Characterization of porous solids II: proceedings of the IUPAC Symposium, COPS II, Alicante, Spain, May 6-9, 1990

797 Pages·1991·8.889 MB·English

by  F. Rodriguez-Reinoso, J. Rouquerol, K. S. W. Sing, K. K. Unger

Studies in Surface Science and Catalysis 62
CHARACTERIZATION OF POROUS SOLIDS II
This Page Intentionally Left Blank
Studies in Surface Science and Catalysis
Advisory Editors: B. Delmon and J.T. Yates
Vol. 62
CHARACTERIZATION OF
POROUS SOLIDS II
Proceedingso f the IUPAC Symposium (COPS 11). Alicante, Spain,
May 6- 9,1990
Editors
F. Rodriguez-Reinoso
Departamento de Quimica lnorgdnica e Ingenieria Quimica, Universidad de
Alicante, Apartado 99, Alicante, Spain
J. Rouquerol
Centre de Thermodynamiquee t de Microcalorimetrie, CNRS, 7 3003 Marseille,
France
K.S.W. Sing
Department of Chemistry, Brunel University, Uxbridge, Middlesex UB8 3PH,
U.K .
and
K.K. Unger
lnstitut fur Anorganische Chemie und Analytische Chemie, Johannes
Gutenberg-Universitat,0 -6500M ainz, F. R. G.
- - -
ELSEVIER Amsterdam Oxford New York Tokyo 1991
ELSEVIER SCIENCE PUBLISHERS B.V.
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Library of Congress Cataloging-in-Publication Data
IUPAC Symposium. COPS (2nd : 1990 : Alicante. Spain)
Characterization of porous solids I1 : proceedings of the IUPAC
Symposium, COPS 11. Alicante. Spain. May 6-9. 1990 I editors, F.
Rodriguez-Reinoso ... [et al.1.
p. cm. -- (Studies in surface science and catalysis ; 62)
Includes bibliographical references and indexes.
ISBN 0-444-88569-2
1. Porous materials--Congresses. I. Rodrjguez-Reinoso. F., 1941-
11. International Union of PGre and Applied Chemistry. 111. Title.
IV. Title. Characterization of porous solids 2. V. Title:
Characterization of porous solids two. VI. Series.
TA418.9.P6196 1990
620.1'16--d~20 91 - 10354
C1P
ISBN 0-444-88569-2
0 Elsevier Science Publishers B.V., 199 1
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V
CONTENTS
Preface XI11
Characterization of porous solids: an introductory survey
K.S.W. Sing 1
Simulation of adsorption in model microporous graphite
D. Nicholson 11
Theory of adsorption in micropores
Z. Tan and K.E. Gubbins 21
Sorption of gases on microporous solids: pore size characterization by
gas sorption
S.W. Webb and W.C.Conner 31
Analysis of the percolation properties of a real porous material
G. Mason and D.W. Mellor 41
The five types of porous structures and their hysteresis loops
V. Mayagoitia 51
Model study of the combined effect of heteroporosity of macroscopic
heterogeneity gas relative permeability of porous solids
N.K. Kanellopoulos, J.K. Petrou and J.H. Petropoulos 61
Percolation theory of capillary hysteresis phenomena and its
application for characterization of porous solids
A.V. Neimark 67
Modelling of mercury intrusion and extrusion
M. Day, I.B. Parker, J. Bell, M. Thomas, R. Fletcher and
J. Duffie 75
Wetting phenomena in porous solids: Mechanisms and models
A. Winter 85
The contact angle of liquids in porous media
U. Demlehner 97
The main principles of modelling of porous solids. Models of systems
with needle-like particles
A.P. Karnaukhov 105
Adsorption-desorption hysteresis in porous networks
D.K. Efremov and V.B. Fenelonov 115
VI
The determination of the pore size distribution of porous solids
using a molecular model to interpret nitrogen adsorption measurements
C.A. Jessop, S.M. Riddiford, N.A. Seaton, J.P.R.B. Walton
