Chapter 16: Composites ISSUES TO ADDRESS... • What are the classes and types of composites? • What are the advantages of using composite materials? • How do we predict the stiffness and strength of the various types of composites? 1 Composite • Combination of two or more individual materials • Design goal: obtain a more desirable combination of properties (principle of combined action) – e.g., low density and high strength 2 Terminology/Classification • Composite: -- Multiphase material that is artificially made. • Phase types: -- Matrix - is continuous -- Dispersed - is discontinuous and surrounded by matrix Adapted from Fig. 16.1(a), Callister & Rethwisch 8e. 3 Terminology/Classification • Matrix phase: woven fibers -- Purposes are to: - transfer stress to dispersed phase - protect dispersed phase from environment 0.5 mm -- Types: MMC, CMC, PMC cross metal ceramic polymer section view • Dispersed phase: -- Purpose: MMC: increase s , TS, creep resist. 0.5 mm y CMC: increase K Reprinted with permission from Ic D. Hull and T.W. Clyne, An PMC: increase E, s , TS, creep resist. y Introduction to Composite Materials, 2nd ed., Cambridge University Press, -- Types: particle, fiber, structural New York, 1996, Fig. 3.6, p. 47. 4 Classification of Composites Stiffer particulate bears Adapted from Fig. 16.2, fraction of load, restrain Callister & Rethwisch 8e. matrix movement in vicinity Small dispersed particles impede motion of dislocations 5 • For which particle reinforced composite would bond strength be more important? • What geometric/spatial properties of particles in dispersed phase would influence performance? 6 Particle-reinforced Fiber-reinforced Structural Classification: Particle-Reinforced (i) • Examples: - Spheroidite matrix: particles: Adapted from Fig. ferrite (a) cementite 10.19, Callister & steel Rethwisch 8e. (Fig. ( Fe C ) (ductile) 10.19 is copyright 3 (brittle) United States Steel Corporation, 1971.) 60mm Adapted from Fig. - WC/Co matrix: particles: 16.4, Callister & cemented cobalt WC Rethwisch 8e. (Fig. 16.4 is courtesy (ductile, (brittle, carbide Carboloy Systems, toug: h ) hard) Department, General Electric Company.) 600mm Adapted from Fig. - Automobile matrix: 16.5, Callister & particles: Rethwisch 8e. (Fig. rubber tire rubber carbon 16.5 is courtesy (compliant) Goodyear Tire and black Rubber Company.) (stiff) 0.75mm 7 Particle-reinforced Fiber-reinforced Structural Classification: Particle-Reinforced (ii) Concrete – gravel + sand + cement + water - Why sand and gravel? Sand fills voids between gravel particles Reinforced concrete – Reinforce with steel rebar or remesh - increases strength - even if cement matrix is cracked Prestressed concrete - Rebar/remesh placed under tension during setting of concrete - Release of tension after setting places concrete in a state of compression - To fracture concrete, applied tensile stress must exceed this compressive stress Posttensioning – tighten nuts to place concrete under compression threaded rod nut 8 9 Particle-reinforced Fiber-reinforced Structural Classification: Particle-Reinforced (iii) • Elastic modulus, E , of composites: c -- two “rule of mixture” extremes: upper limit: E = V E + V E c m m p p E(GPa) 350 Data: lower limit: Adapted from Fig. 16.3, Cu matrix 30 0 Callister & Rethwisch 8e. 1 V V w/tungsten 250 = m + p (Fig. 16.3 is from R.H. Krock, ASTM Proc, Vol. particles E E E 20 0 c m p 63, 1963.) 150 0 20 4 0 6 0 8 0 10 0 vol% tungsten (Cu) (W ) • Application to other properties: -- Electrical conductivity, s : Replace E’s in equations with s ’s. e e -- Thermal conductivity, k: Replace E’s in equations with k’s. 10
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