DECEMBER 2011 Published by CCPIA CHINA AGROCHEMICALS

32 Pages·2011·9.13 MB·English

DECEMBER 2011
Published by CCPIA
CHINA AGROCHEMICALS
TH
11 AGROCHEMEX
SPECIAL
(PAGE 8-PAGE 15)
China Top 20 Agrochemical
Enterprises in 2010 (page 2)
China Output Ups 15.7% in First
9 Months (page 3)
Responsibility Care of Paraquat
Working Group (page 7)
www.ccpia.org.cn/en

CHINA AGROCHEMICALS
CONTENTS
INDUSTRIAL NEWS MARKET ANALYSIS
16 Sales of Paraquat up in September
2 New Generic Active Compounds Approval
16 Analysis of China Export of Glyphosate and Carbodazim
2 China Top 20 Agrochemical Enterprises in 2010
3 China Output Ups 15.7% in First 9 Months Companies
4 The Main Arochemical Commodities in China
17 Jiangsu Changqing Fomesafen AI Production Project
6 Technology Award of CPCIF in 2011
18 Hunan Haili will Invest the Agrochem Project
7 Responsibility Care of Paraquat Working Group
19 Jiangsu Kesheng New Agrochemical Patenting Activity
R&D
th
11 AgroChemEx Special
20 Synthesis, Crystal Structure and Biological Activity of
N-tert-Butyl-N-(3-methoxylbenzoyl)-N-(4-methyl-1,2,3-
8 Interview of Experts in AgroChemEx thiadiazole-5-formyhydrazine)
11 China Agrochemical Industry Awards
Products
13 Comments of the Report of 11th AgroChemEx
14 Review of the 11th AgroChemEx 24 Pesticides with Pyridine Ring Research Progress
Director of Editorial Dept.: Sun Shubao
Editor in Chief: Connie Ao
Executive Editors: Duan Yousheng, Zhu WeiJuan, Luo Yan
Consultant: Hu Xiaoxing
Sponsor: China Crop Protection Industry Association (CCPIA)
Address: Room 920, Anhuili 4th Area, Chaoyang District,Beijing,China Postal Code: 100723 Fax: [phone]
Websites:www.ccpia.org.cn/en www.agrochemex.net/en(exhibition)
ADVERTISING SALES Connie Ao Tel: [phone]
GENERAL ENQUIRIES E-mail: [email protected] Tel: [phone]
All rights reserved.
DEC 2011
INDUSTRIAL NEWS
New Generic Active Compounds China Top 20 Agrochemical
Approval Enterprises in 2010
According to MIIT(Ministry of Industry and China’s top 20 pesticide manufactures achieved
Information Technology), the raw material total sales of Yuan 21.2 billion (3.3 billion at the
department recently publicized offi cial website current rate) in 2010. Specifi c rankings see the table
of approved list of agrochemical enterprises in below. Zhejiang Wynca Chemical Co., Ltd., Jiangsu
2011 (second batch). The list involves Shanghai Yangnong Chemical Co., Ltd. and Zhejiang Jinfanda
HeTeng Fine Chemical Co., Ltd., Anhui FuTian Biochemical Co., Ltd. placed top 3.
Agrochemicals Co., Ltd., Lianyungang HeTian
Chemical Co., Ltd. and Nantong JiaHe Chemical Co., CChhiinnaa TToopp 2200 aaggrroocchheemmiiccaall eenntteerrpprriisseess iinn 22001100
Ltd..
Sales
Enterprise
Enterprises Project (100million yuan)
Shanghai HeTeng Fine Chemical
Ethiprole Technical Zhejiang Wynca Chemical Co., Ltd. 18.73
Co., Ltd.
