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CORRELATIONS WEAK AND STRONG: DIVERS GUISES OF 8 THE TWO-DIMENSIONAL ELECTRON GAS 9 9 1 A.H.MACDONALD n Physics Department, Indiana University, Bloomington, IN 40475, USA a E-mail [email protected] J 6 Thethree-dimensionalelectron-gasmodelhasbeenamajorfocusformany-bodytheory applied to the electronic properties of metals and semiconductors. Because the model ] neglects bandeffects, whereas electronicsystems aregenerallymorestronglycorrelated l in narrow band systems, it is most widely used to describe the qualitative physics of e weaklycorrelatedmetalswithunambiguousFermiliquidproperties. Themodelismore - r interesting in two space dimensions because it provides a quantitative description of t electronsinquantumwellsandbecausethesecanformstronglycorrelatedmany-particle s . states. Weillustratetherangeofpossiblemany-particlebehaviorsbydiscussingtheway at correlationsaremanifestedin2Dtunnelingspectroscopy experiments. m - d 1 Introduction n o In metals and semiconductors electrons interact among themselves and with nuclei c which are localized, in ordered solids, near lattice sites. Even after ignoring the [ translational degrees of freedom of the nuclei, we are left with a host of different 1 many-body problems for interacting electron systems. In elemental solids, we have v ∼100 different interacting electron problems specified, for example, by the atomic 7 numbers and lattice constants of the periodic table on the inside front cover of 3 0 the text by Ashcroft and Mermin.1 Problems of current interest in many-electron 1 physics are more likely to be found in complicated compounds such as the quater- 0 nary cuprate superconductors, or in artificially fabricated systems such as metallic 8 magnetic multilayers or semiconductor quantum dots. The set of possible many- 9 electron problems is endless and, fortunately for this scientific subfield, the history / at of condensed matter physics teaches that discoveries of unanticipated properties in m newly synthesized materials will also be endless. - Given the large number of many-electron problems, the hopeless difficulty of d each,andthedifferencebetweenthelargestenergyscalesoftheseproblemsandthe n energyscalesofthe excitationsthatdetermine physicalpropertiesatroomtemper- o ature andbelow, acommonstrategyof many-bodytheories is to workwith models c : thatareintendedtofaithfullydescribeessentialaspectsoftheobservedbehaviorof v classesofmaterialswithoutintroducingincidentalcomplications. Perhapsthemost i X commonlystudiedmodelsarethe Hubbardmodel,whichemphasizesthe physicsof r strong repulsion between electrons near the same lattice site, and the electron gas a model which mistreats atomic-like correlations at short length scales and captures instead the physics of screening and long-length scale correlations in metals. All electron ab-initio calculations are generally limited to the considerationof physical propertiesandsystemsforwhichself-consistent-fieldapproximations,stillpresentin practice even in modern density-functional2 based electronic-structurecalculations, are adequate. This situation frequently creates a difficulty in judging whether dis- crepancies between many-body theories and experiment are due to inadequacies of 1 a model, or due to inadequacies of the approximations used to estimate the prop- erties of a model. The case of electrons in semiconductor quantum wells is unusual in this respect. At energies below the subband splitting of the quantum well, these systemsareextremelyaccuratelymodeledbyatwo-dimensional(2D)versionofthe electron-gasmodel. Inthis paperwediscusssomerecentexperimentalandtheoret- ical work on the many-body physics of the 2D electron gas. We limit our attention to the one-particle Greens function, which can be probed experimentally in these systems by 2D-2D tunneling spectroscopy.3,4,6 The paper is organized as follows. In section II we discuss the case of a 2D electron system in a strong magnetic field with a partially filled Landau level. In this limit, the electronic ground state is not a Fermi liquid and the one-particle Greens function exhibits strongly non-perturbative behavior in which a large gap surrounding the Fermi energy is present in the tunneling density-of-states. This behavior is characteristic of strongly correlated electronic states. In section III we discussthecaseofzeromagneticfield,whereexperimentalresultsconfirmtheFermi- liquid nature ofthe electronic state,and tunneling experiments imply quasiparticle lifetimes in semi-quantitative agreement with simple random-phase-approximation estimates. Section IV offers some speculations on changes that should be expected in the zero-field tunneling density of states as the electron density is lowered and the electronic system becomes more strongly correlated. We conclude in Section V with a brief sumamry. 