Carbon Nanomaterials in Clean Energy Hydrogen Systems

920 Pages·2009·138.66 MB·English

by  T. N. Veziroglu (auth.)

Carbon Nanomaterials in Clean Energy
Hydrogen Systems
NATO Science for Peace and Security Series
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Series C: Environmental Security
Carbon Nanomaterials in Clean
Energy Hydrogen Systems
Edited by

Bogdan Baranowski

Institute of Physical Chemistry of PAS,
Warsaw, Poland

Svetlana Yu. Zaginaichenko

Institute of Hydrogen and Solar Energy,
Kiev, Ukraine

Dmitry V. Schur

Institute for Problems of Materials Science of NAS,
Kiev, Ukraine

Valeriy V. Skorokhod

Institute for Problems of Materials Science of NAS,
Kiev, Ukraine

and
Ayfer Veziroglu

International Association for Hydrogen Energy,
University of Miami, Miami, U.S.A.

Published in cooperation with NATO Public Diplomacy Division
Proceedings of the NATO Advanced Research Workshop on
Using Carbon Nanomaterials in Clean-Energy Hydrogen Systems
Sudak, Crimea, Ukraine
22–28 September 2007
Library of Congress Control Number: 2008932434
ISBN 978-1-4020-8897-1 (PB)
ISBN 978-1-4020-8896-4 (HB)
ISBN 978-1-4020-8898 -8 (e-book)
Published by Springer,
P.O. Box 17, 3300 AADordrecht, The Netherlands.
www.springer.com
Printed on acid-free paper
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CONTENTS

Preface xv

80th Anniversary of the Birthday of Academician B. Baranowski xvii

Erwin Sсhrödinger (12.08.1887, Vienna–04.01.1961, Vienna) xxi

150th Anniversary of the Birthday of GERTS, Genrich Rudolf (22.02.1857, xxiii
Hamburg–01.01.1894, Bonn)

140th Anniversary of the Birthday of Maria Skłodowska-Curie (07.111867, xxv
Wassaw–04.07.1934, Savoy)

On Centenary of Vera Ivanovna Mikheeva (1906–1981) xxix

C Fullerene xxxi
60

Saga of Hydrogen Civilization 1
T.N. Veziroglu

A Sight at the Future of a Science and Technics 7
F.P. Sanin

Search and Development of New Materials for Hydrogen Storage in the 25
Connected State
B.P. Tarasov

Hydrogen Technology for Porous Metals (Gasars) Production 29
V.I. Shapovalov, J.C. Withers

The Forming Peculiarities of C Molecule 53
60
D.V. Schur, S.Yu. Zaginaichenko, E.A. Lysenko, T.N. Golovchenko, N.F. Javadov

The Special Features of Formation of Carbon Nanostructures, Their 67
Classification and Site on the State Diagram of Carbon
D.V. Schur, S.Yu. Zaginaichenko, Z.A. Matysina

Solubility and Transformation of Fullerene C Molecule 85
60
D.V. Schur, S.Yu. Zaginaichenko, A.D. Zolotarenko, T.N. Veziroglu

Thermally Controlled Hydrogen Storage System Using Novel Carbon 97
Materials
L.L. Vasiliev, L.E. Kanonchik, V.A. Babenko

Composite Sorbents Based on Carbon Fibre “Busofit” for Hydrogen Storage and 111
Transportation
L.L. Vasiliev, L.E. Kanonchik, A.A. Antuh

Physical and Chemical Bases of Metal Hydrides’ Synthesis 123
U. Mirsaidov, A. Badalov, B.A. Gafurov

Composite Electrodes Based on Platinum Nanoparticles, Carbon Nanotubes, 127
and Nickel Micro-Wire Arrays Produced by Template Synthesis Technique
P. Ndungu, W. Davids, R. Fakir, M. Williams, G. Vaivars,
A. Nechaev, V. Linkov

v
vi CONTENTS
Synthesis of Carbonic-Nickel Nanostructures and Their Application for 137
Proton Pumps
V.A. Bortyshevskyy, D.S. Kamenskyh, V.A. Yevdokymenko,
R.V. Korzh, T.V. Tkachenko, S.L. Melnykova, V.G. Motorniy

The Role of Interface in the Mechanism of Hydrogen Absorption 151
by Metal-Polymer Composites
G. Carotenuto, R. Checchetto, N. Bazzanella, A. Miotello

