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Covalent Organic Frameworks: Chemistry, Properties, and Energy Applications for a Sustainable Future PDF

506 Pages·2022·37.496 MB·English
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Covalent Organic Frameworks Covalent organic frameworks-based nanomaterials have emerged as promising candi- dates for energy applications owing to their superior electrochemical properties, surface area, nano-device integration, multifunctionality, printability, and mechanical flexibility. This book provides fundamentals, various synthesis approaches, and applications of cova- lent organic frameworks-based nanomaterials and their composites for generating energy. The main objective of this book is to provide current, state-of-the-art knowledge about covalent organic frameworks-based nanomaterials and their composites for supercapaci- tors, batteries, photovoltaics, and fuel cells, covering almost the entire spectrum in the energy field under one title. Aimed at widening fundamental understanding about cova- lent organic frameworks and mechanisms for realization and advancement in devices with improved energy efficiency and high storage capacity, this book will provide new direc- tions for scientists, researchers, and students to better understand the principles, technolo- gies, and applications of covalent organic frameworks. Covalent Organic Frameworks Chemistry, Properties, and Energy Applications for a Sustainable Future Edited by Tuan Anh Nguyen and Ram K. Gupta CRC Press Boca Raton and London First edition published 2023 by CRC Press 6000 Broken Sound Parkway NW, Suite 300, Boca Raton, FL 33487-2742 and by CRC Press 4 Park Square, Milton Park, Abingdon, Oxon, OX14 4RN CRC Press is an imprint of Taylor & Francis Group, LLC © 2023 selection and editorial matter, Tuan Anh Nguyen and Ram K. Gupta; individual chapters, the contributors Reasonable efforts have been made to publish reliable data and information, but the author and publisher can- not assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, includ- ing photocopying, microfilming, and recording, or in any information storage or retrieval system, without writ- ten permission from the publishers. For permission to photocopy or use material electronically from this work, access www.copyright.com or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978-750-8400. For works that are not available on CCC please contact [email protected] Trademark notice: Product or corporate names may be trademarks or registered trademarks and are used only for identification and explanation without intent to infringe. ISBN: 9781032069883 (hbk) ISBN: 9781032073514 (pbk) ISBN: 9781003206507 (ebk) DOI: 10.1201/9781003206507 Typeset in Palatino by KnowledgeWorks Global Ltd. Contents List of Contributors ........................................................................................................................ix Editor Biographies .........................................................................................................................xv 1. Covalent Organic Framework: An Introduction ..............................................................1 Gagandeep Kaur, Pooja Upadhyay, Karan Basve, and Pawan Kumar 2. Materials, Chemistry, and Synthesis of Covalent Organic Frameworks ..................19 Mohaddeseh Afshari and Mohammad Dinari 3. Recent Development in Synthesis of Covalent Organic Frameworks .......................39 Ferda Civan Çavuşoğlu, Gülsüm Özçelik, and Şahika Sena Bayazit 4. Architectural Aspects of Covalent Organic Frameworks for Energy Applications .............................................................................................................57 Biswajit Nayak and Gopal Das 5. Functionalized Covalent Organic Frameworks for Improved Energy Applications .............................................................................................................75 Yong Li, Weiran Zheng, and Lawrence Yoon Suk Lee 6. Covalent Organic Frameworks: Fundamentals to Advanced Energy Applications .............................................................................................................95 Shiva Bhardwaj, Felipe M. de Souza, and Ram K. Gupta 7. Covalent Organic Frameworks for Fuel Cell Applications ........................................113 Federico Roncaroli 8. Covalent Organic Frameworks-Based Nanomaterials for Hydrogen Reduction Reactions...........................................................................................................137 Sandeep Kaushal 9. Covalent Organic Frameworks-Based Nanomaterials for Hydrogen Evolution Reactions ............................................................................................................153 Felipe M. de Souza and Ram K. Gupta 10. Covalent Organic Frameworks-Based Nanomaterials for Oxygen Evolution Reactions ............................................................................................................171 Moein Darabi Goudarzi, Negin Khosroshahi, Parisa Miri, and Vahid Safarifard 11. Covalent Organic Frameworks as Efficient Electrocatalysts for Oxygen Evolution Reactions ............................................................................................................185 Kayode Adesina Adegoke, Thabo Matthews, Tebogo Mashola, Siyabonga Mbokazi, Thobeka Makhunga, Cyril Selepe, Memory Zikhali, Kudzai Mugadza, Nobanathi Wendy Maxakato, and Olugbenga Solomon Bello v vi Contents 12. Emerging Applications of Covalent Organic Frameworks and Their Architectural Aspects for Improved Oxygen Evolution Reactions ..........................199 Karan Chaudhary