Texts and Monographs in Physics Series Editors: R. Balian W. Beiglb6ck H. Grosse E. H. Lieb N. Reshetikhin H. Spohn W Thirring Springer Berlin Heidelberg New York Barcelona Budapest Hong Kong London Milan Paris Santa Clara Singapore Tokyo Texts and Monographs in Physics Series Editors: R. Balian W. Beiglb6ck H. Grosse E. H. Lieb N. Reshetikhin H. Spohn W. Thirring From Microphysics to Macrophysics Supersymmetric Methods in Quantum I + II Methods and Applications of and Statistical Physics By G. Junker Statistical Physics By R. Balian CP Violation Without Strangeness Variational Methods in Mathematical Electric Dipole Moments of Particles, Physics A Unified Approach Atoms, and Molecules By P. Blanchard and E. Brtining By I. B. Khriplovich and S. K. Lamoreaux Quantum Mechanics: Inverse Schrodinger Scattering Foundations and Applications in Three Dimensions 3rd enlarged edition By A. Bohm By R. G. Newton The Early Universe Scattering Theory of Waves Facts and Fiction 3rd corrected and Particles 2nd edition and enlarged edition By G. Borner By R. G. Newton Operator Algebras and Quantum Quantum Entropy and Its Use Statistical Mechanics I + II 2nd edition By M. Ohya and D. Petz By O. Bratteli and D. W. Robinson Generalized Coherent States Geometry of the Standard Model and Their Applications of Elementary Particles By A. Perelomov By A. Derdzinski Essential Relativity Special, General, Scattering Theory of Classical and Cosmological Revised 2nd edition and Quantum N-Particle Systems By W. Rindler By J. Derezinski and C. Gerard Path Integral Approach Effective Lagrangians to Quantum Physics An Introduction for the Standard Model 2nd printing By G. Roepstorff By A. Dobado, A. G6mez-Nicola, Finite Quantum Electrodynamics A. L. Maroto and J. R. Pelaez The Causal Approach 2nd edition Quantum By G. Scharf The Quantum Theory of Particles, Fields, From Electrostatics to Optics and Cosmology By E. Elbaz A Concise Electrodynamics Course Quantum Relativity By G. Scharf A Synthesis of the Ideas of Einstein The Mechanics and Thennodynamics and Heisenberg of Continuous Media By M. Silhavy By D. R. Finkelstein Large Scale Dynamics of Interacting Quantum Mechanics I + II Particles By H. Spohn By A. Galindo and P. Pascual The Theory of Quark and Gluon The Elements of Mechanics Interactions 2nd completely revised By G. Gallavotti and enlarged edition By F. J. Yndurrun Local Quantum Physics Relativistic Quantum Mechanics and Fields, Particles, Algebras Introduction to Field Theory 2nd revised and enlarged edition By F. J. Yndurrun ByR. Haag Iosif B. Khriplovich Steve K. Lamoreaux CP Violation Without Strangeness Electric Dipole Moments of Particles, Atoms, and Molecules With 36 Figures Springer Iosif B. Khriplovich Steve K. Lamoreaux Budker Institute of Nuclear Physics University of California 630090 Novosibirsk, Russia Los Alamos National Laboratory Los Alamos, NM 87545, USA Editors Roger Balian Nicolai Reshetikhin CEA Department of Mathematics Service de Physique Theorique de Saclay University of California F-91191 Gif-sur-Yvette, France Berkeley, CA 94720-3840, USA Wolf Beiglb6ck Herbert Spohn Institut flir Angewandte Mathematik Theoretische Physik Universitat Heidelberg Ludwig-Maximilians-Universitat Miinchen 1m Neuenheimer Feld 294 TheresienstraBe 37 0-69120 Heidelberg, Germany 0-80333 Miinchen, Germany Harald Grosse Walter Thirring Institut fiir Theoretische Physik Institut flir Theoretische Physik Universitat Wien Universitat Wien Boltzmanngasse 5 Boltzmanngasse 5 A-I 090 Wien, Austria A-I 090 Wien, Austria Elliott H. Lieb Jadwin Hall Princeton University, P. O. Box 708 Princeton, NJ 08544-0708, USA Library of Congress Cataloging-in-Publication Data. Khriplovich, 1. B. (Iosif Bentsionovich) CP violation without strangeness: electric dipole moments of particles, atoms, and molecules IIosif B. Khriplovich, Steve K. Lamoreaux. p. em. - (Texts and monographs in physics, ISSN 0172-5998) Includes bibliographical references and index. 1. CP violation (Nuclear physics) 2. Time reversal. 3. Dipole moments. I. Lamoreaux, Steve Keith. II. Title. 111. Series. QC793.3.V5K47 1997 539.7'25-dc21 97-28480 ISSN 0172-5998 ISBN-13: 978-3-642-64577-8 e-ISBN-13: 978-3-642-60838-4 DOl: 10.1007/978-3-642-60838-4 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. 