and N. Quirke 123
Standardisation, reference materials and comparative measurements
for surface area and pore characterisation
E. Robens and K.-F. Krebs 133
Fractal characterization of the porosity of organic tissue by
interferometry
M. Sernetz, H.R. Bittner, P. Bach and B. Glittenberg 141
Determination of surface properties of porous solids
K.S. Birdi, D.T. Vu, S.I. Andersen, A. Winter, H. Topsrae and
S.V. Christensen 151
A new apparatus for continuous adsorption. Application to the
characterization of microporous solids
H. Ajot, J.F. Joly, F. Raatz and C. Russmann 161
A new mercury intrusion-retraction simulator used as a means for the
characterization of porous materials
C.D. Tsakiroglou and A.C. Payatakes 169
Film surface area measurements for microporosity and surface
roughness analysis
G.P. Johnston, D.M. Smith, A.J. Hurd and P. Pfeifer 179
Some problems about gas adsorption isotherm measurements by automated
procedures in manometric devices
J.L. Ginoux and L. Bonnetain 189
Morphological influences on unsteady gas diffusivities in porous solids
W. C. Conner, S.W. Webb, P. Buckley, S.V. Christiansen,
G. Parthun, J.A. Hansen and H. Topsrae 199
Textural characterization of ultrafiltration membranes by thermoporometry
and liquid flow measurement
J.F. Quinson, N. Nameri and B. Bariou 209
Characterization of the surface fractal dimension of evaporated silver
and gold films through adsorption isotherm measurements
J. Krim and V. Panella 217
Influence of pore structure parameters on the intraparticle pressure
change during adsorption
S.E. Scholl and A.B. Mersmann 225
VII
Neutron scattering investigation of adsorption processes in model
porous systems
J.D.F. Ramsay and R.G. Avery 235
Small angle and ultra-small angle scattering techniques for characterization
of porous materials
J.C. Dore and A.N. North 245
Gel-precipitated oxide gels with controlled porosity-determination of
structure by small angle neutron scattering and adsorption isotherm
measurements
J.D.F. Ramsay, P.J. Russell and S.W. Swanton 257
Small-angle neutron scattering study of fumed silica powder compaction
A.J. Hurd, G.P. Johnston and D.M. Smith 267
The determination of permeability and binary gas diffusion coefficients
in novel forms of porous carbons
S.B. Bhowmik, S.P. Waldram, R. McMurray and S.R. Tennison 273
Pore-size analysis for permeability estimation in porous material
T. Sat0 283
The effects of pore and particle geometry on NMR diffusion measurements
in adsorbed liquids
S. Bahceli, A.R.S. Al-Kaisi, K. Krynicki and J.H. Strange 293
Pore size analysis of wet materials via low-field NMR
D.M. Smith and P.J. Davis 30 1
Characterization of microporosity and surface homogeneity by the study
of argon and nitrogen isotherm crossing and measurement of differential
enthalpies of adsorption
J.M. Martin-Martinez, F. Rodriguez-Reinoso, Y. Grillet,
F. Rouquerol and J. Rouquerol 311
Adsorptive properties of activated carbons prepared from kevlar
J.J. Freeman, F.G.R. Gimblett, R.A. Hayes, Z. Mohd. Amin
and K.S.W. Sing 319
Modification in porous texture and oxygen surface groups of activated
carbons by oxidation
M. Molina-Sabio, M.A. Muiiecas-Vidal and F. Rodriguez-Reinoso 329
Adsorption of methanol and water by charcoal cloth
A.M. Gonplves da Silva, M.M.L. Ribeiro Carrott, P.J.M. Carrott
and M.M. Brotas de Carvalho 341
VIII
