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Catalytic Olefin Polymerization: Proceedings of the International Symposium on Recent Developments in Olefin Polymerization Catalysts, Tokyo, Octobe PDF

597 Pages·1990·17.5 MB·English
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Studies in Surface Science and Catalysis 56 CATALYTIC OLEFIN POLYMERIZATION Proceedings of the International Symposium on Recent Developments in Olefin Polymerization Catalysts, Tokyo, October 23- 25, 1989 This Page Intentionally Left Blank Studies in Surface Science and Catalysis Advisory Editors : B. Delmon and J. T. Yates Vol. 56 CATALYTIC OLEFIN PO LY ME RIZATION PROCEEDINGS OF THE INTERNATIONAL SYMPOSIUM ON RECENT DEVELOPMENTS IN OLEFIN POLYMERIZATION CATALYSTS, TOKYO, OCTOBER 23-25,1989 Edited by Tominaga Keii Professor Emeritus, Tokyo Institute of Technology Kazuo Soga Professor, Tokyo Institute o f Technology KODANSHA ELSEVIER 1990 Tokyo Amsterdam-Oxford- New York-Tokyo Copublished by KODANSHA LTD., Tokyo and ELSEVIER SCIENCE PUBLISHERS B. V., Amsterdam exclusive sales rights in Japan KODANSHA LTD. 12-21, Otowa 2-chome, Bunkyo-ku, Tokyo 112, Japan for the U.S . A . and Canada ELSEVIER SCIENSE PUBLISHING COMPANY, INC. 655 Avenue of the Americas, New York, N. Y. 10010, U. S. A. for the rest of the world ELSEVIER SCIENSE PUBLISHERS B. V. 25 Sara Burgerhartstraat, P. 0. Box 211, 1000 AE Amsterdam, The Netherlands ISBN 0- 444- 98747 - 9(V0l. 56) ISBN 0-444-41801 -B(Series) ISBN 4-06-20491 6-3(Japan) Copyright 01 990 by Kodansha Ltd. All rights reserved No part of this book may be reproduced in any form, by photostat, microfilm, retrieval system, or any other means, without the written permission of Kodansha Ltd. (except in the case of brief quotation for criticism or review) PRINTEIDN J APAN List of Contributors Numbers in parentheses indicate the chapter (5 ) in which the authors’ contributions appear. Albornoz, A. (29) Polymer Laboratory, Chemistry Center, IVIC, Apartado 21827, Caracas 1020A, Venezuela Almquist, V. (6) Statoil, 3960 Stathelle, Norway Antberg, M. (35) Hoechst AG, 6230 Frankfurt a. Main 80, F.R.G. Arzoumanidis, G.G. (12) Amoco Chemical Company, P. 0. Box 3011, Naperville, Illinois 60566, U.S.A. Barazzoni, L. (28) EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy Bark, A. (31) Institut fiir Anorganische und Angewandte Chemie, Universitat Hamburg, Martin-Luther-King Platz 6, 2 Hamburg 13, F.R.G. Bernard, A. (30) Solvay et Cie S.A., Laboratoire Central, Rue de Ransbeek 310, B-1120 Bruxelles, Belgique Bobichon, C. (3) (8) CNRS, Laboratoire des Materiaux Organiques, BP 24, 69390 Vernaison, France B-, C. (9) Groupe de Recherches de Lacq, BP34 LACQ, 64170 Artix, France Bu, N. (4) Department of Chemical Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2G6 Chang, H.S. (21) Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, P.O. Box 131 Cheongryang, Seoul, Korea Cheng, H.N. (32) Research Center, Hercules Incorporated, Wilmington, Delaware 19894, U.S.A. Chida, K. (15) Tonen Sekiyukagaku K.K., Tonen Corporate Research & Development Laboratory, Inuna-gun, Saitama 354, Japan vj List of Contributors Chien, J.C.W. (38) Department of Polymer Science and Engineering, Department of Chemistry, University of Massachusetts, Amherst, MA 01003, U.S.A. Choi, H.K: (26) Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, Korea Chu, K.J. (21) Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, P. 0. Box 131, Cheongryang, Seoul, Korea Chung, M.C. (26) Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, P.O.Box 131, Cheongryang, Seoul, Korea Curtis, S. (32) Fina Oil and Chemical Company, P.O. Box 1200, Deer Park, Texas 77536, U.S.A. Dake, I. (31) Institut fur Anorganische und Angewandte Chemie, Universitat Hamburg, Martin-Luther-King Platz 6, 2 Hamburg 13, F. R. G Dolle, V. (35) Hoechst AG, 6230 Frankfurt a. Main 80, F. R. G. Duranel, L. (8) Atochem G.R.L., BP 34 LACQ, 64170 Artix, France Elder, M.J. (32) Fina Oil and Chemical Company, P.O. Box 1200, Deer Park, Texas 77536, U.S.A. Endo, K. (18) Department of Applied Chemistry, Faculty of Engineering, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558, Japan Ewen, J.A. (32) Fina Oil and Chemical Company, P.O. Box 1200, Deer Park, Texas 77536, U.S.A. Fenzl, W. (19) Max-Planck-Institut & Kohlenforschung, Kaiser-Wilhelm-Platz-1, D-4330 Mulheim a.d. Ruhr-1, F. R. G. Ferrero, C. (28) EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy Fiasse, P. (30) Solvay et Cie S.A., Laboratoire Central, Rue de Ransbeek 310, B-1120 Bruxelles, Belgique Fink, G.(19) Max-Planck-Institut fur Kohlenforschung, Kaiser-Wilhelm-Platz-1, D-4330 Miilheim a.d. Ruhr-1, F.R.G. Follestad, A. (6) Statoil, 3960, Stathelle, Norway Listof Gmhbium vii Fuentes, A. (29) Polymer Laboratory, Chemistry Center, IVIC, Apartado 21827, Caracas 1020A, Venezuela Fujita, T. (17) Yokkaichi Research Center, Mitsubishi Petrochemical Co., Ltd., 1 Toho-cho, Yokkaichi, Mie 510, Japan Furuhashi, H. (14) (15) Tonen Sekiyukagaku K.K., Tonen Corporate Research & Development Laboratory, Inuna-gun, Saitama 354, Japan Grubbs, R.H. (24) Arnold and Mabel Bechman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena CA 91125, U S A . Guyot, A. (3) (8) CNRS, Laboratoire des Materiaux Organiques, BP 24, 69390 Vernaison, France Harkonen, M. (7) Helsinki University of Technology, Department of Chemical Engineering, Kemistintie 1, SF-02150 Espoo, Finland Hattori, I. (25) Elastomers Laboratory, Technical Center, Japan Synthetic Rubber Co., Ltd., 100 Kawajiri-cho, Yokkaichi, Mie 510, Japan Helleborg, S. (6) Statoil, 3960 Stathelle, Norway Herfert, N. (19) Max-Planck-Institut fur Kohlenforschung, Kaiser-Wilhelm-Platz-1, D-4330 Miilheim a.d. Ruhr-1, F.R.G. Ihm, S.K. (21) Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, P. 0. Box 131, Cheongryang, Seoul, Korea Iiskola, E. (11) Polyolefins R & D, Neste Chemicals, SF-06850 Kulloo, Finland Imai, M. (14) Tonen Sekiyukagaku K.K., Tonen Corporate Research & Development Laboratory, Iruma-gun, Saitama 354, Japan Invernizzi, R. (28) EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy Ishii, K. (22) Toho Titanium Co. Ltd., 3-3-5 Chigasaki, Chigasaki-shi, Kanagawa 253, Japan Jaber, I.A. (2) (19) Max-Planck-Institut fur Kohlenforschung, Kaiser-Wilhelm-Platz-1, D-4330 Mdheim a.d. Ruhr-1, F. R. G. (present address) Jejelowo, M.O. (4) Department of Chemical Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2G6 vii List of Contributors Job, J.F. (9) CNRS, Laboratoire des Materiaux Organiques, BP 34, 69390 Vernaison, France Jones, R.L. (32) Fina Oil and Chemical Company, P.D. Box 