Jiangsu Yangnong Chemical Co., Ltd. 14.96
AcetochIor Technical,
Anhui FuTian Agrochemicals
Pretilachlor Technical,
Co., Ltd. Zhejiang Jinfanda Biochemical Co.,Ltd 14.55
Butachlor Technical
Benmijunzhi Technical, Shenzhen Noposion Agrochemical Co., Ltd. 14.34
Lianyungang HeTian Chemical Benfuracarb Technical,
Co., Ltd. Fluazinam Technical, Hubei Sanonda Co., Ltd.HH 13.85
Flumetsulam Technical
Jiangsu Tianrong Group Co., Ltd. 11.30
Propyzamide Technical,
Nantong JiaHe Chemical Co., Ltd. Oxyfl uorfen Technical,
Bayer CropScience China Co., Ltd. 11.15
Difl ufenican Technical
Shandong Weifang Rainbow Chemical Co., Ltd 10.65
Shandong Qiaochang Chemical Co., Ltd. 10.60
Nantong Jiangshan Agrochemical& Chemical Co.,Ltd. 10.18
Shangdong Binnong Technology Co., Ltd. 9.39
Jiansu Lianhe Chemical Technology Co.,Ltd. 9.15
Anhui Guangxin Agrochemical Co., Ltd. 8.90
Nanjing Redsun Co., Ltd 8.64
Anhui Huaxing Chemical Co., Ltd. 8.53
Jiangsu Huifeng Agrochemical Co., Ltd. 7.90
Jiangsu Changqing Agrochemical Co., Ltd. 7.46
Sichuan Fuhua Agricultural Technology Group 7.36
Jiangsu Fengshan Group Co., Ltd. 7.25
More info. Visit: www.ccpia.org.cn/en
About agrochemical show: www.agrochemex.net Qingdao Hansen Biologic technology Co., Ltd 7.10
-2- Dec 2011 www.ccpia.org.cn/en www.agrochemex.net
INDUSTRIAL NEWS
China Output Ups 15.7%
in First 9 Months
Agrochemicals output in the fi rst 9 months
of 2011 increased by 15.7%, representing
the consecutive quarters of double digit growth.
1.Pesticide Production
According to the data released by the National
Bureau of Statistics, the production of pesticide
TTaabbllee 33 ppeessttiicciiddee eexxppoorrtt aanndd ffaavvoorraabbllee ttrraaddee bbaallaannccee iinn
products in fi rst 9 months of 2011 is shown as
the fi rst 9 M of 2011(1,000 tonnes, $1billion)
follows:
Table 1 Pesticide Production in the fi rst half of Export Favorable trade
2011 (a.i.100%, 1,000t) Amount Value balance
Type
First 9 Growth First 9 Growth First 9 Growth
Output Percentage (%) months (±%) months (±%) months (±%)
Type Total 61.1 38.8 1.85 44.1 1.47 57.2
First 9 M
Growth (±%) First 9 M 2011 Insecticides 15.8 23.1 0.54 29.9 0.45 43.3
2011
Fungicides 5.9 23.8 0.29 43.7 0.13 50.0
Total 1920 15.7
Herbicides 37.7 49.5 1.0 52.9 0.88 64.9
Insecticides 514 7.3 26.8
Fungicides 118 8.3 6.1
It is shown from the table above that the exported
Herbicides 837 9.0 43.6
pesticide increased greatly. The imported pesticide
amount was 41,000 tonnes, decreased by 0.7%; the
In the fi rst 9 months of 2011, accumulated production
imported pesticide value reached $ 0.38 billion,
of technical pesticide products was 1,920,000 tons,
increased by 9.0%, the imported average price was
increased by 15.7% over the same period of 2010,
$ 9,268.3/t, increased by 13.8%. Among them,
among which insecticides 514, 000 tonnes, fungicides
imported insecticide, herbicide and fungicide
118, 000 tonnes, herbicides 837, 000 tonnes, up
increased by -11.6%, 38.8% and-8.7%, respectively.
