Chemical Thermodynamics of Tin - Volume 12 - Nuclear Energy Agency

646 Pages·2013·7.16 MB·English

C T
HEMICAL HERMODYNAMICS
T
OF IN

Heinz GAMSJÄGER (Chair)
Lehrstuhl für Physikalische Chemie
Montanuniversität Leoben
Leoben (Austria)
Tamás GAJDA James SANGSTER
Department of Inorganic and Sangster Research Laboratories
Analytical Chemistry Montreal (Canada)
University of Szeged
Szeged (Hungary)

Surendra K. SAXENA Wolfgang VOIGT
Center for Study of Matter Institut für Anorganische Chemie
at Extreme Conditions TU Bergakademie Freiberg
Florida International University Freiberg (Germany)
Miami (United States)

Edited by
Jane Perrone (Project Co-ordinator and Volume Editor)
OECD Nuclear Energy Agency, Data Bank
Issy-les-Moulineaux (France)
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CHEMICAL THERMODYNAMICS

Vol. 1. Chemical Thermodynamics of Uranium, Wanner, H., Forest, I., OECD Nuclear
Energy Agency Data Bank, Eds., North Holland Elsevier Science Publishers B. V.,
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Holland Elsevier Science Publishers B. V., Amsterdam, The Netherlands, (2003).
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Eds., North Holland Elsevier Science Publishers B. V., Amsterdam, The Netherlands,
(2005).
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Bank, Eds., North Holland Elsevier Science Publishers B. V., Amsterdam, The
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Vol. 8. Chemical Thermodynamics of Zirconium, OECD Nuclear Energy Agency Data
Bank, Eds., North Holland Elsevier Science Publishers B. V., Amsterdam, The
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Zr, Ni and Se with selected organic ligands, OECD Nuclear Energy Agency Data Bank,
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Bank, Eds., OECD Publications, Paris, France, (2008).

CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012

Preface

This volume is the 12th in the “Chemical Thermodynamics” series edited and produced
by the OECD Nuclear Energy Agency (NEA). It is a critical review of the
thermodynamic properties of tin, its compounds and aqueous complexes, initiated by
the Management Board of the NEA Thermochemical Database Project Phase III (NEA
TDB III). The European members of the TDB Sn Review Team − Wolfgang Voigt
(Freiberg University of Mining and Technology, Germany), Tamás Gajda (University
of Szeged, Hungary) and Heinz Gamsjäger as Chairman (Montanuniversität Leoben,
Austria) − first met at the NEA in Issy-les-Moulineaux (France) in September 2004. The
overseas members − Surendra K. Saxena (Florida International University, Miami,
United States) and James Sangster (Sangster Research Laboratories, Montreal, Canada)
participated in this kickoff meeting via phone and video link. Four subsequent plenary
meetings took place at the NEA in March 2005, October 2005, March 2006 and October
2006. The latter was held in conjunction with the TDB III Executive Group Meeting on
25 October and the TDB III Management Board Meeting on 26-27 October 2006. In
these meetings the Review Team reported that key values on Sn4+ formation and the
redox couple Sn4+/Sn2+ were lacking. Moreover, essential formation data on Sn(IV)
chlorido and hydroxido complexes were also lacking. Therefore the Review Team
submitted a proposal to the Management Board requesting to fund an experimental
programme to obtain values for the most important critical data, while the already
completed sections dealing with solids and gases were sent to peer review. The
Management Board agreed and the experimental investigation was carried out under the
leadership of Tamás Gajda at the University of Szeged Department of Inorganic and
Analytical Chemistry. From 7 to 10 August 2008 the solution chemistry group
comprising Wolfgang Voigt, Tamás Gajda and Heinz Gamsjäger met at
Montanuniversität Leoben to include the results of the experimental study in the tin
draft. The publication of these results, mandatory by NEA standards for including new
data in chemical thermodynamics volumes, appeared in 2009. Heinz Gamsjäger
presented these results at the meeting of the TDB IV Executive Group on 19 May 2010
in Karlsruhe.
Hans Wanner participated in meetings of the Review Team as the designated
member of the Executive Group until he retired from this position in 2007. At the NEA
Data Bank the responsibility for the overall co-ordination of the project was placed with
Federico Mompean (from its initiation in 2004 to 2007), with Mireille Defranceschi
(2008 to 2010) and Jane Perrone (2011). Jane Perrone was in charge of the preparation
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
vi Preface
of the successive drafts, updating the NEA Thermodynamic Database and editing the
book in its present final form.
Primary responsibility for the different chapters was divided as follows. James
Sangster and Surendra Saxena assessed the thermodynamic properties of solid and
gaseous compounds, while Wolfgang Voigt, Tamás Gajda and Heinz Gamsjäger were
in charge of the aqueous chemistry. Surendra Saxena drafted the sections on solid
oxides, hydrides, halides, pnictides and selected minerals. James Sangster prepared the
sections on elemental tin, gaseous compounds of all groups and solid compounds not
treated by Surendra Saxena. Tamás Gajda drafted the sections on hydrolysis of Sn(II)
and Sn(IV) and the sections on aqueous Sn(II) and Sn(IV) complexes. Wolfgang Voigt
prepared the sections on solubilities of all groups. The chairman drafted the sections on
simple aqua ions and those on solubilities of Sn(II) as well as Sn(IV) oxides and
hydroxides. The key values for Sn(IV) which were lacking prompted close co-operation
of the solution chemistry group. This contributed favourably to the final solution of the
problem and to the quality of the solution chemistry section.
It is worth noting that the selection of key values, e.g., for Sn2+, revealed gaps
in our knowledge which may stimulate rewarding projects on the experimental
thermodynamics of tin compounds.