Some Physical Aspects of bcc Hydrogen Storage Alloys 157
G. Mazzolai

Very Large C – Expectations and Reality 167
n
N. Koprinarov, M. Konstantinova

Energetics of Metal Hydrides Formation in Electrochemical Systems 175
A.V. Zvyagintseva, Y.N. Shalimov

Theory of Chemisorption of a Single Hydrogen Atom on Graphene 183
V.A. Margulis, E.E. Muryumin

Carbon-Carbon Composites – Carriers for Heterogeneous Catalysts for 195
Dehydrogenation of Hydrocarbons
M.N. Efimov, L.M. Zemtsov, G.P. Karpacheva, M.M. Ermilova,
N.V. Orekhova, E.L. Dzidziguri, E.N. Sidorova, O.N. Efimov

Structure and Physical Properties of Nanocarbon Containing Polymer Systems 201
J. Rashidov, U. Shoimov, J. Salomov, Sh. Tuichiev, S. Tabarov
B.M. Ginzbur, E. Osawa

Simulation of Hydrogen Polycondensation by Single-Walled Carbon 207
Nanotubes
S.A. Beznosyuk, O.A. Maslova, S.V. Vazhenin, M.S. Zhukovsky,
T.M. Zhukovsky

Transformation Evolution of Graphene and Nickel Nanoparticles 215
S.A. Beznosyuk, S.V. Vazhenin, O.A. Maslova, M.S. Zhukovsky,
T.M. Zhukovsky

Carbon Nanotubes from Graphenes in the Pores of Inorganic Membranes 225
A.P. Soldatov, O.P. Parenago

Effect of Pore Structure of Activated Carbon Fibers on Hydrogen 233
Adsorption
R.G. Ding, X.D. Yao, Z.H. Zhu, G.Q. Lu, Z.F. Yan

ESR Study of Hydrogen Sorption/Desorption Kinetics in Poly(Ortho- 241
Anisidine) and POA/SWNTs Composite Films
A.A. Konchits, S.P. Kolesnik, V.S. Yefanov, F.V. Motsnyi,
E. Tamburri, M.-L. Terranova

Production of Nickel-Carbon Fibres with the Increased Content of Highly 251
Dispersive Metal and Nanosized Structurally-Ordered Carbon
A.M. Safonova, O.V. Bezhok, L.E. Shpilevskaya
CONTENTS vii
Creation of New Composite Materials for Hydrogen Energy Purposes. 255
I. New Lines of Membrane Production Technology
O.K. Alexeeva, M.M. Chelyak, A.A. Kotenko, B.L. Shapir,
Yu.S. Nechaev

Structural Investigation of Carbonmetallic Nanocompositions on the Basis 263
of LaMnNi
E.A. Samedov

Modification of Ultrathin α-C:H Films by Short Voltage Pulses in STM 269
A.S. Baturin, A.A. Chouprik, E.P. Sheshin, V.D. Frolov,
E.V. Zavedeev

Influence of the Mechanical Activation on the Thermal Stability of the AlH 275
3
in Al-C-H System
R.V. Lukashev, S.N. Klyamkin, B.M. Bulychev, B.P. Tarasov

Electrodes for Fuel Cells Based on Carbon Nanotubes and Catalysts 279
M.O. Danilov, G.Ya. Kolbasov, A.V. Melezhyk

The Problem of Carbon Nanotubes Using in Lithium-Ion Batteries 285
A.M. Skundin

Influence of Carbon Nanofibers on Cyclization and Carbonization Processes 291
of Polyacrylonitryle
G.N. Gubanova, T.E. Sukhanova, A.I. Grigoriev, Yu.N. Sazanov,
A.V. Novoselova, A.V. Gribanov, G.N. Fiodorova, A.A. Kutin

Growth Features of Carbon Nanostructures on Co Particles Deposited 297
on SiO and Al O
2 2 3
A.A. Volodin, P.V. Fursikov, Yu.A. Kasumov, B.P. Tarasov

Equipment and Technology of Nanostructured Carbon Materials Production 301
A.G. Tkachev

On Possible Synthesis of Some Organic Microstructures in a Process 307
of Fullerene Fabrication by Means of an Argon Arc Discharge
V.I. Podgornyi, V.P. Kiselev, A.N. Yakovlev, B.Z. Belashev,
A.N. Ternovoi

Ferromagnetic Nanoparticles Produced by Arc-Discharge Evaporation 313
of Fe-Ni-Graphite Electrodes
V.E. Muradyan, Yu.M. Shulga, M. Leonowicz