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Typesetting: Data conversion by Satztechnik Katharina Steingraeber, Heidelberg Cover design: design & production GmbH, Heidelberg SPIN: 10520214 55/3144-543210 -Printed on acid-free paper Preface Electric dipole moments (EDMs) have interested physicists since 1950, when it was first suggested that there was no experimental evidence that nuclear forces are symmetric under parity (P) transformation. This question was regarded as speculative because the existence of an EDM, in addition to P violation, requires a violation of time-reversal (T) symmetry. In 1964 it was discovered that the invariance under CP transformation, which combines charge conjugation (C) with parity, is violated in K-meson decays. This provided a new incentive for EDM searches. Since the combined operations of CPT are expected to leave a system invariant, breakdown of CP invariance should be accompanied by a violation of time-reversal symmetry. Thus there is a reason to expect that EDMs should exist at some level. The original neutron EDM experiments were later supplemented with checks of T invariance in atoms and molecules. These investigations are pursued now by many groups. Over the years, the upper limit on the neutron EDM has been improved by seven orders of magnitude, and the upper limit on the electron EDM obtained in atomic experiments is even more strict. Even without the discovery of the effects sought, the neutron and atomic experiments have ruled out most models of C P violation suggested to explain the effects in K-meson decays; in fact, one could argue that the neutron EDM measurement has ruled out more theoretical models than any other experiment in the history of physics. As to the mechanism of C P violation incorporated in the standard model of electroweak interactions, which is most popular at present, the prediction for the neutron EDM is six orders of mag nitude below the present experimental bound. The gap for the electron EDM in this model is much larger. But does this mean that the experiments discussed in this book are of no serious interest for the elementary particle physics, that they are nothing but mere exercises in precision spectroscopy? Just the opposite. It means that these experiments now, at the present level of accuracy, are extremely sensitive to possible new physics beyond the standard model, physics to which the kaon decays are insensitive. These experiments have been described as "the poor man's high-energy physics" [1], insofar as they are typically done by relatively small collaborations (less than 10 participants), with a relatively VI Preface small budget. They certainly provide valuable information complementary to the more traditional high-energy experiments. It is essential that there are no fundamental restrictions to the accuracy that can be obtained in a precision spectroscopy experiment, barring counting statistics and systematic effects. Of course, at any given time, any specific experiment runs into technical limitations, but over the last fifty years for example, the limit on the neutron EDM has been reduced by nearly two orders of magnitude per decade. It is interesting to note that, at each stage of the progress, the technical difficulties were enormous and certainly the maximum sensitivity, given the state of the art, was achieved. Nonetheless, after each stage new ideas would arise, and experimentalists had the courage and support to put those ideas into practice; taken together with the great theoretical progress in regard to interpretation of the experiments, the study of EDMs has been, and will remain, a fruitful and exciting subject. We believe that this circumstance is by itself a good reason to write a book on the subject. Besides, we hope that the wide-ranging collection of physical problems presented here will be useful for advanced studies of various branches of physics. It is impossible to list here all those who generously shared with us their knowledge and understanding of the subject. However, we cannot help men tioning some persons whose collaboration has influenced so much the content of this book: R.S. Conti, V.V. Flambaum, E.N. Fortson, R. Golub, B.R. Heckel, V.M. Khatsymovsky, J.M. Pendlebury, M.E. Pospelov, N.F. Ramsey, O.P. Sushkov, A.I. Vainshtein, A.S. Yelkhovsky, and A.R. Zhitnitsky. We owe special thanks to D.P. DeMille for critical comments on the manuscript. To our friends, those whose names are given here and those who we could not mention, we owe our deep and sincere gratitude. Novosibirsk, Russia I.B. Khriplovich Los Alamos, New Mexico, USA S.K. Lamoreaux May 1997 Contents 1. Introduction.............................................. 