Influence of coal preoxidation and reactive gas flow rate on textural
properties of active carbons
J.A. Pajares, J.J. Pis, A.B. Fuertes, A.J. PCrez, M. Mahamud
and J.B. Parra 347
Evaluation of microporosity in steam activated brown coal humic acids
chars
T. Siemieniewska, K. Tomkow, J. Kaczmarczyk, A. Albiniak,
Y. Grillet and M. FranGois 357
Induced porosity in activated carbons by catalytic activation
A. Linares-Solano, M. Almela-Alardn, C. Salinas-Martinez
de Lecea, M.J. Muii6z-Guillena and M.J. IllPn-G6mez 367
Characterization of activated carbon: an approach to the activation
process by SAXS and optical microscopy
J.M. Guet, Q. Lin, A. Linares-Solano and C. Salinas-
Martinez de Lecea 379
Dynamic micropore structures of micrographitic carbons during
adsorption
K. Kaneko, T. Suzuki, Y. Fujiwara and K. Nishikawa 389
Characterization of the porosity of activated charcoals by adsorption
from solution
J. FernPndez-Colinas, R. Denoyel and J. Rouquerol 399
The porosity of textile fibre surfaces
A. McInally, R.R. Mather and K.S.W.Sing 409
Further comments on low pressure hysteresis in activated carbons:
effect of preparation method
F. Rodriguez-Reinoso, J.M. Martin-Martinez, A. Linares-Solano
and R. Torregrosa 419
Multi-stage micropore filling of N, and Ar by microporous carbon
fibers
K. Kakei, S. Ozeki, T. Suzuki and K. Kaneko 429
Porous structure of synthetic active carbons
N.T. Kartel, A.M. Puzy and V.V. Strelko 439
Evaluation of microporosity in activated carbons with high ash
(Cr20,) content
M.A. Martinez-Shchez, J.M. Martin-Martinez, A.C. OrgilCs-
Barcel6, F. Rodriguez-Reinoso and M.J. SellCs-PCrez 449
Influence of coal oxidation on coke porosity
J.J. Pis, R. MenCndez, J.J. Lorenzana, A.J. PCrez, H. Marsh
and E. Romero 459
IX
Comparative studies of the microporous structure parameters
evaluated from the adsorption isotherms of various adsorbates on
activated carbons
M. Jaroniec, J. Choma, F. Rodriguez-Reinoso and
J.M. Mart in-Mart inez 469
Estimating micropore sizes in activated carbons from adsorption
isotherms
B. McEnaney and T.J. Mays 477
A comparative study of the porous structure of active carbons using
benzene and water adsorption, inmersion calorimetry and liquid chromatography
K.H. Radeke and P. Briickner 49 1
Mercury porosimetry of porous glass and active carbon preloaded with
n-decane or water
H. Lentz and Y. Zhou 499
Sorption of hydrocarbons in silicalite-1 and Nay zeolites
J.A. Hampson, R.V. Jasra and L.V.C Rees 509
How can an adsorption system show phase transition. A case study on
the adsorption of p-xylene in ZSM-5
D. Pan and A.B. Mersmann 5 19
Crystallochemical structure of zeolite micropores and adsorption-
energetic characteristics
G.U. Rakhmatkariev, A.A. Isirikjan 525
Sorption of argon and nitrogen on network types of zeolites and
aluminophosphates
H. Reichert, U. Muller, K.K. Unger, Y. Grillet, F. Rouquerol,
J. Rouquerol and J.P. Coulomb 535
Porosity of silicas: comparison of nitrogen adsorption and mercury
penetration
D.R. Milburn, B.D. Adkins and B.H. Davis 543
Characterization and stability of porous structure of titanium-silicalite
by sorption methods
G. Lmfanti, F. Genoni, M. Padovan, G. Petrini, G. Trezza and
A. Zecchina 553
Study of the pore network of dealuminated faujasites by water vapor
adsorption
M.H. Simonot-Grange, A. Elm’Chaouri, M. Nafis, G. Weber,
P. Dufresne, F. Raatz and J.F. Joly 5 65