates by Transformation 87 Plasticity: Possible Applications to Fiber-Matrix Interphases in Ceramic Composites R. S. Hay, G. Fair, E. E. Boakye, P. Mogilevsky, T. A. Parthasarathy, and J. Davis v Influence of Fiber Architecture on Impact Resistance of Uncoated 97 SiC/SiC Composites Ramakrishna T. Bhatt, Laura M. Cosgriff, and Dennis S. Fox Oxidation Kinetics and Strength versus Scale Thickness for 105 Hi-NICALON™-S SiC Fiber R. S. Hay, G. Fair, E. Urban, J. Morrow, J. Somerson, and M. Wilson Ceramic Matrix Composites Densif¡cation by Active Filler 113 Impregnation Followed by a P.I.P. Process S. Le Ber, M.-A. Dourges, L. Maillé, R. Pailler, and A. Guette High Potential of Composites with Carbon Fibers and a Self-Sealing 125 Ceramic Matrix in Moist Environments under High Pressures at 600°C L. Quémard, F. Rebillat, F., A. Guette, H. Tawil, and C. Louchet-Pouillerie Quantification of Higher SiC Fiber Oxidation Rates in Presence of 135 B 0 under Air 2 3 F. Rebillat, E. Garitte, and A. Guette Overview on the Self-Sealing Process in the SiC/[Si,C,B] 151 M Composites under Wet Atmosphere at High Temperature F. Rebillat, X. Martin, E. Garitte, and A. Guette NDE for Characterizing Oxidation Damage in Reinforced 167 Carbon-Carbon Don J. Roth, Richard W. Rauser, Nathan S. Jacobson, Russell A. Wincheski, James L. Walker, and Laura A. Cosgriff Silicon Nitride and Silicon Carbide Components as Enabling Tools 181 in Avionics, Space and Dispersing Technology Karl E. Berroth á/â SiAION Based Composites Incorporated with MoSi for 189 2 Electrical Applications Erhan Ayas, Alpagut Kara, and Ferhat Kara Microstructure Characteristics and High-Temperature Performance of 197 In-Situ Reinforced á-SiAION Ceramics Yu Zhou, Feng Ye, and Chunfeng Liu Synthesis Process and Microstructure for AI 03/TiC/Ti Functionally 207 2 Gradient Materials Enrique Rocha-Rangel, David Hernández-Silva, Elizabeth Refugio-García, José G. Miranda-Hernández, and Eduardo Terrés-Rojas Brazing of MIEC Ceramics to High Temperature Metals 213 S. Dabbarh, E. Pfaff, A. Ziombra, and A. Bezold vi · Design, Development, and Applications of Engineering Ceramics and Composites ADVANCED CERAMIC COATINGS Thermodynamic Data for Y-O-H(g) from Volatilization Studies 227 E. Courcot, F. Rebillat, and F. Teyssandier From the Volatility of Simple Oxides to that of Mixed Oxides: 235 Thermodynamic and Experimental Approaches E. Courcot, F. Rebillat, and F. Teyssandier Nanolaminated Oxide Ceramic Coatings in the Y2O3-AI2O3 System 245 Nadine K. Eils, Peter Mechnich, Martin Schmücker, and Hartmut Keune Thermochemical Stability of Rare Earth Sesquioxides under a Moist 257 Environment at High Temperature E. Courcot, F. Rebillat, and F. Teyssandier Manufacture of P-Type ZNO Thin Film by CO-Sputtering of ZN and 265 LI C0 Targets Simultaneously 2 3 Yang-Ming Lu, Shu-Yi Tsai, and Shin-Yi Wu Synthesized Zircon and Zircon Composite from Liquid Chemical 273 Process Yanxia Lu Zr0 -Environmental Barrier Coatings for Oxide/Oxide Ceramic 285 2 Matrix Composites Fabricated by Electron-Beam Physical Vapor Deposition Peter Mechnich and Wolfgang Braue GEOPOLYMERS Development of Geopolymers from Plasma Vitrified Air Pollution 297 Control Residues from Energy from Waste Plants loanna Kourti, D. Amutha Rani, D. Deegan, C. R. Cheeseman, and A. R. Boccaccini Synthesis of Zeolite-X from Waste Porcelain Using Alkali Fusion 305 Takaaki Wajima and Yasuyuki Ikegami The Ageing Process of Alkali Activated Metakaolin 315 C. H. Rüscher, E. Mielcarek, W. Lutz, A. Ritzmann, and W. M. Kriven Testing of Geopolymer Mortar Properties for Use as a Repair 325 Material Wanchai Yodsudjai, Prasert Suwanvitaya, Weerapong Pikulprayong, and Banjerd Taweesappaiboon Author Index 335 Design, Development, and Applications of Engineering Ceramics and Composites · vii Preface This proceedings contains 32 peer-reviewed papers (invited and contributed) from the following five symposia held during the 8th Pacific Rim Conference on Ceram- ic and Glass Technology (PACRIM 8), May 31-June 5, 2009 in Vancouver, Cana- da: • Engineering Ceramics and Ceramic Matrix Composites: Design, Develop- ment, and Applications; • Advanced Ceramic Coatings: Processing, Properties and Applications; • Computational Approaches in Materials Research and Design; • Geopolymers; and • Advanced Thermal Management Materials and Technologies We would like to thank all of the symposium organizers for their tireless work in the planning and execution of the excellent technical program. The editors also wish to extend their gratitude and appreciation to all the authors for their contribu- tions, to all the participants and session chairs for their time and effort, and to all the reviewers for their valuable comments and suggestions. Finally, we thank the dedi- cated and courteous staff at The American Ceramic Society for organizing and sponsoring this meeting and making this proceedings volume possible. DILEEP SINGH, Argonne National Laboratory, USA DONGMING ZHU, NASA Glenn Research Center, USA YANCHUN ZHOU, Shenyang National Laboratory for Materials Science, China IX Introduction The 