2 One-particle Greens Function at Strong Magnetic Fields For a non-interacting electronsystem, the one-particleGreens function G (ǫ) has a i single pole at ǫ=ǫ , where ǫ is an eigenvalue of the one-body Hamiltonian. Since i i many observables can be expressed entirely in terms of the one-particle Greens function,7 the way in which it is altered by interactions is a central topic of many- body theory. In 2D systems tunneling experiments6 have proved particularly valu- able for experimental studies of the one-particle Greens function. In a tunneling- Hamiltonian formalism,8 the tunneling current between weakly linked electronic systems is given at zero temperature by 2πe µ+eV I = |t(i ,i )|2 dǫA+(ǫ)A−(ǫ−eV). (1) ¯h L R Z iL iR iXL,iR µ where µ is the Fermi energy, L and R labels are used to distinguish 2D systems on opposite sides of the tunneling barrier, A+(ǫ) and A−(ǫ) are the particle and i i holecontributionstothespectralweightfunctionforsingle-particlelabeliandV is the bias voltage. The spectral weights are related to the exact one-particle Greens function as described below. When interactions are neglected A+(ǫ) = δ(ǫ−ǫ ) if i i state i is empty, A−(ǫ) = δ(ǫ−ǫ ) if state i is occupied and the spectral weights i i are otherwise zero. In strongly correlated systems, the spectral function can be qualitatively altered. In the presence of a perpendicular magnetic field, the single-particle kinetic- energy spectrum consists of Landau levels9 with energy ǫ = h¯ω (n + 1/2) and n c 2 macroscopic degeneracy N = AB/Φ . Here ω = eB/mc is the cyclotron fre- φ 0 c quency, A is the system area, B is the magnetic field strength, and Φ = hc/e is 0 the magnetic flux quantum. The one-particle Greens function is defined by ∞ dt ∞ dt G (ǫ)= exp(iǫt/¯h)G (t)=−i exp(iǫt/¯h)hΨ |T[c (t)c† (0)]|Ψ i n Z ¯h n Z ¯h 0 n,m n,m 0 −∞ −∞ (2) where c and c† are respectively fermion annihilation and creation operators n,m n,m foroneofthedegeneratestateswithinthen’thLandaulevel,and|Ψ iistheground 0 state of the interacting electron system.10 We restrict our attention here to n = 0 anddroptheLandaulevelindexonG (ǫ). TheGreensfunctioncanthenbewritten n in the form A+(ǫ′) A−(ǫ′) G(ǫ)= dǫ′ + (3) Z ǫ−ǫ′+iη ǫ−ǫ′−iη (cid:2) (cid:3) wheretheparticleandholespectralfunctionsA+ andA− havethefollowingformal expression in terms of exact eigenstates of the Hamiltonian: A+(ǫ)= |hΨ (N +1)|c† |Ψ (N)i|2 α m 0 X α ×δ(ǫ−[E (N +1)−E (N)]) α 0 A−(ǫ)= |h|Ψ (N −1)|c |Ψ (N)i|2 α m 0 X α ×δ(ǫ−[E (N)−E (N −1)]) (4) 0 α When interactions are neglected, states in the lowest Landau level are degen- erate and are occupied with probability ν where ν = N/N and N is the number φ of electrons in the many-particle system. It follows that A (ǫ) = (1−ν)δ(ǫ) and + A (ǫ) = νδ(ǫ). When these spectral functions are inserted in Eq.( 1) we find that − I ∝ ν(1−ν)δ(eV). If interactions were unimportant, a sharp peak in the tunnel- ing current would occur near zero bias. The experimental results11 of Eisenstein et al. shown in Fig.