Design and Construction of Coordination Polymers

419 Pages·2009·68.245 MB·English

DESIGN AND CONSTRUCTION
OF COORDINATION POLYMERS
DESIGN AND CONSTRUCTION
OF COORDINATION POLYMERS
Edited by
MAO-CHUN HONG
LING CHEN
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LibraryofCongressCataloging-in-PublicationData:
Designandconstructionofcoordinationpolymers/
[editedby]Mao-ChunHongandLingChen
Includesbibliographicreferencesandindex
ISBN978-0-470-29450-5(cloth)
PrintedintheUnitedStatesofAmerica
10987654321
Dedicatedto
theFujianInstituteofResearchontheStructureofMatter,
ChineseAcademyofSciences,ontheoccasionof
thefiftiethanniversaryofitsfounding
and
ProfessorXin-TaoWu,oneofthepioneersinthe
developmentoftheFujianInstitute,onthe
occasionofhisseventiethbirthday
CONTENTS
Contributors xi
Preface xv
1 Coordinative Flexibility of Monovalent Silver in
[AgI!L1]L2 Complexes 1
GerdMeyer,MuhametSehabi,andIngoPantenburg
1.1 Introduction, 1
1.2 Ligands L1 with 1,2 N-Donor Functions, 2
1.3 Ligands L1 with 1,3 N-Donor Functions, 7
1.4 Ligands L1 with 1,4 N-Donor Functions, 12
1.5 Conclusions, 19
References, 22
2 Indium(III)–Organic Coordination Polymers with Versatile
Topological Structures Based on Multicarboxylate Ligands 25
LianChen,Fei-LongJiang,Zheng-ZhongLin,andMao-ChunHong
2.1 Introduction, 25
2.2 Architectures Constructed by In(III) and Benzenedicarboxylates, 27
2.3 Architectures Constructed by In(III) and Benzenetricarboxylates, 35
2.4 Architectures Constructed by In(III) and Other
Benzenemulticarboxylates, 49
2.5 Luminescence, Ion Exchange, and Hydrogen Storage, 55
2.6 Conclusions, 56
References, 59
vii
viii CONTENTS
3 Crystal Engineering of Coordination Polymers via
Solvothermal In Situ Metal–Ligand Reactions 63
Jie-PengZhangandXiao-MingChen
3.1 Introduction, 63
3.2 Metal-Redox Reaction, 65
3.3 Conversion of Carboxylic Acid, 69
3.4 Carbon–Carbon Bond Formation, 72
3.5 Heterocycle Formation from Small Molecules, 75
3.6 Transformation of Sulfur-Containing Ligands, 81
3.7 Conclusions, 83
References, 84
4 Construction of Some Organic–Inorganic Hybrid
Complexes Based on Polyoxometalates 87
Can-ZhongLu,Quan-GuoZhai,Xiao-YuanWu,Li-JuanChen,
Shu-MeiChen,Zhen-GuoZhao,andXiao-YuJiang
4.1 Introduction, 87
4.2 Complexes Built Up by POMs with 1,2,4-Triazolate
and Its Derivatives, 88
4.3 Complexes Built Up by Molybdenum Oxide Chains
with Pyridine Derivatives, 102
4.4 Conclusions, 107
References, 108
5 Silver(I) Coordination Polymers 111
Cheng-YongSu,Chun-LongChen,Jian-YongZhang,andBei-ShengKang
5.1 Introduction, 111
þ
5.2 Coordination Geometries of Ag Ions, 112
5.3 Ligands in Silver(I) Coordination Polymers, 121
5.4 Supramolecular Interactions and Counter Anions
in Silver(I) Coordination Polymers, 128
5.5 One- to Three-Dimensional Coordination Polymers
Based on Silver–Ligand Coordination Bonds, 130
5.6 Intertwining or Interpenetrating of Silver(I)
Coordination Polymers, 135
5.7 Properties of Silver(I) Coordination Polymers, 137
References, 139
6 Tuning Structures and Properties of Coordination Polymers
by the Noncoordinating Backbone of Bridging Ligands 145
MiaoDuandXian-HeBu
6.1 Introduction, 145
6.2 Ligand Design for Coordination Polymers, 146
CONTENTS ix
6.3 Role of Noncoordinating Backbones of Bridging Ligands, 150
6.4 Conclusions, 164
References, 165
7 Ferroelectric Metal–Organic Coordination Compounds 71
Heng-YunYe,WenZhang,andRen-GenXiong
7.1 Introduction, 71
7.2 Homochiral Discrete or Zero-Dimensional MOCCs, 173
7.3 Acentric MOCPs Produced by Supramolecular
Crystal Engineering, 179
7.4 Homochiral MOCPs Constructed with Optical
Organic Ligands, 183
7.5 Conclusions, 191
References, 192
8 Constructing Magnetic Molecular Solids by Employing
Three-Atom Ligands as Bridges 195
Xin-YiWang,Zhe-MingWang,andSongGao
8.1 Introduction, 195
8.2 Coordination Characteristics of Three-Atom Bridges
and Their Role in Mediating Magnetic Interaction, 197
8.3 Co-Ligands, Templating Cations, and Other Short Bridges, 200
8.4 Magnetic Molecular Solids Based on Three-Atom Bridges, 202
8.5 Conclusions, 222
References, 223
9 Structures and Properties of Heavy Main-Group Iodometalates 229
Li-MingWuandLingChen
9.1 Introduction, 229
9.2 Structural Features of Iodobismuthates and Iodoplumbates, 230
9.3 Structural Modification, 249
9.4 Optical and Thermal Properties, 255
9.5 Summary, 262
References, 263
10 Cluster-Based Supramolecular Compounds from
Mo(W)/Cu/S Cluster Precursors 267
Jian-PingLang,Wen-HuaZhang,Hong-XiLi,andZhi-GangRen
10.1 Introduction, 267
10.2 Strategies for Design and Assembly, 268
