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CHEMISTRY OF METALLOPROTEINS WILEY SERIES IN PROTEIN AND PEPTIDE SCIENCE VLADIMIR N. UVERSKY, Series Editor Metalloproteomics (cid:129) Eugene A. Permyakov InstrumentalAnalysisofIntrinsicallyDisorderedProteins:AssessingStructureand Conformation (cid:129) Vladimir Uversky and Sonia Longhi Protein Misfolding Diseases: Current and Emerging Principles and Therapies (cid:129) Marina Ramirez-Alvarado, Jeffery W. Kelly, and Christopher M. Dobson Calcium Binding Proteins (cid:129) Eugene A. Permyakov and Robert H. Kretsinger ProteinChaperonesandProtectionfromNeurodegenerativeDiseases(cid:129)Stephan Witt Transmembrane Dynamics of Lipids (cid:129) Philippe Devaux and Andreas Herrmann FlexibleViruses:StructuralDisorderinViralProteins(cid:129)VladimirUverskyandSonia Longhi ProteinFamilies:RelatingProteinSequence,Structure,andFunction(cid:129)ChristineA. Orengo and Alex Bateman ChemistryofMetalloproteins:ProblemsandSolutionsinBioinorganicChemistry(cid:129) Joseph J. Stephanos and Anthony W. Addison CHEMISTRY OF METALLOPROTEINS Problems and Solutions in Bioinorganic Chemistry JOSEPH J. STEPHANOS ANTHONY W. ADDISON Copyright2014byJohnWiley&Sons,Inc.Allrightsreserved PublishedbyJohnWiley&Sons,Inc.,Hoboken,NewJersey PublishedsimultaneouslyinCanada Nopartofthispublicationmaybereproduced,storedinaretrievalsystem,ortransmittedinanyform orbyanymeans,electronic,mechanical,photocopying,recording,scanning,orotherwise,exceptas permittedunderSection107or108ofthe1976UnitedStatesCopyrightAct,withouteithertheprior writtenpermissionofthePublisher,orauthorizationthroughpaymentoftheappropriateper-copyfeeto theCopyrightClearanceCenter,Inc.,222RosewoodDrive,Danvers,MA01923,(978)750-8400, fax(978)750-4470,oronthewebatwww.copyright.com.RequeststothePublisherforpermission shouldbeaddressedtothePermissionsDepartment,JohnWiley&Sons,Inc.,111RiverStreet,Hoboken, NJ07030,(201)748-6011,fax(201)748-6008,oronlineathttp://www.wiley.com/go/permission. LimitofLiability/DisclaimerofWarranty:Whilethepublisherandauthorhaveusedtheirbestefforts inpreparingthisbook,theymakenorepresentationsorwarrantieswithrespecttotheaccuracyor completenessofthecontentsofthisbookandspecificallydisclaimanyimpliedwarrantiesof merchantabilityorfitnessforaparticularpurpose.Nowarrantymaybecreatedorextendedbysales representativesorwrittensalesmaterials.Theadviceandstrategiescontainedhereinmaynotbesuitable foryoursituation.Youshouldconsultwithaprofessionalwhereappropriate.Neitherthepublishernor authorshallbeliableforanylossofprofitoranyothercommercialdamages,includingbutnotlimitedto special,incidental,consequential,orotherdamages. Forgeneralinformationonourotherproductsandservicesorfortechnicalsupport,pleasecontactour CustomerCareDepartmentwithintheUnitedStatesat(800)762-2974,outsidetheUnitedStates at(317)572-3993orfax(317)572-4002. Wileyalsopublishesitsbooksinavarietyofelectronicformats.Somecontentthatappearsinprintmay notbeavailableinelectronicformats.FormoreinformationaboutWileyproducts,visitourwebsite atwww.wiley.com. LibraryofCongressCataloging-in-PublicationData: Stephanos,JosephJ.,author. Chemistryofmetalloproteins:problemsandsolutionsinbioinorganicchemistry/byJosephJ. Stephanos,AnthonyW.Addison. p.;cm.