Carbon Dioxide Utilization for Global Sustainability, Proceedings of 7the International Conference on Carbon Dioxide Utilization PDF
Preview Carbon Dioxide Utilization for Global Sustainability, Proceedings of 7the International Conference on Carbon Dioxide Utilization
iiix PREFACE The global environmental problems, especially the global warming caused by the accelerative accumulation of carbon dioxide in the atmosphere, are nowadays the most crucial for human beings as well as global sustainability. Due to this global environmental issue, the scientists and engineers, who had a strong interest and wished to contribute to solve the carbon dioxide problem from technological aspects, gathered and discussed the countermeasures in this conference. As a result of this effort, carbon dioxide utilization has been making a progress and distinct contributions in conducting the strategies for carbon dioxide mitigation and in finding the solution of these environmental problems by adoption of a variety of technologies. In this regard, since the first conference, held in 1991 at Nagoya, Japan, the ICCDU conferences have been held every two years (alternating between North America, Europe, and Asia) with the aim of coveting the latest developments in the field of carbon dioxide chemistry as it pertains to utilization. The 7th International Conference on Carbon Dioxide Utilization (7th ICCDU) was held successfully at the Hoam Convention Center in Seoul, Korea from October 21 to October ,61 2003. We would like to express sincere thank all the members of the Local Organizing Committee for their active supports for the conference, the several organizations for their financial support, and all the distinguished participants who have traveled to Korea from around the world. The attendance in this conference was very encouraging with respect to the futuristic perspective of the scientific field and the efforts for the development on carbon dioxide utilization. The 7th ICCDU Conference was organized by Korea Research Institute of Chemical Technology (KRICT) and Carbon Dioxide Reduction & Sequestration (CDRS) R&D Center in Korea. During the 4 day meeting of the 7th ICCDU, 5 plenary lectures, 41 keynote lectures, and 35 papers were presented orally in 4 sessions and 66 papers were presented as posters. Their topics of the 7th ICCDU covered the followings: 2OC separation and recovery including advanced 2OC separation system and - materials for 2OC separation 2OC as oxidant including dehydrogenation and oxidative conversions - heterogeneous catalysis of 2OC including catalytic 2OC conversions, plasma & - microwave application and 2OC rich syngas from biomass & fossil fuels - homogeneous catalysis of 2OC including chemicals from CO2, polymers using 20C and electro- and photocatalytic reduction of 20C biology and biochemistry of C02 utilization - vix studies in supercritical 2OC including spectroscopic techniques and reactions in - supercritical 2OC - utilization of 4HC/2OC hydrates This book was conceived as the proceedings of the 7th ICCDU, which reflect the most recent research results and stimulating scientific discussions with new challenges in advancing the development of carbon dioxide utilization. These topics are important in green chemistry and technology that are considered as essential fields for the global sustainability. The organizers wish to express sincere appreciation to attendees of the 7th ICCDU and the authors for submitting their manuscripts to the proceedings. We are grateful to the outstanding scientists who accepted our invitation to overview vital research areas in plenary lectures and the keynote lectures that introduce the important topics of each session covered by