1 1.1 Overview of C P Violation Without Strangeness . . . . . . . . . . . . 1 1.2 The Neutron Electric Dipole Moment: Early History . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 1.3 Molecular Electric Dipole Moments and C P Violation ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 1.4 T-Odd Effects Without CP Violation. . . . . . . . . . . . . . . . . . . . . 5 l.4.1 Can an Unstable Particle Have a Dipole Moment? . . . . 5 1.4.2 Spurious EDM Effect Due to Nuclear Anapole Moment 7 2. Kinematics of Discrete Symmetries . . . . . . . . . . . . . . . . . . . . . . . 9 2.1 CPT Theorem: Intuitive Approach .. . . . . . . . . . . . . . . . . . . . . . 9 2.2 T-Even and T-Odd Electromagnetic Multipole Moments .... 11 2.3 General Structure of Four-Fermion Operators. . . . . . . . . . . . .. 15 3. General Features of EDM Experiments............ . . .. . .. 19 3.1 Interaction of an EDM with an Electric Field. . . . . . . . . . . . .. 19 3.1.1 Sensitivity Limit Due to the Uncertainty Principle. . .. 20 3.1.2 Ramsey's Method of Separated Oscillatory Fields. . . .. 23 3.1.3 Linewidth and Sensitivity with Separated Oscillatory Fields. . . . . . . . . . . . . . . . . .. 25 3.2 Ground State Optical Pumping and Detection of Atomic Polarization . . . . . . . . . . . . . . . . . . . .. 25 3.2.1 Atomic Spin Magnetometers.. .. . . . . . . . . . . . . . . . . . .. 27 3.3 Electric Fields and Coherence Times in Various Systems. . . .. 31 3.3.1 Electric Fields in Vacuum. . . . . . . . . . . . . . . . . . . . . . . .. 31 3.3.2 Electric Fields in Gases ..................... . . . . .. 33 3.3.3 Electric Fields in Liquids. . . . . . . . . . . . . . . . . . . . . . . . .. 33 3.3.4 Electric Fields in Solids. . . . . . . . . . . . . . . . . . . . . . . . . .. 33 3.3.5 Coherence Times for Various Systems. . . . . . . . . . . . . .. 34 3.4 Magnetic Field Control and Generation .............. . . . .. 35 3.4.1 Field Stability and Homogeneity Requirements. . . . . .. 35 3.4.2 Magnetic Shields. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 36 3.4.3 Field Generation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 40 VIII Contents 3.5 Systematic Effects. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 42 3.5.1 Leakage Current Effects. . . . . . . . . . . . . . . . . . . . . . . . . .. 43 3.5.2 Problems Related to Polarizability and Electric Quadrupole Moments. . . . . . . . . . . . . . . . .. 44 3.5.3 The v x E Problem .............................. 45 4. The Search for the Neutron EDM ..... ............ .... . .. 53 4.1 Properties of the Neutron ............................... 53 4.2 Interaction of Neutrons with Matter. . . . . . . . . . . . . . . . . . . . .. 55 4.2.1 Neutron Polarization. . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 61 4.2.2 Production and Moderation of Neutrons. . . . . . . . . . . .. 63 4.2.3 Transport of Cold Neutrons. . . . . . . . . . . . . . . . . . . . . . .. 64 4.3 Neutron Beam EDM Experiments . . . . . . . . . . . . . . . . . . . . . . .. 65 4.3.1 The Oak Ridge Experiment of 1950. . . . . . . . . . . . . . . .. 65 4.3.2 The Oak Ridge Experiment of 1967 . . . . . . . . . . . . . . . .. 68 4.3.3 The Crystal Scattering Experiment of 1967 . . . . . . . . .. 69 4.3.4 Pendellosung Fringes. . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 73 4.3.5 Neutron Beam Experiments, 1968-1973 .. . . . . . . . . . .. 75 4.3.6 The Institut Laue-Langevin (ILL) Experiment of 1977 77 4.4 Ultracold Neutrons .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 77 4.4.1 Sources of Ultracold Neutrons. . . . . . . . . . . . . . . . . . . . .. 80 4.5 Neutron EDM Measurements with Stored Ultracold Neutrons ......... . . . . . . . . . . . . . . . .. 81 4.5.1 Present Limits for the Neutron EDM ............... 81 4.5.2 Stored UCN EDM Experiment at the Institut Laue-Langevin. . . . . . . . . . . . . . . . . . . . .. 81 4.5.3 UCN EDM Experiment at the VVR-M Reactor, Petersburg Nuclear Physics Institute. . . . . . . . . . . . . . .. 88 4.5.4 The 199Hg Comagnetometer UeN Experiment. . . . . .. 91 4.6 The Future: Superftuid He Neutron EDM with a 3He Comagnetometer . . . . . . . . .. . . . . . . . . . . . . . . . . . .. 