10.3 Structural Features, 273
10.4 Luminescent and Third-Order Nonlinear Optical Properties, 298
x CONTENTS
10.5 Conclusions, 301
References, 302
11 Microporous Metal–Organic Frameworks as Functional
Materials for Gas Storage and Separation 307
LongPan,Kun-HaoLi,JeongYongLee,DavidH.Olson,andJingLi
11.1 Introduction, 307
11.2 Design, Rational Synthesis, and Structure Description, 309
11.3 Structure Stability, Permanent Microporosity, and
Hydrogen Adsorption, 322
11.4 Hydrocarbon Adsorption, 332
11.5 Ship-in-Bottle Synthesis, 348
11.6 Summary and Conclusions, 349
References, 350
12 Design and Construction of Metal–Organic Frameworks
for Hydrogen Storage and Selective Gas Adsorption 353
Sheng-QianMa,ChristopherD.Collier,andHong-CaiZhou
12.1 Introduction, 353
12.2 Hydrogen Storage in Porous Metal–Organic Frameworks, 354
12.3 Porous Metal–Organic Frameworks for Selective
Gas Adsorption, 366
12.4 Outlook, 369
References, 370
13 Structure and Activity of Some Bioinorganic
Coordination Complexes 375
Jin-TaoWang,Yu-JiaWang,PingHu,andZong-WanMao
13.1 Introduction, 375
13.2 Biomimetic Modeling of a Metalloenzyme with a
Cluster Structure, 376
13.3 Bioinspired Complexes with a Recognition Domain, 384
13.4 Functional Complexes as Therapeutic Agents, 391
13.5 Conclusions, 400
References, 401
Index 405
PREFACE
This volume, Design and Construction of Coordination Polymers, is published in
recognition of the fiftieth anniversary of the beginning of the Fujian Institute of
ResearchontheStructureofMatter,ChineseAcademyofScience,andisdedicatedto
Prof.Xin-TaoWu,ontheoccasionofhisseventiethbirthday.Thevolumecontains13
chaptersthatfocusonthistheme,contributedbyformergraduatesandfriendsofthis
institution.Theyspanawiderangeoftopics,systems,andapproachestocoordination
polymers. In Chapter 1, G. Meyer and co-workers describe a variety of AgL L
1 2
coordinationcomplexesachievedwithmixedN-containingligands,someofwhich
exhibit particularly short Ag--N distances. A series of indium(III)–carboxylate
coordinationpolymers with avariety ofdimensionalities are reported inChapter2
by M.-C. Hong and colleagues. Following this, in Chapter 3, X.-M. Chen and co-
workersexamineaninterestingseriesofcoordinationpolymersthatareformedby
solvothermal reactions between diverse metals and ligands, covering a variety of
functionalitiesandreactiontypes.InChapter4,C.-Z.Luandco-workersreportona
varietyofhybridpolyoxometallatesbuiltofoxo-Mo,oxo-Cu,andoxo-Agcentersand
1,2,4-triazolateorpyridinederivatives.InChapter5,C.-Y.Suandothersdescribethe
rangeofAg(I)coordinationenvironmentsthatcanbeobtainedwithvariousligand
typesaswellasinterpenetratingpolymersandtheirdiversepropertiesandapplica-
tions.Adifferent type ofvarietyresultswhen coordination polymers are tuned via
systematicvariationsinthebridgingorganicbackboneswithinmultidentateligands,
asrelated by X.-H. Bu and othersinChapter6.
Chapter 7, by R.-G. Xiong and co-workers, features a different direction, the
design and synthesis offerroelectric coordination compounds or polymers that are
constructedofmonochiralligandsandoccurinpolarspacegroups.Thegeneration
andpropertiesofparamagneticsolidsofdifferentdimensionalitiesfromthree-atom
xv
xvi PREFACE
bridging ligands and 3d metal ions are described by S. Gao and colleagues in
Chapter 8. In Chapter 9, L.-M. Wu and L. Chen describe and explain structural,
optical, and thermal properties of various iodometallic phases of Pb or Bi with
differentdimensionalitiesandmotifs.J.-P.Langandco-workersrelateinChapter10
the design, construction, and optical properties of supramolecular cluster-based
phases of Mo(W)/Cu/S. Microporous metal–organic frameworks as materials for
gas storage and separation are addressed in Chapter 11 by J. Li and colleagues. In
Chapter 12, H.-C. Zhou and co-workers enumerate the design, construction, and
propertiesofvariousmetal–organicframeworksforstorageandseparationofgases,
H in particular. Finally, in Chapter 13, Z.-W. Mao and colleagues outline the
2
applicationofsomebioinorganiccoordinationcompoundsasmimicsormodelsfor
arange ofbiological functions ortherapeutic agents. Enjoy!
Wearegratefulforalltheauthorswhounselfishlyspenttheirmostprecioustimein
writingcontributionsforthevolumeandmeetingdeadlines.Specialthanksaregiven
toProf.ThomasC.W.MakattheChineseUniversityofHongKong,Prof.Bei-Sheng
KangatSunYat-SenUniversity,GuangzhouandProf.Qiu-TianLiuatFIRSMfor
theirkindhelp,andA.LekhwaniandR.AmosofJohnWiley&Sons,Inc.foreditorial
assistance.
MAO-CHUN HONG
LING CHEN
Fuzhou
August2008