the conference. We are also grateful to Dr. Choong Seob Kim (President of KRICT), Dr. Sang Do Park (Director of CDRS), Prof. Yoichi Kaya (RITE/NEDO), Prof. Eunyoung Heo (Seoul National Univ.) for their generous financial and administrative support. We wish to thank Dr. Soo Min Oh (KRICT), Dr. Myoung-Jae Choi (KRICT), and Prof. Woonsup Shin (Sogang Univ.), who have spent so much time and efforts for the success of the 7th ICCDU conference. Furthermore, we wish to thank members of the Research Center for Nanocatalysis (RCNC), KRICT, especially Dr. Sung Hwa Jhung and Mr. Do-Young Hong, who very efficiently helped in the preparation of the proceedings. Finally we wish to acknowledge the help and support by co-operating organizations and sponsors from industries. Seoul, October 2003 Editors Sang-Eon Park Jong-San Chang Kyu-Wan Lee XV Chairman's Remark Thanks to the Contributors of 7 ht ICCDU, This proceedings contain papers presented and displayed as posters at the Seventh International Conference on Carbon Dioxide Utilization (ICCDU VII) held for four days during October 12--16, 2003 at Hoam Convention Center in Seoul, Korea. The ICCDU conferences are held every two years alternating continental. The First ICCDU was held in Nagoya, Japan in 1991, the second at Bari, Italy in 1993, the third at Oklahoma, USA in 1995, the fourth in Kyoto, Japan in 1997, the fifth at Karlsruhe, Germany in 1999, the sixth at Breckenridge, USA in 2001 and the Seventh in Seoul, Korea in 2003. The eighth will be held in Norway in 2005. This Conference was aimed to cover the latest developments in the field of carbon dioxide chemistry as it pertains to utilization in the world. In the 7 ht Conference included seven fields and 12 detail subjects and emphasized specially on the presentations of research results scale in pilot and demonstration operation and utilization of biomass and CO2/methane hydrates which are recently more interested as sustainable and renewable energy sources. This ICCDU VII, was organized jointly by Korea Research Institute of Chemical Technology (KRICT) and Carbon Dioxide Reduction & Sequestration R&D Center (CDRS). The conference was financially supported by the Ministry of Science and Technology of Korea, Korea Research Institute of Chemical Technology, Carbon Dioxide Reduction & Sequestration R&D Center and Research Institute of Innovative Technology for the Earth (RITE)/New Energy and Industrial Technology Development Organization (NEDO) in Japan. I would like express my sincere thank to the all attendees and organizations for their contribution to and cooperation in the 7 ht ICCDU. Greetings from Yanji, Jilin, China Chairman of ICCDU VII Prof. .rD Ing. Kyu-Wan Lee Yanbian University of Science & Technology (YUST), Yanji, Jilin, China 133000 xvii noitazinagrO Organizing Committee Chairman Kyu-Wan Lee KRICT, Korea yraterceS Sang-Eon Park Inha Univ., Korea International Advisory Board Michele Aresta Campus ,.vinU Italy David Beecy Department of Energy, ASU Son-Ki Ihm KAIST, Korea Donald Darensbourg saxaT A &M Univ., ASU Tomoyki Inui Kyoto Univ., Japan Eckhard Dinjus Karlsruhe Research Centre, Germany Yoichi Kaya Research Institute of Innovative Technology for eht Earth, Japan Baldur Eliasson ABB Switzerland Ltd., Switzerland Kenneth Nicholas Univ.of Oklahoma, ASU International Scientific Committee Alfons Baiker Swiss Federal Institue of ,ygolonhceT Switzerland Philip Jessop Queen's Univ., Canada Danielle Ballivet Universit~ de Bourgogne, France Klaus .S Lackner Los Alamos National Laboratory, ASU Dan DuBois .vinU of North Carolina, ASU Jae-Sung Lee POSTECH, Korea David Dyrssen Chalmers .vinU of Technology and Gothenburg Univ., Sweden Kyu-Wan Lee KRICT, Korea Giuseppe