Chemistry of electronic ceramic materials

540 Pages·1991·31.4 MB·English

by  Davies, Peter K

United States Department of Commerce
National Institute of Standards and Technology
NIST
PUBLICATIONS
A111D3 M7flMSb
MSr Special Publication 804
Chemistry of Electronic Ceramic Materials
Peter K. Davies and Robert S. Roth, Editors
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1991
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NIST Special Publication 804
Chemistry of Electronic Ceramic Materials
Proceedings of the International Conference on
the Chemistry of Electronic Ceramic Materials,
August 17-22, 1990 held at Jackson, WY
Edited by
Peter K. Davies
University of Pennsylvania
Robert S. Roth
National Institute of Standards and Technology
Editorial Assistant
Mary A. Clevinger
National Institute of Standards and Technology
Sponsored by
NIST
NASA
ONR
DuPont
Idaho National Engineering Laboratory
University of Pennsylv£inia
January 1991
U.S. Department of Commerce
Robert A. Mosbacher, Secretary
National Institute of Standards and Technology
John W. Lyons, Director
National Institute of Standards U.S. Government Printing Office For sale by the Superintendent
and Technology Washington: 1991 of Documents
Special Publication 804 U.S. Government Printing Office
Natl. Inst. Stand. Technol. Washington, DC 20402
Spec. Publ. 804
513 pages (Jan. 1991)
CODEN: NSPUE2
PREFACE
The International Conference on the Chemistry of Electronic Ceramic Materials was
held at The Sojourner Inn, in the Teton Village, Jackson Hole, Wyoming from August
17-22, 1990. In an attempt to maximize the development of this rapidly moving,
multidisciplinary field, this conference brought together major national and international
researchers to bridge the gap between those primarily interested in the pure Chemistry
of Inorganic Solids and those interested in the Physical and Electronic Properties of
Ceramics. With the many major discoveries that have occurred over the last decade, one
of the goals of this meeting was to evaluate our current understanding of the Chemistry
of Electronic Ceramic Materials, and to assess the state of a field that has become one of
the most important areas of Advanced Materials Research.
The conference consisted of 18 extended invited lectures, 10 contributed oral
presentations, and 37 poster presentations. The meeting was attended by scientists from
a broad spectrum of fields based at universities, industries, and national laboratories.
Approximately one-third of the attendees were from outside the United States and
represented 10 different countries. In addition to the quality of the science, the meeting
was also memorable for the large number of family members who were able to attend,
resulting in many new friendships.
The scientific presentations covered many topics including new methods for the
synthesis of ceramics, the structures and properties of dielectric and ferroelectric
materials, crystal chemistry, surface chemistry, high-T^, superconductors, and theory and
modeling. The papers appearing in these proceedings provide an up-to-date review of
many aspects of these areas. For most of the oral presentations the discussions following
the paper were successfully transcribed. Edited versions appear in these proceedings after
each paper. In addtion to clarifying certain aspects of the material covered in the lecture,
the unedited comments, transcribed by a local court reporting service, also provided
considerable amusement for the editors and speakers.
The success of a meeting depends on many parameters ranging from the science to
the weather. One of the most important is sponsorship and support. For this we are
grateful to NIST, NASA, ONR, DuPont, the Idaho National Engineering Laboratory, and
the University of Pennsylvania. The smooth running of a meeting also depends upon
considerable work by those who often receive little recognition. In this respect we were
truly fortunate to have Mary Clevinger as our conference coordinator who has also
ensured that these proceedings appeared in an accurate form in a timely manner. We
would also like to thank Audrey Roth and Kathy Davies for organizing an outstanding
activities program for the many family members who attended the meeting. Thanks are
also due to Denice Gilbert, Nancy Dickinson, and Tony Kostick in the Materials Science
Department at Penn, who assisted in many typing duties and several tedious budgetary
matters.
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We hope that these proceedings will contribute to the development of the Chemistry
