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1069 Pages·2017·33.08 MB·English
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Springer Aerospace Technology Luigi De Luca Toru Shimada Valery P. Sinditskii Editors Max Calabro Chemical Rocket Propulsion A Comprehensive Survey of Energetic Materials Springer Aerospace Technology Moreinformationaboutthisseriesathttp://www.springer.com/series/8613 Luigi T. DeLuca • Toru Shimada Valery P. Sinditskii • Max Calabro Editors Chemical Rocket Propulsion A Comprehensive Survey of Energetic Materials 123 Editors LuigiT.DeLuca ToruShimada SpacePropulsionLaboratory(SPLab) InstituteofSpaceandAstronautical DepartmentofAerospaceScience Science(ISAS) andTechnology JapanAerospaceExploration PolitecnicodiMilano Agency(JAXA) Milan,Italy Sagamihara,Japan ValeryP.Sinditskii MaxCalabro DepartmentofChemicalEngineering TheInnerArch MendeleevUniversity Poissy,France ofChemicalTechnology Moscow,Russia ISSN1869-1730 ISSN1869-1749 (electronic) SpringerAerospaceTechnology ISBN978-3-319-27746-2 ISBN978-3-319-27748-6 (eBook) DOI10.1007/978-3-319-27748-6 LibraryofCongressControlNumber:2016941937 ©SpringerInternationalPublishingSwitzerland2017 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpartof thematerialisconcerned,specificallytherightsoftranslation,reprinting,reuseofillustrations,recitation, broadcasting,reproductiononmicrofilmsorinanyotherphysicalway,andtransmissionorinformation storageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilarmethodology nowknownorhereafterdeveloped. Theuseofgeneraldescriptivenames,registerednames,trademarks,servicemarks,etc.inthispublication doesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexemptfromtherelevant protectivelawsandregulationsandthereforefreeforgeneraluse. Thepublisher,theauthorsandtheeditorsaresafetoassumethattheadviceandinformationinthisbook arebelievedtobetrueandaccurateatthedateofpublication.Neitherthepublishernortheauthorsor theeditorsgiveawarranty,expressorimplied,withrespecttothematerialcontainedhereinorforany errorsoromissionsthatmayhavebeenmade. Printedonacid-freepaper ThisSpringerimprintispublishedbySpringerNature TheregisteredcompanyisSpringerInternationalPublishingAGSwitzerland Preface This book deals with energetic materials and their application to chemical rocket propulsionasinitiallydiscussedatthe12thIWCPtitled“NewEnergeticMaterials for Space Exploration.” This event was held at Politecnico di Milano (PoliMi), Campus Bovisa, Milan, Italy, 9–10 June 2014 and was attended by about 200 participantsfrom20countries.Intotal,37technicalpaperswereoffered,including 28 oral presentations and 9 poster papers. The Workshop was a unique gathering and opportunity, where participants could freely discuss the future of chemical rocketpropulsionforaccess to,andexplorationof,space.Distinguishedscientists andpropulsionengineersfromacademia,government,andindustrywereinvitedto attend.TheofficialGroupPhotooftheMilanWorkshopisshownasFig.1. This book includes selected technical papers of high-quality presented at the Workshop, with several additional papers invited from the relevant international scientific community. All papers were accepted for publication only after passing a careful and severe peer review process by two to five anonymous international experts, according to the same comprehensive procedures employed by the most qualifiedarchivalpublications.EveryprintedpaperhasaDOIreference.Therefore, this volume should not be considered an unfiltered collection of conference proceedings but rather an advanced supplemental reading for graduate students, lecturers,researchers,andscientistsinacademiaorresearchcenters,engineers,and industrialists. TheInternationalWorkshoponCombustionandPropulsion(IWCP)serieswas started in 1990 by the Space Propulsion Laboratory (SPLab) of Politecnico di Milano as an attempt to bridge the gap between researchers of the Eastern and Western blocs, which were until that time rigidly separated, in the broad areas of combustionapplicationsforpropulsionandrocketpropulsion.Convenientlylocated