[1] evidence quite the opposite behavior; the tunneling current is immeasurably small at zero bias and is peaked instead near a bias voltage of ∼5mV. Since I(V) depends on the product of electronand hole spectral functions at energies within eV of the Fermi energy, it follows that both are extremely small close to the Fermi energy. Similar conclusions can be drawn on the basis of 3D-2D tunneling experiments4,12 by Ashoori and collaborators. This experimental result can be understood in qualitative terms as a consequence of strong correlations in the ground state of the electron system. When an additional electron is added to the ground state of an N electron system, it is not strongly correlated with the electronsalreadypresent. The resultingN+1particle state willhavea smallover- lap with the groundstate or any low energy states of the strongly correlatedN+1 electron system. A (ǫ) should therefore be peaked at energies well above the en- + ergy difference between the groundstates of the N+1 andN particle systems, the chemical potential µ. 3 Figure 1: Low temperature tunneling I-V characteristics for bulk 2D to 2D tunneling in the fractional Hall regime. The traces are at magnetic fields separated by 0.25 Tesla and for this sample cover a range of filling factors from ν = 0.48 to ν = 0.83. The higher bias potential peakisduetoLandaulevelmixingwhilethelowerbiaspotential peakisduetotunnelingwithin the lowest Landau level. The tunneling current is the convolution of particle and hole spectral weightfunctions,atenergiesseparated byeV. Thisexperimentshowsthatthetunnelingcurrent isstronglysuppressednearzerobiasandhencethatthespectral weightfunctions aresuppressed at energies near the Fermi energy over a broadrange of filling factors. Features inthe tunneling dataassociatedwithparticularincompressiblestates,forexampletheonethatoccursatν=2/3, areweak. TheinsetshowstheonsetandpeakvaluesoftheintraLandauleveltunnelingcurrents. (AfterEisensteinet al. inRef.11.) Despite the achievementofanumberofvaluableinsights,13 westilldonothave acompletely satisfactorytheoryforthe spectralweightfunctioninthe strongmag- netic field limit. Nevertheless, the connection between the energy at which the tunneling currentispeakedandcorrelationsinthegroundstateoftheelectronsys- temsuggestedby theprecedingwordscanbe made moreprecise.14,15 Thefollowing sum rules for the zeroth and first moments of A(ǫ) ≡ A (ǫ)+A (ǫ) follow from − + Eqs.( 4): dǫA(ǫ)=hΨ |c† c +c c† |Ψ i=1 (5) Z 0 m m m m 0 and dǫǫA(ǫ)=hΨ |[H,c† ]c +c [H,c† ]|Ψ i Z 0 m m m m 0 =ǫ . (6) HF 4 In Eq.( 6), ǫ =ν [hm,m′|V|m,m′i−hm′,m|V|m,m′i] (7) HF Xm′ isthesingle-particleHartree-Fockenergyforthissystem. ThelastidentityinEq.(6) follows from translational invariance which requires that hΨ |c† c |Ψ i=ν for all 0 m m 0 m. These sum rules should be compared with those for A : − dǫA (ǫ)=hΨ |c† c |Ψ i=ν (8) Z − 0 m m 0 and dǫǫA (ǫ)=hΨ |[H,c† ]c |Ψ i=2ǫ (ν). (9) Z − 0 m m 0 0 where ǫ (ν)=E /N is the many-particle ground state energy per lowest-Landau- 0 0 φ level orbital. The last identity is an adaptation, to the case of Hamiltonians that include only an interaction term, of the expression for the ground state energy in terms of the one-particle Greens function, derived using an equation of motion approach in many-body theory texts.7 Its application here rests on the observation thathΨ |[H,c† ]c |Ψ iisindependentofm. Theintegratedweightoftheholepart 0 m m 0 ofthespectralweightfunctionisν anditsmeanenergyisthereforehǫ i=2ǫ (ν)/ν. − 0 For A(ǫ), the integrated weight is 1 and the mean energy is ǫ . It follows that HF the mean energy in the particle part of the spectral weight function is νǫ −2ǫ (ν) HF 0 hǫ i=hǫ i+ (10) + − ν(1−ν) The second term on the right hand side of this equation is a sum rule estimate of the gap separating peaks in the hole and particle portions of the spectral weight, ∆ . ∆ will give an accurate value for the peak position whenever the peak is sr sr sharp and its position well defined; a property established for the present case by experiment. The dependence of ∆ on ν is illustrated in Fig.[2]; when corrected sr for finite quantum well width effects these results agree well with experiment. Since in the present case there is no one-body term in the Hamiltonian, the groundstate energyper orbitalin the Hartree-Fockapproximationis νǫ /2. The HF gap is proportionalto the amount by which the ground-state energy lies below the Hartree-Fock approximation ground-state energy, i.e., the gap is proportional to the correlation energy. We see that in the strong-magnetic-field case where the kinetic energy can be completely removed from the problem, the intuitive notion thatthereshouldbeagapintheelectronicspectralfunctionrelatedtoground-state correlationshas surprisingexactness. Now we turnto the zero magnetic fieldlimit, where interactions are in competition with the kinetic energy. 