7.3%, 8.3% and 9.0% over the same period of 2010,
The exported pesticide amount reached 611,000
respectively.
tonnes, increased by 38.8%, the exported pesticide
2.Import and Export
value reached $1.85 billion, increased by 44.1%, and
According to the data released by the General
the exported average price was $ 3,027.8/t, increased
Administration of Customs, pesticide import/export
by 5%. The amount of exported pesticides accounts
and trade favorable balance in the 9 months of 2011
for 31.8% of the total output. Among them, exported
is shown in table 2 and table 3:
herbicides volume was 377,000 tonnes, increased
by 49.5%, accounting for 61.7% of the total export,
Table 2 pesticide import in the fi rst 9 M of 2011
45.0% of herbicide production. The exported
(1,000 tonnes, $1billion)
herbicide value was $ 1.00 billion; the average
exported price was $2,653/t, increased by 9.7%. The
Import Percentage (%)
exported fungicide was 59,000 tonnes, increased by
Type
23.8%, accounting for 9.7% of the total exported
First 9 M
Amount Value Growth(±%)
2011 volume, 50.0% of fungicide production; the exported
fungicide value reached $ 290 million, up 43.7%, the
First 9 First 9
Growth (±%) Growth (±%) average exported price was $ 5,000/t, increased by
months months
13.8%. The favorable trade balance was $1.47billion,
Total 41 -0.7 0.38 9.0
increased by 57.2%.
Insecticides 5 -22.0 0.09 -11.6
Fungicides 15 33.4 0.16 38.8 More Info. Visit: www.ccpia.org.cn/en
Herbicides 14 -26.0 0.10 -8.7 About Agrochemical Show: www.agrochemex.net
Dec 2011 www.ccpia.org.cn/en www.agrochemex.net -3-
INDUSTRIAL NEWS
The Main Arochemical Commodities
in China
In recent years, the pesticide industry in China
has enjoyed rapid development as evidenced by
a considerable amount of products accounting for
over 70% of international production capacity and
Acetochlor
generating more than 10 billion in sales.
China’s capacity of acetochlor production recorded
During 2010 to 2011, 13 groups have been launched,
140,000 tons per year in 2010.
including those for glyphosate, paraquat, 2,4-D,
acetochlor, Triazine herbicides, imidacloprid,
chlorpyrifos, abamectin, acephate, Pymetrozine, Company Quality
chlorothalonil, mancozeb, carbendazim.
Nantong Jiangshan
92%
Glyphosate Agrochemical
By June 2011, there have been 124 registered Shandong Binnong
92%
enterprises of glyphosate manufactures in China, Technology
of which about 8 licensed enterprises in regular
Dalian Regar Pesticides 92%
production.
Shandong Zhongshi
92%
Pharmaceutical
Company Route Quality
Henan Nutrichem 97%
Wynca Glycine 80,000 95% Jiangsu Lulilai 92%
Anhui Shangyu Yingtai Fine
IDA 20,000 95% 97%
Huaxing Chemical
Nantong IDA/
70,000 95%
Jiangshan Glycine
Leshan 2, 4-Dichlorophenoxy
Glycine 70,000 95%
Fuhua Currently, there are only 9 enterprises with a valid
registration certificate of 2,4-D technical, including
Yangnong IDA 30,000 95%
5 manufacturing license holders, with a total
Good deliverability of 30,000 tons or so against a total
IDA 30,000 95%
Harvest domestic demand of approximately 8,000 tons.
Jiema
IDA 18,000 95%
Chemial
Company Quality
Shandong Weifang Rainbow
Paraquat
95%
Paraquat is the second largest herbicide after Chemical Co., Ltd.
glyphosate. The domestic paraquat capacity accounts Changzhou Wintafone
95%
for 70% of total capacity. Chemical Co., Ltd.
