biomaterials > e-book Biopolymers in Packaging Applications This report aims to illustrate the drivers, rationale, technologies, actualities and outlook factors shaping the development, integration and penetration of biopolymers in the packaging market. WWW.INTERTECHPIRA.COM Biopolymers in Packaging Applications IntertechPira Business Intelligence Ashley Gange Providing knowledge for niche, emerging and high-growth industries Published by About viewing this ebook Services IntertechPira This document will attempt to open in IntertechPira provides events, market research, publications, strategic and technical consulting to 19 Northbrook Dr full page viewing mode by default for niche, emerging and high-growth industries. Market coverage includes lighting and displays, clean Portland, Maine 04105 a more immersive reading experience energy, home and personal care, industrial biotechnology, performance materials and chemicals. USA and to maximize screen space. 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Spear, Jr. [email protected] Find out more www.intertechpira.com Assistant editor Contact: Pira International Sales Mina Odavic Bill Allen [email protected] +44 (0)1372 802086 [email protected] Customer services manager Denise Davidson [email protected] T +44 (0)1372 802080 WWW.INTERTECHPIRA.COM table of contents 3 4 Executive Summary 1 Processing Biopolymers Biopolymers in Packaging Overview Packaging Types Introduction and Objective Renewable and Non-Renewable Biodegradable 4Rigid Packaging Objective and Scope Composites 4Flexible and Films Packaging Abbreviations and Definitions Renewable Biodegradable Biopolymers End Use Sectors Non-Renewable, Biodegradable Biopolymers 4Food Packaging 2 Renewable, Non-Biodegradable Biopolymers 4Beverage Packaging Biopolymer Material Profiles 4Non-food Packaging 4AgroResin 4Food Service Packaging 4Biomax Biopolymers: State of the Industry 4Bionolle 5 Eco-Concern 4BIOPar Consumer Demand 4Biocycle Political and Regulatory Environment 4Cereplast Composting Infrastructure 4Ecovio Biopolymer Packaging on the Horizon Retailer Initiatives and Private Label 4Enpol Market Outlook Certification and Logos 4Ingeo 4Market Size Costs and Commodity Prices 4Mater-Bi 4Packaging Type Trends Market Supply and Demand 4Mirel 4Material Type Trends 4NatureFlex Emerging Sources of Biopolymers: Algae 4Plantic Emerging Technology: Nanotechnology List of Tables and Figures WWW.INTERTECHPIRA.COM biomaterials > e-book > biopolymers in packaging applications Executive Summary • Eco-concern played a key role in encouraging the development to the addition of added value and differentiative characteristics of biopolymers in packaging applications over the review period. to price competitiveness. The higher cost of This occurred directly via consumer demand for eco-friendly raw materials used products as well as indirectly via the political and ensuing • Product standard certification and logos became increasingly in the manufacture regulatory environment. supported by manufacturers and retailers as a tool to of biopolymers communicate benefits to customers as the review period was a major factor • From the consumer demand perspective, preferences developed progressed. Commonly used standards included ASTM D6400 in in some markets and sectors to the point that product eco- the US and EN13432 in the EU, while logos used included those hindering the friendliness was considered to be a brand expectation rather promoted by the Biodegradable Products Institute in the US and market penetration than a point of differentiation. There were, however, signs in European Bioplastics in Europe. of biopolymer other markets that a degree of eco-fatigue had settled in due to packaging. overuse or misuse of the eco-friendly concept. • The higher cost of raw materials used in the manufacture of biopolymers was a major factor hindering the market penetration • In terms of the political and regulatory environment, of biopolymer packaging. However, the price advantage of governments in a number of regions encouraged a reduction in conventional polymers was eroded over the review period due waste going to landfill and sought to foster conditions to aid to commodity price fluctuations, which in combination with the the development and implementation of solutions such as those growing scale of biopolymer production enabled biopolymer based on biopolymers. In Sweden, Germany and the Netherlands packaging to become more price competitive. for example, such conditions have created significant composting infrastructure and separate collections of waste which enable the • A wide and expanding range of biopolymer based materials for marketing benefits of biopolymer packaging compostability to be packaging