Cyclodextrins : properties and applications

337 Pages·2017·11.681 MB·English

by  Girek, Tomasz, Sliwa, Wanda

Cyclodextrins

Cyclodextrins
PropertiesandApplications
WandaSliwaandTomaszGirek
TheAuthors AllbookspublishedbyWiley-VCHare
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v
Contents
Acknowledgment vii
Introduction 1
PartI CharacteristicFeaturesofCDs 7
1 CD-BasedRotaxanesandPolyrotaxanesasRepresentative
Supramolecules 9
1.1 CD-BasedRotaxanes 10
1.2 CD-BasedPolyrotaxanes 19
1.2.1 CD-BasedPolyrotaxaneswithTriblockandPentablockBackbones 19
1.2.2 CD-BasedPolyrotaxaneswithotherBackbones 26
1.3 CD-BasedPseudopolyrotaxanes 43
2 CD-BasedMicelles,Vesicles,andMetalNanoparticles 51
2.1 CD-BasedMicelles 52
2.2 CD-BasedVesicles 68
2.3 CD-BasedMetalNanoparticles 75
3 CDInclusionComplexes 87
3.1 CDInclusionComplexeswithMonocarboxylicAromaticAcids 87
3.2 Theβ-andγ-CDInclusionComplexeswithSelectedGuest
Components 88
4 CDDimers 99
4.1 CDDimersBridgedbyVariousSpacers 99
4.2 CDDimersBridgedbyAzobenzeneMoietyandbyPlatinum(IV)
ComplexasSpacers 119
References 129
vi Contents
PartII PolymericCDs 145
5 CDMultiarmPolymers 147
5.1 MultiarmPolymersContainingaCDCore 147
5.2 MicellesandMultiarmCDPolymersContainingaPOSSCore 159
6 CD-BasedDendrimers 167
6.1 MonomericDendrimerswithaCDCore 167
6.2 PolymericCD-BasedDendrimers 171
6.2.1 PolymericDendrimerswithaPAMAMCore 171
6.2.2 PolymericDendrimerswithaCDCore 180
7 CD-BasedPolymericGels 187
7.1 PolymericGelsBuiltExclusivelyfromCD 187
7.2 PolymericGelsBuiltfromCDandselectedPolymers 190
7.3 CD-BasedPolymericGelsasNanosponges 199
7.4 CD-BasedGelsBuiltwiththeuseofILs 209
References 219
PartIII CDAssemblieswithNanocarbonsandFinalRemarks
ConcerningCDApplications 229
8 CDAssemblieswithNanocarbons 231
8.1 CDAssembleswithFullerenes 232
8.1.1 CDCovalentAssemblieswithFullerenes 232
8.1.2 CDNoncovalentAssemblieswithFullerenes 235
8.2 CDAssemblieswithNanotubes 248
8.3 CDAssemblieswithGraphene 259
9 CDApplications 269
9.1 CDMedicalApplications 270
9.2 CDEnvironmentalProtectionApplications 276
9.3 CDIndustrialApplications 286
References 297
Conclusion 309
Index 311
vii
Acknowledgment
WeexpressourespecialgratefulnesstoBeataGirek,M.Sc.withmanythanksfor
herhelpandattentioninthepreparationofthebook.
WandaSliwaandTomaszGirek