3 2D Tunneling Spectroscopy of the Fermi Liquid State At zero magnetic field, we can label states in the 2D electron system by two- dimensional wavevectors. A unique feature of 2D-2D tunneling between quantum 5 0.8 Sum Rule Gap 0.6 sr0.4 ∆ 0.2 0.0 0.0 0.2 0.4 0.6 0.8 1.0 ν Figure 2: Sum rule estimate for the gap between particle and hole contributions to the spectral weightfunctionofatwo-dimensionalelectrongasatstrongmagneticfieldsasafunctionofLandau level fillingfactor ν. Thetunneling conductance ispeaked when eV =∆sr. These estimates are forthecaseofanidealtwo-dimensionalelectrongasandneedtobereducedtoaccount forfinite thickness effects when comparing with experimental systems. The gap is expressed in units of e2/ǫℓwhereℓ=(¯hc/eB)1/2 isthemagneticlength. AfterMoriet al. inRef. 14. wells in epitaxial layered semiconductors, is the near perfect translational invari- ance perpendicular to the tunneling direction which selects momentum-conserving tunneling processes. Accounting for spin-degeneracy at zero field, the tunneling current is 4πe|t|2 µ+eV I = dǫA+(ǫ)A−(ǫ−eV). (11) ¯h Z ~k ~k X~k µ For non-interacting 2D electrons,the spectral-weightfunction had a delta-function peak in the hole contribution for |~k|<k and a delta-function peak in the particle F contributionfor |~k|>k where k is the Fermi wavevector. The tunneling current F F consequently has a delta-function peak at zero bias. At zero magnetic field, it is generally expected that the interacting 2D electron system should be in a Fermi- liquidstateinwhichalargefractionofthespectralweightliesinasharpLorentzian quasiparticle peak centered at the quasiparticle energy: z Γ A (ǫ)= ~k ~k +Ainc(ǫ) (12) ~k π (ǫ−E )2+Γ2 ~k ~k ~k Here Γ = h¯/2τ where τ is the quasiparticle lifetime, E is the quasiparticle ~k ~k ~k ~k energy, z < 1 is the quasiparticle normalization factor, and Ainc is the part of ~k ~k the spectral function non included in the quasiparticle peak. In a Fermi liquid, the quasiparticle lifetime diverges in the limit of zero temperature as k approaches k . F 6 If we ignore the renormalizationof the quasiparticle energy due to interactions andthedecreaseofthequasiparticlelifetimeonmovingawayfromtheFermisurface, the contribution to the integrals in Eq.( 11) from the quasiparticle portion of the spectral function can be evaluated analytically with the result Gqp(V)= I(V) = zk2Fe2|t|2Aν0 2h¯/τ (13) V ¯h (eV)2+(h¯/τ)2 where ν is the 2D Fermi-gas density of states. A finite quasiparticle lifetime turns 0 the δ function peakinthe tunneling conductanceinto a Lorentzian. This is exactly whatisseeninexperiment,16providingaverydirectconfirmationoftheFermi-liquid natureofthe2Delectron-gasstateatzerofield. Thezero-biaspeakinthetunneling conductanceatzerofieldstandsinstarkcontrastwith the extremelysmallconduc- tanceatsmallbiasfoundatstrongfieldsanddiscussedintheprevioussection. The 2D tunneling-spectroscopy experiment is a sensitive indicator of the nature of the manyelectronstate. Thissimpleresultforthetunneling-conductance-spectroscopy lineshapeapplieswhenallquasiparticlelifetimesareapproximatedbytheirvalueat |~k|=k . Detailed calculations17,18 show thatthe true line shape is notLorentzian, F but that the voltage at which Gqp is reduced to half of its V = 0 value is in- creased by only 20% when the ~k dependence of the quasiparticle lifetime is taken into account. Thus it is possible to read off the quasiparticle lifetime at the Fermi energy by looking at the width of the zero-bias tunneling conductance peak. As illustrated in Fig.[3], the measuredlifetimes are in reasonableaccordwith random- phase-approximation theoretical estimates. Theoretical and experimental lifetimes can be brought into closer agreement by incorporating proposals for improving on the random-phase approximation from the electron-gas many-body-theory litera- ture. The improved agreement supports the efficacy of exchange-correlation local- field corrections to the random phase approximation.19 The sharp peak in the tunneling conductance near zero bias is due entirely to quasiparticle peaks in the spectral weight functions. As long as the 2D electron systemisa Fermiliquid, this peak willbe present. However,asthe electronsystem becomes more strongly correlated, the quasiparticle normalization factor z will ~k become smaller and the incoherent part of the spectral function will become more dominant. We now turnour attentionto somespeculations onwhatwillhappen in this regime. 