betweenthetwobigcountries,Italyhaskeptcommunicationchannelsopenbetween AmericanandRussianscientists,evenduringthehardtimesofglobalcompetition. The IWCP series intends to promote free technical discussion and knowledge exchangein a relaxedatmosphere.Themeetingformatwas builtin orderto favor detailed discussions among leading international researchers on selected areas of interest, rather than formal presentations of final results by registered authors on v vi Preface a wide range of topics. Plenary Lectures by outstanding speakers are meant to offeracriticalsurveyofspecificthemesandpavethewaytodetailedcontributions from the authors as well as general discussions within the audience. For quality assurance, participation of lecturers/speakers/observers is normally restricted to a small number of invited people internationally selected for their demonstrated technical competence but also innovative vision or provocative approach. Serious effortsaremadetoensurethattheresultsarereadilyandeasilyavailabletoawide rangeofinternationalreaders,andtheleveloftechnicalaccuracyatallstages,from paperpresentationstowrittendiffusionofresults,issetatthehighestprofessional standards. Although some of these features may have been diluted or adapted during the years,thebasicflavorhasbeenkept.Theattendanceofworldwiderenownedauthors inthemeetingsandtimelinessoftopicscontainedintheIWCPcollectionofevents prove the effectiveness and success of the series in advancing energetic material combustionandrocketpropulsionunderstanding. The 12th IWCP addressedthe currentstatus in the field of energeticmaterials, from the viewpointboth of formulationand related topics from rocketpropulsion to other applications. The workshop also looked for inspiring perspectives in a number of areas related to the energetic materials specifically used in chemical rocketpropulsion. Subsequently,thebookwill: • Surveythecurrentinternationalstatusofenergeticmaterialsforpropulsion • Identifynewpromisingingredientsfornovelenergeticmaterialsformulation • Provide an insight into powerful new energetic formulations under study at world-wideadvancedlaboratories • ProvidesomerarelyaccessibleinformationfromRussianandChinesesources • Recommend future directions for a wide range of themes, from chemical propulsiontoapplications,resortingtoenergeticmaterials • Offer the advantage of a common source for several topics treated in the book butscatteredintheopenliterature • Discuss little-known propulsion topics such as gel propulsion, catalytic tech- niques,andnanosizedingredients Thebookismeanttoofferacomprehensivesurveyofchemicalrocketpropulsion from the energetic materials viewpoint. Thus, the whole “life-cycle” of energetic materialsiscovered:fromtheirconceptualformulationtopracticalmanufacturing, includingtheoreticalandexperimentalballisticsaswellasperformanceproperties, laboratory-scale and full system-scale, management (handling, storage, ageing, hazards,impact,disposal,remediation),andsoon.Eachofthechaptersshallfocus ononeofmainaspects,withouthoweveroverlookingpossibleinteractionswiththe remaining issues. All topics are considered from a broad international viewpoint. In order to offer readers a comprehensivesurvey of currenttechnical problems, a fineselectionofaccomplishedexpertsfromthepioneeringeraofspacepropulsion Preface vii as well as of current technologists from some of the most advanced international laboratorieswasputtogetherandagreedtosupportthiseditorialinitiative. The whole collection of 45 accepted papers is structured in the following 11 bookchapterswithacommontargetof“advancingchemicalpropulsionsystemsby addressingallaspectsofpropellants”(asexpressedbyananonymousreviewer). Thebookisopenedbyacollectiveintroductorychapterthatprovidesaconsistent theme for the volume and shows how distinctly different chapters fit into this themeandcooperatetoreachacommonfinalgoal.Suchchapterwasassembledby collectingwell-focusedessaysbyinternationallyrecognizedexpertsinthecovered area, who briefly introduce each chapter. This introductory chapter will