Bioinorganic Chemistry

219 Pages·2014·40.13 MB·English

Concepts and Applied Principles of
Bioinorganic Chemistry
Volume II
Warren Gibbs
Concepts and Applied Principles of Bioinorganic Chemistry
Volume II
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Concepts and Applied Principles
of Bioinorganic Chemistry
Volume II
Edited by Warren Gibbs
Published by Academic Pages,
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Concepts and Applied Principles of Bioinorganic Chemistry: Volume II
Edited by Warren Gibbs
© 2017 Academic Pages
International Standard Book Number: 978-1-9789-2205-1
This book contains information obtained from authentic and highly regarded sources. Copyright for all individual chapters
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Contents
Preface IX
Chapter 1 Sensitive Marker of the Cisplatin-DNA Interaction: X-Ray
Photoelectron Spectroscopy of CL 1
Fangxing Xiao, Xiaobin Yao, Qianhong Bao, Danzhen Li and Yi Zheng
Chapter 2 Computational Study of the Structure of a Sepiolite/Thioindigo
Mayan Pigment 11
Manuel Alvarado Jr., Russell C. Chianelli and Roy M. Arrowood
Chapter 3 A Comparison of Epithelial Cells, Fibroblasts, and Osteoblasts
in Dental Implant Titanium Topographies 17
Fu-Yuan Teng, Chia-Ling Ko, Hsien-Nan Kuo, Jin-Jia Hu,
Jia-Horng Lin, Ching-Wen Lou, Chun-Cheng Hung,
Yin-Lai Wang, Cheng-Yi Cheng and Wen-Cheng Chen
Chapter 4 Synthesis, Characterization and In Vitro Antibacterial Studies of
Organotin(IV) Complexes with 2-Hydroxyacetophenone-2-
methylphenylthiosemicarbazone (Hdampt) 26
2
M. A. Salam, M. A. Affan, Ramkrishna Saha, Fasihuddin B. Ahmad
and Norrihan Sam
Chapter 5 SOD-Mimic Cu(II) Dimeric Complexes Involving Kinetin and Its
Derivative: Preparation and Characterization 35
Radka Novotná, Zdeněk Trávníček and Radovan Herchel
Chapter 6 Studies on Synthetic and Natural Melanin and Its Affinity for
Fe(III) Ion 43
T. G. Costa, R. Younger, C. Poe, P. J. Farmer and B. Szpoganicz
Chapter 7 Spectroscopic, Thermal, and Antimicrobial Studies of Co(II), Ni(II),
Cu(II), and Zn(II) Complexes Derived from Bidentate Ligands
Containing N and S Donor Atoms 52
Kiran Singh, Yogender Kumar, Parvesh Puri and Gulab Singh
Chapter 8 Hydroxyapatite Coating of Titanium Implants Using
Hydroprocessing and Evaluation of Their Osteoconductivity 61
Kensuke Kuroda and Masazumi Okido
Chapter 9 DNA-Binding and Topoisomerase-I-Suppressing Activities of Novel
Vanadium Compound Van-7 68
Xiao-mei Mo, Zhan-fang Chen, Xin Qi, Yan-tuan Li and Jing Li
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VI Contents
Chapter 10 Antifungal and Antioxidant Activities of Pyrrolidone
Thiosemicarbazone Complexes 77
Ahmed A. Al-Amiery, Abdul Amir H. Kadhum
and Abu Bakar Mohamad
Chapter 11 Immobilization of Laccase in Alginate-Gelatin Mixed Gel and
Decolorization of Synthetic Dyes 83
Mehdi Mogharabi, Nasser Nassiri-Koopaei,
Maryam Bozorgi-Koushalshahi, Nastaran Nafissi-Varcheh,
Ghodsieh Bagherzadeh and Mohammad Ali Faramarzi
Chapter 12 Analysis of the Release Characteristics of Cu-Treated Antimicrobial
Implant Surfaces Using Atomic Absorption Spectrometry 89
Carmen Zietz, Andreas Fritsche, Birgit Finke, Vitezslav Stranak,
Maximilian Haenle, Rainer Hippler, Wolfram Mittelmeier
and Rainer Bader
Chapter 13 Enhancement of Antibacterial Activity of Capped Silver
Nanoparticles in Combination with Antibiotics, on Model
Gram-Negative and Gram-Positive Bacteria 94
Aruna Jyothi Kora and Lori Rastogi
Chapter 14 DNA-Platinum Thin Films for Use in Chemoradiation
Therapy Studies 101
Mohammad Rezaee, Elahe Alizadeh, Darel Hunting and Léon Sanche
Chapter 15 Spectroscopic Characterization and Biological Activity of
Mixed Ligand Complexes of Ni(II) with 1,10-Phenanthroline
and Heterocyclic Schiff Bases 110
Y. Prashanthi, K. Kiranmai, Ira, Sathish kumar K,
Vijay kumar Chityala and Shivaraj
Chapter 16 Cytotoxicity and In Vitro Antileishmanial Activity of Antimony (V),
Bismuth (V), and Tin (IV) Complexes of Lapachol 118
Marcele Neves Rocha, Paula Monalisa Nogueira, Cynthia Demicheli,
Ludmila Gonçalvez de Oliveira, Meiriane Mariano da Silva,