Optimization of Synthesis Methods of Single-Walled Carbon Nanotubes 317
Using 3d Transition Metals
V.E. Muradyan, B.P. Tarasov, N.S. Kuyunko

Dependence of Electronic Structure Peculiarities of Carbon Nanotubes on 321
Diameter and Presence of Defects
Ya.V. Zaulychnyy, Yu.M. Solonin, E.V. Pryluckij, S.S. Zviezda

Biocompatibility of Multiwall CNT and Nanocomposites on the Base 327
of Polymers
Yu.I. Sementsov, N.A. Gavriluk, G.P. Prikhod’ko, T.A. Aleksyeyeva,
O.N. Lazarenko, V.V. Yanchenko
viii CONTENTS
Studies of Electrochemical Kinetics of Hydrogen Oxidation on the 335
Nanodispersed Diamond
G.P. Bogatyreva, M.A. Marinich, G.A. Bazaliy

Dielectric Properties of Epoxyamine Composites Modified by Carbon 343
Nanofibers in Microwave Range
V.E. Muradyan, E.A. Sokolov, S.D. Babenko, A.P. Moravsky

Electrolytic Ni-Based Composite Coatings Containing Molybdenum and Silicon 347
for Hydrogen Evolution Reaction
J. Kubisztal, J. Panek, A. Budniok

Formation of Carbon Nanostructures During IR-Pyrolysis of 357
Polyacrylonitrile in Presence of Fe and Co
L.M. Zemtsov, G.P. Karpacheva, K.A. Bagdasarova,
E.L. Dzidziguri, E.N. Sidorova

Influence of Impurities and Defects on Electronic Structure of Carbon 365
Nanotubes
A.P. Popov, I.V. Bazhin

About Quasi-Liquid Spontaneous Deformation in Iron-Hydrogen System 369
V.I. Shapovalov

Equilibrium Configuration and Electronic Structure of the C H Molecule 375
32 8
Isomers
A.P. Popov, I.V. Bazhin

Proton-Conducting Membranes Based on Copolymer Composites 379
G.F. Myachina, T.G. Ermakova, N.P. Kuznetsova, L.I. Volkova,
B.A. Trofimov, D.M. Mognonov

Selective Synthesis of Carbon Nanotubes by Methane Pyrolysis and 385
Preparation Pt/С Electrocatalysts on Their Basis
E.V. Gerasimova, A.A. Volodin, B.P. Tarasov

Pt Nanoclusters on Carbon Nanomaterials as Hydrogenation Catalysts 389
S.D. Kushch, N.S. Kuyunko, B.P. Tarasov

Electrochemical Characterization of Ni-Mo and Ni-Mo + PE Coatings 395
Ni
as Materials for Hydrogen Evolution
J. Niedbała

Algorithms of Parameters Estimation of Hydrogen Permeability Model 403
Yu.V. Zaika, E.P. Bormatova

Magnetic Properties of Gd Fe BH Hydrides 415
2 14 x
R. Bezdushnyi, R. Damianova, S.A. Nikitin, E.A. Tereshina,
G.S. Burkhanov, I.S. Tereshina, O.D. Chistyakov

Thermodynamics of Thermolysis of Alkali Metals Boronhydrides 423
S.Yu. Zaginaichenko, D.V. Schur, T.A. Trifonova, Z.A. Matysina
CONTENTS ix
Interaction Peculiarities of Hydrogen and Ni-B Galvanic Alloys 437
A.V. Zvyagintseva

Mechanisms of Metal Hydrides Formation in the Presence of Boron 443
Compounds
A.V. Zvyagintseva, Y.N. Shalimov

Some Aspects of Producing and Using Boron Compounds 449
S.A. Melnikov, A.P. Parshin, V.A. Popov, K.Yu. Zhizhin, V.M. Retivov,
N.T. Kuznetsov

Metallographic Investigations and Hydrogenation Peculiarities of the Alloy 457
Mg-La-Ni
P.V. Fursikov, D.N. Borisov, V.A. Yartys, B.P. Tarasov

Investigation of Hydrogen-Thermal Treatment Influence on the Properties of 461
Boron Nitride Based Materials
I.A. Morozov, R.A. Morozova, T.V. Dubovik, A.I. Itsenko, V.M. Panashenko,
A.A. Rogozinskaya, V.S. Tsyganenko, V.V. Lychko