Leoben, Austria, May 2012 Heinz Gamsjäger, Chairman

CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
Acknowledgements

For the preparation of this book, the authors have received financial support from the
NEA TDB Phase III Project. The following organisations take part in the project:
ONDRAF/NIRAS, Belgium
NWMO, Canada
RAWRA, Czech Republic
POSIVA, Finland
ANDRA, France
CEA, France
KIT, Germany
JAEA, Japan
ENRESA, Spain
SKB, Sweden
SKI, Sweden
ENSI, Switzerland
NAGRA, Switzerland
PSI, Switzerland
NDA, United Kingdom
DoE, United States

Heinz Gamsjäger would like to express his gratitude to the Lehrstuhl für
Physikalische Chemie of the Montanuniversität Leoben for having provided the
infrastructure necessary for his contributions to this project. Tamás Gajda gratefully
acknowledges the technical support of the Department of Inorganic and Analytical
Chemistry at the University of Szeged.
The authors thank the TDB III Management Board for funding the
experimental programme which enabled them to determine the standard potential of the
Sn4+/Sn2+ couple which thermodynamically links Sn(II) and Sn(IV) chemistry. Heinz
Gamsjäger greatly appreciates Robert Lemire’s continuous willingness to share his
expertise and to give invaluable advice in all TDB review matters.
The unceasing efforts of Federico Mompean are greatly appreciated. He acted
as co-ordinator for the TDB Sn project during the time the first version of this book was
assembled and drafted and the part on solid and gaseous compounds of tin was edited
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
viii Acknowledgements
for peer review. The authors are also indebted to Mireille Defranceschi who succeeded
in the position as co-ordinator from 2008 to 2010. A special acknowledgement goes to
Jane Perrone who accompanied the evolution of the tin review from start to finish as
volume editor and finally as series editor and project co-ordinator. She provided a
pleasant working climate at TDB Sn meetings and harmonised several author
contributions, prepared in many different formats, with admirable alertness and
scientific competence.
The entire manuscript has undergone a peer review by an independent,
international group of reviewers, according to the procedures in the TDB-6 Guideline,
available from the NEA. The peer reviewers have seen and approved the modifications
made by the authors in response to their comments. The peer review comment records
may be obtained on request from the NEA. The peer reviewers were Prof. Erik Rosén,
University of Umeå, Sweden for the section on solid and gaseous compounds of tin and
Prof. Willis Forsling, University of Luleå, Sweden for the section on solution chemistry.
Their valuable contributions to this review are gratefully acknowledged.

CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012