1200, Deer Park, Texas 77536, U.S.A. Kakugo, M. (13) (27) (36) Chiba Research Laboratory, Sumitomo Chemical Co. Ltd., 2-1 Kitasode, Sodegaura-cho, Kimi- tsu-gun, Chiba 299-02 Japan Kaminsky, W. (31) Institut fur Anorganische und Angewandte Chemie, Universitat Hamburg, Martin-Luther-King Platz 6, 2 Hamburg 13, F.R.G. Kang, K.S. (21) Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, Korea Karayannis, N.M. (12) Amoco Chemical Company, P.O.Box 3011, Naperville, Illinois 60566, U.S.A. Kashiwa, N. (33) (34) Iwakuni Polymer Research Laboratories, Mitsui Petrochemical Industries, Ltd., Waki -cho, Kuga-gun, Yamaguchi 740, Japan Kataoka, T. (5) Toho Titanium Co. Ltd., 3-3-5253, Chigasaki, Chigasaki-shi, Kanagawa 253, Japan Keii, T. (1) (5) Tokyo Institute of Technology, Preparation Committee of JAIST, Monbusho 7F1, Kasumigaseki 3-2-2, Chiyoda-ku, Tokyo 100, Japan Kim, I. (26) Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, P.O.Box 131, Cheongryang, Seoul, Korea Kim, J.H. (26) Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, P.O.Box 131, Cheongryang, Seoul, Korea Kioka, M. (33) (34) Iwakuni Polymer Research Laboratories, Mitsui Petrochemical Industries, Ltd., Waki-cho, Kuga-gun, Yamaguchi 740, Japan Klein, R. (35) Hoechst AG,6230 Frankfurt a. Main 80, F.R.G. Lacombe, J.L. (3) DPPG, Atochem, Mont, BP 3 Argagnon, 64300 Orthez, France Lin, s. (20) Institute of Polymer Science, Zhongshan University, Guangzhou, China Liscano, J. (29) Polymer Laboratory, Chemistry Center, IVIC, Apartado 21827, Caracas 1020A, Venezuela List of Gmtribntm ix Loontjens, A.J. (2) DSM, Research and Patents, Geleen, Holland Lynch, D.T. (4) Department of Chemical Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2G6 Makino, K. (25) Elastomers Laboratory, Technical Center, Japan Synthetic Rubber Co., Ltd., 100 Kawajiri-cho, Yokkaichi, Mie 510, Japan Mallin, D.T. (38) Department of Polymer Science and Engineering, Department of Chemistry, University of Massachusetts, Amherst, MA 01003, U.S.A. Malquori, S. (28) EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy Masi, F. (28) EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy Menconi, F. (28) EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy Mise, T. (37) The Institute of Physical and Chemical Research, Hirosawa, Wako-shi, Saitama 351-01, Japan Miya, S. (37) Chisso Petrochemical Corporation, 5- 1 Goikaigan, Ichihara-shi, Chiba 290, Japan Miyatake, T. (13) (36) Chiba Research Laboratory, Sumitomo Chemical Co. Ltd., 2-1 Kitasode, Sodegaura-cho, Kmi- tsu-gun, Chiba 299-02, Japan Mizunuma, K. (13) (36) Chiba Research Laboratory, Sumitomo Chemical Co. Ltd., 2-1 Kitasode, Sodegaura-cho, Kimi- tsu-gun, Chiba 299-02, Japan Moalli, A. (28) EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy Miiller, T. (19) Max-Planck-Institut fur Kohlenforschung, Kaiser-Wilhelm-Platz-1, D-4330 Mulheim a.d. Ruhr-1, F.R.G. Munoz-Escalona, A. (29) Polymer Laboratory, Chemistry Center, IVIC, Apartado 21827, Caracas 1020A, Venezuela Murata, M. (14) Tonen Sekiyukagaku K.K., Tonen Corporate Research & Development Laboratory, Iruma-gun, Saitama 354, Japan Nakano, A. (14) (15) Tonen Sekiyukagaku K.K., Tonen Corporate Research & Development Laboratory, Iruma-gun, Saitama 354, Japan

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