Dalian Songliao Chemical Co.,
Company Quality 95%
Ltd
Syngenta (China) 42% Hubei Sanonda 95%
Red Sun Group 42% Zhejiang Yongnong
95%
Chemical
Shandong Luba Chemical 42%
Shandong Lvfeng 95%
Hubei Sanonda 42%
Shandong Kexin
Zhejiang Yongnong 95%
42% Biochemical
Chemical
Shandong Lvfeng 42%
Imidacloprid
Shandong Kexin At present, there are altogether more than 30
4,000
Biochemical registered imidacloprid manufactures in China with
-4- Dec 2011 www.ccpia.org.cn/en www.agrochemex.net
INDUSTRIAL NEWS
an annual capacity of 25,000 tons (off 100% ai.).
China’s imidacloprid output is about 12,000 tons/ Company Quality
year, accounting for almost 70% of the world’s total
output. Hubei SANONDA Co., Ltd. 97%
Zhejiang Jiahua Chemical
97%
Corporation
Company Quality
Guangdong Daguangming 97%
Jiangsu Kesheng Group 95% Hebei VEYONG Biochemical
97%
Co., Ltd.
Shandong United industry
95%
Co., Ltd. Jiangsu Lanfeng Biochemial
97%
Co., Ltd.
Jiangsu Changlong Chemical 95%
Shandong Huayang
Red Sun Group 95% 97%
Technology Co., Ltd.
Qingdao Hailier
95%
Pharmaceutical
Jiangsu Changqing 95%
Abamectin
China’s current abamectin capacity is about 4,600
tons/year. Of which 75% of the total production is for
export.
Chlorpyrifos
China has been the leader in chlorpyrifos production
Company Quality
and consumption around the world. China’s
production capacity exceeds 100,000 tons/year and
Hebei Veyong Biochemical Co 95%
its sales volume this year is expected to be over
Qilu King Phar Pharmaceutical 95%
60,000 tons among which 25,000 tons are for export.
China’s production capacity accounts for 70% of the Hua Shu Pharmaceutical 95%
global chlorpyrifos production capacity.
Hebei Xingbai
95%
Pharmaceutical
Zhejiang Shenghua Biok
Company Quality 95%
Biology Company
Red Sun Group 98% Shandong Zhicheng
95%
Shandong Tiancheng Chemical Company
98%
Chemical Company
Zhejiang Xinnong Chemical
98% Carbendazim
Company The market of carbendazim is expanding as many
Jiangsu Baoling Chemical newly developed application areas emerged such as
98%
Company mildew proof in industry and so on.
Zhejiang Dongfeng Chemical
98%
Company
Company Quality
Jiangsu Jinghong Chemical
98%
Company
Jiangsu Lanfeng Biochemical
98%
Shanxi Sanwei Fenghai Co., Ltd.
98%
Chemical Industry Company
Anhui Guangxin Agricultural
98%
Chemicals Co., Ltd.
Ningxia Sanxi Chemicals Co.,
98%
Acephate Ltd.
In China, there are 26 enterprises with license of
acephate production and only 8 of them are operating
now, with a total deliverability of approximately Mancozeb
30,000 tons against a demand of 25,000 tons. As of the end of June 2010, the global mancozeb
Dec 2011 www.ccpia.org.cn/en www.agrochemex.net -5-
INDUSTRIAL NEWS
capacity is about 225,000 tons (off 80% ai.), of which, Other products
172,000 tons are produced by international producers
Product Quality
and 51, 000 tons are produced by domestic producers.
Isoprocarb 97%,
Tebuconazole 97%
Company Quality
Fenobucarb 95%
Limin Chemical Co., Ltd. 90% Thiophanate-Methyl 95%
Lambda-cyhalothrin 97%
Hebei Shuangji 90%
Cypermethrin 95%
Xi’an Jindai 90%
Bifenthrin 95%
Ethephon 92%
Chlorothalonil
Carbofuran 98%
At present, the domestic output of chlorothalonil is
1,4-dichlorobenzene 95%
about 18,000 tons/year, less than 8,000 tons of which
is for the domestic market and the remaining of which Triazophos 95%
is for export. Tricyclazole 95%
Dipterex 95%
Company Quality Omethoate 95%
Monosultap 98%
Jiangsu Xinhe Agrochemical
98%
Company
Technology Award of CPCIF in
Jiangsu Suli Fine Chemical
98%
Company 2011
Shandong Dacheng Pesticide
98% Science and technology department of China
Company
Petrochemical Industry Association recently
announced Science and Technology award of 2011
Pymetrozine
China Petroleum and Chemical Industry Federation.