applications is being marketed by a growing number achieved. of suppliers. The characteristics of various biopolymers vary in terms of sustainability, packaging application performance • On the high-street, leading grocery chains reacted to rising and price/cost, leading to the processing and marketing of consumer eco-concern by supporting the use of sustainable composites for specific functionality and to cut cost. and/or biodegradable biopolymer packaging in place of that based on conventional plastics. This was particularly the case in • Umbrella brand ranges also encompass a wide range of private label product ranges under their control, which generally products marketed with various degrees of sustainability and gained share of sales by brand over the review period, partly due biodegradability. Demand factors that typically determine the 4 CHAPTER ES 1 2 3 4 5 TOC WWW.INTERTECHPIRA.COM biomaterials > e-book > biopolymers in packaging applications Executive Summary choice of blend and its composition include market positioning, is forecast to grow in volume terms at a CAGR of 24.9% price positioning, end application requirements, material from 125,295 tonnes in 2010 to 1,305,810 tonnes in 2015. performance and regulatory requirements. Comparable growth in constant value terms is projected to be recorded at 23.5% to reach a global market value of US$1.3 • One of the most significant recent occurrences with regard to billion in 2015. biopolymer processing and potential market penetration was the development by Brazilian petrochemical company Braskem, in • Bio-PE is expected to record greatest actual growth in sales 2010, of a 200 thousand tonne per year production capacity of volume by biopolymer packaging material type during this time. relatively price competitive renewable bio-PE derived from sugar This will be driven by factors shaping demand for biopolymers cane. This is expected to be accompanied by a further bio-PE overall as well as the marketing activities of Braskem and Dow production capacity of 350 thousand tonnes per year to be Chemicals who are forecast to have a combined supply capacity established by Dow Chemical in Brazil in 2011. of bio-PE of over half a million tonnes per year by 2012. • The global market for biopolymers in packaging applications was • Sources of biopolymers that are expected to become increasingly valued at US$455 million and 125 thousand tonnes in 2010. significant over the outlook period include those that do not It grew at CAGR’s in volume and current value terms by 22.9% compete with food production for resources, such as Algae, and and 21.7% respectively over the 2005 to 2010 review period, materials suitable for packaging applications based on Algae illustrating rapid growth in demand and a decline in average are projected for launch in 2011. Furthermore, technological prices. advances, such as those based on nanotechnology, are forecast to continue improving biopolymer properties and increasing the • Although market shares by biopolymer type differ significantly number of potential applications for such materials in packaging. by region, PLA leads in global terms with a value share of 29.3% in 2010 followed by starch and cellulose with 17.1% and 16.4% value shares respectively. Europe is the largest regional market for biopolymer packaging, accounting for 53.7% of global demand by volume in 2010, followed by North America and Asia with 25.4% and 16.4% volume shares respectively. • The global market for biopolymers in packaging applications 5 CHAPTER ES 1 2 3 4 5 TOC WWW.INTERTECHPIRA.COM biomaterials > e-book > biopolymers in packaging applications 1 Introduction and Objective Objective and Scope applications for biopolymer based materials by end use, while the This report aims to illustrate the drivers, rationale, technologies, Biopolymers Packaging on the Horizon section outlines how the This report aims actualities and outlook factors shaping the development, biopolymer based packaging market may be expected to evolve to illustrate the integration and penetration of biopolymer based concepts in the over the next five to ten years. drivers, rationale, packaging market. For the purposes of this report, biopolymers technologies, are defined as those that are biodegradable and/or derived from Abbreviations and Definitions actualities and renewable resources. Packaging and materials that incorporate oxodegradable additives in their composition are excluded from the Aliphatic polyesters Aliphatic polyesters include materials outlook factors scope of this report. such as polycaprolactone, polylactic acid, polyhydroxy butyrate shaping the and polybutylene succinate. They are biodegradable and may development, Biopolymers in Packaging Applications