4 Strong Correlations at Zero Magnetic Field A2Delectronsystembecomesincreasinglycorrelatedatlowelectrondensities. The density is usually parameterized in terms of the electron gas parameter r defined s by the following equation: n=N/A=(πr2a2) (14) s 0 where a = h¯2ǫ/m∗e2 is the host semiconductor Bohr radius, m∗ is the band- 0 structure effective mass of the electrons, and ǫ is the host semiconductor dielectric constant. When r is large,the typicalinteraction-energyscale is muchlargerthan s the typical kinetic-energy scale, and the electronsystem is strongly correlated. For 7 Figure3: Half-widthathalf-maximumforthezero-bias2D-2Dtunnelingspectroscopypeakinthe Fermi liquidstate of a 2D electron gas. This width is inversely proportional to the quasiparticle lifetimeattheFermienergy. Theoretical resultsincludinglocal-fieldcorrections totheRPA(full line),theoreticalresultsintheRPA(dashedline),andexperimentalresults(dottedline)reported byMurphyet al. inRef. 17. AfterJungwirthet al. inRef. 17. r larger than20 about 30 a phase transition between the Fermi-liquid electronic s stateandaWigner-crystalstatewithbrokentranslationalsymmetryisexpectedto occur. Existingtunneling experimentsin 2Delectronsystemshavebeen performed on samples with r <2, which have moderate correlationsadequately described by s therandom-phaseapproximation. Weexpectthatwhenexperimentsareperformed insampleswithmuchlowerdensity,thezero-biasFermi-liquidpeakinthetunneling conductancewillbeembeddedinabroaderstructurewithaminimumnearzerobias similartowhathasalreadybeenobservedforstronglycorrelatedstatesinpartially filled Landau levels. This expectation follows from a sum-rule analysis similar to that in Section II. At zero magnetic field, the one-particle Greens function is diagonal in a repre- sentationofwavevectorsandspins,~k andσ. Although,unlike the strongfieldcase, the Greens function is dependent on its single-particle state labels, it still satisfies similar identities for the zeroth and first moments of the full spectral function: ∞ A (ǫ)=hΨ |c† c +c c† |Ψ i=1 (15) Z ~k,σ 0 ~k,σ ~k,σ ~kσ ~kσ 0 −∞ and dǫǫA (ǫ)= hΨ |[H,c† ]c +c [H,c† ]|Ψ i Z ~k,σ 0 ~k,σ ~k,σ ~kσ ~kσ 0 N 1 = ǫ + V(~q =0)− V(~k−~k′)n ~k A A ~k′,σ X ~k′ 8 = E (16) ~k NotethatinEq.(16),n =hΨ |c† c |Ψ iratherthanthenon-interactingFermi ~k,σ 0 ~k,σ ~k,σ 0 gas occupation number. If not for this distinction, E would be the Hartree-Fock ~k approximation to the quasiparticle energy. Below we compare the total energy of the electron system with the quantity 1 E˜ ≡ n (ǫ +E ). (17) 2 ~k,σ ~k ~k X ~k,σ Ifn wereequalto its non-interactingvalue,E˜ wouldbe the Hartree-Fockapproxi- ~k mationtotheground-stateenergy. Actually,E˜ willbelargerthantheHartree-Fock ground-state energy, since the kinetic energy is increased and the exchange energy reduced in magnitude by the partial occupation of states outside the Fermi sea. Thedifferencebetweentheexactground-stateenergyE andtheapproximatevalue obtainedinaHartree-Fockapproximationisgenerallyreferredtoasthecorrelation energy of an interacting electron system. In the following, we will appropriate this language in referring to the difference between E and E˜. We employ an exact identity7 that follows from the equation of motion for the one-particle Greens function and relates the hole part of its spectral weight to the total energy: 1 E = n ǫ +hǫ−i . (18) 2 ~k ~k ~k X~k,σ (cid:2) (cid:3) (−) Herewehavenotedthatn isthezerothmomentofA (ǫ)anddefinedtheaverage ~k ~k hole energy hǫ−i as the ratio of the first and zeroth moments. Comparing this ~k expression with the expression for E˜, we find that the correlation energy can be written in the form: −1 E ≡E−E˜ = n (1−n )(hǫ+i−hǫ−i) (19) corr 2 ~k ~k ~k ~k X ~k,σ wherehǫ+iisthemeanenergyintheparticleportionofthespectralweightfunction ~k so that n hǫ−i+(1−n )hǫ+i=E . (20) ~k ~k ~k ~k ~k For a low-density 2D electron gas, correlations are strong. The correlation energy is negative and comparable in magnitude to the total energy per electron. One way in which this can be consistent with Eq.