also help inarousingtheinterestofpotentialreadersandwillhopefullypromptthemtolook intoindividualchaptersorpapers. It is our great pleasure to thank the following international reviewers for their substantial help in raising the quality of the book. Without their efforts, the publicationofthisvolumewouldhavebeenimpossible: ShaliniAnand,HiroshiAoki,HiroyaAsakawa,ValeryA.Babuk,M.Balduccini, Yann Batonneau, L. Boccaletto, Manfred A. Bohn, Ch. Bonhomme, Ch. Bonnal, Max Calabro, Leonard H. Caveny, S. Mary Celin, N. Cesco, Helmut Ciezki, Adam S. Cumming, B. D’Andrea,E. D’Aversa, W.P.C. de Klerk, Luigi T. DeLuca, Y. Fabignon, Go Fujii, Luciano Galfetti, S. Gallier, A. Gany, N.G. Glumac, T.I.Gorbenko,J.F.Guéry,DietrichHaeseler,OskarJ.Haidn,StephenD.Heister, Keiichi Hori, N. Ierardo, Charles Kappenstein, Arif Karabeyog˘lu, Thomas M. Klapötke, M.J. Klopfstein, A. Korotkikh, Bernard M. Kosowski, C.J. Lee, David Lempert,FilippoMaggi,AnthonyP.Manzara,K.Menke,HarunoriNagata,Ichiro Nakagawa,BenvenisteNatan,A.Neri,J.Neutz,O.Orlandi,BryanA.Palaszewski, D.Pavarin,WeiQiangPang,P.Pempie,AllaN.Pivkina,S.Peters,S.Petitot,Sergey A.Rashkovskiy,TakashiSakurai,KeisukeSawada,H.Schöyer,ToruShimada,Y.J. Shu,IrinaL.Simakova,ValeryP.Sinditskii,HaridwarSingh,V.I.Trushlyakov,Ruth Tunnell,D.Yagodnikov,N.Wingborg,Q.L.Yan,VladimirE.Zarko,FengQiZhao. In addition, the technical language of many non-native English authors was polished by Dr. Adam S. Cumming, Dr. Anthony P. Manzara, Mr. Bryan A. Palaszewski,andDr.RuthTunnell,whodeservespecialthanksfortheirpatientand generousassistanceinthephaseofpaperrevision.We wouldalsoliketothankall the authors for their paper contribution and collaboration in following the format specified by SpringerInternationalPublishingAG. Finally, special thanksare due toMs.CharlotteCrossforhercontinuousassistanceinthemanypublishingissues wehadtoface. Furtherhigh-qualitypresentationsweremadeattheWorkshopbyI.G.Assovskiy (SemenovInstituteofChemicalPhysics,Russia),P.Bellomi(Avio,Italy),E.Bucci (Avio, Italy), Helmut Ciezki (DLR, Germany), Charles Kappenstein (University of Poitiers, France), Bernard M. Kosowski (MACH I, USA), K.K. Kuo (Pennsyl- vania State University, USA), Z. Mansurov (Institute of Combustion Problems, Kazakhstan), M. Persson (ECAPS, Sweden), S. Schlechtriem (DLR, Germany), viii Preface and N. Wingborg (FOI, Sweden). Unfortunately, these contributions could not be included in the book, but the authors are greatly thanked for their active participation. In addition to the several chapter authors listed in the Table of Contents,furthershortcontributionswereprovidedbyDr.ChaoyangZhang(China AcademyofEngineeringPhysics,Mianyang,Sichuan,China),Dr.QinghuaZhang (ChinaAcademyofEngineeringPhysics,Mianyang,Sichuan,China),andDr.Hao Feng(Xi’anModernChemistryResearchInstitute,Xi’an,Shaanxi,China). ThisbookwasstartedatPolitecnicodiMilano,Milan,Italy,byoneoftheeditors (Luigi T. DeLuca), continued after his retirement at Konkuk University, Seoul, Korea, and finally completed at Nanjing University of Science and Technology, Nanjing, China. Sincere thanks are due to both Konkuk University and Nanjing UniversityofScienceandTechnologyforprovidinganexcellentatmosphereandall neededprofessionalsupport.ThisopportunityistakentothankalsoMs.I.Palmucci, Mr.D.Trache,Dr.WeiQiangPang,andMr.GiovanniColombofortheirvaluable andcontinuousassistanceduringtheentireWorkshoporganizationandconduction. Wesincerelywishthatthisjointinternationaleffortwillhelpallreaderstogain abetterunderstandingofthepuzzlingintricaciesandappealingsecretsofenergetic materials as well as of the perplexing difficulties but also fascinating horizons of spacepropulsion! Sicituradastra(Virgil,AeneidBookIX,line641,19BC) 30September2015 TheVolumeCo-Editors Milan,Italy LuigiT.DeLuca Sagamihara,Japan ToruShimada Moscow,Russia ValeryP.Sinditskii Poissy,France MaxCalabro Preface ix 4 1 0 2 e n u J 0 1 – 9 y, al It n, a Mil a, s vi o B s u p m a C Mi, oli P p, o h s k or W P C W I h 2t 1 o ot h P p u o Gr 1 g. Fi

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