is primarily aimed at the be processed on conventional equipment into foams, blown and integration and packaging industry although it may also be of interest at other extruded films, and injection moulded products. However, they lack penetration of levels including: commercial i.e. manufacturers of consumer many of the mechanical properties common to aromatic polyesters. biopolymer based products and purchasers of packaging; and retailing i.e. buyers, Aliphatic-aromatic copolyesters (AAC) With relatively high sellers and distributors of consumer products. melting points for degradable plastics (around 200°C), these concepts in the copolyesters combine the mechanical advantages of aromatic packaging market. The State of the Industry section analyses the factors driving the polyesters, such as PET, with the common biodegradability of development and marketing of biopolymer packaging concepts. aliphatic polyesters. It focuses on industry drivers ranging from environmental, Biodegradable Of such a nature that it is capable of undergoing consumer, retailer, economic and regulatory perspectives, as well physical, chemical, thermal or biological decomposition such that as providing an overview of the state of the industry in terms of most of the finished compost ultimately decomposes into carbon market size and supply. dioxide, biomass and water. BMW Biodegradable municipal waste The Biopolymers Processing section identifies the feedstocks and BOPLA Biaxially oriented poly lactic acid processes used to manufacture biopolymer based materials. It BOPP Biaxially oriented polypropylene includes profiles of a selection of biopolymer based materials, CA Cellulose acetate detailing their properties, characteristics and packaging applications. CDA Cellulose diacetate Compostable Compostable is defined as capable of undergoing The Biopolymers in Packaging section addresses packaging biological decomposition in a compost site as part of an available 6 CHAPTER ES 1 2 3 4 5 TOC WWW.INTERTECHPIRA.COM biomaterials > e-book > biopolymers in packaging applications Introduction and Objective program, such that the plastic is not visually distinguishable and Machinability Machinability, also known as machine breaks down to carbon dioxide, water, inorganic compounds, and performance, is the ability of a film to travel and track well through biomass, at a rate consistent with known compostable materials. a packaging machine. Different machines favour different film Compostable polymer A polymer which is biodegradable under properties. Therefore, a film may demonstrate good machinability composting conditions. The polymer must break down under on one piece of equipment and not on another. the action of micro-organisms, total conversion into CO2, H2O, MM(S) Millimetre(s) inorganic compounds and biomass under aerobic conditions MPET Modified polyethylene tetraphalate. PET that has been must be obtained and the mineralisation rate must be high and modified by the incorporation of monomers to create weak links compatible with the composting process in the polymeric chain that may enable degradation. Includes Copolyesters Combinations of aromatic esters with aliphatic materials such as PBAT and PAT. esters or other polymer units such as ethers and amides. Frequently Monomer The smallest repeating unit in a polymer chain, a used to produce materials with adjustable degradation rates. monomer may join with other molecules to form a polymer. Degradability Defined as the ability of materials to break down OP Oriented polyester Ecotoxicity The toxicity of residues, volatile gases or leachate to Opacity Opacity is a common measurement that describes a the environment during biodegradation. substrate’s light-blocking ability. A perfectly opaque substrate has EPS Expanded polystyrene an opacity value of 100%. EVOH Ethylene vinyl alcohol OPET Oriented polyester Foamed starch Produced in a blow process using water steam, OPP Oriented polypropylene foamed starch may be used as a substitute for polystyrene foam. It Organic recycling Aerobic or anaerobic treatment of materials is insulating, shock absorbing and antistatic. under controlled conditions using micro-organisms to produce GR(S) Gramme(s) methane, carbon dioxide and organic residues. GSM Grammes per square metre OTC Over-the-counter HDPE High density polyethylene OTR Oxygen transmission rate KG(S) Kilogramme(s) PC Polycarbonate L Litre PAT Polytetramethylene adipate/terephthalate LCA Life cycle analysis PBAT Polybutylene adipate/terephthalate LDPE Low density polyethylene PE Polyethylene LLCA Limited life cycle analysis PEN Polyethylene naphthalate LLDPE Linear low density polyethylene PET Polyethylene terephthalate 7 CHAPTER ES 1 2 3 4 5 TOC WWW.INTERTECHPIRA.COM