ThomasM.Klapötke ChemistryofHigh-EnergyMaterials Also of interest EnergeticMaterialsEncyclopedia. Klapötke,2018 ISBN978-3-11-044139-0,e-ISBN978-3-11-044292-2 EnergeticCompounds. MethodsforPredictionofTheirPerformance Keshavarz,Klapötke,2017 ISBN978-3-11-052184-9,e-ISBN978-3-11-052186-3 ThePropertiesofEnergeticMaterials. DeterminationandPredictionofCombustionProperties Keshavarz,Klapötke,2018 ISBN978-3-11-057220-9,e-ISBN978-3-11-057222-3 ChemicalKinetics. ForEngineers Csavdari,2021 ISBN978-3-11-047515-9,e-ISBN978-3-11-047517-3 IndustrialInorganicChemistry. Benvenuto,2017 ISBN978-3-11-049446-4,e-ISBN978-3-11-049447-1 HighTemperatureMaterialsandProcesses. HiroyukiFukuyama(Editor-in-Chief) ISSN0334-6455,e-ISSN2191-0324 Thomas M. Klapötke Chemistry of High- Energy Materials 5th Edition Author Prof.Dr.ThomasM.Klapötke Ludwig-MaximiliansUniversityMunich DepartmentofChemistry Butenandtstr.5–13(BuildingD) 81377Munich,Germany [email protected] ISBN978-3-11-062438-0 e-ISBN(PDF)978-3-11-062457-1 e-ISBN(EPUB)978-3-11-062469-4 LibraryofCongressControlNumber:2019946369 BibliographicinformationpublishedbytheDeutscheNationalbibliothek TheDeutscheNationalbibliothekliststhispublicationintheDeutscheNationalbibliografie;detailed bibliographicdataareavailableontheInternetathttp://dnb.dnb.de. ©2019WalterdeGruyterGmbH,Berlin/Boston Typesetting:MetaSystemsPublishing&PrintservicesGmbH,Wustermark Printingandbinding:CPIbooksGmbH,Leck Coverimage:antorti/E+/GettyImages www.degruyter.com “Wewillnotwaver;wewillnottire;wewillnotfalter; Andwewillnotfail.Peaceandfreedomwillprevail.” G.W.Bush, PresidentialAddresstotheNation, October7th2001 Preface to this 5th English edition Everything which has been said in the preface to the first German, as well as in the first to fourth English editions still holds true, and essentially does not need any addition or correction. In this revised fifth edition in English, the manuscript has been updated and various recent aspects of energetic materials have been added: (i) Someerrorswhichwereunfortunatelypresentinthefourtheditionhavebeen correctedandthereferenceshavealsobeenupdatedwhereappropriate. (ii) Chapters on the critical diameter, colored smokes, delay compositions, sensi- tivities, gun erosion, TKX-50, liners, thermobaric weapons and nitrocellulose havebeenupdated. (iii)FournewchaptersonAging(6.7),AirBags(13.6),SpentAcid(10.4)andToxici- tyMeasurements(13.7)havebeenadded. In addition to the people thanked in the German and first four English editions, theauthorwouldliketothankDr.ManfredBohn(ICT),Dr.JohannGlück(ZF),Dr. PaulWanninger(PWX),Mr.MoritzMühlemann(BIAZZI),Mr.MarcelHoller(Bayern Chemie), Ms. Cornelia Unger (LMU) and Ms. Teresa Küblböck (LMU) for many in- spireddiscussions. Munich,July2019 ThomasM.Klapötke https://doi.org/10.1515/9783110624571-203 Preface to the 4th English edition Everything which has been said in the preface to the first German, as well as in the first to third English editions, still holds and essentially does not need any additionorcorrection.InthisrevisedfourtheditioninEnglish,themanuscripthas beenupdatedandvariousrecentaspectsofenergeticmaterialshavebeenadded: (i) Someerrors,whichwereunfortunatelypresentinthethirdedition,havebeen corrected,andthereferenceshavealsobeenupdatedwhereappropriate. (ii) The chapters on shaped charges, visible pyrotechnics, smokes (addition of P N ), primary explosives (MTX-1), composite and double-base propellants, 3 5 andGurneyenergyhavebeenupdated. (iii)FournewchaptersonElectricDetonators(5.4),DetonationvelocityfromLaser Induced Air Shock (9.7), Thermally Stable Explosives (9.8), and Explosive Welding(13.5)havebeenadded. In addition to the people thanked in the German and first three English editions, theauthorwouldliketothankProfessorDr.MohammadH.Keshavarz,Dr.Tomasz Witkowski,Col.Dr.AhmedElbeih,Cpt.MohamedAbd-Elghany,M.Sc.andLt.An- dreeaVoicu,M.Sc.formanyinspireddiscussions. Munich,July2017 ThomasM.Klapötke https://doi.org/10.1515/9783110624571-204 Preface to the 3rd English edition Everything which has been said in the preface to the first German and first and second English editions still holds and essentially does not need any addition or correction. In this revised third edition in English the manuscript has been up- datedandvariousrecentaspectsofenergeticmaterialshavebeenadded: (i) someerrorswhichunfortunatelyoccurredinthefirstandsecondeditionshave beencorrectedandthereferenceshavealsobeenupdatedwhereappropriate. (ii) The chapters on critical diameters, delay compositions, visible light (blue) pyrotechnics,polymer-bondedexplosives(PBX),HNS,thermodynamiccalcula- tions,DNAN,smoke(yellow)formulationsandhigh-nitrogencompoundshave beenupdated. (iii)Five new short chapters on Ignition and Initiation (chapters 5.2 and 5.3), the Plate Dent Test (chapter 7.4), Underwater Explosions (chapter 7.5) and the TrauzlTest(chapter6.6)havebeenadded. In addition to the people thanked in the German and first and second English editions,theauthorwouldliketothankDr.VladimirGolubevandTomaszWitkow- ski (both LMU) for many inspired discussions concerning hydrocode calculations. The author is also indebted to and thanks Dr. Manuel Joas (DynITEC, Troisdorf, Germany)forhishelpwiththepreparationofchapters5.2and5.3. Munich,October2015 ThomasM.Klapötke https://doi.org/10.1515/9783110624571-205 Preface to the 2nd English edition Everything said in the preface to the first German and first English editions still holdsandessentiallydoesnotneedanyadditionorcorrection.Inthisrevisedsec- ond edition in English we have up-dated the manuscript and added some recent aspectsofenergeticmaterials: (i) We have tried to correct some mistakes which can not be avoided in a first editionandalsoupdatedthereferenceswhereappropriate. (ii) The chapters on Ionic Liquids, Primary Explosives, NIR formulations, Smoke CompositionsandHigh-NitrogenCompoundswereupdated. (iii)TwonewshortchaptersonCo-Crystallization(9.5)andFutureEnergeticMateri- als(9.6)havebeenadded. In addition to the people thanked in the German and first English edition, the authorwouldliketothankDr.JesseSabatiniandDr.KarlOyler(ARDEC,Picatinny Arsenal,NJ)formanyinspireddiscussionsconcerningpyrotechnics. Munich,May2012 ThomasM.Klapötke https://doi.org/10.1515/9783110624571-206