As a variety of rice insecticide, pymetrozine is low
The companies below were granted Science and
toxicity, efficient and environmental—friendly on
Technology progress Award due to some technology
control rice planthopper.
progress.
Company Quality Prochloraz ai GB 22623-2008 project
Jiangsu Anpon Electrical Shenyang Chemical Research Institute Co., Ltd.
95%
chemical Co., Ltd Rosi Chemical Co., Ltd.
Nanjing Red Sun Co.,Ltd.
Jiangsu Kesheng Group 95%
Nantong Jiangshan Agrochemical & Chemical Co., Ltd.
Shenyang Kechuang 95%
New technology development and industrialization of
synthetic four kinds of aromatic amine herbicides
Triazine herbicides
Triazine herbicides are including total of 36 species.
Among them, atrazine is the highest sales of triazine Jilin University
Jilin Chemical Group Agrochemical Co., Ltd.
herbicides, accounting for 1/3 of this type of
Environment-friendly plant-based anti-virus formulation
herbicide. At present, the domestic output of triazine
Chemical Industry Press
herbicides is about 80,000 tons/year.
Guizhou University
Company Quality Technology of efficient fungicide epoxiconazole
production
Shandong Weifang Rainbow 92%
Zhejiang Zhongshan 92% Shenyang chemical Research Institute Co., Ltd.
Shenyang Sciencreat Chemicals Co.,Ltd.
Shandong Binnong 92%
-6- Dec 2011 www.ccpia.org.cn/en www.agrochemex.net
INDUSTRIAL NEWS
offering training to doctors for treatment of paraquat
Recycling technology of mother liquor of glyphosate poisoning, free medical activated carbon, test kit and
the treatment guidance principle for improving the
level of paraquat poisoning cure.
Nantong Jiangshan Agrochemical & Chemical Co., Ltd.
In addition, the Working Group also trains farmers
Hangzhou Tianchuang water equipment Co., Ltd.
to use of paraquat safely and correctly,to reduce the
impulsive suicide and paraquat poisoning.
Emamectin benzoate ai GB 20693-2006
Shenyang Institute of Chemical Industry Co., Ltd.
Hebei Veyong Biochemical Co., Ltd.
Zhejiang Hisun Chemical Co., Ltd.
Qingdao Kai Yuan Xiang Chemical Co., Ltd.
Shandong Jingbo Agrochemicals Co., Ltd.
Fomesafen ai GB 22167-2008
Shenyang Chemical Research Institute Co., Ltd.
Dalian Songliao Chemical Co., Ltd.
Jiangsu Changqing Agrochemical Co., Ltd.
Dalian RAJ Agrochemical Co., Ltd.
Responsibility Care of Paraquat
Working Group
Paraquat is popular with farmers and has become
an important environment-friendly and resource-
saving product in modern agricultural production
as its unique properties. However, rapid promotion
of paraquat products in Chinese rural, its usage
increases every year which facilitated abnormal
poisoning incidents occurring occasionally.
To strengthen the paraquat product management and
improving social awareness of Responsible Care,
Chinese paraquat manufacturers Product Management
and Social Responsibility Care Working Group was
set up by China Crop Protection Industry Association
in 2011. Working Group organized major domestic
paraquat manufactures to undertake positively
social responsibility, implement extensively social
responsibility care.
Under the guidance of paraquat poisoning treatment
experts, the Working Group opened two "Paraquat
Poisoning 24 hours (free) advice hotline" (400-099-
0766, 400 -886-7120), to provide the most timely
and correct treatment advice forthe poisoned patients,
their families and nursed.
