Hideyuki Kanematsu · Dana M. Barry Editors Corrosion Control and Surface Finishing Environmentally Friendly Approaches Corrosion Control and Surface Finishing ThiSisaFMBlankPage Hideyuki Kanematsu (cid:129) Dana M. Barry Editors Corrosion Control and Surface Finishing Environmentally Friendly Approaches Editors Dr.HideyukiKanematsu,Ph.D. Dr.DanaM.Barry,Ph.D. DeputyPresident ResearchProfessor,DepartmentsofChemical& Professor,DepartmentofMaterials BiomolecularEngineeringandElectrical& Science&Engineering ComputerEngineering NationalInstituteofTechnology, ClarksonUniversity SuzukaCollege Potsdam,NY Suzuka,Mie USA Japan SeniorTechnicalWriter&Editor Fellow CenterforAdvancedMaterialsProcessing InstituteofMaterialsFinishing (CAMP) U.K. ClarksonUniversity Potsdam,NY USA ISBN978-4-431-55955-9 ISBN978-4-431-55957-3 (eBook) DOI10.1007/978-4-431-55957-3 LibraryofCongressControlNumber:2016934603 ©SpringerJapan2016 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpartof the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilarmethodologynowknownorhereafterdeveloped. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publicationdoesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexempt fromtherelevantprotectivelawsandregulationsandthereforefreeforgeneraluse. Thepublisher,theauthorsandtheeditorsaresafetoassumethattheadviceandinformationinthis book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained hereinorforanyerrorsoromissionsthatmayhavebeenmade. Printedonacid-freepaper ThisSpringerimprintispublishedbySpringerNature TheregisteredcompanyisSpringerJapanKK Acknowledgment Wetheeditors(whoalsoserveasauthors)wouldliketothanktheNationalInstitute of Technology, Suzuka College and its President Yasutsugu Nitta, Professor Toshihiro Tanaka and Professor Eiji Arai along with Osaka University, Clarkson University, CAMP (Clarkson’s Center for Advanced Materials Processing), Clarkson’sDepartmentofChemical&BiomolecularEngineeringandDepartment ofElectrical&ComputerEngineering,theAmericanChemicalSociety,Professor Dr. Roger Haw, and Ansted University, for their greatly appreciated support. We also thank ISIJ (Iron and Steel Institute of Japan) and its Division of Process Evaluation and Material Characterization for their encouragement and financial support.Muchoftheknowledgeandinformationinthisbookisderivedfromtheir forumactivitiesintheIronandSteelSocietyofJapan.Theirfundingandplanning madeitpossibleforustodiscussthebooktogetherinperson.Alsowearegrateful to the Iketani Science and Technology Foundation. We thank the great surface finishingsocietiesintheUnitedStates(NationalAssociationforSurfaceFinishing, NASF), the United Kingdom (Institute of Materials Finishing, IMF) and Japan (Surface Finishing Society of Japan, SFSJ) for their encouragement and cooperation. Someinformationcontainedinthisbookwasobtainedfromworkcarriedoutfor nationalfundingprojectsinJapan.Alsowearegratefultoallofourchapterauthors, andtoourcolleaguesandcollaborators,especiallythoseinJapanandtheUS. Our sincerest appreciation is expressed to Springer Japan and to the Editor for LifeSciences,Dr.MeiHannLee. Inaddition,wewouldliketothankourfamiliesfortheircontinuedinterestand support: Dr. Kanematsu’s parents (Shoji and Michiko Kanematsu), his wife (Reiko), and children (Hitomi and Hiroyuki); Dr. Barry’s parents (Daniel and CeliaMalloy),herhusband(James),andchildren(James,Brian,Daniel,andEric). HideyukiKanematsu DanaM.Barry v ThiSisaFMBlankPage Contents Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 HideyukiKanematsuandDanaM.Barry PartI FundamentalsofCorrosionandSurfaceFinishing forCorrosionControl TheFundamentalsofCorrosionScienceandEngineering: EquilibriumTheoryandItsMeaning. . . . . . . . . . . . . . . . . . . . . . . . . . . 13 HideyukiKanematsuandDanaM.Barry MeasurementandEvaluationforCorrosion. . . . . . . . . . . . . . . . . . . . . 23 HideyukiKanematsuandDanaM.Barry IndustrialSurfaceTreatments. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 DanaM.BarryandHideyukiKanematsu SurfaceAnalysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 NobumitsuHirai CorrosionandSurfaceFinishing. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57 DanaM.BarryandHideyukiKanematsu PartII EnvironmentalRegulationsforMetallicMaterials BackgroundofEnvironmentalRegulations. . . . . . . . . . . . . . . . . . . . . . 69 HideyukiKanematsuandDanaM.Barry WorldHealthOrganization’sStandardsfromtheViewpointofHealth Risks. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79 DanaM.BarryandHideyukiKanematsu EuropeanUnion(EU)DirectivesandRegulations. . . . . . . . . . . . . . . . . 89 DanaM.BarryandHideyukiKanematsu vii viii Contents RegulationsbytheEnvironmentalProtectionAgencyintheUS. . . . . . 97 DanaM.BarryandHideyukiKanematsu JapaneseEnvironmentalRegulations. . . . . . . . . . . . . . . . . . . . . . . . . . . 107 HideyukiKanematsuandDanaM.Barry PartIII ConventionalEnvironmentalEvaluationProcesses forSurfaceFinishing TheNecessityandMeaning. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 DanaM.BarryandHideyukiKanematsu FrequentlyUsedEvaluationsforEffluents. . . . . . . . . . . . . . . . . . . . . . . 127 MihoTanakaandJunichiHirata FrequentlyUsedEvaluationsforAerialandSolidPollution. . . . . . . . . 141 KazuyaTakahashi DissolutionAssay. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153 SeijiYokoyama PartIV NovelBiologicalEnvironmentalEvaluationProcesses GeneAnalysisfortheEvaluationoftheEffectofEnvironmental Factors. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169 SatoshiWakai TheApplicationofMammalianCellsforAssessmentofMetallic Products(InVitroProcess). . . . .. . . . . . . . . .. . . . . . . . .. . . . . . . . . .. 185 AkikoOgawa MetalIonSensorofPore-FormingToxinforEnvironmental Evaluation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203 HajimeIkegai ApplicationofPhytoplankton. . . . .. . . . . . . . . . . . .. . . . . . . . . . . .. . . 213 ToshiyukiTakahashi TheApplicationofFish. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 225 MasahiroYamaguchi LifeCycleAssessment(LCA)ofSurfaceTreatmentProducts. . . . . . . . 237 HotakaKai PartV EnvironmentallyFriendlySurfaceFinishing WhatIsEnvironmentallyFriendlySurfaceFinishing?. . . . . . . . . . . . . 251 HideyukiKanematsuandDanaM.Barry SubstitutionwithMoreFriendlyElements. . . . . . . . . . . . . . . . . . . . . . . 261 HideyukiKanematsuandDanaM.Barry Contents ix ChangefromMetalstoNonmetals. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 271 DanaM.BarryandHideyukiKanematsu ProcessChanges. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 281 HideyukiKanematsuandDanaM.Barry TheApplicationofCorrosionProtection. . . . . . . . . . . . . . . . . . . . . . . . 291 HideyukiKanematsuandDanaM.Barry FutureScope. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 299 HideyukiKanematsuandDanaM.Barry