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Chemistry and Modern Society. Historical Essays in Honor of Aaron J. Ihde PDF

210 Pages·1984·2.7 MB·English
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1 0 0 w 8.f 2 Chemistry and Modern Society 2 0 4- 8 9 1 k- b 1/ 2 0 1 0. 1 oi: d 4 | 8 9 1 3, 2 st u g u A e: at D n o ati c bli u P In Chemistry and Modern Society; Parascandola, J., el al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1984. 1 0 0 w 8.f 2 2 0 4- 8 9 1 k- b 1/ 2 0 1 0. 1 oi: d 4 | 8 9 1 3, 2 st u g u A e: at D n o ati c bli u P In Chemistry and Modern Society; Parascandola, J., el al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1984. Chemistry and Modern Society Historical Essays in Honor of Aaron J. Ihde John Parascandola, EDITOR University of Wisconsin James C. Whorton, EDITOR 1 00 University of Washington w 8.f 2 2 0 4- 8 9 1 k- b 1/ 2 0 1 0. 1 oi: d 4 | 8 9 1 3, 2 st u g u A e: at D n o ati c bli u P 228 ACS SYMPOSIUM SERIES AMERICAN CHEMICAL SOCIETY WASHINGTON, D. C. 1983 In Chemistry and Modern Society; Parascandola, J., el al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1984. Library of Congress Cataloging in Publication Data Chemistry and modern society. (ACS symposium series, ISSN 0097-6156;228) Bibliography: p. Includes index. 1 1. Chemistry—History—Congresses. 2. Ihde, Aaron 0 0 John, 1909- . I. Ihde, Aaron John, 1909- . II. Para- w 28.f sIVca. nAdmolear,i cJaonh Cn.h eImIIi.c aWl Shoocrietotyn., VJa. mSeersi,e s1. 942- 2 84-0 QISDB1N5 .C0-4864 12-0791598-X3 306'.45 83-11740 19 ISBN 0-8412-0803-4 (pbk) k- b 1/ 2 0 1 0. 1 oi: d 4 | 8 9 1 3, 2 st Copyright © 1983 u g u A American Chemical Society e: Dat All Rights Reserved. The appearance of the code at the bottom of the first page of each n article in this volume indicates the copyright owner's consent that reprographic copies of catio tshpeec aifritci ccleli emnatsy. bTeh ims acdone sfeonrt piesr sgoivneanl oorn i nthteer ncaoln udsiteio onr, fhoorw tehvee rp,e rthsoant atlh oe rc ionpteierrn apla uys eth oef bli stated per copy fee through the Copyright Clearance Center, Inc. for copying beyond that Pu permitted by Sections 107 or 108 of the U.S. Copyright Law. This consent does not extend to copying or transmission by any means—graphic or electronic—for any other purpose, such as for general distribution, for advertising or promotional purposes, for creating new collective work, for resale, or for information storage and retrieval systems. The copying fee for each chapter is indicated in the code at the bottom of the first page of the chapter. The citation of trade names and/or names of manufacturers in this publication is not to be construed as an endorsement or as approval by ACS of the commercial products or services referenced herein; nor should the mere reference herein to any drawing, specification, chemical process, or other data be regarded as a license or as a conveyance of any right or permission, to the holder, reader, or any other person or corporation, to manufacture, reproduce, use, or sell any patented invention or copyrighted work that may in any way be related thereto. PRINTED IN THE UNITED STATES OF AMERICA In Chemistry and Modern Society; Parascandola, J., el al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1984. ACS Symposium Series M. Joan Comstock, Series Editor 1 0 0 w 8.f 2 2 4-0 Advisory Board 8 9 1 k- David L. Allara Robert Ory b 1/ 2 0 1 Robert Baker Geoffrey D. Parfitt 0. 1 doi: Donald D. Dollberg Theodore Provder 4 | 8 19 Brian M. Harney Charles N. Satterfield 3, 2 ust W. Jeffrey Howe Dennis Schuetzle g u A e: Herbert D. Kaesz Davis L. Temple, Jr. at D n o Marvin Margoshes Charles S. Tuesday ati c ubli Donald E. Moreland C. Grant Willson P In Chemistry and Modern Society; Parascandola, J., el al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1984. FOREWORD 1 0 0 w The ACS SYMPOSIUM SERIES was founded in 1974 to provide 8.f a medium for publishing symposia quickly in book form. The 2 2 4-0 format of the Series parallels that of the continuing ADVANCES 98 IN CHEMISTRY SERIES except that in order to save time the 1 k- papers are not typeset but are reproduced as they are sub b 21/ mitted by the authors in camera-ready form. Papers are re 0 0.1 viewed under the supervision of the Editors with the assistance 1 oi: of the Series Advisory Board and are selected to maintain the 4 | d integrity of the symposia; however, verbatim reproductions of 98 previously published papers are not accepted. Both reviews 1 3, and reports of research are acceptable since symposia may 2 st embrace both types of presentation. u g u A e: at D n o ati c bli u P In Chemistry and Modern Society; Parascandola, J., el al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1984. 1 0 0 pr 8. 2 2 0 4- 8 9 1 k- b 1/ 2 0 1 0. 1 oi: d 4 | 8 9 1 3, 2 st u g u A e: at D n o ati c bli u P Professor Ihde in his office at the University of Wisconsin about 1964 viii In Chemistry and Modern Society; Parascandola, J., el al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1984. PREFACE A.ARON IHDE'S CONTRIBUTIONS to our understanding of the evolution of chemistry are remarkable nearly as much for their breadth as for their quantity and quality. This volume originated in a desire to honor the dean of American 1 historians of chemistry, Aaron J. Ihde, at the time of his retirement from 0 pr0 the University of Wisconsin faculty in 1980. From the beginning, how 28. ever, the editors were determined to avoid the typical "Festschrift" volume 2 4-0 consisting of a collection of papers on miscellaneous subjects held to 8 9 gether only by the association of the authors as students or colleagues of 1 k- the honorée. Convinced that a book of essays with a central unifying b 21/ theme would be a more valuable contribution to the literature we strove 0 0.1 to achieve that objective. More as a result of chance than editorial wisdom, 1 oi: we have succeeded to a greater extent than we originally dared hope. 4 | d The result is this publication on "Chemistry and Modern Society". 