Meanwhile, the Working Group also creates
paraquat poisoning medical assistance system,
Dec 2011 www.ccpia.org.cn/en www.agrochemex.net -7-
th
11 AGROCHEMEX SPECIAL
11th national agrochemical symposium was held gave the wonderful presentation. Related to
in Shanghai by CCPIA during 19-21st October, their points, we recorded some documentary
2011. In the period, several international experts content as follows:
Interview of Experts in AgroChemEx
A: For many years solvent based represent to about 55% of all
emulsifiable concentrates (EC) formulation types, while at the
and powder formulations (DP and same time newer and safer water
WP) have been very popular for based and water dispersible granule
agrochemical formulations around formulations represent about 30%
the world. In recent years there has of all formulation types. China is also
been a trend to move away from the moving towards the safer and more
use of solvents towards water based environment friendly formulations.
formulations such as suspension However, the latest figures from
concentrates (SC) and oil-in-water ICAMA, Beijing indicate that EC,
emulsions (EW). At the same time DP and WP formulations represent
dusty powder formulations are about 65% of all formulations,
being replaced by dust-free water and newer and safer water based
dispersible granules (WG). and water dispersible granule
Alan Knowles
formulations represent about 20% of
BSc CChem FRSC Q: You have many years of research all formulation types. Recent changes
experience and has been in China for to ICAMA regulations regarding
a quite while from 1993, What are the the policy to reduce of the number
Q: Over the last decade, formulation differences between Chinese and the of EC formulation plants and to
technology has developed rapidly, developed country? How to improve? register more environment friendly
although the proportion is decreasing, formulations in the future suggest that
but the EC is still one of the most A: It is currently estimated that in the ratio of old to new formulation
convenient formulation, how do you developed countries the proportion technologies will gradually meet the
think it's prospects? of EC, DP and WP formulations average in developed countries.
Q: Will your company cooperate is biggest. But the fungicides and
with more Chinese companies in the herbicides market is growing rapidly.
future? What products are involved? Worldwide, herbicides are the biggest
market.
A: Our company has been
collaborating with Chinese companies Q: How many agrochemicals
for many years. We purchase large enterprises in India?
quantity of different intermediates
from China. In future we want to A: India has a large number of
have more cooperation with Chinese agrochemical enterprises. There are
companies, including import of about 30 big manufacturers and more
pesticide Technicals. than 250 formulators in India. Dr. B. Saha
Ph.D, MBA
Q: How about aspects of export and Q: Could you introduce of your
import of pesticides in India? company briefly? Senior Vice President-
A: Nagarjuna Agrichem Limited, R&D and Technology
A: India is one of the leading belonging to Nagarjuna Group, is one
exporters of pesticides. We export of the most reputed agrochemical
our products all over the world companies in India. It has turnover Nagarjuna Agrichem Limited has got
including USA, Europe, Australia and of about 140 million USD. The ISO-9001, ISO-14001 and OHSAS
Asia. Indian companies give lots company has 3 manufacturing 14001 certification. We are the only
of importance to quality which has plants. We produce both Technicals agrochemical company in India who
helped us to secure business from all and formulations. We are contract has implemented "Zero Liquid Effluent
over the world. manufacturer for leading agrochemical Discharge" scheme for environmental
India also imports pesticides from companies of the world. Also, we protection. Our Quality Assurance
different countries including China. have strong presence in the Indian Laboratory has all sophisticated
domestic market where we sell our instruments including GC-MS, LC-
Q: As a big generic agrochemicals own brands.There are 8850 dealers MS, HPLC, GLC, Spectrophotometers
manufacturers, which agrochemical in India who sell our products. We etc. At present we are setting up
varieties are advanced in the world? are present in all the segments such Corporate R&D Centre at a cost of 5
as insecticides, herbicides, fungicides million USD. We are also planning to
A: In India, insecticides market and plant growth regulators. set up GLP lab for regulatory studies.
-8- Dec 2011 www.ccpia.org.cn/en www.agrochemex.net