–(Wileyseriesinproteinandpeptidescience) Includesbibliographicalreferencesandindex. ISBN978-1-118-47044-2(paperback) I. Addison,A.W.,author.II. Title.III. Series:Wileyseriesinproteinandpeptidescience. [DNLM:1.Metalloproteins–chemistry–ExaminationQuestions.QU18.2] QP551 5720.6076–dc23 2013041995 PrintedintheUnitedStatesofAmerica 10 9 8 7 6 5 4 3 2 1 CONTENTS Preface ix 1 Introduction 1 Proteins:Formation,Structures,andMetalloproteins, 4 References, 28 2 AlkaliandAlkalineEarthCations 31 References, 67 3 NonredoxMetalloenzymes 71 Carboxypeptidases, 75 CarbonicAnhydrase, 84 AlcoholDehydrogenase, 88 References, 91 4 CopperProteins 95 Introduction, 95 ElectronicSpectraofCopperIons, 96 ESRSpectraofCopperIons, 105 CopperProteins, 117 Plastocyanin, 119 AzurinandStellacyanin, 127 SuperoxideDismutase, 131 v vi CONTENTS Hemocyanin, 135 AscorbicOxidase, 139 References, 142 5 IronProteins 147 Introduction, 147 ElectronicSpectraofIronIons, 148 MössbauerSpectroscopyofIronIons, 155 ESRSpectraofIron(III), 161 IronBioavailability, 166 Siderophores, 171 IronStorageandTransferProteins, 184 Ferritin, 184 Transferrin, 187 DioxygenaseIronProteins, 195 Iron–SulfurProteins, 207 Rubredoxin, 207 Ferredoxins, 212 2Fe–2SFerredoxins, 212 4Fe–4SFerredoxins, 221 Aconitase, 226 Hydroxylases, 229 Hydrogenases, 232 Nitrogenases, 240 BinuclearIronProteins, 251 Hemerythrin, 253 RibotideReductase,PurpleAcidPhosphate,and MethaneMonooxygenase, 260 Hemoproteins:ClassificationandBehaviorofHemein AbsenceofGlobins, 267 MyoglobinandHemoglobin, 275 Myoglobin, 275 Hemoglobin, 280 CytochromeC, 298 ElectronTransferinPorphyrinsandMetalloporphyrins, 301 Catalases, 311 Peroxidases, 315 CytochromeP-450, 322 ElectronicSpectraofHemoproteins, 327 ESRSpectraofHemoproteins, 362 References, 378 CONTENTS vii 6 VitaminB 393 12 References, 405 7 Chlorophyll 407 References, 421 Index 423

Description:
Addresses the full gamut of questions in metalloprotein science Formatted as a question-and-answer guide, this book examines all major families of metal binding proteins, presenting our most current understanding of their structural, physicochemical, and functional properties. Moreover, it introduce
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Chemistry of metalloproteins : problems and solutions in bioinorganic chemistry PDF

451 Pages·2014·20.91 MB·English
by  Joseph J. Stephanos
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CHEMISTRY OF METALLOPROTEINS WILEY SERIES IN PROTEIN AND PEPTIDE SCIENCE VLADIMIR N. UVERSKY, Series Editor Metalloproteomics (cid:129) Eugene A. Permyakov InstrumentalAnalysisofIntrinsicallyDisorderedProteins:AssessingStructureand Conformation (cid:129) Vladimir Uversky and Sonia Longhi Protein Misfolding Diseases: Current and Emerging Principles and Therapies (cid:129) Marina Ramirez-Alvarado, Jeffery W. Kelly, and Christopher M. Dobson Calcium Binding Proteins (cid:129) Eugene A. Permyakov and Robert H. Kretsinger ProteinChaperonesandProtectionfromNeurodegenerativeDiseases(cid:129)Stephan Witt Transmembrane Dynamics of Lipids (cid:129) Philippe Devaux and Andreas Herrmann FlexibleViruses:StructuralDisorderinViralProteins(cid:129)VladimirUverskyandSonia Longhi ProteinFamilies:RelatingProteinSequence,Structure,andFunction(cid:129)ChristineA. Orengo and Alex Bateman ChemistryofMetalloproteins:ProblemsandSolutionsinBioinorganicChemistry(cid:129) Joseph J. Stephanos and Anthony W. Addison CHEMISTRY OF METALLOPROTEINS Problems and Solutions in Bioinorganic Chemistry JOSEPH J. STEPHANOS ANTHONY W. ADDISON Copyright2014byJohnWiley&Sons,Inc.Allrightsreserved PublishedbyJohnWiley&Sons,Inc.,Hoboken,NewJersey PublishedsimultaneouslyinCanada Nopartofthispublicationmaybereproduced,storedinaretrievalsystem,ortransmittedinanyform orbyanymeans,electronic,mechanical,photocopying,recording,scanning,orotherwise,exceptas permittedunderSection107or108ofthe1976UnitedStatesCopyrightAct,withouteithertheprior writtenpermissionofthePublisher,orauthorizationthroughpaymentoftheappropriateper-copyfeeto theCopyrightClearanceCenter,Inc.,222RosewoodDrive,Danvers,MA01923,(978)750-8400, fax(978)750-4470,oronthewebatwww.copyright.com.RequeststothePublisherforpermission