Catalytic membrane reactor for waste water treatments

275 Pages·2017·19.98 MB·French

by  Ali Abusaloua

Catalytic membrane reactor for waste water treatments
Ali Abusaloua
To cite this version:
Ali Abusaloua. Catalytic membrane reactor for waste water treatments. Other. Université Claude
Bernard - Lyon I, 2010. English. ￿NNT: 2010LYO10122￿. ￿tel-00703265￿
HAL Id: tel-00703265
https://theses.hal.science/tel-00703265
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N° d’ordre :122 Année 2010
THESE DE L‘UNIVERSITE DE LYON
Délivrée par
L’UNIVERSITE CLAUDE BERNARD LYON 1
ECOLE DOCTORALE de Chimie

DIPLOME DE DOCTORAT en Génie Chimique
(arrêté du 7 août 2006)
soutenue publiquement le 9 Juillet 2010
par
Ali ABUSALOUA
Réacteur catalytique membranaire pour
le traitement d’effluents liquides

Directeur de thèse: Anne GIROIR-FENDLER
Koffi FIATY
JURY
Madame GIROIR-FENDLER Anne
Monsieur DUPREZ Daniel
Monsieur FIATY Koffi
Monsieur IOJOIU Eduard
Monsieur KADDOURI Abdel-Hakim
Monsieur VALVERDE Jose Luis

9 Juillet 2010
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Acknowledegment
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Acknowledegment

ACKNOWLEDGEMENT

I would like to take this opportunity to extend my deepest gratitude and special thanks to my
supervisor, Dr. Anne GIROIR- FENDLER, of the Lyon I University.
Dr. GIROIR- FENDLER has a sharp eye for tracking the details and superb analytical skills;
that have been instrumental in the success of my thesis.
I need to reiterate my deep gratitude to my supervisor, Dr. Anne GIROIR- FENDLER,
for accepting to guide me during the completion of the PhD program after the death of my
former supervisor Dr. Sylvain MIACHON.
Also I wish to extend my sincere gratitude to my co-supervisor Dr. Koffi FIATY of the
Lyon I University. Dr. FIATY has a keen eye for spotting the details as well as excellent
analytical skills, which have been paramount in the success of my thesis. In addition, Dr.
Koffi FIATY provided insight in membrane reactor modelling, partial differential equations
manipulations and MATLAB programming.
My deep gratitude and special thanks goes to my former supervisor the late Dr. Sylvain
MIACHON who passed away after two years of a valiant struggle with disease. Dr.
MIACHON still lives on scientist in my memory forever. I continue to abide to his invaluable
recommendations on being an astute. I wish to express my condolence to Dr. MIACHON
family, and to our team of research (Engineering) in IRCELyon.
My gratitude also is extended to Dr. J-A. DALMON. Dr. DALMON has moved on to
retirement a few months ago.
I am also grateful to my colleague’s in-group meeting (WATERCATOX), particularly,
and beside Dr. J-A. DALMON, Dr. Nolven GUILHAUME, Dr. Marc PERA-TITUS and Dr.
Mohamed ALAME, for providing fruitful discussions.
Special thanks to all my colleagues in IRCELYON, who have been very supportive
during my years as a doctorate student. They have show always concern for my progress and
my well being. Some of who, over the years, have become good friends.
Special acknowledgment is also given to Libyan Embassy-Paris for funding this
research thesis. The Libyan scholarship Funding enabled the purchase of materials,
instruments, and software for the research thesis.
Last but not least, I am greatly indebted to my mother, my father, my wife and my
family for their understanding, patience and support during the entire period of my study.

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Acknowledegment

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‘‘À ceux qui m’ont appris à monter l’escalier de la vie avec patience et sagesse
ma mère et mon père ’’

A mon épouse Zuhira et
mes enfants Abdulalhadi, Fatima, Mohamed, Kawala, Hammam
Je dois avouer ma reconnaissance devant cet aboutissement,
qui n’aurait pu se faire sans le soutien de ma femme
et de mes parents

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CONTENTS
Introduction.......................................................................................................................17
1 BIBLIOGRAPHIC STUDY.........................................................................................21
1.1 Water Pollution...............................................................................................................................23
1.2 Wastewater Treatment Processes................................................................................................23
1.2.1 Physical Processes.......................................................................................................................24
1.2.2 Biological treatment....................................................................................................................24
1.2.3 CHEMICAL PROCESSES......................................................................................................................25
1.3 MEMBRANE SEPARATION PROCESSES............................................................................................25
1.4 Selection of wastewater treatment process.................................................................................26
1.5 Overview of WAO processes........................................................................................................28
1.6 Industrial WAO processes............................................................................................................31
1.6.2 Heterogeonous WAO processes...............................................................................................32
1.7.1 Monometallic Catalysts..............................................................................................................33
1.7.2 Catalyst stability and deactivation...........................................................................................33
1.9 WAO of carboxylic acids...........................................................................................................39
1. 10 CWAO OF PHENOL....................................................................................................................................40
1.11 CWAO of Real effluents and miscellaneous compounds.......................................................42
1.13.1 Membrane: the state of art......................................................................................................45
1.13.2 Inorganic membranes:.............................................................................................................47
1.14 Inorganic membranes for membrane reactors (MR).............................................................48
1.15 Catalyst Preparation methods....................................................................................................52
1.15.1 Monometallic catalyst preparation........................................................................................53
1.15.1.2 The precipitation methods....................................................................................................54
1.16 Bimetallic catalyst preparation..................................................................................................54
1.16.3 The (LBL) electrolyte deposition............................................................................................55
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