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Catalysis. Volume 32 PDF

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Catalysis Volume 32 1 0 0 P F 7- 7 4 9 1 0 8 8 7 1 8 7 9 9/ 3 0 1 0. 1 oi: d g | or c. s s.r b u p s:// p htt n o 0 2 0 2 y ar u n a J 7 1 n o d e h s bli u P View Online 1 0 0 P F 7- 7 4 9 1 0 8 8 7 1 8 7 9 9/ 3 0 1 0. 1 oi: d g | or c. s s.r b u p s:// p htt n o 0 2 0 2 y ar u n a J 7 1 n o d e h s bli u P View Online A Specialist Periodical Report Catalysis Volume 32 1 0 0 P F 7- 7 4 A Review of Recent Literature 9 1 0 8 8 7 1 8 Editors 7 9 9/ James J. Spivey, Louisiana State University, USA 3 10 Yi-Fan Han, East China University of Science and Technology, 0. 1 Shanghai, China oi: d Dushyant Shekhawat, National Energy Technology Laboratory, USA g | or c. s s.r Authors b u p Weijian Diao, University of South Carolina, USA ps:// Yanze Du, SINOPEC Dalian Research Institute of Petroleum and n htt Petrochemicals, China o 0 Anne M. Gaffney, University of South Carolina and Idaho National 2 20 Laboratories, USA y ar L. Hu, Institute of Chemical Research of Catalonia, Spain u an Ben W.-L. Jang, Texas A&M University–Commerce, USA J 17 Deeksha Jain, The Ohio State University, USA n o Ruifeng Li, Taiyuan University of Technology, China d he Yang Liu, Dalian University of Technology, China s bli Jingjun Lu, Taiyuan University of Technology, China u P Michal Mazur, Charles University, Czech Republic John R. Monnier, University of South Carolina, USA Umit S. Ozkan, The Ohio State University, USA Paraskevi Panagiotopoulou, Technical University of Crete, Greece D. Pinto, Delft University of Technology, The Netherlands Bo Qin, SINOPEC Dalian Research Institute of Petroleum and Petrochemicals, China Hengshan Qiu, Zhengzhou University, China Daniel N. Rainer University of St Andrews, UK , John R. Regalbuto, University of South Carolina, USA John Meynard M. Tengco, University of South Carolina, USA View Online A. Urakawa, Delft University of Technology, The Netherlands and Japan Science and Technology Agency, Japan Xenophon E. Verykios, University of Patras, Greece Huigang Wang, SINOPEC Dalian Research Institute of Petroleum and Petrochemicals, China Qianqian Wang, Taiyuan University of Technology, China Xiaoliang Yan, Taiyuan University of Technology, China 1 0 0 P F 7- 7 4 9 1 0 8 8 7 1 8 7 9 9/ 3 0 1 0. 1 oi: d g | or c. s s.r b u p s:// p htt n o 0 2 0 2 y ar u n a J 7 1 n o d e h s bli u P View Online ISBN: 978-1-78801-774-9 PDF ISBN: 978-1-78801-947-7 1 0 EPUB ISBN: 978-1-78801-948-4 0 P F DOI: 10.1039/9781788019477 7- 7 Print ISSN: 0140-0568 4 9 1 Electronic ISSN: 1465-1920 0 8 8 7 1 8 A catalogue record for this book is available from the British Library 7 9 9/ 3 10 r The Royal Society of Chemistry 2020 0. 1 doi: All rights reserved g | or sc. Apart from fair dealing for the purposes of research for non-commercial bs.r purposes or for private study, criticism or review, as permitted under the u s://p Copyright, Designs and Patents Act 1988 and the Copyright and Related p Rights Regulations 2003, this publication may not be reproduced, stored or htt n transmitted, in any form or by any means, without the prior permission in o 0 writing of The Royal Society of Chemistry or the copyright owner, or in the 2 0 2 case of reproduction in accordance with the terms of licences issued by the y ar CopyrightLicensingAgencyintheUK,orinaccordancewiththetermsofthe u n a licences issued by the appropriate Reproduction Rights Organization outside J 17 the UK. Enquiries concerning reproduction outside the terms stated here n o should be sent to The Royal Society of Chemistry at the address printed on d he this page. s bli u P Whilst this material has been produced with all due care, The Royal Society of Chemistry cannot be held responsible or liable for its accuracy and completeness, nor for any consequences arising from any errors or the use of the information contained in this publication. The publication of advertisements does not constitute any endorsement by The Royal Society of Chemistry or Authors of any products advertised. The views and opinions advancedbycontributorsdonotnecessarilyreflectthoseofTheRoyalSociety ofChemistrywhichshallnotbeliableforanyresultinglossordamagearising as a result of reliance upon this material. The Royal Society of Chemistry is a charity, registered in England and Wales,Number207890,andacompanyincorporatedinEnglandbyRoyal Charter (Registered No. RC000524), registered office: Burlington House, Piccadilly, London W1J 0BA, UK, Telephone: +44 (0) 207 4378 6556. For further information see our web site at www.rsc.org Printed and bound by CPI Group (UK) Ltd, Croydon, CR0 4YY View Online 1 0 0 P F 7- 7 4 9 1 0 8 8 7 1 8 7 9 9/ 3 0 1 0. 