shouldbeaddressedtothePermissionsDepartment,JohnWiley&Sons,Inc.,111RiverStreet,Hoboken, NJ07030,(201)748-6011,fax(201)748-6008,oronlineathttp://www.wiley.com/go/permission. LimitofLiability/DisclaimerofWarranty:Whilethepublisherandauthorhaveusedtheirbestefforts inpreparingthisbook,theymakenorepresentationsorwarrantieswithrespecttotheaccuracyor completenessofthecontentsofthisbookandspecificallydisclaimanyimpliedwarrantiesof merchantabilityorfitnessforaparticularpurpose.Nowarrantymaybecreatedorextendedbysales representativesorwrittensalesmaterials.Theadviceandstrategiescontainedhereinmaynotbesuitable foryoursituation.Youshouldconsultwithaprofessionalwhereappropriate.Neitherthepublishernor authorshallbeliableforanylossofprofitoranyothercommercialdamages,includingbutnotlimitedto special,incidental,consequential,orotherdamages. Forgeneralinformationonourotherproductsandservicesorfortechnicalsupport,pleasecontactour CustomerCareDepartmentwithintheUnitedStatesat(800)762-2974,outsidetheUnitedStates at(317)572-3993orfax(317)572-4002. Wileyalsopublishesitsbooksinavarietyofelectronicformats.Somecontentthatappearsinprintmay notbeavailableinelectronicformats.FormoreinformationaboutWileyproducts,visitourwebsite atwww.wiley.com. LibraryofCongressCataloging-in-PublicationData: Stephanos,JosephJ.,author. Chemistryofmetalloproteins:problemsandsolutionsinbioinorganicchemistry/byJosephJ. Stephanos,AnthonyW.Addison. p.;cm.–(Wileyseriesinproteinandpeptidescience) Includesbibliographicalreferencesandindex. ISBN978-1-118-47044-2(paperback) I. Addison,A.W.,author.II. Title.III. Series:Wileyseriesinproteinandpeptidescience. [DNLM:1.Metalloproteins–chemistry–ExaminationQuestions.QU18.2] QP551 5720.6076–dc23 2013041995 PrintedintheUnitedStatesofAmerica 10 9 8 7 6 5 4 3 2 1 CONTENTS Preface ix 1 Introduction 1 Proteins:Formation,Structures,andMetalloproteins, 4 References, 28 2 AlkaliandAlkalineEarthCations 31 References, 67 3 NonredoxMetalloenzymes 71 Carboxypeptidases, 75 CarbonicAnhydrase, 84 AlcoholDehydrogenase, 88 References, 91 4 CopperProteins 95 Introduction, 95 ElectronicSpectraofCopperIons, 96 ESRSpectraofCopperIons, 105 CopperProteins, 117 Plastocyanin, 119 AzurinandStellacyanin, 127 SuperoxideDismutase, 131 v vi CONTENTS Hemocyanin, 135 AscorbicOxidase, 139 References, 142 5 IronProteins 147 Introduction, 147 ElectronicSpectraofIronIons, 148 MössbauerSpectroscopyofIronIons, 155 ESRSpectraofIron(III), 161 IronBioavailability, 166 Siderophores, 171 IronStorageandTransferProteins, 184 Ferritin, 184 Transferrin, 187 DioxygenaseIronProteins, 195 Iron–SulfurProteins, 207 Rubredoxin, 207 Ferredoxins, 212 2Fe–2SFerredoxins, 212 4Fe–4SFerredoxins, 221 Aconitase, 226 Hydroxylases, 229 Hydrogenases, 232 Nitrogenases, 240 BinuclearIronProteins, 251 Hemerythrin, 253 RibotideReductase,PurpleAcidPhosphate,and MethaneMonooxygenase, 260 Hemoproteins:ClassificationandBehaviorofHemein AbsenceofGlobins, 267 MyoglobinandHemoglobin, 275 Myoglobin, 275 Hemoglobin, 280 CytochromeC, 298 ElectronTransferinPorphyrinsandMetalloporphyrins, 301 Catalases, 311 Peroxidases, 315 CytochromeP-450, 322 ElectronicSpectraofHemoproteins, 327 ESRSpectraofHemoproteins, 362 References, 378 CONTENTS vii 6 VitaminB 393 12 References, 405 7 Chlorophyll 407 References, 421 Index 423

Description:
Addresses the full gamut of questions in metalloprotein science Formatted as a question-and-answer guide, this book examines all major families of metal binding proteins, presenting our most current understanding of their structural, physicochemical, and functional properties. Moreover, it introduce
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