( 19) is if, for ∼ N values of ~k, the spectral-weight function A (ǫ) has a substantial portion of its weight distributed ~k between non-quasiparticle peaks located near hǫ−i and hǫ+i and relatively little ~k ~k weightattachedtoitsdispersivequasiparticlepeak. Thisispreciselywhathappens inthe strongfieldlimit where, inaccordwiththe non-Fermi-liquidcharacterofthe ground state, the quasiparticle peak is entirely absent. We now consider two quite differentexamples,inwhichthisscenarioisrealized. Thegeneralityofthebehavior convinces us that it is ubiquitous in strongly correlated fermion systems. 9 Theone-bandHubbardmodelisalatticemodelinwhichelectronsinteractonly if they occupy the same lattice site. The one-band version of this model has been extremely widely studied21 in connection with the strong correlations that exist in the planar cuprate superconductors, especially in the underdoped regime. Elec- trons in this model become strongly correlated when the band is near half-filling and when the on-site interaction U is larger than the intersite hopping energy t. The one-particle Greens function is readily evaluated at half-filling in the narrow- band (t→0) limit. The ground state has eigenenergy 0 and is 2N fold degenerate. Thezeroenergystatesarethosewithoneelectronofeitherspinoneachlatticesite. Averagingoverthesestatesgivesn =1/2. Removinganelectronfromanylattice ~k,σ site in any ofthe 2N states givesa state with zero energy so that for eachwavevec- tor in the Brillouin zone, A− (ǫ) = (1/2)δ(ǫ) and hǫ−i = 0. Adding an electron ~k,σ ~k on any lattice site produces a state with energy U so that A+ (ǫ)=(1/2)δ(ǫ−U) ~k,σ and hǫ+i = U. These two peaks in the spectral function are referred to as the ~k lower and upper Hubbard bands and they broaden when t 6= 0. The mean-field single-particle energy, calculated from the mean occupation numbers but includ- ing exchangecorrectionswhich eliminate interactions between parallelspins on the same site, is E = U/2 and, taking note of the double-counting factor for this in- ~k teraction energy, the corresponding total energy is E˜ = NU/4. In this case, the spectral weight is entirely comprised of non-dispersive delta-function hole and par- ticle contributions. This non-Fermiliquidstate has nodispersivequasiparticlepole which sharpens on crossing the Fermi energy. In precise agreement with Eq.( 19), the two peaks are split by an amount proportional to the correlation energy per particle. For finite t, the Hubbard model is generally expected to have a Fermi liquid ground state away from the half-filled band condition. An important issue21 in the many-body theory of the Hubbard model has been the question of whether the dispersive quasiparticle peaks at the Fermi energy are created by moving one of the Hubbard bands to the Fermi energy or by drawing weight away from the Hubbard bands to quasiparticle bands at the Fermi energy. Since the correlation energy can be strongly dependent on band-filling, the sum rules discussed here ap- pear to preclude the former possibility and argue for quasiparticle bands which are energetically separate from both quasiparticle bands. Another example that is relevant to the case of a 2D electron gas occurs when the translational symmetry is broken in the Wigner-crystal ground state. The broken symmetry requires a modification of our analysis that we will not detail here, since the Greens function in no longer diagonal in wavevector. Nevertheless, the connection between strong correlations and peaks in the spectral function that areawayfromthechemicalpotentialisagainpresent. Thechemicalpotentialinthis systemistheenergyincreaseuponaddingaparticlebyslightlydecreasingthelattice constant,ortheenergydecreaseuponremovingaparticlebyslightlyincreasingthe latticeconstant. Theparticleportionofthespectralfunctionhasapeakatenergies far above the chemical potential since the particle can be added at an arbitrary position,includingenergeticallyunfavorablepositionsnearoneofthecrystallattice sites. The hole portion of the spectral-weight function is peaked at energies well below the chemicalpotential, since the state with a particle removedfroma lattice 10

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