98 A bibliography of Idhe's contibutions (see appendix) which ranges 1 3, from Boyle's definition of the element to the establishment of food stan 2 st dards, from Paracelsus to pesticides, reflects something more than Idhe's u ug extra-ordinary curiosity. It expresses a rich appreciation of the insepa A e: rability of theoretical and technical progress in chemistry, and of the Dat participation of each in intellectual and social history. That last topic, the on impact of chemistry on its social environment, has long been a special cati interest of Professor Ihde's, and he and his students have made significant ubli contributions to the literature on this subject. Indeed, his chief work, P "The Development of Modern Chemistry," opens with the announce ment that one of its purposes is to provide "an object lesson of the role of pure science in the development of technology, agriculture, and med icine." Subsequent chapters fulfill that promise, exploring chemistry's influence on western society's transformation from an agricultural to a high-technology industrial base with more thorough and up-to-date cov erage than any other broad survey of chemical history. The purpose of the present volume is to modestly offer in tribute a few additional object lessons illuminating chemistry's diverse roles in modern civilization, fo cusing especially on the American scene. ix In Chemistry and Modern Society; Parascandola, J., el al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1984. The theme of Professor Ihde's Dexter Award address, the formation of hybrid sciences, is extended by an analysis of the conceptual origins of geochemistry. This analysis reveals how the maturation of physical chemistry in the late nineteenth century provided access to the internal dynamics of geological processes and spawned a new specialty in which American scientists took the lead. A more pragmatic application of chem­ istry to geological deposits (and one having renewed relevance of late) is examined in a detailed study of the history of the production of synthetic petroleum from coal. Petroleum synthesis, of course, has been largely an exercise in chemical engineering, another hybrid discipline. A crucial stage in that profession's conceptual development is dealt with in a dis­ 01 cussion of the early twentieth century utilization of the notions of unit 0 pr operations and unit processes. 8. 22 Another area in which chemistry has had an important impact on 0 4- modern society is in the field of health. Professor Ihde has been a major 8 9 1 contributor to the history of nutritional biochemistry, and hence it is k- b appropriate that this volume includes a paper dealing with the early his­ 1/ 02 tory of vitamin research. A somewhat different merger between chem­ 1 0. istry and the health sciences has been the pursuit of pharmaceutical in­ 1 oi: vestigation, an activity that, however thriving now, at first took fre­ d 4 | quently halting steps. The checkered fortunes of Charles Holmes Herty 8 9 are striking testimony to the difficulties of organizing sophisticated drug 1 3, research in the 1920s. 2 ust The mention of drug research is a reminder that the career of chem­ g Au istry has been checkered during the twentieth century. The term "drug e: therapy" is nearly as likely to trigger the response "thalidomide" as to at D make one think of penicillin. As the side effects of chemical progress n atio have become more apparent, the whole science has come to be regarded blic as the great benefactor as well as the great despoiler, a symbol of modern Pu society's paradox of unprecedented prosperity shadowed by the potential for unparalleled devastation. "The Development of Modern Chemistry" concludes on just such a note, with the ominous injunction that although chemistry "can still do much for mankind," it "can also be his undoing." The double-edged action of chemistry on society is the minor theme run­ ning through this volume. The 1937 Elixir Sulfanilamide tragedy, for ex­ ample, serves as a dramatic backdrop for a presentation of the vicissi­ tudes affecting drug regulation, while the establishment of standards for synthetic food colors demonstrates the uncertainties confounding the po­ licing of substances of significant economic value but indeterminate tox­ icity. Diet has been contaminated by chemical theory as well. Food fads such as the uric acid fetish have been legitimized in practitioners' minds χ In Chemistry and Modern Society; Parascandola, J., el al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1984. by self-serving distortions of biochemical principles. Finally, chemistry has altered the face of war in the twentieth century, as exemplified by the production of toxic gases for use in World War I. The interface between chemistry and society refuses to be drawn in such neat lines as good and bad, however. The search for chemical war fare agents popularized the method of project research that would be used so fruitfully in peacetime investigations. The ravages of Elixir Sul fanilamide provoked the present stricter food and drug legislation. These case studies suggest some of the complexity, as well as the diversity, of chemistry's influence on modern civilization. 1 JOHN PARASCANDOLA 0 0 pr University of Wisconsin 28. Madison, Wisconsin 2 0 4- 8 9 JAMES WHORTON 1 k- b University of Washington 1/ 2 Seattle, Washington 0 1 0. 1 oi: March 18, 1983 d 4 | 8 9 1 3, 2 st u g u A e: at D n o ati c bli u P xi In Chemistry and Modern Society; Parascandola, J., el al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1984.

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Content: Introduction / Aaron J. Ihde -- The intellectual basis of specialization : geochemistry in America, 1890-1915 / John W. Servos -- Synthetic petroleum from high-pressure coal hydrogenation / Anthony N. Stranges -- From unit operations to unit processes : ambiguities of success and failure in
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