8th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM 8), was the eighth in a series of international conferences that provided a forum for pre- sentations and information exchange on the latest emerging ceramic and glass tech- nologies. The conference series began in 1993 and has been organized in USA, Korea, Japan, China, and Canada. PACRIM 8 was held in Vancouver, British Columbia, Canada, May 31-June 5, 2009 and was organized and sponsored by The American Ceramic Society. Over the years, PACRIM conferences have established a strong reputation for the state-of-the-art presentations and information exchange on the latest emerging ceramic and glass technologies. They have facilitated global dialogue and discussion with leading world experts. The technical program of PACRIM 8 covered wide ranging topics and identified global challenges and opportunities for various ceramic technologies. The goal of the program was also to generate important discussion on where the particular field is heading on a global scale. It provided a forum for knowledge sharing and to make new contacts with peers from different continents. The program also consisted of meetings of the International Commission on Glass (ICG), and the Glass and Optical Materials and Basic Science divisions of The American Ceramic Society. In addition, the International Fulrath Symposium on the role of new ceramic technologies for sustainable society was also held. The technical program consisted of more than 900 presentations from 41 different coun- tries. A selected group of peer reviewed papers have been compiled into seven vol- umes of The American Ceramic Society's Ceramic Transactions series (Volumes 212-218) as outlined below: • Innovative Processing and Manufacturing of Advanced Ceramics and Composites, Ceramic Transactions, Vol. 212, Zuhair Munir, Tatsuki Ohji, and Yuji Hotta, Editors; Mrityunjay Singh, Volume Editor Topics in this volume include Synthesis and Processing by the Spark Plasma xi Method; Novel, Green, and Strategic Processing; and Advanced Powder Processing • Advances in Polymer Derived Ceramics and Composites, Ceramic Transactions, Vol. 213, Paolo Colombo and Rishi Raj, Editors; Mrityunjay Singh, Volume Editor This volume includes papers on polymer derived fibers, composites, function- ally graded materials, coatings, nanowires, porous components, membranes, and more. • Nanostructured Materials and Systems, Ceramic Transactions, Vol. 214, Sanjay Mathur and Hao Shen, Editors; Mrityunjay Singh, Volume Editor Includes papers on the latest developments related to synthesis, processing and manufacturing technologies of nanoscale materials and systems includ- ing one-dimensional nanostructures, nanoparticle-based composites, electro- spinning of nanofibers, functional thin films, ceramic membranes, bioactive materials and self-assembled functional nanostructures and nanodevices. • Design, Development, and Applications of Engineering Ceramics and Composite Systems, Ceramic Transactions, Vol. 215, Dileep Singh, Dong- ming Zhu, and Yanchun Zhou; Mrityunjay Singh, Volume Editor Includes papers on design, processing and application of a wide variety of materials ranging from SiC SiAlON, Zr0 , fiber reinforced composites; ther- 2 mal/environmental barrier coatings; functionally gradient materials; and geopolymers. • Advances in Multifunctional Materials and Systems, Ceramic Transac- tions, Vol. 216, Jun Akedo, Hitoshi Ohsato, and Takeshi Shimada, Editors; Mrityunjay Singh, Volume Editor Topics dealing with advanced electroceramics including multilayer capaci- tors; ferroelectric memory devices; ferrite circulators and isolators; Varis- tors; piezoelectrics; and microwave dielectrics are included. • Ceramics for Environmental and Energy Systems, Ceramic Transac- tions, Vol. 217, Aldo Boccaccini, James Marra, Fatih Dogan, Hua-Tay Lin, and Toshiya Watanabe, Editors; Mrityunjay Singh, Volume Editor This volume includes selected papers from four symposia: Glasses and Ce- ramics for Nuclear and Hazardous Waste Treatment; Solid Oxide Fuel Cells and Hydrogen Technology; Ceramics for Electric Energy Generation, Stor- age, and Distribution; and Photocatalytic Materials. • Advances in Bioceramics and Biotechnologies, Ceramic Transactions, Vol. 218; Roger Narayan and Joanna McKittrick, Editors; Mrityunjay Singh, Volume Editor Includes selected papers from two cutting edge symposia: Nano-Biotechnolo- gy and Ceramics in Biomédical Applications and Advances in Biomineralized Ceramics, Bioceramics, and Bioinspiried Designs. 1 would like to express my sincere thanks to Greg Geiger, Technical Content Manager of The American Ceramic Society for his hard work and tireless efforts in xii ■ Design, Development, and Applications of Engineering Ceramics and Composites the publication of this series. I would also like to thank all the contributors, editors, and reviewers for their efforts. MRITYUNJAY SINGH Volume Editor and Chairman, PACRIM-8 Ohio Aerospace Institute Cleveland, OH (USA) Design, Development, and Applications of Engineering Ceramics and Composites · xiii

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