Filardo .vinU of Palermo, Italy Chang-jun Liu Tianjin Univ., China Martin .M Halmann Weizmann Institute of Science, Israel nah-uY Sun Chinese Academic of Sciences, China xvii noitazinagrO Organizing Committee Chairman Kyu-Wan Lee KRICT, Korea yraterceS Sang-Eon Park Inha Univ., Korea International Advisory Board Michele Aresta Campus ,.vinU Italy David Beecy Department of Energy, ASU Son-Ki Ihm KAIST, Korea Donald Darensbourg saxaT A &M Univ., ASU Tomoyki Inui Kyoto Univ., Japan Eckhard Dinjus Karlsruhe Research Centre, Germany Yoichi Kaya Research Institute of Innovative Technology for eht Earth, Japan Baldur Eliasson ABB Switzerland Ltd., Switzerland Kenneth Nicholas Univ.of Oklahoma, ASU International Scientific Committee Alfons Baiker Swiss Federal Institue of ,ygolonhceT Switzerland Philip Jessop Queen's Univ., Canada Danielle Ballivet Universit~ de Bourgogne, France Klaus .S Lackner Los Alamos National Laboratory, ASU Dan DuBois .vinU of North Carolina, ASU Jae-Sung Lee POSTECH, Korea David Dyrssen Chalmers .vinU of Technology and Gothenburg Univ., Sweden Kyu-Wan Lee KRICT, Korea Giuseppe Filardo .vinU of Palermo, Italy Chang-jun Liu Tianjin Univ., China Martin .M Halmann Weizmann Institute of Science, Israel nah-uY Sun Chinese Academic of Sciences, China xvii noitazinagrO Organizing Committee Chairman Kyu-Wan Lee KRICT, Korea yraterceS Sang-Eon Park Inha Univ., Korea International Advisory Board Michele Aresta Campus ,.vinU Italy David Beecy Department of Energy, ASU Son-Ki Ihm KAIST, Korea Donald Darensbourg saxaT A &M Univ., ASU Tomoyki Inui Kyoto Univ., Japan Eckhard Dinjus Karlsruhe Research Centre, Germany Yoichi Kaya Research Institute of Innovative Technology for eht Earth, Japan Baldur Eliasson ABB Switzerland Ltd., Switzerland Kenneth Nicholas Univ.of Oklahoma, ASU International Scientific Committee Alfons Baiker Swiss Federal Institue of ,ygolonhceT Switzerland Philip Jessop Queen's Univ., Canada Danielle Ballivet Universit~ de Bourgogne, France Klaus .S Lackner Los Alamos National Laboratory, ASU Dan DuBois .vinU of North Carolina, ASU Jae-Sung Lee POSTECH, Korea David Dyrssen Chalmers .vinU of Technology and Gothenburg Univ., Sweden Kyu-Wan Lee KRICT, Korea Giuseppe Filardo .vinU of Palermo, Italy Chang-jun Liu Tianjin Univ., China Martin .M Halmann Weizmann Institute of Science, Israel nah-uY Sun Chinese Academic of Sciences, China xviii Allan .A Johansson The Technical Research Centre of Pinland (VTT), Finland Tatsuaki amihsaY Research Institute of lnnovative Technology for the Earth, Japan Shohei Inoue Tokyo Univ. of Science, Japan Shin-ya Yokoyama AIST Chugoku National Institute of Advanced Industrial Science and Technology, Japan Local Advisory Board Yong-Bok Chae Seoul National Univ., Korea Hyun-Ku Rhee Seoul National Univ., Korea Ho-In Lee Seoul National Univ., Korea Sang-Chul Shim Kyungpook National Univ., Korea Local Organizing Committee Kyu-Wan Lee (Chairman) KRICT, Korea Sang-Eon Park (Secretary) Inha Univ., Korea Jong-San Chang KRICT, Korea Jin-Suck Lee KIER, Korea Soon-Haeng Cho KIER, Korea Kew-Ho Lee KRICT, Korea Jae-Ou Choi Pohang Institute of Industrial Science and Technology, Korea Dae-Won Park Pusan National Univ., Korea Sung Hwa Jhung KRICT, Korea Myoung-Jae Choi KRICT, Korea Sang-Do Park KIER, Korea Hee-Moon muE KEPRI, Korea Woonsup Shin Sogang Univ., Korea Sung-Hwan naH Hanyang Univ., Korea Supporting Organizations The Organizing Committee gratefully acknowledges the receipt of financial support from Korea Research Institute of Chemical Technology (KRICT) Ministry of Science dna Technology (MOST) Korea Science dna Engineering Foundation (KOSEF) xviii Allan .A Johansson The Technical Research Centre of Pinland (VTT), Finland Tatsuaki