of Electronic Ceramic Materials and, judging from the enthusiastic response of all who
attended this meeting, we look forward to the Second International Conference sometime
in the not too distant future.
October 1990 Peter K. Davies (Univ. of Pennsylvania)
Robert S. Roth (NIST)
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TABLE OF CONTENTS
PREFACE
I. DIELECTRIC CERAMICS
CHEMICAL REACTION CONTROLLED MICROSTRUCTURES 3
AND PROPERTIES OF FERROELECTRIC CERAMICS (Invited)
D. Kolar
CHEMISTRY AND PROPERTIES OF TEMPERATURE 21
COMPENSATED MICROWAVE DIELECTRICS (Invited)
T. Negas, G. Yeager, S. Bell, and R. Amren
TUNABLE TRANSDUCERS: NONLINEAR PHENOMENA IN 39
ELECTROCERAMICS (Invited)
R. E. Newnham
STRUCTURAL AND ELECTRONIC PROPERTIES OF SOME 53
PEROVSKITES (Invited)
P. D. Battle
FERROELECTRIC AND FERROELASTIC DOMAIN STRUCTURES 67
IN PIEZOELECTRIC CERAMICS (Invited)
L. A. Bursill and P. JuLin
CATION SUBSTITUTION IN BARIUM TITANATE FOR 77
DIELECTRIC CERAMIC APPLICATIONS
F. Batllo, A. Beauger, B. Jannot, J. C. Jules, M. Laurent, M.
Maglione, and J. C. Niepce
LIQUID PHASE SINTERING OF LiF-FLUXED BaTiOa 85
S. F. Wang, W. Huebner, and C. Randall
A REAL SPACE ANALYSIS OF SHORT RANGE ORDER IN 93
FERROELECTRIC Pb(Mgi/3Nb2/3)03
H. D. Rosenfeld, T. Egami, and A. Bhalla
V
MECHANISM OF PNN BASED PEROVSKITE CERAMICS
FORMATION
Y. Sasaki, A. Nagai, and T. Yoshimoto
CONVENTIONALLY PREPARED SUBMICRON ELECTRO-
CERAMIC POWDERS BY REACTIVE CALCINATION
T. R. Shrout
LOW-TEMPERATURE SYNTHESIS AND CHARACTERIZATION
PREPARATION OF YBa2Cu307.5 FROM HOMOGENEOUS METAL
ALKOXIDE SOLUTION: SYNTHESES OF MIXED-LIGAND
COPPER (II) ALKOXIDES
D. M. Millar and D, A. Payne
MOLECULAR CHEMISTRY AND THE SYNTHESIS OF
PRECURSORS TO ELECTRONIC CERAMIC MATERIALS (Invited)
J. J. Ritter, J. F. Kelly, D. E. Newbury, and D. B. Minor
ION EXCHANGE REACTIONS OF LAYERED
PHOSPHATOANTIMONIC ACIDS: A ROUTE FOR NEW
CATALYSTS AND LUMINESCENT MATERIALS (Invited)
Y. Piffard
MIXED METAL OXIDES WITH THE PYROCHLORE STRUCTURE
AS CATALYSTS FOR METHANE OXIDATIVE COUPLING
(Invited)
A. J. Jacobson, L T. Lewandowski, C. A. Mims, R. B. Hall,
and G. R. Myers
SOFT CHEMICAL SYNTHESIS OF METASTABLE TITANIUM,
VANADIUM, AND MOLYBDENUM OXIDES
T. P. Feist and P. K. Davies
PRELIMINARY SOLID-STATE MULTINUCLEAR NMR OF
TITANIUM AND ZIRCONIUM OXIDE CERAMICS AND
PRECURSORS
J. J. Fitzgerald, S. S. Han, S. F. Dec, M. F. Davis, C. E.
Bronnimann, and G. E. Maciel
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POLYMERIC SYNTHESIS OF PEROVSKITE POWDERS AND 179
FILMS
H. U. Anderson, M. M. Nasrallah, F. D. Blum, and M. S.
Smith
ELECTRODEPOSITION OF NANOMODULATED ELECTRONIC 185
CERAMIC THIN FILMS
J. A. Switzer
III. SOLID-STATE SYNTHESIS AND CHARACTERIZATION
PROPERTIES OF SOME MIXED URANIUM OXIDES 195
P. G. Dickens, A. V. Powell, and G. P. Stuttard
INVESTIGATIONS ON THE STRUCTURAL, ELECTRICAL AND 207
MAGNETIC PROPERTIES OF Nd2.xM^Ni04+5, M = Ca^+ and Ba^+
B. W, Arbuckle, Z. Zhang, and M. Greenblatt
SYNTHESIS AND CHARACTERIZATION OF La^^SfJiOa
(0<x<0.05) 217
S. M. Kauzlarich, J. E. Sunstrom, IV, and P. Klavins
SYNTHESIS AND CHARACTERIZATION OF PHASES IN THE
SYSTEM Ba-Au-Ag-02 225
R. S. Roth, C. J. Rawn, and M. D. Hill
STRUCTURE AND PROPERTIES OF REDUCED EARLY
TRANSITION METAL OXIDE SINGLE CRYSTALS GROWN 237
FROM BORATE FLUXES
S. A. Sunshine, B. Hessen, T. Siegrist, A. T. Fiory, and J. V.
Waszczak
THE KINETICS AND MECHANISM OF THE CRYSTALLIZATION
OF Mg2Al4Si50i8 FROM MgAl204 AND Si02 IN THE PRESENCE 245
OF A BISMUTH OXIDE FLUX
R, W. Dupon, A. C. Tanous, and M. S. Thompson
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IV. CRYSTAL CHEMISTRY
SOLID STATE CHEMISTRY OF PEROVSKITE AND RELATED
OXIDES CONTAINING Fe^^, Ni^+, and Cu^^ (Invited)
M. Takano
IMPURITY INCORPORATION MECHANISMS IN LiNbOj
D. P. Birnie, III
ALKALINE EARTH NITRIDES AND HYDRIDES
N. E. Brese
OXYGEN DIFFUSION IN Y2O3-CONTAINING TETRAGONAL
ZIRCONIA POLYCRYSTALS (Y-TZP)
Y. Ikuma
A STRUCTURAL BASIS FOR THE DIFFERENT DIRECTIONS OF
OXYGEN NONSTOICHIOMETRY IN La2Cu04 AND Nd2Cu04
D. J. L. Hong and D. M. Smyth
RUDDLESDEN-POPPER PHASES A„+iM„03„+i: STRUCTURES
AND PROPERTIES
J. S. Kim, J. Y. Lee, J. S. Swinnea, H. Steinfmk, W. M. Reiff,
P. Lightfoot, S. Pei, and J. D, Jorgensen
V. SUPERCONDUCTORS
MICROSTRUCTURES IN HIGH TEMPERATURE
SUPERCONDUCTORS (Invited)
H. W. Zandbergen
CRYSTAL CHEMISTRY OF OXIDE SUPERCONDUCTORS
(Invited)
A. W. Sleight
OUT OF PLANE DISPLACEMENTS OF OXYGEN FROM THE
CUO2 SHEETS IN Ca ^^St 15CUO2 BY ATOM-PAIR DISTRIBUTION
FUNCTION ANALYSIS
S. J. L. Billinge, P. K. Davies, and T. Egami
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