95 4.6.1 The Production of UCN in Superftuid 4He. . . . . . . . . .. 95 4.6.2 Superftuid 4He Neutron EDM Search with a 3He Comagnetometer ....................... 100 4.6.3 Dressed Spin Magnetometry ....................... 102 4.6.4 Analysis of the Dressed Spin System and Systematic Effects ............................ 104 4.7 Comparison of Experimental Techniques ................... 105 5. Theoretical Predictions for Neutron and Electron Dipole Moments ............................ 107 e 5.1 The CP-Violating Term in Quantum Chromodynamics ........................... 108 5.2 Predictions of the Standard Model for Dipole Moments ..................................... 111 Contents IX 5.3 Spontaneous CP Violation in the Higgs Sector ............. 112 5.4 Phenomenological Approach ............................. 116 6. EDM Experiments with Paramagnetic Atoms ................................ 119 6.1 The Shielding Problem .................................. 119 6.2 Enhancement of the Electron EDM in Paramagnetic Atoms ................................. 121 6.3 Overview of Paramagnetic Atom Experiments .............. 122 6.4 The Cs EDM Experiment ............................... 124 6.5 The TI EDM Experiment ................................ 126 6.6 Future Prospects for Improving the Electron EDM Limit ................................ 133 6.7 EDM Limits of Some Other Elementary Particles ........... 135 6.7.1 The Proton ...................................... 135 6.7.2 The Neutrino .................................... 135 6.7.3 The Muon ....................................... 135 6.7.4 The AO Hyperon ................................. 136 6.7.5 The T Lepton .................................... 136 7. EDM Experiments with Diamagnetic Atoms .............. 137 7.1 Shielding in the ISO System .............................. 137 7.2 The 129Xe EDM Experiment ............................. 139 7.3 The 199Hg EDM Experiment ............................. 142 7.4 3He - 129Xe Comparison ................................ 147 8. Atomic Calculations ...................................... 149 8.1 Wave Function of an Outer Electron at Short Distances ...................................... 149 8.2 The Electron EDM in Paramagnetic Heavy Atoms .......... 152 8.3 CP-Odd Electron-Nucleon Interaction .................... 155 8.3.1 CP-Odd Mixing of Atomic Levels .................. 156 8.3.2 Paramagnetic Atoms .............................. 157 8.3.3 Diamagnetic Atoms ............................... 159 8.3.4 Summary of the Constants k1,2,3 .............•..... 162 8.4 Electron EDM in Diamagnetic Atoms ..................... 164 8.5 CP-Odd Nuclear Moments .............................. 167 8.5.1 The Schiff Moment ............................... 167 8.5.2 Magnetic Quadrupole Moment ..................... 172 9. T Violation in Molecules .................................. 177 9.1 Enhancement of an Applied Field by a Polar Molecule. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 177 9.2 TIF Beam Experiments ................................. 179 9.3 What Have We Learned from the TIF Experiment? ......... 183 X Contents 9.4 Paramagnetic Molecules ................................. 185 9.5 What Will Be Gained from Experiments with Paramagnetic Molecules? ........................... 186 10. CP-Odd Nuclear Forces .................................. 189 10.1 CP-Odd Mixing of Opposite-Parity Nuclear Levels ......... 189 10.2 Nuclear Moments Induced by T- and P-Odd Potentials ...................... 192 10.3 Enhancement Mechanisms for T- and P-Odd Nuclear Multi- poles .................................................. 195 10.4 Theoretical Predictions and Implications .................. 198 11. What Do We Really Know About T-Odd, but P-Even Interactions? ................................. 203 11.1 Long-Range Effects . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203 11.2 TOPE Fermion-Fermion Interactions. One-Loop Approach .................................... 205 11.3 TOPE Fermion-Fermion Interactions. Two-Loop Approach .................................... 207 11.4 Conclusions on TOPE eN and N N Interactions ............ 211 11.5 T-Odd /3 Decay Constants ............................... 213 References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 217 Index ......................................................... 227