Thermal Stability and H-Desorption Properties of Mg MnNi H Prepared 467
3 2 x
by Reactive Mechanical Alloying
of Powders Mg, Mn, Ni IN H -Atmosphere
2
V.D. Dobrovolsky, О.G. Еrshova, Yu.M. Solonin, R.V. Denys,
I.Yu. Zavaliy

Thermal Stability and Hydrogen Sorption Properties of the MgH Hydride 473
2
Derived by the Reactive Milling of the Mg + 10 wt% Ti Mixture
O.G. Ershova, V.D. Dobrovolsky, Yu.M. Solonin, O.Yu. Khyzhun

Effect of Ball Milling and Additions of Metal Hydrides and Amides on the 485
Thermal Stability of AlH
3
M.S. Dulya, B.M. Bulychev, B.P. Tarasov

Kinetics of the Orientational Long-Range Ordering of Interstitial Hydrogen 489
Atoms in Metals Having Hexagonal-Close Packed Structure
T.M. Radchenko, V.A. Tatarenko

Effect of Mn and Zr on Hydrogen Absorption in Mg-based Nanocomposites 497
X. Yao, Z.H. Zhu, G.Q. Lu, C.Z. Wu, P. Wang, H.M. Cheng

Levels of Ion-Implanted Deuterium Retention in Zr and in the Two-Layer 503
Zr-Pd System
I.M. Neklyudov, A.N. Morozov, V.I. Zhurba, V.М. Azhazha,
A.А. Andreev, E.V. Pyatenko, V.G. Kulish

Simulation of Phase Diagrams in LaNi −H (D ) System and Inversion of 509
5 2 2
Isotopic Effect
V.S. Marinin, Yu.F. Shmalko, K.R. Umerenkova

Features of Phase Transformations in FeCH System at Hydrogen High 517
Pressure
L.M. Poltoratsky
x CONTENTS
Electrochemical and Hydrogen Sorption Properties of AB –Type Alloys 523
5
Where A – La, Ce; B – Ni, Co, Mn, Fe, Cu, Cr, Al
T.A. Zotov, I.A. Romanov, S.V. Mitrokhin, V.N. Verbetsky, O.A. Petrii

Peculiarities of Hydrogen Interaction with Intermetallic Compounds AB 533
2
E.Yu. Anikina

Hydrogen Sorption Properties of Metal Hydride and Glass Phase 543
L. Grinberga, J. Kleperis

Formation of Linear Structures in Metal-Hydrogen Interstitial Alloys 549
N.Z. Namoradze, I.G. Ratishvili

Effect of Alloying Elements on the Formation of FeTiH : An Ab Initio 573
4
Study
F.G. Sen, A. Kinaci, M.K. Aydinol

“Hysteresis” in Interaction of Nanocrystalline Magnesium with Hydrogen 579
K.B. Gerasimov, I.G. Konstanchuck, S.A. Chizhik, J.-L. Bobet

Hydrogen Permeability of Metals at Presence of Internal Stresses 587
N.M. Vlasov, I.I. Fedik

Computer Models of Nanoparticles Inclusive of Hybrid Ones 595
G.S. Yurjev

Ab-Initio Investigation of Hydrogen Absorption by Magnesium 603
Nanoparticles
A.S. Fedorov, G.N. Churilov, A.A. Kuzubov, M.V. Serjantova

Effect of Pressure on Thermodynamic Properties of Light Element Hydrides 611
Yu.М.Goryachev, V.I. Dekhteruk, M.I. Siman, L.I. Fiyalka

Conductivity of Metallic Hydrogen Under High Pressure and Temperature 615
V.T. Shvets

Surface-Modified AB Alloys with Enhanced Hydrogen Absorption Kinetics 625
5
M. Williams, M. Lototsky, A. Nechaev, V. Linkov, V. Yartys, Q. Li

Deformation of Aluminium Membrane Induced by Hydrogen Transport 637
T.A. Ryumshyna, E. Lunarska, O. Chernyaeywa

Influence of Metal Substitute on Electrochemical and Sorption 645
Characteristics of LaNi Based Alloys
5
L.G. Shcherbakova, Yu.M. Solonin, Ye.N. Severyanina

Electronic Structure of the Face-Centred Cubic MoO Phase Obtained Due 651
1.9
to Reduction of Hydrogen Bronze H MoO
1.63 3
O.Yu. Khyzhun, V.L. Bekenev, Yu.M. Solonin

Interaction of Pseudo Alloys Mg–REM–Ni and Composites on Their Base 659
with Hydrogen
D.N. Borisov, P.V. Fursikov, B.P. Tarasov