1 oi: d g | or c. s s.r b u p s:// p htt n o 0 2 0 2 y ar u n a J 7 1 n o d e h s bli u P Preface DOI: 10.1039/9781788019477-FP007 InChapter1, P.Panagiotopoulou(TechnicalUniversityofCrete,Greece) and X. E. Verykios (University of Patras, Greece) reviews recent reports 7 0 onMetal–SupportinteractionsofRu-basedcatalystsunderconditionsof 0 P 7-F CO and CO2 Hydrogenation. In this chapter, Several parameters about 7 metal–support interactions including the nature of both the metallic 4 9 1 phase and the support, the morphology and size of metal particles, the 0 8 8 oxidationstateofthemetal,aswellasthenatureandspecificconditions 7 1 8 under which the reaction is taking place have been reviewed. Such 7 9 9/ interactions give rise to electronic, geometric and bifunctional effects, 3 10 whichstronglyinfluencethereactivityofreactantmoleculesinanumber 0. 1 of applications. Ruthenium particles dispersed on oxide supports is a doi: well-known catalyst formulation for its capacity to undergo metal– g | support interactions, a parameter that could be utilized to influence or c. theactivityandselectivityofseveralcatalyticreactions,includingtheCO s ubs.r and CO2 hydrogenation. Finally, the general subject of metal–support ps://p irnestepreaccttitoons(ao)ccvuarriroinugs opvheyrsRicuocbhaesmediccaaltaalnysdtsoipsedriastcinugssepdarianmdeettearislwainthd htt on (b) their effect in hydrogenating both CO and CO2. 0 InChapter2,X.Yan,J.Lu,Q.Wang(TaiyuanUniversityofTechnology, 2 0 2 China), Y. Du, B. Qin, H. Wang (SINOPEC Dalian Research Institute of y ar Petroleum and Petrochemicals, China), R. Li (Taiyuan University of u an Technology China), and Ben W.-L. Jang (Texas A&M University, USA) J 17 review the work on Ni Catalysts from Laboratory Investigations to n o Chemical Industry. Heterogeneous Ni catalysts exhibit promising inter- d he ests and applications in laboratory and industry. It is thus desirable for s bli researcherstodiscoveranddesignefficientcatalystsfrombotheconomic u P andecologicalaspects.Inthischapter,theauthorsdiscussthemaximum Ni utilization, such as single atom Nicatalysts and some novel methods forsuperiormetalutilization,theimportanceofinterfacebetweenNiand support, the effect of location between Ni and support on catalytic per- formance,andtheindustrialapplicationandreuseoftheNicatalyst.The illustration from this chapter would bridge the gap from academic studies in laboratory to practical applications in industry not only for catalysis field but also for environmental protection. In Chapter 3, D. Jain and U. S. Ozkan (Ohio State University, USA) dis- cuss electrocatalytic applications of heteroatom-doped carbon nanostruc- tures.Thischapterhighlightstheimportanceofcarbonnanostructuresin four emerging low temperature electrocatalytic technologies: (i) energy storageintheformofunitizedregenerativefuelcellsandsecondaryzinc– air batteries; (ii) electrochemical carbon dioxide reduction; (iii) halogen production using oxygen depolarized cathodes and (iv) direct electro- chemical hydrogen peroxide synthesis. Additionally, it summarizes the challenges as well as the progress in the development of carbon-based catalysts for these applications, understanding electrocatalytic reaction Catalysis,2020,32,vii–ix | vii (cid:2)c TheRoyalSocietyofChemistry2020 View Online mechanisms while gaining insights into the nature of catalytically active sites which will be useful in a rational catalyst design. In Chapter 4, Yang Liu (Dalian University of Technology, China) reviews catalytic decomposition of gas-phase benzene with respect to material design, reaction mechanism and future prospect. In this chap- ter, benzene is taken as the target volatileorganic compound (VOC) and focus on the development during the past twenty years, including prep- 7 0 arationandmodificationofthematerialsforgaseousbenzeneoxidation 0 P F and the mechanisms for the catalytic benzene oxidation. Finally, the 7- 7 possible future prospects for material design are also be discussed. 4 9 1 InChapter5,researchersfromUniversityofSouthCarolina,Columbia, 0 8 8 USA(W.Diao;J.M.M.Tengco;A.M.Gaffney–alsofromIdahoNational 7 1 8 Laboratories,USA;J.R.Regalbuto;andJ.R.Monnier)reviewtheconcepts 7 9 9/ of electroless deposition (ED) methods for preparation of bimetallic 3 10 catalysts where both metals are co-existent in the same particle in a 0. 