and Dhanraj T. Masram 13. Covalent Organic Frameworks-Based Nanomaterials for Oxygen Reduction Reactions...........................................................................................................211 Marcos Martínez-Fernández, Emiliano Martínez-Periñán, Encarnación Lorenzo, and José L. Segura 14. Recent Development in Covalent Organic Framework Electrocatalysts for Oxygen Reduction Reactions .....................................................................................235 Kayode Adesina Adegoke, Thabo Matthews, Tebogo Mashola, Siyabonga Mbokazi, Thobeka Makhunga, Cyril Selepe, Memory Zikhali, Kudzai Mugadza, and Nobanathi Wendy Maxakato 15. Metal-Air Batteries Based on Nanostructured Covalent Organic Frameworks ..........................................................................................................251 Maria Mechili, Christos Vaitsis, Nikolaos Argirusis, Pavlos K. Pandis, Georgia Sourkouni, and Christos Argirusis 16. Metal-Sulfur Batteries Based on Nanostructured Covalent Organic Frameworks ..........................................................................................................................269 Yu Cao, Fusheng Pan, and Jie Sun 17. Photocatalysts Based on Covalent Organic Frameworks ...........................................287 Nazanin Mokhtari and Mohammad Dinari 18. Recent Advancement in Covalent Organic Frameworks for Photocatalytic Activities ...............................................................................................................................303 El-Sayed M. El-Sayed and Daqiang Yuan 19. Covalent Organic Frameworks and Clusters in Storing Hydrogen .........................325 Sukanta Mondal, Prasenjit Das, and Pratim Kumar Chattaraj 20. Covalent Organic Frameworks-Based Nanomaterials for Hydrogen Storage .......345 Turkan Kopac 21. Covalent Organic Frameworks-Based Adsorbents for Methane Storage: Experimentation and Simulations ..................................................................................361 Raghubir Singh and Varinder Kaur 22. Covalent Organic Frameworks-Based Nanomaterials for Greenhouse Gases Capture and Storage: CH and CO .....................................................................379 4 2 Heriberto Díaz Velázquez and Rafael Martínez-Palou 23. Covalent Organic Frameworks-Based Membranes and Adsorbents for Water Treatment and Gas Separation ......................................................................397 Sana Eid, Ahmed Gulzar, Ali Al Najjar, Gabriele Scandura, Twinkle Paul, Dinesh Shetty, Hassan Arafat, Georgios N. Karanikolos, and Ludovic F. Dumée Contents vii 24. Covalent Organic Framework-Based Nanoparticles for Catalytic Environmental Remediation ............................................................................................411 Muhammad Sohail Bashir, Syed Shoaib Ahmad Shah, Tayyaba Najam, Aqsa Safdar, and Humaira Bashir 25. Covalent Organic Frameworks in Polymer Nanocomposites with Superior Thermo-Mechanical Properties and Electrochemical Applications .........................................................................................................................431 Parisa Najmi, Navid Keshmiri, Bahram Ramezanzadeh, and Mohammad Ramezanzadeh 26. Recent Development in Covalent Organic Frameworks-Based Materials for Supercapacitors ..........................................................................................449 Christos Vaitsis, Maria Mechili, Nikolaos Argirusis, Pavlos K. Pandis, Georgia Sourkouni, and Christos Argirusis 27. Covalent Organic Frameworks-Based Nanomaterials as Electrode Materials for Supercapacitors ..........................................................................................465 Hani Nasser Abdelhamid Index .............................................................................................................................................485 Contributors Hani Nasser Abdelhamid Christos Argirusis Advanced Multifunctional Materials Laboratory of Inorganic Materials Laboratory Technology Department of Chemistry, Faculty of School of Chemical Engineering Science National Technical University of Athens Assiut University Athens, Greece Assiut, Egypt TU Clausthal Proteomics Laboratory for Clinical Clausthaler Zentrum für Materialtechnologie Research and Materials Science Clausthal-Zellerfeld, Germany Department of Chemistry Assiut University Nikolaos Argirusis Assiut, Egypt mat4nrg GmbH Clausthal-Zellerfeld, Germany Kayode Adesina Adegoke Department of Chemical Sciences Humaira Bashir University of Johannesburg Department of Botany Doornfontein, South Africa University of the Punjab Lahore, Pakistan Mohaddeseh Afshari Department of Chemistry Stockbridge School of Agriculture Isfahan University of Technology University of Massachusetts Isfahan, Islamic Republic of Iran Amherst, USA Syed Shoaib Ahmad Shah Muhammad Sohail Bashir Hefei National Laboratory for Physical Hefei National Laboratory for Physical Sciences at the Microscale Sciences at the Microscale CAS Key Laboratory of Soft Matter CAS Key Laboratory of Soft Matter Chemistry Chemistry Department of Chemistry Department of Polymer Science and University of Science and Technology of Engineering China University of Science and Technology of Hefei, Anhui, China China Hefei, Anhui, China Hassan Arafat Center for Membranes and Advanced Karan Basve Water Technology (CMAT) Material Application Research Laboratory Department of Chemical Department of Nano Sciences and Engineering Materials Khalifa University Central University of Jammu Abu Dhabi, United Arab Emirates Jammu, India ix

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