amihsaY Research Institute of lnnovative Technology for the Earth, Japan Shohei Inoue Tokyo Univ. of Science, Japan Shin-ya Yokoyama AIST Chugoku National Institute of Advanced Industrial Science and Technology, Japan Local Advisory Board Yong-Bok Chae Seoul National Univ., Korea Hyun-Ku Rhee Seoul National Univ., Korea Ho-In Lee Seoul National Univ., Korea Sang-Chul Shim Kyungpook National Univ., Korea Local Organizing Committee Kyu-Wan Lee (Chairman) KRICT, Korea Sang-Eon Park (Secretary) Inha Univ., Korea Jong-San Chang KRICT, Korea Jin-Suck Lee KIER, Korea Soon-Haeng Cho KIER, Korea Kew-Ho Lee KRICT, Korea Jae-Ou Choi Pohang Institute of Industrial Science and Technology, Korea Dae-Won Park Pusan National Univ., Korea Sung Hwa Jhung KRICT, Korea Myoung-Jae Choi KRICT, Korea Sang-Do Park KIER, Korea Hee-Moon muE KEPRI, Korea Woonsup Shin Sogang Univ., Korea Sung-Hwan naH Hanyang Univ., Korea Supporting Organizations The Organizing Committee gratefully acknowledges the receipt of financial support from Korea Research Institute of Chemical Technology (KRICT) Ministry of Science dna Technology (MOST) Korea Science dna Engineering Foundation (KOSEF) xviii Allan .A Johansson The Technical Research Centre of Pinland (VTT), Finland Tatsuaki amihsaY Research Institute of lnnovative Technology for the Earth, Japan Shohei Inoue Tokyo Univ. of Science, Japan Shin-ya Yokoyama AIST Chugoku National Institute of Advanced Industrial Science and Technology, Japan Local Advisory Board Yong-Bok Chae Seoul National Univ., Korea Hyun-Ku Rhee Seoul National Univ., Korea Ho-In Lee Seoul National Univ., Korea Sang-Chul Shim Kyungpook National Univ., Korea Local Organizing Committee Kyu-Wan Lee (Chairman) KRICT, Korea Sang-Eon Park (Secretary) Inha Univ., Korea Jong-San Chang KRICT, Korea Jin-Suck Lee KIER, Korea Soon-Haeng Cho KIER, Korea Kew-Ho Lee KRICT, Korea Jae-Ou Choi Pohang Institute of Industrial Science and Technology, Korea Dae-Won Park Pusan National Univ., Korea Sung Hwa Jhung KRICT, Korea Myoung-Jae Choi KRICT, Korea Sang-Do Park KIER, Korea Hee-Moon muE KEPRI, Korea Woonsup Shin Sogang Univ., Korea Sung-Hwan naH Hanyang Univ., Korea Supporting Organizations The Organizing Committee gratefully acknowledges the receipt of financial support from Korea Research Institute of Chemical Technology (KRICT) Ministry of Science dna Technology (MOST) Korea Science dna Engineering Foundation (KOSEF) xviii Allan .A Johansson The Technical Research Centre of Pinland (VTT), Finland Tatsuaki amihsaY Research Institute of lnnovative Technology for the Earth, Japan Shohei Inoue Tokyo Univ. of Science, Japan Shin-ya Yokoyama AIST Chugoku National Institute of Advanced Industrial Science and Technology, Japan Local Advisory Board Yong-Bok Chae Seoul National Univ., Korea Hyun-Ku Rhee Seoul National Univ., Korea Ho-In Lee Seoul National Univ., Korea Sang-Chul Shim Kyungpook National Univ., Korea Local Organizing Committee Kyu-Wan Lee (Chairman) KRICT, Korea Sang-Eon Park (Secretary) Inha Univ., Korea Jong-San Chang KRICT, Korea Jin-Suck Lee KIER, Korea Soon-Haeng Cho KIER, Korea Kew-Ho Lee KRICT, Korea Jae-Ou Choi Pohang Institute of Industrial Science and Technology, Korea Dae-Won Park Pusan National Univ., Korea Sung Hwa Jhung KRICT, Korea Myoung-Jae Choi KRICT, Korea Sang-Do Park KIER, Korea Hee-Moon muE KEPRI, Korea Woonsup Shin Sogang Univ., Korea Sung-Hwan naH Hanyang Univ., Korea Supporting Organizations The Organizing Committee gratefully acknowledges the receipt of financial support from Korea Research Institute of Chemical Technology (KRICT) Ministry of Science dna Technology (MOST) Korea Science dna Engineering Foundation (KOSEF)
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