Frédéric Frézard, Maria Norma Melo and Rodrigo Pedro Soares
Chapter 17 Physicochemical Properties and Cellular Responses of
Strontium-Doped Gypsum Biomaterials 125
Amir Pouria, Hadis Bandegani, Milad Pourbaghi-Masouleh,
Saeed Hesaraki and Masoud Alizadeh
Chapter 18 Synthesis, Characterization, Mössbauer Parameters, and Antitumor
Activity of Fe(III) Curcumin Complex 134
Mutasim Ibrahim Khalil, Aisha Mohamed Al-Zahem
and Maha Hamad Al-Qunaibit
Chapter 19 Thermodynamic Investigation and Mixed Ligand Complex Formation
of 1,4-Bis-(3-aminopropyl)-piperazine and Biorelevant Ligands 139
Ahmed A. El-Sherif, Mohamed R. Shehata, Mohamed M. Shoukry and
Mohammad H. Barakat
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Contents VII
Chapter 20 Temporal Changes in Concentrations of Some Trace Elements in
Muscle Tissue of Crayfish, Astacus leptodactylus (Eschscholtz, 1823),
from Keban Dam Lake 149
Onder Aksu, Ragip Adiguzel, Veysel Demir, Numan Yildirim, Durali
Danabas, Sebahat Seker, Safak Seyhaneyildiz Can and Mustafa Ates
Chapter 21 Synthesis, Spectral Characterization, and Antiproliferative Studies
of Mixed Ligand Titanium Complexes of Adamantylamine 153
Raj Kaushal, Nitesh Kumar, Ashun Chaudhary, Saroj Arora
and Pamita Awasthi
Chapter 22 Evaluation of DNA Binding, Cleavage, and Cytotoxic Activity of
Cu(II), Co(II), and Ni(II) Schiff Base Complexes of
1-Phenylindoline-2,3-dione with Isonicotinohydrazide 165
Ramadoss Gomathi, Andy Ramu and Athiappan Murugan
Chapter 23 Novel Zinc(II) Complexes of Heterocyclic Ligands as Antimicrobial
Agents: Synthesis, Characterisation, and Antimicrobial Studies 177
Ramesh S. Yamgar, Y. Nivid, Satish Nalawade, Mustapha Mandewale,
R. G. Atram and Sudhir S. Sawant
Chapter 24 Synthesis, Characterization, Antimicrobial, DNA Cleavage, and In
Vitro Cytotoxic Studies of Some Metal Complexes of Schiff Base
Ligand Derived from Thiazole and Quinoline Moiety 187
Nagesh Gunvanthrao Yernale and Mruthyunjayaswamy Bennikallu
Hire Mathada
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List of Contributors
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Preface
Bioinorganic chemistry is a field of science that focuses on the examination of the role of metals in biology.
This branch of chemistry is about the, function, mechanism and structure dynamics of any and all biologically
relevant metal complexes and metal-containing proteins. Bioinorganic chemistry describes the shared relationship
between the two sub-disciplines of biochemistry and inorganic chemistry, with emphasis on the function of
inorganic substances and chemicals in living systems, as well as processes including the speciation, transport and
mineralisation of inorganic materials, along with the use of inorganics in medicinal therapy and diagnosis. This
field of study also studies the arena of both natural phenomena such as the behaviour of metallo-proteins as well
as artificially introduced metals. These studies also include those that are non-essential metals and chemicals such
as in medicine and toxicology. Bioinorganic chemistry is important in elucidating the consequences of substrate
bindings and activation, electron-transfer proteins, atom and group transfer chemistry as well as metal properties in
biological chemistry. Chemists in this arena use contemporary synthetic methods, theoretical calculations, biological
manipulations and advanced characterization techniques that include ultrafast spectroscopy, single-molecule
spectroscopy along with synchrotron-based x-ray spectroscopy and diffraction. This is a highly specialized branch
of chemistry that requires skilled researchers and scientists to work on new developments and thus the need for
newer research is also rapidly increasing.
This book attempts to compile and collate the research and data available in the field of bioinorganic chemistry. I
am grateful to those who put in effort and hard work in this field. I am also thankful to those who supported me
in this endeavour. I also wish to thank my family for their endless support in my life at every step.
Editor
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