1 relatively-controlled manner of preparation. The compositions of the doi: bimetallicparticlescanbevariedinasystematicmannerbychangingthe org | amount and rate of second metal deposited on the base metal. Higher c. coveragesofthesecondmetalresultinformationofcore–shellbimetallic s bs.r particles that give more efficient use of the shell metal component and u s://p electronic epitaxial effects at the core–shell interface. Adjustment of ED p parametersmakeitpossibletoconductEDoveraverywidecombination htt n of metals and metal salts. Continuous ED can be extended to co- o 0 deposition of two metal salts to give ultimate control of formation of 2 0 2 uniform, bimetallic shells that provide the possibility of surface alloys y ar with unique properties and stability. u n a InChapter6,D.N.Rainer(UniversityofStAndrews,UK)andM.Mazur J 17 (Charles University, Czech Republic) provide an overview focused on n o electron microscopy and related characterization techniques as well as d he their utilization in the fields of design, synthesis, and formation of s bli crystals, characterization, and performance of zeolites as heterogeneous u P catalysts. Scanning electron microscopy and atomic force microscopy describe the morphology and surface of crystals of zeolite catalysts. Transmission electron microscopy, including scanning mode (STEM), supported by electron diffraction methods can give crucial information about structure, especially when conventional methods are limited for thefulldescriptionofsolidcatalysts,likezeolites.Oftenthosetechniques are supported by energy-dispersive X-ray spectroscopy for the elemental analysis of the samples. In Chapter 7, H. Qiu (Zhengzhou University, China) discusses the concepts of catalysis and surface science and the several promising aspects of surface science studies related to heterogeneous catalysis. Emphasis is given to the microscopic view on catalytic reactions, struc- tural and electronic requirement of a catalyst, the surface science approaching to explore mechanism of heterogeneous catalytic reactions occurringonsurface,subsurfaceandsupportedmetalnanoparticles,and the development of operando surface science techniques. In Chapter 8, L. Hu (Institute of Chemical Research of Catalonia, Spain), D. Pinto (Delft University of Technology, The Netherlands), and viii | Catalysis,2020,32,vii–ix View Online A. Urakawa (Japan Science and Technology Agency) review oxidative couplingofmethane(OCM)toproduceethaneandethylene.Despitethe extensive efforts over the last three decades, our general understanding on OCM is rather poor due to the complexity arising from the reaction network, and also from the various gradients such as temperature and gaseous concentration present in OCM reactors. This chapter highlights reactions active under OCM conditions and how they are interlinked. 7 0 Special emphasis is given on space-resolved analytical methodologies as 0 P F promising key enabling tools towards rational development of catalytic 7- 7 materials and processes for OCM. 4 9 1 0 8 8 James J. Spivey, Louisiana State University, Baton Rouge, USA 7 1 8 Yi-fan Han, East China University of Science and Technology, 7 9 9/ Shanghai, China 3 10 Dushyant Shekhawat, U.S. Department of Energy, 0. 1 National Energy Technology Laboratory, Morgantown, USA oi: d g | or c. s s.r b u p s:// p htt n o 0 2 0 2 y ar u n a J 7 1 n o d e h s bli u P Catalysis,2020,32,vii–ix | ix Editor biographies DOI: 10.1039/9781788019477-FP010 JamesSpiveyisShiversProfessorofChemical 0 1 Engineering at Louisiana State University, 0 P F USA. He is past Director of the Center for 7- 47 Atomic-levelCatalystDesign,andisFellowof 9 01 the Royal Society of Chemistry. His research 8 78 focuses on heterogeneous C1 catalysis, clean 1 78 fuels, syngas conversion, methane reactions, 9 9/ and acid catalysts. 3 0 1 0. 1 oi: d g | or c. s s.r b u Prof. Dr Yi-Fan Han received his PhD from p s:// East China University of Science and Tech- p htt nology (ECUST) with honors in 1997. He is n o interested in heterogenous catalysts, espe- 0 02 cially revealing the origin of dynamic active 2 y sites using Operando spectroscopies. He has ar u published more than 100 papers in top pro- n a 7 J fessional journals J. Am. Chem. Soc., Angew. 1 n Chem., Int. Ed., ACS Catal., J. Catal., AIChE J., o d with15nationalinventionpatents. e h s bli u P Dr Dushyant Shekhawat is serving as a team supervisor for Reaction Engineering team at NationalEnergytechnology(U.S.Department of Energy), Morgantown, USA. His research interests include fuel processing for fuel cell applications, reaction engineering, hetero- geneous catalysis, energy, plasma and micro- wave-assisted catalytic reactions. He has published over 200 peer-reviewed journal publications, conference proceedings, and reports,sevenbook chapters, two books,and 16patents(disclosedorfull).Heisaregistered Professional Engineer (PE) in West Virginia and also serves in the NCEES’s PE Chemical Engineering Examination Developmentcommittee. x | Catalysis,2020,32,x (cid:2)c TheRoyalSocietyofChemistry2020

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